The invention discloses a
lithium ion battery
silicon-carbon composite negative
electrode material and a preparation method and application thereof.The
lithium ion battery
silicon-carbon composite negative
electrode material comprises a rigid three-dimensional
porous carbon skeleton, elastic carbon and nanometer
silicon, and three-dimensional holes are formed in the rigid three-dimensional
porous carbon skeleton; three-dimensional holes formed by the rigid three-dimensional
porous carbon skeleton are filled with the elastic carbon and the
nano silicon, the rigid three-dimensional porous
carbon skeleton is obtained by carbonizing
polyurethane foam with a through three-dimensional porous structure, and the elastic carbon is obtained by carbonizing a
carbon source. The rigid three-dimensional porous
carbon skeleton has a submicron-scale three-dimensional through hole structure, and the pore channel structure is filled with elastic carbon and
nano silicon. Through the synergistic confinement effect of the rigid three-dimensional
carbon skeleton and the elastic carbon, the
volume expansion / shrinkage problem of the
nano silicon is buffered, and the elastic carbon cannot be broken due to the
volume change of the nano silicon. The
lithium ion battery prepared by the method has the advantages of high specific capacity,
cycling stability and the like, and has a potential application prospect in high-specific-energy lithium ion batteries.