2938 results about "Composite membrane" patented technology

The invention relates to the technical field of high polymer material preparation, and discloses a bamboo fiber graft modified full-biodegradable composite membrane material preparation process which comprises the following steps: firstly, performing hot mixing and cooling on dried bamboo fiber powder, anhydrous citric acid, choline chloride, activated zinc oxide and pentaerythritol to prepare a bamboo fiber modified premix; then mixing the biodegradable polyester resin with the premix; adding the mixture into an extruder, injecting epoxidized soybean oil into a barrel through a liquid metering device, and performing melt extrusion granulation under a vacuum exhaust condition; and finally carrying out blow molding to form the film. Through in-situ reaction extrusion of multi-component synergism, surface grafting of bamboo fibers, chain extension of a polyester matrix and interface chemical bonding of the bamboo fibers and the polyester matrix are achieved, interface compatibility is effectively improved, degradation of the material in the processing process is inhibited, and the mechanical property and thermal stability of the composite film material are remarkably improved; the process is efficient and environment-friendly, and the cost is controllable.

The invention discloses a partitioned multifunctional metal double-cavity vacuum coating process and system, and belongs to the technical field of material surface treatment. The process comprises the steps of base material pretreatment, double-cavity preparation, vacuum inspection, first cavity bottom layer deposition, vacuum transfer, second cavity functional layer deposition and cooling, the double cavities are provided with corresponding target materials respectively, and parallel operation and vacuum seamless transfer are supported; the system comprises double coating cavities, a vacuum transmission channel, a vacuum acquisition and control module, a coating deposition module, a workpiece bearing module and a process parameter regulation and control module, and each of the double cavities is provided with a multi-target mounting rack and carries a real-time monitoring unit and an intelligent control system. Integrated preparation of the composite film layer and synchronous production of multifunctional workpieces are achieved, operation gaps are eliminated, the compactness and adhesive force of the film layer are improved, parameter deviation and the reject ratio are reduced, and batch production requirements are met.

The invention relates to the technical field of biomedical materials, and discloses an electret electrostatic therapy membrane and a preparation process thereof.The electret electrostatic therapy membrane is prepared from, by mass, 15%-20% of fluorinated polyether ester, 10%-20% of a composite nano-fiber material, 10%-20% of a composite nano-fiber material, 10%-20% of a composite nano-fiber material and the balance water. 1%-2% of carboxymethyl chitosan; 2-5% of nano cerium oxide particles with the particle size of 50-100 nm; 0.5-1.0% of graphene quantum dots, the particle size of which is 5-10 nm; 1%-2% of sodium hyaluronate; the components are prepared into a film through an electrostatic spinning method, electret performance is given to the film through a charge injection process, finally, the film body is attached to a flexible silica gel adhesion layer, and the flexible silica gel adhesion layer is externally coated with a peelable protective film so that the structural integrity can be kept before the flexible silica gel adhesion layer is used. The composite membrane body disclosed by the invention shows excellent adhesion, charge activation capability and thermal response performance in applications of electrostatic therapy, dielectric assisted stimulation and the like, and has good multi-scene adaptability and clinical application potential.

The diamond coated glass structure may include a glass substrate in which the deposited nanocrystal diamond is coated on the glass substrate. A layer of ultra-nanocrystalline diamond may be deposited on the deposited nanocrystalline diamond. The combination of the deposited nanocrystal diamond and ultra-nanocrystal diamond may have a surface roughness of less than 9 nanometers RMS.

The invention discloses a visual analysis-based steel-wood combination template welding seam quality detection method, and relates to the related field of machine vision and image processing, the method comprises the following steps: collecting image data of a steel-wood combination template surface welding seam, the images being divided into two types of welding seam defect-free and welding seam defect-having; in view of the reflection difference of different materials of the steel-wood combined template, preprocessing the collected surface weld seam image of the steel-wood combined template, adjusting the brightness distribution of the image surface, and extracting weld seam features; marking welding seam features, training a welding seam quality detection model, and storing model parameters with the best performance as a pre-training model; in a real production environment, inputting a steel-wood combined template surface welding seam image shot in real time into the pre-training model, carrying out deep analysis on welding seam characteristics, and outputting a detection result; and according to a detection result of the model, evaluating the welding seam quality of the steel-wood combined template, and completing a quality detection report. And the welding seam quality detection precision and efficiency are improved.

The invention is applicable to the technical field of proton exchange membranes, and particularly relates to a perfluorosulfonic acid proton exchange composite membrane which is prepared by the following steps: preparing a perfluorosulfonic acid resin solution: dissolving the perfluorosulfonic acid resin solution in a mixed solvent to form a membrane casting solution; impregnating and filling: impregnating a porous base membrane in the obtained perfluorinated sulfonic acid resin solution, and keeping at 20-80 DEG C for 1-120 minutes; drying and forming: taking out the impregnated film, and drying to form a composite film; and protonation treatment: treating the composite membrane in an acid solution, and washing to be neutral to obtain the perfluorosulfonic acid proton exchange composite membrane. According to the invention, the problems of deformation and damage of the battery in operation are effectively avoided; meanwhile, the high proton conductivity is ensured, so that the ion transmission efficiency is maintained; the introduction of the ePTFE porous skeleton enhances the membrane body and reduces the use amount of the perfluorinated sulfonic acid resin at the same time, the composite membrane is compact in structure and balanced in performance, and the durability and reliability of the fuel cell are greatly improved.

The invention discloses a copper surface micro-etching coarsening solution for a fine circuit as well as a preparation method and application of the copper surface micro-etching coarsening solution, and relates to the technical field of printed circuit board manufacturing. The copper surface micro-etching coarsening solution for the fine circuit is prepared from, by mass concentration, 60 g / L to 100 g / L of sulfuric acid, 40 g / L to 60 g / L of hydrogen peroxide, 0.5 g / L to 2 g / L of zinc sulfate, 10 g / L to 30 g / L of copper ions, 0.5 g / L to 1 g / L of pyridine heterocycle-containing Schiff base, 10 g / L to 100 g / L of ethyl alcohol, 1 g / L to 3 g / L of 2-mercaptobenzothiazole, 1 g / L to 5 g / L of methionine and 1 g / L to 5 g / L of polyacrylamide. According to the copper surface micro-etching coarsening solution, the 2-mercaptobenzothiazole and the methionine in the copper surface micro-etching coarsening solution can enable the copper surface to form a honeycomb structure under the low micro-etching amount, the zinc sulfate and the pyridine heterocyclic ring-containing Schiff base can form a composite film layer with copper ions on the surface of the honeycomb structure, and the interlayer binding force is improved.

The invention relates to the technical field of membrane separation, in particular to a composite forward osmosis membrane based on mussel bionic interface enhancement and a preparation method thereof. The preparation method comprises the following steps: immersing a base material in a dopamine hydrochloride solution for oscillation reaction to obtain a modified base material; the surface of the modified base material is coated with a membrane casting solution in a blade coating mode, then phase inversion is carried out, the residual solvent is removed, then airing is carried out, and the composite forward osmosis membrane based on mussel bionic interface enhancement is obtained. By introducing the mussel bionic polydopamine intermediate layer, the long-standing technical contradictions of poor interfacial compatibility and weak binding force between the hydrophobic substrate and the hydrophilic separation layer are ingeniously solved, and the internal concentration polarization effect is remarkably inhibited. The prepared composite membrane has the advantages of high water flux, low salt reverse flux, stable structure and the like, and has wide application prospects in the fields of water treatment and substance separation.

The invention provides a multispectral camouflage infrared wavelength selection thin film and a preparation method thereof, and belongs to the technical field of spectral thermal radiation management, and the preparation method comprises the following steps: screening a material with directional emission in a wave band of 8-14 microns as a directional emission layer material according to an optical constant of a thin film material in the wave band of 3-25 microns; a directional emission layer material is combined with a lossless dielectric material and a metal material to construct a cascaded Fabry-Perot resonant cavity structure; according to the arrangement sequence and the optical constant of each layer of film, taking the thickness of each layer of film as an optimization variable, and utilizing an optimization algorithm taking a quality factor function as a judgment basis to carry out iterative calculation to obtain the optimal thickness of each layer of film; and according to the structure of the multi-layer composite film and the optimal thickness of each layer of film, depositing each layer of film material on the substrate by adopting a magnetron sputtering process to prepare the multi-spectral camouflage infrared wavelength selection film. According to the scheme, the optimization efficiency of the film layer is improved, and efficient thermal management is realized while the multispectral camouflage performance is maintained.

The application discloses a cross-linked ETFE composite film with gradient ultraviolet shielding function and a preparation method and application thereof, and belongs to the technical field of ETFE film preparation. The cross-linked ETFE composite film is composed of three layers of a surface layer, a middle layer and a bottom layer. The surface layer material comprises ETFE resin and fluorinated carbon quantum dots; the middle layer material comprises ETFE resin, allyl-containing comonomer A and phenyl-containing comonomer B; and the bottom layer material comprises ETFE resin and CeO2 nanowires. The fluorinated carbon quantum dots have a particle size of 3-5 nm and contain a -C4F9 structure. The comonomer A is an allyl-containing fluorine olefin monomer, and the comonomer B is a phenyl-containing organic fluorinated compound. Through the synergistic effect of the surface layer self-migration fluorinated carbon quantum dots, the middle layer copolymerization modification and the bottom layer CeO2 nanowires, high light transmittance, full-waveband ultraviolet shielding and long-term weather resistance are achieved.

The invention relates to a PVB (polyvinyl butyral) composite film as well as a preparation method and application thereof. The PVB composite film is prepared from the following raw materials in parts by weight: 100 parts of PVB resin, 1-10 parts of nano praseodymium oxide, 1-10 parts of a dispersing agent, 0.01-1 part of a coupling agent and 20-50 parts of a plasticizer. The nano praseodymium oxide is added into the PVB resin, and the infrared absorption band of the PVB composite film is optimized by utilizing the infrared absorption performance, chemical stability and heat-resistant stability of the nano praseodymium oxide, so that infrared radiation can be efficiently blocked, and the excellent heat insulation effect and long-term use stability of the PVB composite film are realized. Furthermore, the nano praseodymium oxide is modified by a coupling agent, so that the dispersion uniformity of the nano praseodymium oxide in the PVB resin and the interface bonding force of the nano praseodymium oxide and the PVB resin are improved, the light transmittance loss of the PVB composite film is reduced, and the mechanical property and the heat insulation property of the composite film are improved.

The invention relates to the technical field of co-extrusion molding, in particular to a multi-layer co-extrusion molding method of a building composite membrane material, which comprises the following steps: melting and plasticizing a polymer mixture of each layer, and then synchronously co-extruding to obtain a composite tubular melt blank; injecting gas into the composite tubular melt blank and drawing to obtain a composite tubular bubble; judging whether the preparation of the composite tubular vesicle reaches the standard or not according to the vesicle form characterization value; cooling and curing the composite tubular film bubbles reaching the standard to obtain a composite tubular film; when it is judged that the preparation of the composite tubular membrane does not reach the standard according to the circumferential cooling uniformity characterization value, an adjustment strategy when the preparation of the composite tubular membrane does not reach the standard is determined according to the circumferential wind speed extreme value ratio of the cooling wind ring; and flattening and rolling the composite tubular membrane reaching the standard to obtain the composite membrane material for the building. The co-extrusion forming efficiency of the composite membrane material for the building is improved.

The invention belongs to the field of proton exchange membrane water electrolysis hydrogen production, and particularly relates to a functionalized ionic liquid modified PVDF / Nafion composite proton exchange membrane as well as a preparation method and application thereof, which are used for solving the technical problems of high cost, low mechanical strength, swelling at high temperature and low conductivity of a Nafion composite membrane. A PVDF / Nafion solution is subjected to functionalized ionic liquid modification to obtain a membrane casting solution, and then the membrane casting solution is coated and dried to obtain the functionalized ionic liquid modified PVDF / Nafion composite proton exchange membrane. According to the ionic liquid modified PVDF / Nafion composite proton exchange membrane disclosed by the invention, the usage amount of Nafion resin is reduced, the cost is reduced, and meanwhile, the proton conductivity is improved by adding the ionic liquid; the ionic liquid functionalized by different cations can form a hydrogen bond network with sulfonic acid groups of Nafion and fluorine atoms of PVDF, so that the mechanical property and the thermal stability of the proton exchange membrane are improved, and the proton exchange membrane has a good application prospect.

Membranes and related systems and methods for separation of components in liquids are generally described. The membrane may include particles in a polymer matrix (e.g., a polyamide layer). The particles may include metal-organic framework particles comprising functional groups (e.g., from post-synthetic modification) that can, in some instances, improve the rejection and / or selectivity of the membrane. For example, the metal-organic framework may comprise functional groups bound to hydrophobic groups (e.g., alkyl chains) that assist with suspension stability in nonpolar solvents during membrane fabrication. As another example, the metal-organic framework may comprise functional groups bound to crosslinking agents that facilitate in situ crosslinking of the particles with the polymer matrix, thereby reducing voids in the membrane and / or leaching. In some instances, the membrane is a thin-film nanocomposite membrane (e.g., for separating components like charged species and / or neutral species) formed via, for example, interfacial polymerization in the presence of the particles.

The invention relates to the technical field of functional label paper, in particular to degradable bio-based hot-melt pressure-sensitive adhesive label paper and a preparation method thereof.The degradable bio-based hot-melt pressure-sensitive adhesive label paper comprises a base material layer, a hot-melt pressure-sensitive adhesive layer and a release layer; 30-50 parts of the base material layer is a polylactic acid / bamboo fiber / nanocellulose composite film; 40-60 parts of the adhesive layer contains poly (butylene adipate-butylene terephthalate) and the like, and contains a composite toughening agent; and 5-10 parts of a release layer is a beewax / chitosan / montmorillonite coating. The mechanical and adhesive properties of the label paper are improved, and the label paper is good in weather resistance, full-degradable, environment-friendly, stable in process, suitable for the fields of food and medicine and capable of supporting industrialization.

The invention relates to a super-flexible supercapacitor with a multi-layer seamless interlocking interface and a preparation method of the super-flexible supercapacitor. The super-flexible supercapacitor takes a carbon nanotube or a composite film thereof as an electrode; and polyanion gel (polyacrylamide / polyacrylic acid / poly (3-sulfonic acid propyl methyl acrylic acid potassium salt) and polycation gel (polyacrylamide / polyacrylic acid / poly (methacryloyloxyethyl trimethyl ammonium chloride) are used as the double-layer heterogeneous electrolyte. A covalent connection electrode / electrolyte interface is constructed through anchoring interface polymerization, and double-layer gel electrolyte with electrostatic attraction and mutual entanglement is constructed through in-situ polymerization, so that the super-flexible supercapacitor with a multi-layer seamless interlocking interface is realized. Compared with the prior art, the super capacitor has super-strong interface toughness and interface adhesion, can resist mechanical deformation including bending, folding, twisting, winding, extruding, knotting and the like, the capacity retention ratio is greater than 95% after the super capacitor is folded for hundreds of thousands of times, and the capacity retention ratio is greater than 89% after the super capacitor is circularly charged and discharged for hundreds of thousands of times.

The utility model relates to a treatment system for purifying high-salinity wastewater, which is suitable for treating high-salinity wastewater, particularly desulfurization wastewater of a coal-fired power plant and coal chemical wastewater. By combining efficient flocculation, ozone catalysis and membrane distillation technologies, a self-made chitosan-based flocculant is added in a flocculation stage, and suspended solids and heavy metal ions in wastewater are removed by utilizing good adsorption performance and flocculation capacity of the self-made chitosan-based flocculant; in the ozone catalysis stage, a self-made ternary composite catalyst is added, ozone decomposition is promoted, and organic pollutants are further removed; in the membrane distillation stage, a self-made antifouling and moisture-resistant composite membrane is used for efficient desalination and concentration, and finally efficient purification and recycling of the high-salinity wastewater are achieved. The process can significantly improve the wastewater treatment effect, reduce the concentration of salt and harmful substances in the wastewater, also reduce the operation cost, and is suitable for large-scale industrial wastewater treatment.

The invention provides a high-sealing-performance flame-retardant composite film and a preparation method thereof, and belongs to the technical field of composite film material preparation, the high-sealing-performance flame-retardant composite film comprises an outer layer, a middle layer, a transition layer and an inner sealing layer which are sequentially stacked, the material of the middle layer comprises a polypropylene matrix, modified aluminum hydroxide and zinc borate, the material of the transition layer comprises epoxy resin and nano silicon carbide, and the material of the inner sealing layer comprises ethylene-vinyl acetate copolymer and maleic anhydride grafted polyethylene; the flame-retardant PET also contains 12 to 20 weight percent of phosphorus-nitrogen synergistic flame retardant; the outer layer and the middle layer are combined in a physical entanglement mode, and the transition layer and the inner sealing layer are combined in a chemical crosslinking mode. The high-sealing-performance flame-retardant composite film provided by the invention has excellent flame-retardant performance and sealing performance, and is suitable for packaging of new energy automobile batteries and high-end electronic equipment.

The invention relates to the technical field of composite films, and provides a PE film, a preparation method thereof and application of the PE film in metal powder packaging. The PE film comprises an outer layer, a middle layer and an inner layer which are sequentially arranged, preparation raw materials of the outer layer comprise low-density polyethylene, linear low-density polyethylene, metallocene medium-density polyethylene and a processing aid, and preparation raw materials of the middle layer comprise low-density polyethylene, linear low-density polyethylene, high-density polyethylene and a processing aid. And the inner layer is prepared from the following raw materials: low-density polyethylene, an antistatic agent and a processing aid. When the PE film is used for packaging metal powder, the effect that the metal powder does not adhere to a bag can be achieved, the phenomenon that a seal is not firm due to the fact that metal adheres to the seal is avoided, meanwhile, waste of the metal powder is avoided, and the PE film has wide application prospects.

The invention provides a mirror PVC (polyvinyl chloride) composite film and a preparation method thereof, the PVC film is provided with a forming surface and a non-forming surface which are deviated from each other, and the PET film is arranged on the forming surface of the PVC film in a tearable manner. The mirror surface PVC film has the beneficial effects that the synergistic effect of the tearable PET film and the online optical-grade PET laminating process is innovatively adopted, so that the breakthrough improvement of the performance of the mirror surface PVC film is realized; the smooth and matt surface of the PVC film is isolated by the PET film, so that molecular migration extinction caused by contact of the smooth and matt surface is effectively inhibited, the problem of gloss attenuation after storage and transportation of a traditional product is solved, and the mirror surface effect is ensured for a long time in a conventional storage environment; meanwhile, the optical-grade PET film is arranged on the forming surface of the PVC film in an online laminating mode, so that the secondary calendering and brightening coating procedures of a mirror surface roller are omitted, calendering-laminating-rolling integrated production is realized, the mirror surface effect of a product is formed at one time, the production process is simplified, the production line speed is increased, the production efficiency is greatly improved, and the comprehensive production cost is reduced.

The present invention provides a high-thermal-conductivity and high-thickness graphene composite film and a preparation method therefor. The graphene composite film has a thickness of 1-2 mm, a thermal conductivity in the horizontal direction of 1500-1800 W / m•K and a thermal conductivity in the vertical direction of 100-200 W / m•K. The graphene composite film is obtained by mixing, coating, drying and sintering raw materials comprising a graphene oxide slurry, carbon fibers, carbon nanotubes and an adhesive dispersant, wherein on the basis of the mass of the graphene oxide slurry, the mass percentage of the carbon fibers is 4-7%, the mass percentage of the carbon nanotubes is 5-10%, and the mass percentage of the adhesive dispersant is 5-10%. The graphene composite film uses graphene oxide as a base material, and carbon fibers and carbon nanotubes of a certain length and diameter are added thereto to create a thermal conduction channel in the vertical direction. The synergistic combination of the three raw materials solves the current defect of it being difficult to balance the thickness and axial thermal conduction performance of a graphene film.

The invention belongs to the technical field of electrochemical energy storage, and discloses a flow battery composite membrane material and a preparation method thereof, and the preparation method comprises the following steps: spraying a ZIF-8 metal organic framework solution to the positive electrode side of a microporous diaphragm, and drying to obtain the flow battery composite membrane material. According to the zinc-bromine flow battery and the preparation method thereof, ZIF-8 acts on the positive electrode side of the microporous diaphragm, ZIF-8 shows good chemical stability in an acidic electrolyte environment of the zinc-bromine flow battery and is not easily oxidized and degraded by bromine, and a stable framework ensures that a screening pore channel is kept complete in long-term operation and continuously plays a role in resisting bromine, so that the corrosion of a zinc negative electrode and the loss of bromine active substances are reduced, and the service life of the zinc-bromine flow battery is prolonged. The problems of low bromine permeation and bromine reaction rate on the positive electrode side of the zinc-bromine flow battery and the like can be effectively solved, and the coulombic efficiency and the voltage efficiency can be remarkably improved, so that the microporous diaphragm with excellent comprehensive performance is obtained.

An electrolyte for a secondary battery according to an embodiment of the present invention may include a lithium salt, a composite film including an inorganic electrolyte, and a flame-retardant polymer. A secondary battery according to an embodiment of the present invention may comprise: a positive electrode; the negative electrode is arranged opposite to the positive electrode; and an electrolyte layer that is provided between the positive electrode and the negative electrode and contains an electrolyte for the secondary battery.

The invention discloses an antibacterial breathable dressing patch and a preparation method thereof, and belongs to the field of medical dressings, the antibacterial breathable dressing patch comprises a Janus type dressing patch layer which is a composite film containing a hydrocolloid matrix, pH response antibacterial microspheres and bioactive glass nanoparticles; the super-hydrophobic electrostatic spinning outer layer is a super-hydrophobic electrostatic spinning fiber membrane, and the super-hydrophobic electrostatic spinning outer layer and the Janus type dressing skin-attaching layer are compounded to form an asymmetric Janus structure, intellectualization and precision of the antibacterial effect are achieved, and the risks of cytotoxicity and bacterial drug resistance possibly caused by long-term exposure to an antibacterial agent are reduced to the maximum extent; a multi-mechanism and synergistic antibacterial defense system is constructed, more comprehensive and firm protection is provided for wounds, the air permeability and moisture permeability are excellent, a dry and moist ideal healing environment is created for the wounds, the biocompatibility is good, the use safety is high, the wound healing agent is mild to human tissues, the irritation is low, the allergic reaction risk is small, the safety is high, and the wound healing effect is good. The long-term use is facilitated.

The invention relates to the technical field of plastic packaging films, in particular to a casting CPE composite film material and a preparation method thereof.The casting CPE composite film material is characterized in that a corona layer is prepared from, by weight, 72-75 parts of LLDPE, 18-22 parts of LDPE, 5-6 parts of EVA and 1.5-2 parts of an opening slipping agent; the middle core layer is prepared from the following components in parts by weight: 70 to 75 parts of LLDPE (Linear Low Density Polyethylene), 20 to 25 parts of HDPE (High Density Polyethylene), 5 to 8 parts of mPE, 3 to 5 parts of modified nano silicon dioxide and 1 to 3 parts of processing aid; the heat sealing layer is prepared from the following components in parts by weight: 25 to 30 parts of mLLDPE, 68 to 72 parts of LDPE, 0.3 to 0.5 part of antistatic agent and 1 to 2 parts of processing aid. The prepared composite film material has multiple functions of flame retardance, aging resistance, static electricity resistance and the like on the basis of keeping excellent heat sealing performance and mechanical strength.

The invention discloses a recoverable high-barrier-property multilayer composite film and a preparation method thereof. The composite film adopts a five-layer symmetrical structure, namely a heat sealing layer, a first bonding layer, a blocking layer, a second bonding layer and a surface protection layer. Wherein the barrier layer is a montmorillonite modified ethylene-vinyl alcohol copolymer, and montmorillonite is modified by a carboxyl functionalized ammonium bromide intercalator; the bonding layer is maleic anhydride grafted polylactic acid; the heat sealing layer contains modified composite filler; the surface protection layer is a polyethylene / graphene modified coupling agent composite system. The preparation method comprises the steps of intercalation modified montmorillonite preparation, barrier layer material melt blending, five-layer co-extrusion casting, gradient hot pressing and curing treatment. The problems that a traditional high-barrier film is unrecyclable, the interlayer binding force is weak and the high-temperature stability is poor are solved, the ultrahigh barrier performance that the oxygen transmission rate is smaller than or equal to 0.5 cm < 3 > / (m < 2 >. 24 h) and the water vapor transmission rate is smaller than or equal to 1.0 g / (m < 2 >. 24 h) is achieved, and the mechanical property retention rate is larger than or equal to 85% after recycling and re-pelletizing.

The invention belongs to the technical field of lithium ion batteries, and particularly relates to a preparation method of a silicon negative electrode composite SEI membrane based on electrochemical impedance spectroscopy in-situ regulation and control. Comprising the following steps: S1, constructing a battery system, and adding an electrochemical active organic precursor and a film-forming additive into an electrolyte; s2, in-situ monitoring: carrying out in-situ electrochemical impedance spectroscopy (EIS) scanning on the battery, and capturing the growth dynamic state of an SEI film in real time; s3, carrying out feature recognition, analyzing the EIS spectrogram in real time, and obtaining a moment when the RSEI growth rate RSEI / t has an inflection point or tends to be stable as an induction trigger point; s4, dynamic induction: applying an electrochemical induction signal of constant potential and high-frequency pulse to carry out dynamic induction; and S5, completing first circle formation to obtain the composite SEI film. The composite SEI film of the inorganic base layer and the organic flexible layer is constructed through combination of EIS real-time monitoring and dynamic induction, the problem that the SEI film is prone to cracking is effectively solved, intelligent and controllable preparation of the composite SEI film is achieved, the cycle life of a silicon negative electrode battery is prolonged, and the consistency of the silicon negative electrode battery is improved.

The invention relates to the technical field of molecular simulation, and discloses a molecular simulation analysis method of a functionalized covalent organic framework confinement ionic liquid microstructure, and the method specifically comprises the following steps: converting force field files of COF and anions and cations of ionic liquid into coordinate files by using a Python tool; the anions and the cations are confined to a pore channel formed by COF stacking to form a composite membrane, and the whole system is placed in a simulation box; data and input files are generated according to the potential file, and LAMMPS software is used for conducting molecular dynamics simulation on a set simulation box; the two-dimensional density, cation orientation and the like of the ionic liquid are analyzed through a Python post-treatment molecular dynamics track, and meanwhile the porosity and the free volume of the COF are calculated. According to the method, a regulation and control mechanism of the COF confinement ionic liquid can be obtained, and a theoretical basis is provided for design and preparation of a COF confinement ionic liquid membrane material.

The invention discloses a full-automatic vehicle film laminating machine and a hot-pressing compounding process thereof, and aims to improve the production efficiency of a vehicle film and the adhesive force of a film layer. The laminating machine comprises an electrostatic spraying chamber and a hot pressing chamber, and efficient compounding of membrane materials is achieved through the synergistic effect of the electrostatic spraying chamber and the hot pressing chamber; a film material is automatically fed into a laminating machine through an upper-layer film leading-in roller and a base material film leading-in roller, after the film material enters an electrostatic spraying chamber, the surface of the film material is subjected to corona treatment, and a nano coating solution is uniformly sprayed on the surface of an upper-layer film through an atomizer; meanwhile, redundant charged particles on the surface of the substrate film are collected through an electrostatic collection plate; the sprayed membrane material enters a hot-pressing chamber, and is heated and pressurized under the action of a hot-pressing roller, so that the two layers of membranes are tightly combined, and the high bonding strength between the membrane layers is ensured; and finally, the finished product film material is wound through a finished product storage roller, and a high-quality vehicle film product is formed.

The invention relates to the technical field of composite films, and particularly discloses a low-temperature heat-sealable high-strength BOPP composite film and a preparation process thereof.The BOPP composite film is prepared by adopting three-layer co-extrusion and two-way stretching processes, and the balance between high strength and low-temperature heat sealability is achieved. The composite film comprises an anti-adhesion surface layer, a core layer and a low-temperature heat-sealing layer; the anti-adhesion surface layer is prepared from the following raw materials: homo-polypropylene, a composite anti-adhesion agent, a slipping agent and PP-g-MAH; the composite anti-adhesion agent is prepared from modified silicon dioxide and modified diatomite in a mass ratio of 3 to 1; the raw materials of the core layer comprise homo-polypropylene, an antistatic agent and a coupling agent, and the raw materials of the low-temperature heat sealing layer comprise an ethylene-vinyl acetate copolymer, PP-g-MAH, a polyolefin elastomer, POE-g-MAH, a modified nucleating agent and an antioxidant, so that the balance of high strength and low-temperature heat sealability is realized, interlayer performance complementation is realized, the mechanical strength is improved, the heat sealing temperature is reduced, and the service life is prolonged. The overall peel strength is improved, and no layering phenomenon exists during stretching.