12449 results about "Microsphere" patented technology

The present invention relates to the technical field of battery separators and provides a coated modified composite separator, a preparation method thereof and a coating slurry for preparing the composite separator. The coated modified composite separator includes a base membrane and a coating, wherein the coating is coated on either any one side or both sides of the base membrane, and the coating comprises at least two of the following: b2.1 high temperature resistant polymer microspheres, b2.2 high temperature resistant polymer nanofibers, and b2.3 inorganic particles. The coating in the modified composite separator of the present invention notably enhances the thermal dimensional stability of the base membrane, decreases the areal density of the composite separator, boosts the battery's energy density, lowers the probability of occurrence of thermal runaway, and improves battery safety.

The invention discloses immobilized bacteria-algae microspheres, a preparation method thereof and application of the immobilized bacteria-algae microspheres in removal of ammonia nitrogen and total phosphorus in aquaculture water. The preparation method comprises the following steps: adding polyvinyl alcohol and sodium alginate into deionized water, heating and sterilizing while fully dissolving polyvinyl alcohol and sodium alginate to obtain an embedding medium; adding the iron modified biochar powder into a mixed solution of chlorella and photosynthetic bacteria for adsorption to obtain a bacteria-algae-biochar mixture; adding the bacteria-algae-biochar mixture into an embedding medium to form a gel solution; adding the gel solution into a cross-linking agent for cross-linking, and after cross-linking, separating a solid and cleaning to obtain immobilized bacteria-algae microspheres; the preparation method of the iron-modified biochar powder comprises the following steps: adjusting the pH value of a mixed solution containing biochar powder, Fe < 2 + > and Fe < 3 + > to 9.5-10.5, carrying out heat preservation stirring at 75-85 DEG C for 1-5 hours, carrying out solid-liquid separation, taking a solid, washing, and drying to obtain the iron-modified biochar powder.

The invention belongs to the field of petrochemical engineering, and particularly relates to a litchi-shaped hollow polymer microsphere as well as a preparation method and application thereof. The preparation method comprises the following steps: preparing litchi-shaped polymer hollow microspheres by adopting an inverse emulsion polymerization method, uniformly dispersing a water-soluble initiator and a water-soluble monomer solution in an oil-phase continuous phase under the emulsification action of a surfactant, and initiating polymerization in a water-in-oil reaction system through modified mesoporous microspheres loaded with metal copper quantum dots. Because the initiation rates of the water-soluble initiator and the metal copper quantum dots are different, a litchi-shaped structure is presented on the surface of the microsphere, and then the template is etched to form the litchi-shaped hollow-structure microsphere. The hollow structure in the microsphere improves the elastic deformation capacity of the microsphere, and the litchi-shaped appearance of the microsphere can play a better plugging effect, so that the dual functions of'displacement 'and'plugging' of the microsphere are really realized.

The invention belongs to the technical field of nano oil displacement, and particularly relates to rambutan-shaped polyacrylamide nanospheres as well as a preparation method and application thereof. The microspheres prepared by taking PAMAM as a matrix to load the copper quantum dots to initiate acrylamide polymerization have smaller particle sizes. The spherical particle characteristic of the metal copper quantum dots leads to non-uniform polymerization rate, formation of irregular morphology of the nanospheres can be promoted, and finally the rambutan-shaped polyacrylamide nanospheres are prepared. The nanosphere has good hydration expansion performance, the swept volume of injected water is increased, and the effect of deep profile control is achieved. Moreover, the surface of the polyacrylamide nanosphere presents the shape of rambutan, so that the expansion and fracture phenomenon after water absorption can be avoided, the interaction force between the nanospheres is enhanced, and the plugging effect is better. Meanwhile, as the nanospheres absorb water and swell, the swelled antennas play a role in crosslinking the nanospheres, and a better plugging effect can be achieved.

The invention belongs to the field of petrochemical engineering, and particularly relates to a temperature-resistant salt-resistant hollow polymer microsphere as well as a preparation method and application thereof. The preparation method comprises the following steps: preparing polymer hollow microspheres by adopting an inverse emulsion polymerization method, initiating polymerization in a water-in-oil reaction system through modified mesoporous microspheres loaded with metal copper quantum dots, and selectively etching off a template by utilizing hydrofluoric acid, so as to form a hollow structure. The elastic deformation capacity of the microspheres is greatly improved through the hollow structure, when the pressure in front of the blocked pore throat is increased to a certain value, the polymer microspheres can be easily extruded and deformed due to the extrusion effect, so that the polymer microspheres break through the pore throat like an amoeboid, certain negative pressure can be formed between the pore throat and surrounding rocks at the moment, and the pore throat is blocked. The injected water can carry the remaining oil to quickly pass through the small pore throats, and the microspheres can recover the form after passing through the pore throats and continue to move forwards, so that the oil displacement rate is increased.

The invention belongs to the technical field of nano materials, and particularly relates to a burr-shaped polyacrylamide nanosphere as well as a preparation method and application thereof. According to the invention, sulfhydrylated PAMAM is used as a matrix to load copper quantum dots to initiate polymerization of acrylamide monomers, so that the nanoscale polymer microspheres are prepared. The PAMAM has high geometric symmetry, so that dense sulfydryl functional groups are introduced to the surface of the PAMAM and can form stronger coordinate bonds with the metal copper quantum dots, and the quantum dots are uniformly fixed on the outer surface of the PAMAM. And due to the characteristics of the spherical particles, the surface polymerization rate of the sulfhydrylation PAMAM loaded with the metal copper quantum dots is nonuniform, and formation of burr-shaped nanosphere morphology is promoted. After the burr-shaped nanospheres absorb water and expand, the effect of cross-linking and interlocking to improve the plugging efficiency can be achieved, the burr-shaped tip structure can achieve the effect similar to a brush, the acting force between oil drops and rock and the flowing resistance of crude oil in a reservoir are reduced, and therefore the recovery efficiency is improved.

The invention discloses a carbon-silicon negative electrode material and a preparation method and application thereof, and the preparation method comprises the following steps: S1, carrying out mixed reaction on a lithium source compound, a lanthanum source compound and a titanium source compound to obtain a mixed reactant; mixing the mixed reactant with a carbon source compound, and dispersing and emulsifying to obtain element-doped microspheres; s2, carbonizing the element-doped microspheres in the step S1 to obtain carbides, and activating the carbides to obtain a porous carbon material; and S3, performing silicon deposition on the porous carbon material in the S2 to obtain silicon deposition porous carbon, and performing carbon deposition on the silicon deposition porous carbon to obtain the carbon-silicon negative electrode material. The carbon-silicon negative electrode material disclosed by the invention is high in lithium ion transmission rate, the problem of poor electronic conductivity of silicon is solved, and the electrical property of a battery can be effectively improved.

The invention discloses a culture method of anaerobic ammonia oxidation granular sludge with a polydopamine modified charcoal-loaded Fe-Cu sodium alginate microsphere kernel, which comprises the following steps: modifying charcoal by using polydopamine, then carrying out Fe-Cu ion loading, finally preparing sodium alginate microspheres, and taking the prepared sodium alginate microspheres as the kernel to prepare the anaerobic ammonia oxidation granular sludge with the polydopamine modified charcoal-loaded Fe-Cu sodium alginate microsphere kernel. And co-culturing the sodium alginate microspheres and activated bacillus DMF-4 in an oxygen-free environment, continuously culturing for 3 weeks, and collecting by using a gravity settling or centrifugal method to obtain the anaerobic ammonium oxidation granular sludge with the sodium alginate microsphere core. The sodium alginate microspheres serving as the core provide large density and good morphological support for sludge particles, the problem of sludge bulking is avoided, and the settling performance is improved. According to the present invention, the sludge anti-shearing performance is improved, the adsorption capacity of the slowly released and continuously slowly released iron ions on organic matters, ammonia nitrogen and heavy metals is enhanced, the sewage treatment effect is improved, and the iron ions are the biodegradable material so as not to cause secondary pollution in the use process.

The invention discloses injectable sodium hyaluronate-silk fibroin composite hydrogel and a preparation method and application thereof.The injectable sodium hyaluronate-silk fibroin composite hydrogel is composed of sodium hyaluronate composite gel particles and a sodium hyaluronate solution, and the sodium hyaluronate composite gel particles comprise silk fibroin sponge microspheres and sodium hyaluronate gel particles; the silk fibroin sponge microspheres are loaded on the sodium hyaluronate gel particles, the silk fibroin sponge microspheres are physical crosslinking microspheres, the particle size D50 is 10-30 [mu] m, and the particle size D90 is within 100 [mu] m; the sodium hyaluronate gel particles are chemical cross-linked particles, the particle size D50 is 150-300 microns, and the particle size D90 is within 800 microns. After the sodium hyaluronate gel particles are in contact with tissues, sodium hyaluronate is preferentially degraded, and silk fibroin exposed in the degradation process has better degradation resistance and an effect of stimulating generation of collagen fibers, so that in-situ fixation of the composite gel particles is realized, and an instant and lasting filling effect is achieved; the material is a safe and effective medical beauty filling material.

An integrated carbon honeycomb structure material and its preparation method are disclosed, belonging to the field of carbon materials technology. Based on a co-sacrificial template low-temperature pyrolysis strategy, the target material can be obtained through three main steps: preparation of a metal salt-colloidal microsphere template precursor, precursor pressing and molding, and subsequent calcination and carbonization. This technology has the characteristics and advantages of simple preparation process, regular and controllable macroscopic structure of the sample (such as shape, area, and thickness), rich and tunable chemical composition, and three-dimensional interconnection of graphene carbon matrix. It has great application potential in many fields such as electrochemical energy storage, catalysis, gas separation, adsorption, and electromagnetic shielding.

The invention discloses a preparation method of a chitosan-sodium alginate-diatomite composite adsorbent. The preparation method comprises the following steps: (1) carrying out calcination pretreatment on diatomite; (2) dissolving sodium alginate powder in water; (3) adding the calcined diatomite into a sodium alginate solution to prepare a mixed solution a; (4) adding CaCl2 into an acetic acid solution for dissolving; (5) adding chitosan powder into a CaCl2 solution, and uniformly stirring to obtain a mixed solution b; (6) dropwise adding the mixed solution a into the mixed solution b for crosslinking to prepare SA / DM / CS composite gel balls; and (7) washing the gel balls with water for several times, repeatedly freezing and thawing for several times, and drying to obtain the composite adsorbent. The composite adsorbent is prepared by dropwise adding the sodium alginate solution containing the calcined diatomite into the mixed solution of the chitosan and the CaCl2, so that the problem of low mechanical strength of single sodium alginate hydrogel is solved, and the recycling stability of the hydrogel microsphere adsorbent is improved.

The invention provides anti-cracking and anti-seepage high-performance concrete, which relates to the technical field of concrete and comprises Portland cement, aggregate, a high-activity mineral admixture, a calcium-magnesium composite expanding agent, nano silicon dioxide particles, a microcapsule-packaged sodium silicate and calcium lactate solution, paraffin / expanded graphite composite phase change microspheres, steel fibers, PVA fibers and nano cellulose. The self-repairing concrete has the characteristics that the anti-cracking performance is comprehensively improved, the anti-seepage grade is broken through, the self-repairing capability is long-acting, the construction adaptability is enhanced, and the like.

The invention discloses an injection filler and a preparation method and application thereof, the filler is polycaprolactone particles, the polycaprolactone particles are spherical particles, the particle size of the spherical particles is 20-100 [mu] m, and the polycaprolactone particles have rough surfaces or unsmooth surfaces. The polycaprolactone microspheres have rough surfaces or unsmooth surfaces, so that the contact area with cells is increased, the adhesion ability and residence time of the cells are improved, the affinity of the polycaprolactone microspheres is improved, and the growth of collagen can be stimulated and accelerated. In the preparation process, the dosage of each component is scientifically screened, and on the basis of controlling the viscosity of a water-phase solution, the spherical polycaprolactone particles which are regular, rough in surface and uniform in particle size are obtained in cooperation with a rapid membrane emulsification method.

The invention belongs to the technical field of flexible sensors, and relates to a flexible temperature and pressure dual-mode sensor and array equipment. The temperature and pressure dual-mode sensor comprises a first flexible substrate, a force-sensitive conductive layer, an interdigital electrode layer, a second flexible substrate, a counter electrode layer and a temperature-sensitive layer which are sequentially stacked; the force-sensitive conductive layer comprises a microstructure layer stacked on the first flexible substrate and a conductive layer stacked on the microstructure layer; wherein the material of the microstructure layer comprises flexible resin and expanded microsphere powder, the interior of the microstructure layer is provided with a microsphere micropore structure formed by expansion of expanded microspheres, and the surface of the microstructure layer is provided with a plurality of protrusions and recesses; the temperature-sensitive layer is connected between the two counter electrodes of the counter electrode layer, and the temperature-sensitive layer is made of graphene.

Disclosed in the present invention are a rubber filler, a rubber composite material containing same, a preparation method therefor, and the use thereof. The rubber filler comprises polydivinylbenzene microspheres and polydopamine-modified white carbon black loaded onto the polydivinylbenzene microspheres, the mass ratio of the polydivinylbenzene microspheres to the polydopamine-modified white carbon black being 1:(0.5-20). The rubber composite material comprises raw rubber of a solution-polymerized rubber and the rubber filler, the dosage of the rubber filler being 10-60 wt% of the dry-basis mass of the raw rubber of the solution-polymerized rubber. The present invention uses as the filler the polydivinylbenzene microspheres onto which the polydopamine-modified white carbon black is loaded, thereby solving the problems that white carbon black is prone to agglomeration and the binding force between white carbon black and rubber is poor. The rubber composite material obtained by the present invention is suitable for manufacturing green tires.

The invention discloses ultra-high performance concrete and a preparation method thereof. The ultra-high performance concrete comprises the following components in percentage by mass: 15%-25% of cement, 3%-6% of nano SiO2, 30%-35% of fly ash or steel slag powder, 35%-40% of recycled aggregate, 1%-4% of fiber, 0.5% of a microbial remediation agent and 1%-3% of nano TiO2. The preparation method comprises the following steps: S1, pretreating the recycled aggregate; and S2, packaging the microbial remediation agent: mixing the bacillus pasteurii spores with calcium lactate, and wrapping the mixture in calcium phosphate microspheres. S3, step-by-step stirring; S3.1, dry mixing: uniformly stirring the cement, the fly ash, the nano SiO2, the nano TiO2 and the recycled aggregate; s3.2, wet mixing is carried out, water solution fibers containing the polycarboxylic acid water reducing agent are added, uniform stirring is carried out, and the water-binder ratio of the water solution containing the polycarboxylic acid water reducing agent is 0.18; s3.3, final mixing: adding the packaged microbial remediation agent, and uniformly stirring; and S4, directional curing: performing steam curing at 80 DEG C for 48 hours, performing ultraviolet irradiation, and performing constant-temperature and constant-humidity curing for 7 days. The ultra-high performance concrete has the effects of low cost, low carbon emission, multi-function integration and repeatable crack self-repairing.

The invention provides a reinforced pouring type semi-flexible pavement and a construction method thereof, modified magnetic particle micron Fe3O4 (at) SiO2 mesoporous microspheres are doped into a cement-based grouting material, an anti-dispersing agent is doped, and the cement-based magnetic grouting material is prepared. Meanwhile, neodymium iron boron waste is doped into the porous asphalt mixture to serve as a magnetic material to provide a magnetic field, and when the cement-based magnetisable grouting material is injected into the porous asphalt mixture, the magnetic grouting liquid can move directionally and be adsorbed at fixed points under the action of the magnetic field by means of the magnetic adsorption effect; the grouting material for the semi-flexible pavement has the advantages that the filling rate of the grouting material is obviously improved, the bonding performance of an asphalt and cement material interface is obviously improved, the generation of interface cracks is effectively reduced, and the service life of the semi-flexible pavement is prolonged. The semi-flexible pavement cement provided by the invention has good compressive strength, breaking strength, tensile strength, bonding strength, fluidity, dry shrinkage rate and the like, and is an ideal base fluid as a cement-based magnetic grouting fluid.

The invention provides a doped electrode material based on porous silicon carbon and a preparation method thereof.The preparation method comprises the steps that a resin base material is smashed and then put into a high-temperature furnace to be subjected to a carbonization process, the carbonization temperature ranges from 300 DEG C to 1500 DEG C, an alkaline additive, a phosphorus source material and a nitrogen source material are sequentially added in the temperature interval, and phosphorus-nitrogen co-doped porous carbon is obtained; the preparation method comprises the following steps: mixing a silicon dioxide microsphere template into phosphorus-nitrogen co-doped porous carbon, adding a first coating carbon source to carry out first coating treatment, and etching the silicon dioxide microsphere template by using an etching solution to obtain a prefabricated object with a cavity structure; and putting the prefabricated object with the cavity structure into a fluidized bed reactor, introducing silicon source gas and a surface activation auxiliary agent, carrying out deposition at 400-550 DEG C, and then adding a second coating carbon source to carry out secondary coating treatment, thereby obtaining the doped electrode material based on porous silicon carbon. Therefore, the expansion coefficient of the electrode material is effectively reduced, and the rate capability is improved.

The invention relates to the technical field of fertilizer preparation, and discloses an ecological balance fertilizer for yield increase and disease resistance of peanuts and a preparation method of the ecological balance fertilizer. The preparation process comprises the following steps: constructing a PLGA core containing trichoderma harzianum spores and magnesium carbonate through a micro-fluidic chip low-temperature water-in-oil emulsion method; coating bacillus amyloliquefaciens and potassium silicate with ultraviolet-induced cross-linked temperature-sensitive hydrogel to form a middle layer; loading rhizobium by using aminated mesoporous S < iO2 >, and spraying and assembling an enzyme response shell through a fluidized bed; finally, the hydroxyapatite nanorod and a binder are combined and granulated and formed through a fluidized bed. Precise controlled release of functional bacteria and nutrients is realized by constructing a temperature-sensitive-enzyme response type release system, and the activity of a fungicide is guaranteed to be preserved by virtue of trichoderma harzianum-rhizobium synergistic interaction and silicon bond linkage soil remediation in combination with a low-temperature fluidized bed process, so that a'fertilizer-bacterium-soil 'ecological cycle system is finally constructed.

The invention discloses a method for preparing a heat-expanding epoxy foam with electromagnetic shielding properties. In the process of processing the heat-expanding epoxy foam with epoxy resin as a substrate, before curing and foaming treatment, a conductive filler with heat-expanding microspheres grafted on the surface is added to the system. After the processing is completed, the heat-expanding epoxy foam with electromagnetic shielding properties is obtained; the minimum foaming temperature of the heat-expanding microspheres is 110-120°C, and the maximum foaming temperature is 140-150°C; the temperature of the curing and foaming treatment is 15-25°C higher than the minimum foaming temperature of the heat-expanding microspheres; during the curing and foaming treatment, the viscosity of the epoxy resin is less than 1Pa·s. The method of the invention solves the problem that the conductive filler is difficult to disperse in the resin matrix innovatively by introducing heat-expanding microspheres on the surface of the conductive filler. The obtained heat-expanding epoxy foam with electromagnetic shielding properties has good electromagnetic shielding performance and high use value and economic benefits.

The invention discloses a high-bonding-strength flame-retardant composite current collector base film and a preparation method thereof. The high-bonding-strength flame-retardant composite current collector base film is prepared from the following raw materials in parts by weight: 100 parts of PP resin, 1.5 parts of a lubricant, 0.8 part of an antioxidant and 16 parts of reinforced flame-retardant composite particles, the reinforced flame-retardant composite particles are prepared by the following steps: S1, preparing amidated porous carbon microspheres; s2, compounding the amidated porous carbon microspheres with mica powder to prepare a composite carrier; s3, loading a flame retardant to prepare a flame-retardant compound; s4, in-situ grafting of maleic anhydride grafted polypropylene is carried out, and the reinforced flame-retardant composite particles are obtained. By adding the reinforced flame-retardant composite particles into the PP resin, the flame retardance and mechanical strength of the PP-based composite current collector base film and the interface bonding force between the PP base film and the metal conductive layer can be comprehensively improved.

The invention relates to the technical field of coatings, in particular to a mesoporous thermal insulation coating with an infrared heat shielding function and a preparation method thereof.The preparation method comprises the steps that polyurethane-organic silicon emulsion is selected as a base material of the coating, chain extension is conducted on polyurethane prepolymer through a hydroxyl-terminated ternary flame-retardant chain extender, and high-flame-retardant and self-repairing polyurethane-organic silicon emulsion is prepared; hollow silicon dioxide microspheres are selected as a mesoporous material, and the mesoporous material is prepared by a two-step method of performing hydrolytic condensation on phenyltrimethoxysilane and then calcining to remove impurities. The preparation method comprises the following steps: modifying hollow silicon dioxide microspheres to prepare composite hollow silicon dioxide microspheres as a filler, growing cesium-doped tungsten bronze nanoparticles on the surfaces of the hollow silicon dioxide microspheres in situ by adopting a solvothermal method to obtain pretreated hollow silicon dioxide microspheres, and treating the pretreated hollow silicon dioxide microspheres with an epoxy silane coupling agent to obtain epoxidized hollow silicon dioxide. And then grafting a hydroxyl-terminated ternary flame-retardant chain extender by utilizing an epoxy-hydroxyl reaction.

The invention relates to the technical field of detection kits, in particular to a detection kit for neutrophil gelatinase-associated lipocalin and a preparation method of the detection kit. The invention provides a detection kit for neutrophil gelatinase-associated lipocalin. The detection kit comprises an independently packaged reagent R1 and an independently packaged reagent R2, the reagent R1 comprises an HBR series specific blocking agent; the reagent R2 comprises carboxyl latex microspheres coupled with an NGAL antibody; the carboxyl content of the carboxyl latex microspheres is greater than 100 [mu] eq / g, and the particle size is 100-400 nm. According to the kit, an HBR series specific blocking agent is used as a component of the reagent R1, so that endogenous interference is reduced, and false positive and negative detection results of a sample are avoided. Furthermore, the latex with proper particle size is selected to be coupled with the polyclonal antibody, and the sealing condition is optimized, so that the method has the advantages of wide linearity, good analysis sensitivity, simplicity in operation, controllable batch difference and controllable cost.

The invention discloses a low-density low-viscosity polyurethane pouring sealant containing plastic microspheres and a preparation method thereof. The pouring sealant comprises a component A and a component B, the component A comprises the following components in parts by weight: 25-40 parts of castor oil polyol and 9-24 parts of modified castor oil polyol containing a benzene ring structure; 15 to 22 parts of polyester polyol; 10 to 17 parts of plastic microspheres; 12-16 parts of a liquid flame retardant; 0.2 to 0.3 part of an amine catalyst; 0.3 to 0.4 part of a metal catalyst; 0.1 to 0.4 part of a coupling agent; 0.1 to 0.4 part of a defoaming agent; 2-6 parts of a dewatering agent; wherein the ester polyol is Zibo charge beauty CM-1830 polyester polyol. The two-component polyurethane pouring sealant with low viscosity, low density and better mechanical property is prepared by selecting the polyester polyol in the component A and selecting and proportioning other components.

The invention provides a carbon-coated current collector and a preparation method and application thereof. The carbon-coated current collector comprises a current collector base material and a carbon-coated layer on at least one side of the current collector base material; the carbon coating layer comprises a conductive agent, a binder and a cross-linking agent; the binder comprises a polyacrylic acid polymer and polystyrene microspheres. According to the carbon-coated current collector provided by the invention, the cohesive force between the current collector and an electrode active material layer is improved through the synergistic effect of the polyacrylic acid polymer, the polystyrene microspheres and the cross-linking agent, the interface resistance is also reduced, and meanwhile, the electrochemical performance of a pole piece is improved.

According to the mullite castable preparation method based on comprehensive utilization of the secondary aluminum ash nonferrous smelting slag, components are regulated and controlled by controlling the molar ratio of Al2O3 to SiO2, so that porous light mullite stably falls into a mullite phase region, and generation of excessive corundum phases is avoided. PMMA microspheres, corn flour, carbonized rice husks and SiO2 coated calcium carbonate composite pore-forming agent systems are adopted, and a layered slurry formula, gradient slip casting and segmented sintering processes are combined, so that the porosity and strength distribution are accurately regulated and controlled, and low-temperature sintering and amorphous phase change control are realized. By optimizing the grading of the porous light mullite aggregate and adding the homologous fine powder, the bonding strength and compressive strength of the castable are improved. And finally, the surface of the castable is coated with a compact mullite coating, so that the porosity is reduced, and the erosion resistance, corrosion resistance and stripping resistance are remarkably improved. The obtained castable has the advantages of light weight, high temperature resistance, high strength, low cost and excellent thermal stability and erosion resistance.

The invention discloses a method for preparing lubricating oil microspheres based on a microfluidic technology. The method comprises the following steps: preparing an external phase solution, an intermediate phase solution, an internal phase solution and a collection solution; firstly, the internal phase solution is introduced into the micro-fluidic chip, and after the flow of the internal phase solution is stable, the intermediate phase solution is introduced into the micro-fluidic chip to be sheared with the internal phase solution to form nuclear layer liquid drops. After the core layer liquid drops are generated stably, the external phase solution is introduced into the micro-fluidic chip to be sheared with the core layer liquid drops, so that the external phase solution wraps the outer layer of the core layer to form a shell layer with a core-shell structure, and then the double liquid drops are dropped into a collecting solution containing glutaraldehyde to be crosslinked and cured to form the chitosan lubricating oil microspheres. The chitosan lubricating oil microsphere has the following beneficial effects that the lubricating oil is wrapped in the microsphere through a microfluidic technology, so that the chitosan lubricating oil microsphere is of a core-shell structure, and when the lubricating oil is needed, the lubricating oil in the microsphere is released to improve the friction performance of parts.

The invention belongs to the technical field of active substance extraction, and particularly relates to low-fat, low-cost, high-purity and high-quality elastin peptide and a preparation method thereof. The alkali liquor and the sodium carbonate solution are mixed and matched for use, the overall concentration is low, the degreasing agent is more environmentally friendly, and the degreasing effect is better by using the microwave heating technology. The protease is immobilized by using the microspheres, and the enzyme preparation can be fully recycled and repeatedly used, so that the production cost is greatly reduced. The elastin enzymatic hydrolysate is separated, purified and refined by using an ion exchange resin tandem chromatography technology, other impurities are efficiently removed, and the prepared elastin peptide is relatively high in purity. The high-voltage pulsed electric field technology (PEF) is used for sterilization, the sterilization effect is better, the influence of a traditional heat sterilization mode on the color, luster and taste of the product is avoided, and the quality of elastin peptide is better maintained.

The invention discloses a preparation method and application of a conjugated microporous polymer microsphere filler with a hollow structure, silicon dioxide nanospheres are placed in an organic solvent, after uniform ultrasonic dispersion, 1, 3, 5-triacetylene benzene and 2, 6-dibromo-3-aminopyridine are added, after a catalyst is added, a stirring reaction is carried out in a nitrogen atmosphere to obtain yellow powder, and the yellow powder is dried to obtain the conjugated microporous polymer microsphere filler with the hollow structure. Etching with hydrofluoric acid, cleaning the treated product until the filtrate is transparent and colorless, and drying in vacuum to obtain the conjugated microporous polymer microsphere filler with the hollow structure. Nanoscale holes are formed in the hollow-structure conjugated microporous polymer microsphere filler, so that the hollow-structure conjugated microporous polymer microsphere filler has good heat insulation performance and good heat stability at high temperature, and can be used as a heat-resistant performance enhancing filler.

The invention relates to the technical field of microorganism application, in particular to a compound microorganism-based water purifying agent for aquaculture and a preparation method of the compound microorganism-based water purifying agent for aquaculture. Modified compound microorganisms, carboxylated hollow silicon dioxide microspheres and the compound microorganisms are combined to obtain microspheres A, the modified composite microorganism is prepared by taking modified chitosan as a shell and a composite microorganism as a core, nano titanium dioxide particles are immobilized by silicon dioxide microspheres to obtain microspheres B, activated charcoal and bentonite are mixed to obtain microspheres C, and the modified composite microorganism is prepared by compounding the microspheres A, the microspheres B and the microspheres C. The water purifying agent for aquaculture based on the compound microorganisms can purify water, effectively remove organic pollutants and heavy metals in water and provide good water quality conditions for aquaculture, can improve the stability and durability of the compound microorganisms and reduce the putting frequency of the water purifying agent, and has wide application prospects.