Disclosed are a non-
aqueous electrolyte solution and a
lithium battery. In order to reduce or avoid the use of a
sulfur-containing compound in a non-
aqueous electrolyte solution and solve the problems of a poor high-temperature storage performance and cycle performance of a
lithium battery, in the present invention a non-
aqueous electrolyte solution is used, comprising a
lithium salt, an
organic solvent and additives. The additives include an additive A and an additive B. The additive A is one or more of substances as shown in structural general formula (1). In the structural general formula (1) of the additive A, R1 is selected from alkylene, alkyleneoxy, fluoroalkylene, fluoroalkyleneoxy, alkenylene or fluoroalkenylene, and R2 and R3 are independently selected from
hydrogen, phenyl, alkynyl, alkynyloxy,
alkyl, alkoxy, fluoroalkyl, fluoroalkoxy, alkenyl or fluoroalkenyl. The additive B is a
boron-containing lithium salt. In the non-aqueous
electrolyte solution of the present invention, a new additive capable of replacing a
sulfur-containing compound is used, such that the high-temperature storage performance and cycle performance of a
lithium battery can be improved.