6532 results about "Hydrothermal reaction" patented technology

The invention provides a degradable environment-friendly packaging material and a preparation process thereof, and belongs to the technical field of packaging materials. The preparation method comprises the following steps: preparing the modified nano montmorillonite; preparing a composite antibacterial additive; preparing a barrier additive; and preparing the degradable environment-friendly packaging material. The preparation method comprises the following steps: by taking methacrylic acid (2-dimethylaminoethyl) ester and acrylic acid as raw materials, modifying nano-montmorillonite under the initiation of benzoyl peroxide, performing quaternary ammonium salinization, and performing in-situ synthesis of nano-zinc oxide on the surface of the quaternary ammonium salinized montmorillonite through a hydrothermal reaction to prepare the composite antibacterial additive. When the composite antibacterial additive is added into polylactic acid to prepare a packaging material, the growth of various microorganisms such as bacteria and fungi can be effectively inhibited, the packaging material is endowed with strong antibacterial protection capability, and the composite antibacterial additive has a more lasting antibacterial effect so as to prolong the antibacterial validity period of the packaging material.

The invention discloses a modified carbon-coated sodium manganese ferric phosphate pyrophosphate / sodium ferric phosphate pyrophosphate positive electrode material as well as a preparation method and application thereof, and relates to the technical field of new energy materials. The preparation method comprises the following steps: preparing MnFe-MOF from a manganese source, a first iron source and a first organic ligand under a hydrothermal reaction; a second iron source, the MnFe-MOF and a second organic ligand are subjected to a hydrothermal reaction, and MnFe-MOF / Fe-MOF is obtained; uniformly mixing with a sodium source and a phosphorus source, and sintering to obtain a positive electrode material; and carrying out high-temperature gas-phase etching treatment to obtain the fluorine-doped carbon-coated modified sodium manganese ferric phosphate pyrophosphate / sodium ferric phosphate pyrophosphate positive electrode material. The material disclosed by the invention has a coating modified structure, so that an interface side reaction caused by direct contact between sodium ferromanganese phosphate and an electrolyte can be effectively avoided, a manganese dissolution phenomenon is reduced, and the structural stability of the material is improved; and meanwhile, the material has high conductivity, excellent structural stability, excellent long cycle life and excellent rate capability.

The invention discloses a CoFeCuMn LDH nanosheet, a confinement catalytic membrane and a preparation method of the CoFeCuMn LDH nanosheet. The preparation method of the CoFeCuMn LDH nanosheet comprises the steps that A1, cobalt salt, ferric salt, copper salt and manganese salt are dissolved in pure water according to a preset proportion to prepare a first solution, sodium hydroxide is dissolved in pure water to prepare a second solution, and sodium carbonate is dissolved in pure water to prepare a third solution; a2, adding the first solution and the second solution into the third solution, and stirring to obtain a mixed solution; a3, carrying out hydrothermal reaction on the mixed solution; a4, centrifugally washing the product obtained in the step A3 to obtain a precipitate; and A5, the sediment is dried, and the CoFeCuMn LDH nanosheet is obtained. According to the CoFeCuMn LDH nanosheet, the confinement catalytic membrane and the preparation methods of the CoFeCuMn LDH nanosheet and the confinement catalytic membrane, the degradation efficiency and the degradation rate of new pollutants are remarkably improved.

The preparation method comprises the following steps: obtaining a ZnO nano-particle seed crystal layer by a dip-coating-calcining method, and growing the ZnO nano-particle seed crystal layer on a porous ceramic membrane; inducing growth of ZnO nano-clusters on the surface of the ceramic membrane on which the ZnO nano-particles grow and in pore channels of the ceramic membrane through a hydrothermal reaction; and finally, soaking the ceramic membrane on which the ZnO nano-cluster grows in an n-octyltriethoxysilane-absolute ethyl alcohol solution, and carrying out silane chemical grafting treatment. A firm micro-nano composite multilevel structure is obtained on the surface and in pore channels of the ceramic membrane after modification through the method, meanwhile, the surface free energy of the surface and pore channels of the ceramic membrane is reduced through n-octyltriethoxysilane, the surface and the pore channels of the ceramic membrane have super-hydrophobic performance, and the preparation method is simple in preparation process, short in period and suitable for industrial production. And the universality is high.

The invention discloses a ferric sodium pyrophosphate positive electrode material, a preparation method thereof and a battery, and relates to the technical field of batteries. Pre-sintering is performed; sanding and spray drying; and high-temperature sintering. Wherein the pH value of the reaction is controlled by using a Tris-HCl buffer solution in the hydrothermal reaction, so that the precursor is uniformly crystallized and has high crystallinity, and low-temperature segmented presintering is adopted later, so that the compaction density of the material can be controlled, and the related electrical properties of the material are relatively good. In the preparation process, a carbon source and a doping element are supplemented twice, so that carbon coating is uniform in the sintering process, the compaction density of the NFPP positive electrode material is further improved, the properties such as theoretical specific capacity of the positive electrode material are better through doping and carbon coating modification, and the high-compaction and high-capacity ferric sodium pyrophosphate positive electrode material is obtained.

The invention discloses a method for preparing nano barium titanate based on sol-gel synergistic hydrothermal reaction, which comprises the following steps: (1) dissolving barium acetate in an acetic acid aqueous solution to obtain a barium source solution; weighing tetrabutyl titanate according to the molar ratio of barium to titanium being greater than 1.25, and dissolving the tetrabutyl titanate in alcohol to obtain a titanium source solution; (2) uniformly mixing the barium source solution and the titanium source solution, preserving heat at 20-80 DEG C to obtain gel, drying and grinding to obtain white powder of the barium titanate precursor: (3) preparing a 2-4mol / L inorganic strong alkali aqueous solution, adding the white powder and a dispersing agent into the inorganic strong alkali aqueous solution, and fully stirring to obtain a barium titanate precursor suspension; and (4) transferring the barium titanate precursor suspension into a reaction kettle for hydrothermal reaction, and after the reaction is completed, washing, drying and grinding to obtain the nano barium titanate powder. The preparation method is low in cost, and the prepared nano barium titanate powder is uniform in distribution, spherical or sphere-like in morphology, small in particle size, 80-150nm in average particle size and good in particle crystallinity.

The invention belongs to the technical field of synthesis of magnesium hydroxide flame retardants, and provides a synthesis method and flame-retardant application of hexagonal flaky magnesium hydroxide, and the synthesis method comprises the following steps: step 1, dissolving a mineralizer, a crystal form control agent and magnesium chloride in water in proportion; step 2, putting a certain amount of the mixed solution into a high-pressure reaction kettle for hydrothermal reaction; step 3, after the reaction is finished, taking out the cooled solution from the high-pressure reaction kettle, and filtering and separating out a white product; 4, drying the sample, and grinding to obtain pure magnesium hydroxide powder; through reasonable process design and optimization, the prepared magnesium hydroxide not only has regular morphology and better dispersity, but also has excellent performance in the field of flame retardance of high polymer materials, meets the requirement of environmental protection, has the production advantages of low cost and high efficiency, and is suitable for industrial production. The method not only can effectively improve the overall utilization rate of salt lake resources, but also has remarkable economic and application values, and has wide industrial application prospects.

The invention relates to a carbon quantum dot for strengthening and promoting growth of microalgae and application thereof. In the process of preparing the carbon quantum dots by a conventional hydrothermal method, a precursor mixture is subjected to acidification modification in advance, the pH value is adjusted to 2 by using nitric acid, and then a hydrothermal reaction is performed, so that the prepared carbon quantum dots have the capability of promoting the growth of microalgae. However, if other acids are adopted or pH adjustment is not in place, the effect cannot be achieved, and even the inhibition effect can be achieved. The obtained product is good in effect and stable in performance, no special reaction device needs to be additionally arranged in the acidification modification process, and the method has the advantages that operation is easy and convenient, raw materials are easy to obtain, and the process can be quantified; the method is simple and convenient in process operation, has universality and is easy for industrial production.

The present invention discloses a CMO / SO / BVO photoanode and a preparation method and application thereof, and relates to the field of photoelectrochemical technology. The method comprises the following steps in sequence: electrodepositing a BiOI film on a substrate material, and then dripping a dimethyl sulfoxide solution containing vanadium acetylacetonate to obtain a BVO electrode; placing in a NaOH solution containing tetraethyl orthosilicate to obtain a SO / BVO electrode; placing in a CoMoO4 precursor solution, hydrothermally reacting, calcining, and obtaining a CMO / SO / BVO photoanode. The CMO / SO / BVO of the present invention exhibits superior photocurrent and charge separation efficiency compared to the CMO / BVO photoanode under 1.23V vs.RHE conditions. The present invention solves the problem of poor photoelectrochemical performance of the photoanode in the prior art.

The invention provides a carbon ceramic resistor and a preparation method thereof, and relates to the technical field of special material production of power systems and electrical equipment. The preparation method comprises the steps that carbon-containing electric conductor raw materials are mixed to obtain a first mixed raw material, and the carbon-containing electric conductor raw materials comprise, by mass, 15 parts of gluconic acid, 10 parts of aluminum oxide and 55 parts of deionized water; performing hydrothermal reaction on the first mixed raw material to obtain a carbon-containing conductor precursor; the carbon-containing conductor precursor is carbonized in a protective atmosphere, a carbon-containing conductor of a core-shell structure is obtained, and the carbon-containing conductor takes aluminum oxide as an inner core and takes a conductive carbon material formed by gluconic acid as a conductive outer shell; mixing the carbon-containing electric conductor with the core-shell structure with a carbon ceramic matrix raw material to obtain a resistor blank; and sintering the resistor blank to obtain the carbon ceramic resistor. The uniformity, the stability and the reliability of the carbon ceramic resistor are improved, so that the carbon ceramic resistor can better meet the application requirements of ultrahigh-voltage and extra-high-voltage alternating-current power transmission systems.

The invention provides a modified lithium iron manganese phosphate positive electrode material, a preparation method thereof and a lithium ion battery, and relates to the technical field of lithium ion battery materials. The positive electrode material comprises a phosphorus source, an iron source, a manganese source, a lithium source and a magnesium source. Mixing a titanium source solution, carrying out hydrothermal reaction, centrifugally washing and drying to synthesize the lithium manganese iron phosphate, and coating polypyrrole and a glucose carbon layer to improve the electronic conductivity of the lithium manganese iron phosphate. The magnesium-titanium co-doped stable crystal structure is introduced, the lithium ion diffusion path is shortened, the dissolution of the manganese element is inhibited, the structural change in the charging and discharging process is reduced, the side reaction with the electrolyte is inhibited by coating the cobalt boride, and the electrochemical performance of the lithium manganese iron phosphate is improved. The primary nano-particles improve ionic conductivity, and the secondary nano-particles are nano-particles formed by assembling the primary nano-particles and have the advantages of being good in rate capability, high in compaction density and high in tap density.

The invention discloses an organic fiber AGM separator and application thereof, and belongs to the field of storage batteries. The organic fiber AGM separator comprises high-alkali glass wool, medium-alkali glass fiber, bi-component polyester fiber and slurry containing a nitrogen-doped reduced graphene oxide / lead oxide composite material, the nitrogen-doped reduced graphene oxide / lead oxide composite material is prepared by the following steps: uniformly ultrasonically dispersing graphene oxide, deionized water and absolute ethyl alcohol, slowly dropwise adding aniline, and ultrasonically stirring to obtain a mixed solution; and adding lead acetate powder into the mixed solution, carrying out ultrasonic stirring, hydrothermal reaction, washing and freeze drying, and carrying out pyrolysis in a rare gas atmosphere to obtain the nitrogen-doped reduced graphene oxide / lead oxide composite material. After being prepared into slurry, the AGM separator substrate is coated with the slurry, and then acid leaching and curing are carried out; the material has excellent dendritic stabbing resistance, and the service life of the storage battery is prolonged.

The invention belongs to the technical field of environment-friendly materials, and particularly relates to an MIL-88A-WS2 composite material and a preparation method and application thereof. The preparation method comprises the following steps: mixing WS2 taking a 1T phase as a main phase and MIL-88A in a solvent, then carrying out a hydrothermal reaction, in the hydrothermal reaction process, loading the WS2 taking the 1T phase as the main phase on the MIL-88A, forming a Fe < 2 + > / Fe < 3 + > and W < 4 + > / W < 6 + > circulating channel, covalent bonds and ionic bonds between the WS2 taking the 1T phase as the main phase and the MIL-88A, and meanwhile, forming a hollow structure by the MIL-88A, so as to obtain the MIL-88A-WS2 composite material. The MIL-88A-WS2 composite material obtained by the method provided by the invention has many active sites and strong conductivity, and can act together with an oxidizing agent peroxymonosulfate to realize degradation of phenolic pollutants.

The invention relates to the technical field of metal material surface treatment, in particular to an antifouling and anti-drag coating for titanium alloy pipeline binding force and a preparation method and application of the antifouling and anti-drag coating. The preparation method comprises the following steps: carrying out micro-arc oxidation treatment on a titanium alloy to form a ceramic film on the surface of the titanium alloy; the titanium alloy subjected to micro-arc oxidation treatment is subjected to a hydrothermal reaction, and a nanoscale porous thorn microstructure and hydroxyl are introduced to the surface of a ceramic membrane; coating the pre-polymerization liquid on the titanium alloy subjected to hydrothermal treatment, and performing irradiation reaction under ultraviolet light to obtain first network gel; the first network gel is soaked in a beta-sodium glycerophosphate solution, and the ion-covalent double network p (SBMA-co-AAc) / CS-beta-GP DN hydrogel is formed. The stability and durability of the coating prepared by the preparation method provided by the invention are improved, and the coating has long-term stable anti-fouling performance, is strongly combined with a titanium alloy substrate, and has excellent anti-fouling effect and anti-drag effect when being applied to the titanium alloy substrate.

The invention belongs to the field of material preparation and chemical engineering, and particularly relates to an N-doped modified MOFs (Metal-Organic Frameworks) derived core-shell nanoreactor as well as a preparation method and application thereof. The preparation method comprises the following steps: taking cobalt as a node metal, synthesizing an N-doped modified MOFs material with an organic ligand and a nitrogen source through a hydrothermal reaction, then coating the surface of the material with porous silicon dioxide, and preparing the N-doped modified MOFs derived core-shell nanoreactor through a two-step calcination method. The MOFs derived core-shell nanoreactor prepared by the invention has a large specific surface area, a rich pore structure and excellent catalytic activity and stability, and is high in catalytic activity, good in recycling stability and suitable for large-scale popularization and application when being used as a catalyst for alpha, beta-unsaturated aldehyde transfer hydrogenation.

The invention relates to the technical field of biomedical materials, in particular to a titanium implant multifunctional composite coating with anti-active oxygen and anti-inflammatory dual performance and a preparation method of the titanium implant multifunctional composite coating. The coating is composed of a lanthanum oxide (La2O3) nano-particle layer growing on the surface of the titanium implant in situ and queen lily glycoside A (RA) loaded on the lanthanum oxide (La2O3) nano-particle layer and can continuously release La < 3 + > and RA. The preparation method comprises the following steps: performing alkali heat treatment on the titanium substrate; a La (OH) 3 coating is synthesized on the surface in situ through a hydrothermal reaction; the La2O3 nano-particles are calcined and converted into a La2O3 nano-particle layer with a porous structure; and finally loading RA through an impregnation method. The coating can effectively remove ROS, regulate immune inflammatory response, promote osteogenic differentiation and inhibit osteoclast activity, thereby remarkably promoting osseointegration. The problem of osseointegration under the osteoporosis pathological microenvironment is effectively solved, the preparation process is simple and controllable, and the composition is suitable for bone defect repair of osteoporosis patients and has important clinical application value.

The invention discloses a method for preparing a waste gas purification catalyst from red mud and electrolytic manganese residues, a product and application thereof, and belongs to the field of solid waste resource utilization. According to the method, the preparation process is simple, efficient resource utilization of the red mud and the electrolytic manganese residues can be achieved through reasonable burdening, hydrothermal reaction and pyrolysis carbonization processes, and no other waste liquid or secondary solid waste is generated in the preparation process. The prepared waste gas purification catalyst is excellent in catalytic performance and can be used for quickly converting harmful gas of 1, 2-dichlorobenzene.

The invention discloses a compound molecular sieve ozone catalyst and a preparation method and application thereof, and the preparation method comprises the following steps: mixing molecular sieve powder with a low silica-alumina ratio and a salt solution of an active component, heating and stirring the mixed solution to evaporate the solvent, washing, drying, calcining and grinding the residual solid to obtain the compound molecular sieve ozone catalyst. Active component loaded hydrophilic molecular sieve powder is obtained; the preparation method comprises the following steps: mixing all-silicon molecular sieve powder and an NH4F aqueous solution, carrying out a hydrothermal reaction, and after the reaction is finished, washing, drying, calcining and grinding an obtained solid material to obtain fluorinated modified hydrophobic molecular sieve powder; mixing the active component loaded hydrophilic molecular sieve powder, the fluorinated modified hydrophobic molecular sieve powder, an inorganic binder and a pore forming agent, and granulating to obtain spherical catalyst particles; and drying and calcining the spherical catalyst particles to obtain the compound molecular sieve ozone catalyst. The ozone catalyst provided by the invention improves the removal rate of refractory organics in reclaimed water.

The invention discloses a method for preparing a catalyst by using red mud and titanium dioxide acidolysis waste residues as well as a product and application thereof. The method comprises the following steps: calcining red mud, adding titanium dioxide acidolysis waste residues and an auxiliary agent, uniformly stirring, adding a desulfurization waste liquid, uniformly stirring, carrying out a hydrothermal reaction, carrying out solid-liquid separation, and calcining to obtain the catalyst material. The preparation process is simple, and efficient resource utilization of the red mud and the titanium dioxide acidolysis waste residues can be achieved. The catalyst prepared through a hydrothermal reaction and a secondary calcination process realizes efficient removal of COD, ammonia nitrogen, total phosphorus and heavy metal pollutants in waste liquid through a photocatalytic function.

The invention discloses a production method for preparing a potassium humate fertilizer through continuous high-pressure hydrothermal reaction of potassium feldspar, and relates to a wet grinding pulping process, a hydrothermal reaction process, a flash evaporation filter pressing process, a humic acid modified potassium fertilizer preparation process and a causticization and humic acid modified silicon-calcium fertilizer preparation process. The preparation method comprises the following steps: firstly, carrying out high-pressure tubular hydrothermal reaction and tower-type delayed reaction on potassium feldspar alkaline ore pulp prepared by fine grinding to prepare potassium aluminosilicate and calcium silicate, mixing alkaline potassium aluminosilicate filter residues obtained by filtering with humic acid, modifying, granulating and drying to obtain a humic acid coated long-acting slow-release potassium fertilizer product. The alkaline calcium silicate filtrate and lime are subjected to a causticization reaction to obtain a KOH solution, the KOH solution is returned to a wet pulping process to be recycled, and the alkaline calcium silicate and the humic acid are mixed, modified, granulated and dried to produce the humic acid coated long-acting slow-release silicon-calcium fertilizer product.

The invention relates to a preparation method of monodisperse spherical alumina powder with uniform granularity. The preparation method comprises the following steps: dissolving and stirring an aluminum source, a precipitator and a dispersing agent in ultrapure water to prepare an aluminum oxide precursor solution; transferring the prepared aluminum oxide precursor solution into a hydrothermal reaction kettle, carrying out heating reaction, after the hydrothermal reaction is finished, naturally cooling to room temperature, alternately and respectively washing with ultrapure water and ethanol, and drying to obtain aluminum oxide precursor powder; and sintering the prepared aluminum oxide precursor powder in a muffle furnace in an air atmosphere to obtain the spherical aluminum oxide powder. The hydrothermal method is adopted to react in a high-temperature and high-pressure environment, so that the reaction uniformity is improved, and the spherical aluminum oxide precursor with uniform granularity and consistent morphology is obtained. The bending strength of the obtained ceramic material is remarkably improved, and the highest bending strength reaches 245MPa. The method has wide application prospects in the fields of heat-conducting composite materials, integrated circuit films, substrate materials, 3D printing materials, precision polishing materials and the like.

The invention provides a method for preparing analcime from lithium slag, and belongs to the field of zeolite preparation. The method comprises the following steps: acid pickling and impurity removal: mixing lithium slag with an inorganic acid solution, stirring and reacting at 50-70 DEG C for 0.5-3 hours, and then filtering, washing and drying in sequence to obtain impurity-removed lithium slag; activation: mixing the impurity-removed lithium slag with a NaOH solution, carrying out continuous stirring reaction at 75-95 DEG C for 35-72 hours, and aging for 10-30 minutes to obtain a mixture colloid; and crystallization: carrying out hydrothermal reaction on the mixture colloid at 110-130 DEG C for 24-72 hours, and then sequentially filtering, washing and drying to obtain the analcime crystal material. According to the method, the lithium slag obtained after leaching and lithium extraction of spodumene by a sulfuric acid method is taken as a raw material, and on the basis of not calcining and activating and not additionally adding the raw material, the NaOH concentration, the activation temperature and time during activation and the temperature and time during hydrothermal reaction are controlled, so that the high-purity analcime crystal can be obtained.

The invention discloses an oxygen-sulfur double-vacancy modified SnO2 / SnS2 / C nano material as well as a preparation method and application thereof, and belongs to the technical field of electrode materials. The preparation method comprises the following steps: mixing a structure regulating agent with tin salt, dropwise adding alkali liquor, stirring, and carrying out suction filtration to obtain Sn6O4 (OH) 4; the preparation method comprises the following steps: adding glucose and polyvinylpyrrolidone into distilled water, stirring to form a uniform solution, adding Sn6O4 (OH) 4 into the uniform solution, stirring, and carrying out ultrasonic and hydrothermal reaction to obtain SnO2 / glucose; and calcining the SnO2 / glucose and a sulfur source in an inert atmosphere to obtain the SnO2 / SnS2 / C nano material modified by oxygen and sulfur double vacancies. The SnO2 / SnS2 / C disclosed by the invention is used for a lithium / sodium ion battery negative electrode, can effectively relieve volume expansion of tin-based oxysulfide and improve the conductivity of an electrode material, and shows high charge-discharge specific capacity, excellent rate capability and high-rate long-cycle stability.

The invention relates to the field of electrode materials, in particular to an antimony-based composite material and a preparation method and application thereof.The preparation method comprises the steps that graphene quantum dots are dispersed in deionized water to obtain a water phase A, antimony trichloride is added into the deionized water and mixed to be uniform to obtain a water phase B, and the water phase B is prepared; the preparation method comprises the following steps: uniformly mixing a surfactant, n-butyl alcohol, an organic solvent and 1-aminopropyl-3-methylimidazole phosphate to obtain an oil phase, dividing the oil phase into two parts, namely an oil phase A and an oil phase B, respectively adding the water phase A and the water phase B into the oil phase A and the oil phase B, stirring to obtain a microemulsion A and a microemulsion B, mixing the microemulsion A and the microemulsion B, quickly stirring to obtain a mixed reaction solution, and drying to obtain a finished product. Transferring the mixed reaction solution into a hydrothermal reaction kettle, sealing, heating to 100-120 DEG C, reacting for 1-10 hours, recovering to room temperature after the reaction is finished, centrifuging, collecting a product, washing and drying, thereby obtaining the antimony-based composite material which is used as a sodium-ion battery negative electrode material and has excellent electrochemical performance.

The invention discloses preparation of a bionic copper-based MOF nano-enzyme and application of the bionic copper-based MOF nano-enzyme in hydroquinone detection, and the bionic copper-based MOF nano-enzyme is prepared by the following method: dissolving terephthalic acid H2BDC and L-histidine His in N, N-dimethylformamide DMF to obtain a solution A; adding copper chloride CuCl2. 2H2O into the solution A obtained by C1, and stirring to form a uniform mixed solution; carrying out hydrothermal reaction on the mixed solution obtained from C2 for a certain time, centrifuging to obtain a solid precipitate, cleaning the solid precipitate, and drying to obtain the bionic Cu / His-MOF nano-enzyme; the invention also discloses an application of the sensor in hydroquinone detection. The bionic copper-based MOF nano-enzyme has the advantages of being simple and convenient to synthesize, high in substrate affinity, high in catalytic capacity and the like, and meanwhile, a rapid, sensitive and reliable HQ detection method is provided.

The invention discloses a household nano self-cleaning material containing rare earth elements and a preparation method of the household nano self-cleaning material, and aims at solving the problems that a traditional self-cleaning material is narrow in light response range, single in function, poor in durability, non-environment-friendly in preparation process and the like. The material comprises 5-15 parts of rare earth oxide, 50-70 parts of nano titanium dioxide, 10-20 parts of mesoporous silica, 3-8 parts of a fluorinated modifier and 2-5 parts of a bio-based adhesive. Wherein the rare earth elements are doped in titanium dioxide crystal lattices, so that the forbidden band width is reduced, the photocatalytic response range is widened to visible light, and the photocatalytic efficiency is remarkably improved. The preparation method of the material comprises the steps of precursor preparation, hydrothermal reaction, fluorination modification and coating forming, a low-temperature hydrothermal method, supercritical CO2 modification and a photocuring technology are adopted, and the material has the functions of self-cleaning, antibiosis and VOCs degradation, is suitable for various base materials such as household building materials, textiles and electric appliance surfaces, meets the composite requirements of modern home for health and environmental protection, and has wide application prospects. And the preparation process is green and pollution-free, and conforms to the sustainable development concept.

The invention discloses a method for preparing a carbon monoxide oxidation catalyst by using red mud and tungsten-molybdenum smelting slag, which comprises the following steps of: uniformly stirring and mixing the red mud and the tungsten-molybdenum smelting slag at a high speed, mixing with inorganic strong acid, and performing ultrasonic-assisted stirring to obtain acid leaching slag; the acid leaching residues are subjected to low-temperature plasma activating treatment and then microwave activating treatment, and microwave activated plasma residues are obtained; weighing tricalcium phosphate and microwave activated plasma slag, and uniformly stirring to obtain phosphorus-calcium doped activated slag; weighing an ammonium sulfide solution and the phosphorus-calcium doped activated slag, uniformly stirring, transferring the obtained sulfur-phosphorus-calcium doped activated slag into a hydrothermal reaction kettle, carrying out hydrothermal reaction, carrying out compression molding on the obtained hydrothermal composite material, and carrying out pyrolysis carbonization treatment in an inert gas atmosphere to obtain the phosphorus-calcium doped activated slag. The obtained pyrolysis composite material is soaked with a silane coupling agent solution and then roasted again, and the carbon monoxide oxidation catalyst is obtained. The catalyst prepared by the invention can realize efficient oxidation photocatalysis of carbon monoxide under the conditions of normal temperature and normal pressure.

The invention discloses a method for preparing a catalytic material by synergistically utilizing red mud and electrolytic manganese residues as well as a product and application thereof. The method comprises the following steps: mixing electrolytic manganese residues and red mud, uniformly stirring, adding ammonium chloride, stirring, adding a hydrochloric acid solution, stirring, roasting and grinding. And adding an auxiliary agent, uniformly stirring, adding water, granulating, standing, carrying out hydrothermal reaction, and roasting to obtain the catalytic material. The preparation process is simple, the technological process is brief, the needed core raw materials are only the red mud and the electrolytic manganese residues, and resource utilization of the red mud and the electrolytic manganese residues is efficiently achieved. The prepared catalytic material can quickly adsorb pollutants in waste liquid under the condition of no photocatalysis, and the removal effect on COD (Chemical Oxygen Demand), ammonia nitrogen, total phosphorus and heavy metal mercury can be further remarkably improved under the photocatalysis condition.

The invention relates to a preparation method of H12MDA with low trans-trans isomer content and a catalyst used in the preparation method. The catalyst is a supported catalyst and comprises a silicon-aluminum amorphous carrier and an active component, the silicon-aluminum amorphous carrier has a micropore, mesopore and macropore structure and is prepared by carrying out hydrothermal reaction on raw materials comprising an aluminum source and a silicon source in the presence of a template agent, and the template agent is selected from 4, 4-diaminodiphenyl-methane and 2, 4-diaminodiphenyl-methane or 2, 4-diaminodiphenyl-methane or 2, 4-diaminodiphenyl-methane or 2, 4-diaminodiphenyl-methane or 2, 4-diaminodiphenyl-methane or 2, 4-diaminodiphenyl-methane or 2, 4-diaminodiphenyl-methane. The catalyst is one or a combination of two of 1, 4-diaminodiphenylmethane. The catalyst is long in service life and excellent in stability, the yield of an H12MDA target product can be increased, the content of trans-isomers in the product is reduced, and the preparation process is also simple. The invention also provides a method for preparing H12MDA through MDA catalytic hydrogenation, and the method can improve the yield of the H12MDA product and obviously reduce the content of trans-isomers in the product.

The invention relates to the technical field of high-performance polyester fibers, particularly belongs to the patent classification number D01F6 / 00, and discloses a high-moisture-permeability polyester fiber and a preparation method thereof. Comprising the following steps: carrying out hydrothermal reaction on magnesium nitrate hexahydrate and aluminum nitrate nonahydrate to prepare layered double hydroxide nanosheets; then, sodium alginate is prepared into a solution, and the solution is cross-linked with calcium chloride to obtain alginic acid aerogel powder; then, carrying out ultrasonic oscillation dispersion on the two substances in deionized water, and cooling and drying to obtain composite aerogel; then, the composite aerogel and polyethylene glycol 4000 are subjected to melt blending and granulation in a double-screw extruder, and functional master batches are obtained; and finally, mixing the functional master batch with polyethylene glycol terephthalate slices, performing melt spinning at a specific spinning temperature and speed, and performing cooling forming and drafting to obtain the high-moisture-permeability polyester fiber. According to the method, through material compounding and process control, the moisture permeability of the polyester fiber is effectively improved, and the method has a good application prospect in the textile field.