2431 results about "Polyester resin" patented technology

The invention discloses unsaturated polyester resin for imitation jade handicrafts and a preparation method thereof, and belongs to the technical field of polyester resin. Comprising the following components: diethylene glycol, methylpropanediol, propylene glycol, maleic anhydride, phthalic anhydride, an antioxidant, a polymerization inhibitor, paraffin, a stabilizer, an ultraviolet light absorber, a whitening agent and a diluent. The weight ratio of the propylene glycol to the methyl propylene glycol is (1.0-1.3): 1, and the methyl propylene glycol accounts for 20-22% of the total amount of the dihydric alcohol; the weight ratio of maleic anhydride to phthalic anhydride is (0.46-0.52): 1; the preparation method comprises 1) adding the raw materials and the antioxidant into a reactor, carrying out heating, carrying out heat preservation for 0.5-1.0 h and continuing heating, 2) carrying out a reaction for 2-3 h after heating, carrying out dehydration until an acid value is 20-25 mgKOH / g, and 3) carrying out cooling, adding the auxiliary agent and carrying out uniform mixing so that the unsaturated polyester resin is obtained.

The invention relates to the technical field of high polymer material preparation, and discloses a bamboo fiber graft modified full-biodegradable composite membrane material preparation process which comprises the following steps: firstly, performing hot mixing and cooling on dried bamboo fiber powder, anhydrous citric acid, choline chloride, activated zinc oxide and pentaerythritol to prepare a bamboo fiber modified premix; then mixing the biodegradable polyester resin with the premix; adding the mixture into an extruder, injecting epoxidized soybean oil into a barrel through a liquid metering device, and performing melt extrusion granulation under a vacuum exhaust condition; and finally carrying out blow molding to form the film. Through in-situ reaction extrusion of multi-component synergism, surface grafting of bamboo fibers, chain extension of a polyester matrix and interface chemical bonding of the bamboo fibers and the polyester matrix are achieved, interface compatibility is effectively improved, degradation of the material in the processing process is inhibited, and the mechanical property and thermal stability of the composite film material are remarkably improved; the process is efficient and environment-friendly, and the cost is controllable.

The invention relates to the field of quantum dot ink, and discloses diffusion plate printing quantum dot ink and a preparation method thereof.The diffusion plate printing quantum dot ink comprises acrylic resin, hyperbranched polyester resin, a quantum dot material, modified boron nitride, a reactive diluent, a photoinitiator, a wetting agent and a defoaming agent; the hyperbranched polyester resin is prepared by reacting hyperbranched polyester acrylate and a sulfydryl-terminated silicon-containing reaction monomer, wherein the hyperbranched polyester acrylate is prepared by reacting pentaerythritol with 2, 2-dimethylolpropionic acid and then carrying out esterification reaction with acrylic acid; the sulfydryl-terminated silicon-containing reaction monomer is prepared by reacting eugenol with 1, 1, 3, 3-tetramethyldisiloxane and then carrying out esterification reaction with 3-mercaptopropionic acid; the modified boron nitride is prepared by modifying a cationic polymer which is prepared by carrying out a Mannich reaction on triethylene tetramine, formaldehyde and acetone and then carrying out a condensation polymerization reaction with formaldehyde. After the ink prepared by the invention is cured, a coating film is high in hardness, adhesive force and heat conductivity coefficient, and good in flexibility, heat resistance and migration barrier property.

The invention discloses a high-strength low-density proppant as well as a preparation method and an in-situ generation method thereof. The proppant is prepared by compounding recycled glass fiber reinforced plastic powder or glass fiber powder with different meshes and recycled glass fiber reinforced plastic powder in different proportions and blending a styrene system / unsaturated polyester resin system in different proportions. The glass fiber reinforced plastic powder as the filler can improve the mechanical properties of the proppant, such as strength and toughness. The matrix is made of polystyrene or unsaturated polyester or other high polymer materials and is low in density. Therefore, the proppant has the characteristics of high strength and low density. The invention discloses a preparation method of a high-strength and low-density proppant, which can produce the high-strength and low-density proppant with uniform particle size distribution on a large scale by adopting a suspension polymerization method, and can efficiently recover a large amount of glass fiber reinforced plastic wastes. The suspension polymerization method is simple to operate, the produced proppant is high in roundness and sphericity, the mining cost of a coal-bed gas well can be reduced, and the yield of coal-bed gas can be increased.

The invention discloses unsaturated polyester resin for an unmanned aerial vehicle fuselage and a preparation method of the unsaturated polyester resin, and relates to the field of high polymer materials. When the unsaturated polyester resin for the unmanned aerial vehicle fuselage is prepared, a flame-retardant monomer reacts with 2-hydroxy-5-(hydroxymethyl) benzaldehyde to prepare a modified flame-retardant monomer; reacting cellulose with acrylic acid to obtain pre-modified cellulose; the pre-modified cellulose, 1-allyl-1, 1, 3, 3-tetramethyldisiloxane and chloroplatinic acid are subjected to a reaction, and modified cellulose is prepared; maleic anhydride, 5-(1H-imidazole-1-yl)-1, 3-phthalic acid, propylene glycol and the modified flame-retardant monomer are subjected to a reaction, and pre-polyester is prepared; and stirring the pre-polyester, zinc chloride, modified cellulose, benzophenone peroxide and styrene to obtain the anti-aging coating. The prepared unsaturated polyester resin for the unmanned aerial vehicle fuselage has good anti-aging, self-repairing, flame-retardant and self-cleaning performance.

The invention relates to the technical field of ink, and discloses a preparation method of bio-based degradable water-based ink, which comprises the following steps: carrying out esterification polymerization on vanillin-based spiro acetal diglycidyl ether and diacid to obtain bio-based polyester resin, mixing and dispersing the bio-based polyester resin, petroleum-based resin, pigment, auxiliary agent and the like to obtain the bio-based degradable water-based ink. The bio-based degradable water-based ink is prepared. The bio-based resin contains a plurality of hydrophilic hydroxyl groups, has good solubility and dispersibility in the water-based ink, and generates denser hydrogen bonds and other cross-linking effects with the acrylic resin, so that the hardness of the ink is improved. Meanwhile, the polar hydroxyl groups also greatly enhance the hydrogen bond bonding and anchoring effect between the paint film and the base material, so that the adhesive force is improved. In addition, easily-hydrolyzed spiral acetal bonds, polyester structural units and other degradable chemical bonds in molecular chains of the bio-based resin provide more attack sites for water and microorganisms, the degradation rate is increased, and the degradable function is achieved.

The invention relates to the technical field of fabrics, in particular to a moisture absorption and sweat releasing fabric and a preparation process thereof.The preparation process includes the following steps that raw materials including, by weight, 35-40 parts of modified polyester silk, 20-25 parts of functional yarn and 8-12 parts of polyester fiber are weighed; a preparation method of the modified polyester yarn comprises the following steps: melting, blending and extruding polyester resin and a modifier according to a weight ratio of 100: 5; weaving the modified polyester yarns, the functional yarns and the polyester fibers into a knitted fabric body by using a circular knitting machine; setting the knitted fabric body at a high temperature of 115 DEG C for 50 seconds, and obtaining the moisture-absorbing and sweat-releasing fabric after setting is finished. According to the moisture absorption and sweat releasing fabric, the modified polyester yarn, the functional yarn and the polyester fiber are woven into the knitted fabric through the circular knitting machine, the modified polyester yarn is improved and optimized by matching polyester resin with the modifier, and the moisture absorption and sweat releasing performance, the elasticity and the wear resistance of the polyester yarn are enhanced through mutual matching and mutual assistance of the raw materials.

The invention discloses a high-corrosion-resistance powder coating and a preparation method thereof, and belongs to the technical field of powder coatings. Through modification of the resin system, the ultraviolet absorbent modified epoxy resin and the weather-resistant polyester resin are compounded, so that the ultraviolet resistance and the weather resistance of the resin system are remarkably improved, and the corrosion resistance reduction caused by light aging is avoided; the flake graphene forms an excellent physical barrier to block corrosion medium permeation, then chemical passivation of zinc phosphate is combined to inhibit electrochemical corrosion, the synergistic effect is achieved, the corrosion resistance is synergistically enhanced from the physical and chemical angles, the path of the corrosion medium is further prolonged in combination with the laminated structure of the glass flakes, and the corrosion resistance is improved. And meanwhile, the filler A and the filler B can also play a role in enhancing the mechanical strength of the coating, so that the powder coating with high corrosion resistance can be obtained on the whole.

A toner comprises toner particles and an external additive adhering to surfaces of the toner particles, wherein the toner particle includes a crystalline polyester resin and a wax, the external additive includes organic / inorganic composite fine particles and an associated silica having two or more primary particles being associated with each other, and the toner has a softening point of 110° C. or lower.

An electrostatic charge image developing toner, an electrostatic charge image developer, a toner cartridge, a process cartridge, an image forming apparatus, and an image forming method, the electrostatic charge image developing toner having toner particles containing an amorphous polyester resin, a crystalline polyester resin, and cross-linked resin particles, the internal cross-linked resin particles are styrene-(meth) acrylic copolymer particles and have an average dispersion diameter of 100 nm or more and 300 nm or less, and when a 3 [mu] m * 3 [mu] m square region of 600 [pix] 600 [pix] is divided into n * n in a cross-sectional view of the toner particles, the average dispersion diameter of the internal cross-linked resin particles is 1 [mu] m or less, and the average dispersion diameter of the internal cross-linked resin particles is 1 [mu] m or less. When DAR (n) is the coefficient of variation of the area ratio of the added cross-linked resin particles with respect to the area of the divided regions in the n * n divided regions, and slopeF (16) is the slope of an approximate straight line in a dispersion plot plotted by changing n to 3, 4, 6, 8, 12, and 16 with log [1 / n] as the X axis and log [DAR (n)] as the Y axis, formula (1) is satisfied: 0.6 < = slopeF (16).

The recycled bis(4-hydroxybutyl) terephthalate according to one embodiment has a low amount of residual ethylene glycol derivatives and can therefore be used as a polymerization raw material for high crystallinity engineering polyester products or biodegradable polyesters, offering superior qualities, for example, color.

The invention discloses unsaturated polyester resin for an optical cable reinforcing core and a preparation method thereof, and belongs to the technical field of unsaturated polyester resin. The composition is composed of the following components: PG, IPA, a catalyst, maleic anhydride, AA, styrene, an antioxidant, a first polymerization inhibitor, a second polymerization inhibitor and a third polymerization inhibitor. The ratio of alcohol to acid is (1.08-1.12): 1; the activity is (3.4-3.8): 1; the molar ratio of AA to IPA is 1: (12-16); the preparation method comprises the following steps: 1) uniformly mixing propylene glycol, a catalyst and isophthalic acid; 2) raising the temperature, preserving the heat and raising the temperature again; cooling, sequentially adding a first polymerization inhibitor, maleic anhydride and adipic acid, heating, keeping the temperature, and heating again; 3) cooling and adding a second polymerization inhibitor, and 4) cooling and adding styrene, a third polymerization inhibitor and an antioxidant, uniformly mixing, and cooling to less than or equal to 60 DEG C to obtain the unsaturated polyester resin for the optical cable reinforcing core. The unsaturated polyester resin for the optical cable reinforcing core has the characteristics of high bending strength and high temperature resistance.

The invention provides a polyester composition and application thereof. The polyester composition comprises the following components in parts by mass: 40-99.5 parts of polyester resin and 5-35 parts of a flame retardant, the flame retardant is prepared from the following components in parts by mass: 30 to 90 parts of diethyl phosphinate, 0.01 to 3 parts of ethyl phosphonate, 5 to 67 parts of dialkyl phosphinate and 0.01 to 5.5 parts of alkyl phosphinate. According to the flame-retardant polyester composition, the specific flame retardant is introduced, so that the flame-retardant polyester composition plays an excellent and efficient flame-retardant effect, and the polyester composition has excellent flame-retardant property, high deflection, good toughness and bending property and excellent performance in the aspect of mechanical properties.

The invention discloses a degradable resin material, an optical property regulator, an optically-adjustable environment-friendly mulching film and a processing method of the optically-adjustable environment-friendly mulching film, and belongs to the field of degradable environment-friendly materials. The invention provides a degradable polyester resin material with a novel structure, namely polycaprolactone-co-lactide. The degradable polyester resin material is formed by performing ring-opening copolymerization on epsilon-caprolactone and lactide under the catalytic action of a symmetric binuclear Schiff base complex; the ratio of the average chain segment length of caprolactone to the average chain segment length of lactide in the resin material is (2-2.2): (2-2.2), which is close to that of an alternating copolymer. The compound can be used as an optical property regulator, and preparation of an environment-friendly mulching film with adjustable optical properties such as ultraviolet light absorbance, infrared light transmittance and haze can be realized under the condition that no dye or other coloring additives are used.

The present invention relates to the technical field of tackified adhesive films and specifically to a tackified adhesive film. The tackified adhesive film comprises a substrate layer and a UV-tackified adhesive layer applied onto the substrate layer. The UV-tackified adhesive layer is prepared by using a modified polyester resin, which is obtained by the graft polymerization of a hydroxyl-terminated polyester resin, butyl methacrylate, and isocyanatoethyl methacrylate, as a main resin and mixing the main resin with a tackifying resin, a photo-curing agent and the like. The UV-tackified adhesive layer has relatively high cohesive strength and relatively good adhesion to a PET substrate. Before a UV-induced tackification reaction, an initial peel force is not significantly increased with the extension of standing time, so that an adhesive tape can be easily removed without causing damage and contamination such as residual adhesive to an adherend . After the UV-induced tackification reaction, the modified polyester resin can improve the bonding strength between the adhesive tape and the adherend.

The invention discloses a post-curing acid and alkali resistant sealing frame and a preparation method thereof, and relates to the technical field of fuel cell sealing frames, the post-curing acid and alkali resistant sealing frame comprises a release layer, a post-curing hot melt adhesive layer and a base material layer which are arranged in sequence; the post-curing hot melt adhesive layer is composed of acid modified polyolefin resin, sulfur-containing epoxy resin, polyester resin, silane modified polyolefin resin, a curing agent and an organic solvent according to the weight ratio of 100: (1-5): (5-10): (10-20): (0.5-5): (40-200). The temperature resistance and hydrolysis resistance of the post-curing acid and alkali resistant sealing frame are improved.

An adhesive composition (100) comprises: a polyester resin (A) that includes an ester bond which bonds repeating units together and one or more functional groups selected from the group consisting of carboxy groups and carboxylic acid anhydride structures; an epoxy compound (B) in the amount of 1-50 parts by mass with respect to 100 parts by mass of the polyester resin (A); and a cyclic carbodiimide (C) in the amount of 0.1-20 parts by mass with respect to 100 parts by mass of the polyester resin (A).

The invention provides a multifunctional tactile sensor based on a double-taper-region plastic optical fiber and a preparation method thereof.According to the sensor, the middle of a PMMA plastic optical fiber is made into a taper through the fused biconical taper technology, and after tapering, an input optical fiber, a first taper region, a micro optical fiber, a second taper region and an output optical fiber which are sequentially connected from left to right are formed; a coating layer of polyester resin NOA 144 is arranged on the periphery of the second conical region; and the peripheries of the first conical region, the micro optical fiber and the second conical region are also packaged in an elastic cladding of PDMS (Polydimethylsiloxane). According to the sensor, force measurement and sliding direction identification can be carried out, the square distribution of a sensing area can be directly changed through the diameter of the micro optical fiber and the length of the conical area, and therefore the sensitivity of the sensor and the accuracy of pressure measurement are remarkably influenced. And the cone region is obtained by adopting a fused biconical taper technology, the manufacturing process is simple and convenient, the manufacturing cost is low, the device integration degree is relatively high, the stability is strong, and the device has relatively great competitiveness and application prospects in the fields of tactile sensing, medical operation and the like.

The invention discloses an epoxy powder coating and a preparation method thereof, and belongs to the technical field of powder coating production, firstly, the epoxy powder coating is prepared from the following raw materials in parts by mass: 100 parts of epoxy resin, 15-20 parts of modified phenolic resin, 12-15 parts of carboxyl-terminated polyester resin, 4-8 parts of nano cerium oxide coated mica, 1.5-2.0 parts of a flatting agent and 0.5-1.0 part of benzoin; the modified phenolic resin is prepared by carrying out addition on bisphenol A phenolic resin and DOPO, neutralizing and carrying out reduced pressure distillation; the carboxyl-terminated polyester resin is prepared by carrying out esterification polycondensation on terephthalic acid, isophthalic acid, neopentyl glycol and trimethylolpropane, and then modifying by trimellitic anhydride; the nano cerium oxide coated mica is prepared by coating white mica powder with cerium oxide precipitate, and then carrying out surface treatment and crushing.

The invention discloses weather-resistant unsaturated polyester resin as well as a preparation method and photovoltaic application thereof, and relates to the technical field of high polymer materials. When the weather-resistant unsaturated polyester resin is prepared, 1, 6-hexanediol, itaconic acid and an ultraviolet absorption monomer are subjected to esterification and polycondensation to prepare unsaturated polyester; the preparation method comprises the following steps: carrying out reaction on naringenin and 4-isocyanate-tetramethylpiperidine oxide to prepare a functional cross-linking agent; the preparation method comprises the following steps: reacting 3-(4-chlorphenyl) phosphine, 2, 2 '-thiobis (4-chlorophenol) and 2-butene-1, 4-diamine, and polymerizing and coating silicon dioxide to prepare pre-modified silicon dioxide; reacting the pre-modified silicon dioxide, n-butylamine and nickel acetate to obtain modified silicon dioxide; uniformly mixing unsaturated polyester, a functional cross-linking agent and modified silicon dioxide, and performing injection molding to obtain the weather-resistant unsaturated polyester resin. The weather-resistant unsaturated polyester resin prepared by the invention has excellent anti-aging, flame-retardant, self-repairing and mechanical properties.

The invention belongs to the technical field of photovoltaic materials, and provides a photovoltaic profile and a preparation method and application thereof. The preparation method comprises the following steps: carrying out surface conditioning and phosphorization on a steel substrate (carbon steel or recycled steel or low alloy steel), carrying out electrophoretic deposition by using epoxy thermosetting electrophoretic primer, and pre-drying; the outer surface of a workpiece is coated with fluorocarbon finish paint (the fluorocarbon finish paint comprises the following raw materials in specific content: polyester resin with a certain viscosity hydroxyl value, fluorocarbon resin with a certain viscosity hydroxyl value, pigment filler, an organic solvent, a wetting leveling agent, a dispersing agent, a defoaming agent, an adhesion promoter and an aliphatic isocyanate curing agent), and curing is performed. And an electrophoretic primer layer with the thickness of 15-25 microns and a fluorocarbon finish layer with the thickness of 20-30 microns are formed on the outer surface of the steel substrate through curing. According to the photovoltaic profile, the electrophoretic primer layer and the fluorocarbon finish paint layer are formed on the low-cost steel substrate through one-time curing, the process can be simplified, the cost can be reduced, the paint layer is thin, and the photovoltaic profile further has long-term excellent adhesive force, aging resistance, corrosion resistance, weather resistance, gloss retention and the like.

The invention relates to the technical field of high polymer materials, and discloses self-repairing bio-based polyester resin for a matte powder coating as well as a preparation method and application of the self-repairing bio-based polyester resin. The bio-based polyester resin is prepared from the following preparation raw materials in percentage by mole: 20 mol% to 40 mol% of bio-based flexible diol, 20 mol% to 35 mol% of bio-based furandicarboxylic acid, 10 mol% to 25 mol% of isosorbide, 5 mol% to 25 mol% of itaconic acid, 1 mol% to 15 mol% of long-chain bio-based aliphatic dibasic acid, 1 mol% to 10 mol% of bio-based citric acid, 0.1 mol% to 2.0 mol% of zinc acetylacetonate, 0.1 mol% to 1.0 mol% of a microcapsule corrosion inhibitor, 0.1 mol% to 1.0 mol% of an esterification catalyst and 0.1 mol% to 1.5 mol% of an antioxidant. The bio-based polyester resin does not contain petroleum-based monomers and is high in biochar content.

The invention discloses lighting resin as well as a preparation method and application thereof, and belongs to the technical field of lighting type unsaturated polyester resin. Comprising the following components: ethylene glycol, benzoic acid, phthalic anhydride, maleic anhydride, an antioxidant, a defoaming agent, a surfactant, a stabilizer, styrene, a solvent, a first polymerization inhibitor, a second polymerization inhibitor and a third polymerization inhibitor. The alcohol-acid ratio is (1.03-1.13): 1; the molar ratio of unsaturated acid to saturated acid is (2.5-3.5): 1; the mass ratio of benzoic acid to the surfactant is (26.8-44): 1; the preparation method comprises the following steps: 1) reacting ethylene glycol, maleic anhydride, phthalic anhydride, benzoic acid, an antioxidant and a first polymerization inhibitor; the preparation method comprises the following steps of (1) adding a first polymerization inhibitor, (2) heating and preserving heat after the reaction is completed, and (3) cooling, adding a second polymerization inhibitor, cooling, adding a third polymerization inhibitor, a cross-linking agent, a surfactant and a defoaming agent, and adding a solvent to obtain the daylighting resin.According to the preparation method, the surfactant and benzoic acid have a synergistic effect, so that the compatibility of polyester and the cross-linking agent is improved.

The invention discloses a synthesis method of special bio-based unsaturated polyester resin for zero-crystalline silicon quartz stone, which comprises the following steps: firstly, putting bio-based dihydric alcohol, 2, 5-furandicarboxylic acid, itaconic acid, an antioxidant and a polymerization inhibitor into a reaction kettle, heating to 205-210 DEG C, carrying out polymerization reaction for 2-4 hours, then vacuumizing for 2-3 hours, and cooling to room temperature to obtain the special bio-based unsaturated polyester resin for zero-crystalline silicon quartz stone. When the reaction acid value is tested to be smaller than 25 mgKOH / g and the cone plate viscosity at 125 DEG C is 500-900 mpa.s, the reaction endpoint is reached, finally, a bio-based crosslinking monomer is added for dilution, and the bio-based unsaturated polyester resin special for the zero-crystallization silicon quartz stone is obtained. The bio-based unsaturated polyester resin special for the zero-crystalline silicon quartz stone synthesized by the method can meet the requirements of a zero-crystalline silicon quartz stone production process, and solves the problems that a zero-crystalline silicon quartz stone plate is easy to generate surface pulverization corrosion, glass explosion and the like.

The invention relates to the technical field of powdered ink, and discloses a plant-based environment-friendly powdered ink composition which comprises the following components: resin, a coloring agent, a charge control agent, wax / a release agent and an additive. The resin comprises polyester resin and bio-based resin. The polyester resin comprises polyhydric alcohol and polybasic acid. The polyol comprises ethylene glycol, neopentyl glycol and a bisphenol A derivative. The polybasic acid comprises terephthalic acid, isophthalic acid and oxalic acid. Compared with the prior art, the plant-based environment-friendly powdered ink composition provided by the invention has the advantages that the plant-based environment-friendly powdered ink composition is based on a plant-oil-based biodegradable material and is prepared from plant oil, polyhydric alcohols and polybasic acid compounds, so that the excellent biodegradability and moisture resistance of the plant oil are kept; and when the resin is used for preparing the biological powdered ink, the biodegradability and moisture resistance of the powdered ink can be effectively improved, and the biological powdered ink prepared from the resin has excellent biodegradability, moisture resistance, performance retentivity and fixing strength.

Provided is a hard coating film for foldable displays that does not form creases or cracks in the folding portion, and that is also excellent in reducing iridescent colors (interference mottling) caused by fine cracks in an easy-to-adhere resin layer or other layers. The hard coating film for foldable displays contains a polyester film having a thickness of 10 to 80 μm, an easy-to-adhere resin layer, and a hard coating layer, the easy-to-adhere resin layer and the hard coating layer being stacked in this order on at least one surface of the polyester film, wherein the easy-to-adhere resin layer is a cured product of a composition containing at least one compound selected from the group consisting of titanium compounds and zirconium compounds and a polyester resin, and the polyester film having the easy-to-adhere resin layer stacked thereon but not yet having the hard coating layer stacked thereon satisfies characteristics within specific ranges.

A release film comprising: a laminated film in which a first coating layer B1 containing a polyester resin containing an inorganic pigment, a void-containing layer A containing voids therein, and a second coating layer B2 containing a polyester resin containing an inorganic pigment are laminated in this order; and a release layer C on at least one side of the laminated film, wherein the void-containing layer A is made of a composition containing a polyester resin, a polyolefin resin, and a silicone resin, and has an apparent density of 0.80 g / cm3 or more and 1.20 g / cm3 or less.

The present invention relates to a matting agent for HAA powder coatings and a preparation method thereof. The matting agent is a matting polymer containing special groups such as hydroxyl and epoxy groups with significantly different activities. The matting polymer is mainly prepared from glycidyl methacrylate, methyl methacrylate, butyl acrylate, 5-norbornene-2-methanol, 2-methyl-3-butene-2-ol, dicyclopentadiene dioxide, a hydroxyl polyester resin, and an accelerator. Due to the presence of hydroxyl and epoxy groups of varying activities in its structure, supplemented by the accelerator and the physical dispersion effect during the preparation process, the product has excellent matting ability and good storage and matting stability. It can reduce the gloss of HAA system powder coatings to 3-10%.

Provided is a highly adhesive polyester film having excellent adhesion to a functional layer such as a hard coat layer or an adhesive. Also provided is a laminated polyester film provided with the functional layer. The present invention relates to a highly adhesive polyester film having a polyester film base material and a coating layer on at least one surface of the base material, the coating layer comprising a polycarbonate polyurethane resin and a polyester resin, the polycarbonate polyurethane resin and the polyester resin each have a structure in which a cyclohexane ring is included in the molecule, and at least one hydrogen atom in the cyclohexane ring is substituted by a hydrocarbon group.

The application discloses a kind of high-performance coiled material powder coating and preparation method thereof, belong to powder coating technical field, the application is by the compounding of organosilicon modified epoxy resin and carboxyl-terminated polyester resin, after organosilicon modification, the segment of introduction-Si-O-Si in system has high flexibility, and synergistic effect with nano calcium carbonate, it is helpful to balance the adhesion and flexibility of coating, grafting modification graphene oxide, active chromium oxide is added again, can obviously improve the mechanical strength of coating;After then, phosphite group is grafted onto graphene oxide, and is applied in the present powder coating system, can form three-dimensional network structure in system, chemical bond effect, not only can improve its crosslinking stability in system, and the sheet structure of graphene oxide, also can play certain barrier property, can also give coating longer weather resistance, and active chromium oxide synergistic effect is further improved, and the weather resistance and corrosion resistance of coating.