5278 results about "Transition metal" patented technology

The invention relates to the technical field of flue gas treatment, in particular to a sintering flue gas denitration and dust removal integrated post-CO removal method which is specifically completed through cooperation of a sintering flue gas treatment system, and the sintering flue gas treatment system comprises a GGH heat exchanger, a desulfurization reactor, a denitration dust remover and a CO reactor which are sequentially communicated through pipelines. The CO catalyst module is a transition metal oxide CO catalyst; the cleaning device is used for cleaning ash of the CO catalyst module; the ammonia gas is sprayed into the outlet of the desulfurization reactor, so that ammonia escape is reduced, poisoning of the CO catalyst module is reduced, the catalytic efficiency of the CO catalyst module is improved, and the service life of the CO catalyst module is prolonged; the CO catalyst module is regularly subjected to air blowing and back blowing in a closed area, so that impurities such as carbon deposition on the CO catalyst module are cleaned, more active sites are exposed, the service life of the CO catalyst module is prolonged, and the investment and operation cost is reduced by adopting a transition metal oxide CO catalyst.

The invention belongs to the technical field of energy storage materials, and particularly relates to a high-entropy oxide Fe0. 2Co0. 2Ni0. 2Cu0. 2Zn0. 2O and an ultrafast synthesis method and application thereof. According to the preparation method, ferroferric oxide, cobalt oxide, nickel oxide, copper oxide and zinc oxide with equal molar ratio are adopted as direct synthesis raw materials, toxic gases such as chlorine and nitrogen dioxide generated in the synthesis process of a metal salt precursor are avoided, and the uniformly distributed single-phase high-entropy oxide is synthesized in an ultrafast manner within 10 seconds by using a Joule heating technology; the synthesized high-entropy oxide is used as a lithium ion battery negative electrode material, and shows more excellent electrochemical performance and cycling stability compared with other high-entropy oxides prepared from transition metals with different proportions; in the preparation process, extra additives are not needed, operation is easy, the synthesis speed is high, the yield is high, element distribution is uniform, and the method has the advantages of being low in cost, high in efficiency and free of pollution and has the industrialization prospect.

Provided is a polishing composition capable of realizing high polishing removal rate on an object to be polished. The polishing composition provided by this invention is used for polishing an object to be polished. The polishing composition includes water, sodium permanganate as an oxidant, and a transition metal salt different from the oxidant. The polishing composition includes the oxidant in an amount of more than 10 wt %. In some preferable embodiments, the transition metal salt is an oxo-transition metal salt, or a multi-nuclear transition metal complex including a transition metal and one or both of oxygen and hydrogen. The polishing composition can be preferably used in polishing an object formed of a high-harness material having a Vickers hardness of 1500 Hv or higher.

The invention discloses a synthetic method of a water soluble ultraviolet light absorber BP-9. The method mainly comprises the following process steps: (1) carrying out methylation on the main raw materials of 2, 2', 4, 4'-tetrahydroxyl benzophenone, a transition metal salt catalyst and a mixed solvent which is prepared from dichloroethane and anhydrous ethanol in equal parts by weight to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone; (2) carrying out sulfonation reaction on the main raw materials of methylate, sulfamic acid and C1-C3 halohydrocarbon to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone-5, 5'-disulfonic acid; and (3) carrying out neutral reaction on the main raw materials of sulfonated product, inorganic base and ethanol water to finally obtain the BP-9 product. The synthetic method disclosed by the invention is few in reaction step, low in cost, high in product purity and stable in quality, and raw materials are easily available.

The invention belongs to the field of battery materials, and discloses a high-entropy high-nickel positive electrode material which comprises a base material LiNixCoyMzO2, a base further comprises a lithium-site doping element and a nickel-site doping element, the surface of the base is coated with an island-shaped coating layer, and the island-shaped coating layer is a nano metal oxide layer. The preparation method comprises the following steps: uniformly mixing a high-nickel hydroxide precursor, a lithium source, a compound containing an element A and a compound containing an element B, carrying out two-stage sintering, mixing with a metal oxide containing an element C and a metal oxide containing an element D, and sintering to obtain the high-entropy high-nickel positive electrode material. Lithium doping in a bulk phase of the high-entropy high-nickel positive electrode material can improve the electronic conductivity of a single crystal material, increase the interlayer spacing of transition metal and inhibit lithium and nickel positive ions from being mixed, and nickel doping can improve the structural stability and thermal stability of the material, inhibit irreversible phase change of H2-H3 and stabilize lattice oxygen of the material; the doping modification of the two sites further improves the performance of the material.

The invention provides a preparation method and application of a cobalt-based catalyst, and relates to the technical field of chemical production. The cobalt-based catalyst includes cobalt, a transition metal element, and a Group IIIA element other than aluminum. Transition metal elements and IIIA group elements except aluminum are introduced into the cobalt-based catalyst, and the electronic structure and active sites of the cobalt-based catalyst are changed. The method not only can cooperate with catalytic reaction and promote the formation and conversion of intermediates, but also can enhance the adsorption and activation capability on substrates, reduce the reaction activation energy and guide the reaction to be carried out along a specific path. Finally, the effect of efficiently harvesting the 2-methyl pentamethylene diamine and the 3-methylpiperidine at the same time is achieved.

The invention discloses a titanium dioxide nanotube confinement catalyst for methane dry reforming and a preparation method and application thereof, a transition metal element is used as an active phase, the titanium dioxide nanotube confinement transition metal element catalyst is modified by a rare earth metal element, and the weight of the methane dry reforming catalyst is used as a reference. The content of the transition element is 1-10%, preferably 1-5%, and the content of the rare earth element is 1-5%, so that the problems of activity reduction and poor stability caused by easy generation of carbon deposition of the methane dry reforming catalyst in the prior art are solved.

The invention discloses an electrocatalyst for acidic oxygen evolution reaction as well as a preparation method and application of the electrocatalyst, and belongs to the technical field of electrolyzed water. The preparation method of the electrocatalyst for the acidic oxygen evolution reaction comprises the following steps: growing a transition metal oxide on a conductive substrate in situ to obtain a transition metal oxide carrier; the transition metal oxide carrier is subjected to plasma treatment and then placed in a precious metal salt solution for a cation exchange reaction, and the electrocatalyst is obtained. The electrocatalyst prepared by the invention has extremely low initial overpotential (187mV) when a water electrolysis reaction is carried out in a 0.5 M H2SO4 solution, has no obvious performance degradation in a continuous acidic water electrolysis process for 4500h, shows very high operation stability, and has great application potential in the aspects of replacing a commercial RuO2 / IrO2 catalyst and reducing electrode preparation cost and acidic water electrolysis.

The invention discloses a preparation method of metal ion liquid modified co-doped biochar and application of the metal ion liquid modified co-doped biochar in tetracycline removal, and belongs to the technical field of water pollution treatment and adsorption material preparation. The preparation method comprises the following steps: mixing a biochar precursor with a metal ion liquid containing transition metal and a heteroatom source, and carrying out high-temperature carbonization to obtain the metal ion liquid modified co-doped biochar. Multiple modification of the biochar is realized through one-time high-temperature carbonization (transition metal elements and heteroatoms are introduced into a biochar skeleton, abundant surface active sites are provided, and the specific surface area and pore volume of the biochar are improved), so that the adsorption performance of the biochar on tetracycline antibiotics is remarkably improved. The preparation method is simple in process, raw materials are easy to obtain, and the obtained metal ion liquid modified co-doped biochar has excellent adsorption performance on antibiotic pollutants such as tetracycline and is suitable for purification treatment of water polluted by antibiotics.

A modified nickel-based positive electrode material comprises a nickel-based positive electrode material matrix and a doping element doped in the nickel-based positive electrode material matrix, the electronegativity of the doping element is higher than that of lithium and transition metal elements in the nickel-based positive electrode material matrix, and the porosity of the material is 10%-20%. The preparation method comprises the following steps: mixing and sintering a positive electrode material precursor, a lithium source and a doping agent to obtain a sintered product; washing and drying the sintered product to obtain a washed product; and mixing the washed product with a coating agent, and sintering to obtain the modified nickel-based positive electrode material. The invention also discloses a lithium ion battery. In the modified nickel-based positive electrode material, a part of doped elements enter a lattice body of a nickel-based positive electrode material matrix, the electronegativity of the doped elements is larger than that of lithium and transition metal elements, the doped elements have higher covalence, higher bond strength and higher oxidation potential, lattice oxygen in the structure is stabilized, precipitation of the lattice oxygen is reduced, and therefore the structural stability of the material is improved.

The invention provides a modified lithium-rich manganese-based positive electrode material, a preparation method thereof and a lithium ion battery, and relates to the technical field of new energy. According to the modified lithium-rich manganese-based positive electrode material disclosed by the invention, multi-element point position doping is carried out on a base material to enhance the structural stability of a polycrystalline material, inhibit transition metal ion migration and interlayer dislocation, improve the internal lattice strength and manufacture a stable base material core; the heterostructure layer can greatly improve the surface structure phase change and transition metal dissolution of the material surface under high voltage, the stability of the surface of the matrix material is improved, and the rate capability of the material can be improved by the in-situ generated three-dimensional ion channel; the coating layer can effectively reduce side reaction of a solid-liquid interface, improve dissolution of metal ions on the surface and improve the cycle performance of the material; in a word, the internal structure and the surface of the material are effectively modified mainly through three means of doping, interface structure design and coating, the multiplying power of the material can be greatly improved, and the long-term service life of the material can be greatly prolonged.

The invention discloses an acetonitrile hydrogenation catalyst and a preparation method and application thereof. The acetonitrile hydrogenation catalyst is a transition metal modified Pt supported catalyst. A transition metal precursor adopted in the transition metal improvement is an oxide containing transition metal elements; the transition metal element is selected from at least one of titanium, vanadium, manganese, iron, cobalt, nickel and copper; the acetonitrile hydrogenation catalyst also comprises a carrier; the carrier is selected from at least one of gamma-Al2O3, SiO2, an MOR molecular sieve and a ZSM-5 molecular sieve. The catalyst can effectively catalyze acetonitrile hydrogenation to prepare ethylamine under mild reaction conditions. The supported catalyst provided by the invention has excellent reaction performance such as high acetonitrile conversion rate in acetonitrile hydrogenation reaction, the reaction condition is mild, the operation is simple, and the catalyst is easy to prepare and can be recycled.

The invention relates to a preparation method of a high-activity transition metal phosphide catalyst, which comprises the following steps: taking basic nickel cobalt carbonate (NiCo-OH / NF) grown on foamed nickel in situ as a precursor, placing the precursor at the downstream of a tubular furnace, placing NaH2PO2 at the upstream of the tubular furnace, annealing in a nitrogen atmosphere at 350 DEG C for 2 hours, and naturally cooling to obtain NiCoP / NF; the preparation method comprises the following steps: soaking NiCoP / NF in a potassium salt solution of a boride, washing, and carrying out vacuum drying to obtain a boron-potassium modified catalyst precursor NiCoP-BK / NF; in a three-electrode system, electrodeposition is carried out in an electrolyte containing a Ni source, a Fe source and deionized water, and the high-activity transition metal phosphide-nickel iron hydroxide NiCoP-BK-coated NiFe-LDH / NF heterojunction composite catalyst is obtained. The activity and stability of the transition metal phosphide catalyst can be remarkably improved, and the preparation method is simple and low in cost.

This invention relates to materials, methods, and systems for carbon dioxide (CO2) capture. More specifically, this invention relates to materials, methods, and systems for removing, capturing, separating, and / or adsorbing carbon dioxide (CO2) from a gas mixture. Additionally, this invention relates to materials, methods, and systems for direct air capture (DAC) of CO2 from ambient air. This invention also relates to materials, methods, and systems for direct air capture (DAC) and methanation of CO2 from ambient air.

The invention relates to the technical field of luminescent materials, and discloses a preparation method and application of a transition metal and chalcogen ion doped metal halide high-efficiency wide-spectrum luminescent material, the chemical formula of the transition metal and chalcogen ion doped metal halide is Cs2Sn1-x-yCl6: x% Te < 4 + >, yMo < 4 + >, the ultra-wideband fluorescent powder converted light emitting diode (LED) covers the range from visible light (VIS) to near infrared light (NIR), and shows remarkable potential in practical application. According to the invention, ultra-wide spectrum emission from 400 nm to 1400 nm is realized in Mo < 4 + >-Te < 4 + > co-doped Cs2SnCl6, and the photoluminescence quantum yield of 95.3% is achieved, the excellent performance is realized through efficient energy transfer from Te < 4 + > to Mo < 4 + > and passivation synergistic effect of vacancy defects, and the performance can be verified through theoretical calculation and spectral research; finally, the ultra-wideband fluorescent powder conversion LED based on the Mo < 4 + > and Te < 4 + > co-doped Cs2SnCl6 is successfully prepared and is applied to the fields of blood gas analysis and night vision imaging.

Disclosed in the present invention are a biomass-derived graded porous asymmetric coordination monatomic carbon-based electrocatalyst, and a preparation method therefor and the use thereof. The preparation method for the biomass-derived graded porous asymmetric coordination monatomic carbon-based electrocatalyst comprises the following steps: (1) stirring and mixing de-alkalized lignin with a transition metal salt, a nitrogen-containing compound and a template, i.e., magnesium oxide, in a solvent until uniform, so as to obtain a suspension, wherein the transition metal comprises iron and zinc; (2) heating, evaporating and drying off the suspension, so as to obtain a lignin / metal ion / nitrogen-containing compound / template mixed precursor; and (3) subjecting the mixed precursor to high-temperature pyrolysis under the protection of an inert gas, cooling same, and then sequentially washing and drying same, so as to obtain a monatomic carbon-based electrocatalyst. The monatomic carbon-based electrocatalyst provided in the present invention has graded pores of micropores, mesopores and macropores, a surface nanosheet and an asymmetric coordination structure of Fe-N3O at the same time, and can be applied to fuel cells and metal-air cells.

The invention provides a preparation method of a cobalt-based bimetallic alloy positive electrode lithium supplement composite material and an application technology of the cobalt-based bimetallic alloy positive electrode lithium supplement composite material in a battery. The lithium-supplementing composite material is a lithium salt, a cobalt-based bimetallic alloy catalyst for promoting low-pressure decomposition of the lithium salt, and a positive electrode material. The lithium salt is lithium oxalate, the cobalt-based bimetallic alloy catalyst is prepared from nitrogen and sulfur co-doped carbon impregnated in a transition metal salt solution through freeze drying and high-temperature calcination, and the positive electrode material comprises one of lithium iron phosphate, lithium cobalt oxide and ternary high nickel (LiMO2, M = Ni, Co and Mn). When the lithium supplement agent is applied to a secondary lithium ion battery, the decomposition voltage of the lithium supplement agent can be reduced, the irreversible loss of capacity is reduced, and the initial coulombic efficiency is improved.

The invention discloses a P2-phase sodium ion positive electrode material with a superlattice ordered structure and a preparation method of the P2-phase sodium ion positive electrode material. The chemical formula of the P2-phase sodium ion positive electrode material is Na < x > M < 1-a-b > A B O < 2 >, wherein M is a transition metal element Mn or / and Ni; a doping sites are transition metal vacancies, and / or doped metal elements Mg and / or doped metal elements Li; the doping site of B is doped with a transition metal element Fe or doped with a transition metal element Cu or doped with a transition metal element Zn; 0.8 < = x < = 0.9, 0.25 < = a, 0.04 < = b < = 0.09. According to the P2 type material with the superlattice ordered structure, the layered structure stability and the sodium ion transmission efficiency of the material can be remarkably improved, so that the problems of poor structure stability and low ion diffusion rate of a traditional sodium ion positive electrode material are effectively solved; the P2 type material with the superlattice ordered structure can be suitable for preparing a sodium ion battery system with high energy density.

The invention belongs to the technical field of novel energy storage battery materials, and particularly relates to a high-entropy Prussian blue positive electrode material as well as a preparation method and application thereof. The chemical formula of the positive electrode material is NaxM [Fe (CN) 6] y.mH2O (at) C, M comprises five different elements of Fe, Ni, Co, Mn, Zn, Ti, V or Cu, the molar ratio of the five different elements is 1: 1: 1: 1: 1-1: 3: 3: 3: 3, x is larger than 0 and smaller than or equal to 2, y is larger than 0 and smaller than or equal to 3, m is larger than 0 and smaller than or equal to 5, and the molar ratio of a carbon component to a high-entropy Prussian blue component is 1: 5-1: 10. Different physical and chemical properties of a plurality of metal elements are utilized, different transition metal elements are coordinated with cyano groups, respective advantages are exerted, the defects of a single metal element are overcome, a stable continuous transmission channel for sodium ions and electrons is constructed in a Prussian blue structure, and the performance of the Prussian blue is improved. Jahn-Teller distortion can be effectively inhibited through the synergistic effect of various metals, and the long cycle stability of the Prussian blue material is remarkably improved.

A ternary positive electrode material modified with a glassy metal-organic framework, and a preparation method therefor and the use thereof. The ternary positive electrode material modified with a glassy metal-organic framework is obtained by grinding and mixing a ternary positive electrode material and a metal-organic framework, and then subjecting same to a melt quenching treatment under a protective atmosphere. Forming a crack-free glassy metal-organic framework containing nano / sub-nano pores on a surface of the ternary positive electrode material can significantly improve the stability of the ternary positive material, alleviate the dissolution of transition metals, and ultimately improve the electrochemical performance of batteries and prolong the service life of the batteries.

The invention relates to the technical field of environmental functional materials and water treatment, and discloses a preparation method and application of a persulfate activator for efficiently removing drug-resistant bacteria and drug-resistant genes in water. Waste biomass and waste plastics are used as raw materials, solid waste resource utilization is achieved through synergistic pyrolysis, compared with a traditional catalyst, the preparation cost can be reduced by more than 40%, and remarkable economic and environmental benefits are achieved. The catalyst has the following advantages: 1) the limitation of a traditional single-active-site catalyst is broken through through the triple synergistic effect of transition metal oxide variable valence activation, nonmetal doped carbon electron conduction and an oxygen vacancy non-free radical path; 2) physical interception of ARB and enrichment of ARGs can be realized at the same time by utilizing a multi-stage pore channel structure; and (3) activating persulfate to generate free radicals (SO4 <->. / . OH) and non-free radicals (1O2 / electron transfer) to generate a double-path synergistic effect, thereby realizing efficient removal of ARB / ARGs in water.

The invention discloses a molybdenum-doped iridium-based multicomponent alloy core-shell structure PEM water electrolysis catalyst and a preparation method thereof, relates to the technical field of electrocatalysts, and forms an electrocatalyst material which takes precious metal iridium as a shell and transition metal cobalt and iridium as a core and is doped with transition metal molybdenum in the core shell. As the transition metal molybdenum has good corrosion resistance, the structure can improve the stability of the catalyst, and the transition metal is low in price, so that the cost of the catalyst can be reduced, and the activity among multi-metal catalysts is improved; meanwhile, the performance of the catalyst can be further improved by removing redundant metal on the surface and in the catalyst. The catalyst prepared by the method is high in OER activity, good in stability, low in cost and easy to industrialize, overcomes the defects of existing PEM water electrolysis hydrogen production, and has important value in the field of electrochemical application and practical engineering.

Improved electrocatalysts for promoting a hydrogen evolution reaction (HER) or an oxygen evolution reaction (OER) from alkaline fresh water and seawater are disclosed. By incorporating metals, such as tungsten and rare earth elements, into the nickel molybdenum nitride framework, Ni1-xMoxN, the disclosed electrocatalysts demonstrate improved catalytic activity and stability compared to the original Ni&Ni0.2Mo0.8N catalysts, particularly under high-current alkaline conditions, in water electrolysis for hydrogen and oxygen production.

The invention relates to the field of electro-catalytic materials, and particularly discloses a layered transition metal hydroxide catalyst as well as a macro-quantity preparation method and application thereof. According to the method, the nanoparticles are formed through solvent difference induction, the nanoparticles are adsorbed on the foamed nickel substrate, formation of the layered transition metal hydroxide on the foamed nickel substrate is promoted, the layered transition metal hydroxide is prepared through a heterogeneous nucleation mechanism, and compared with a traditional homogeneous nucleation process, disordered aggregation of the nanoparticles can be effectively prevented; the preparation method has the advantages of high dispersity and uniform structure, the preparation method does not depend on conditions such as high temperature and high pressure, the equipment cost, energy consumption and safety risk can be reduced, and the method has universality and environmental friendliness and can be applied to macroscopic preparation of the catalyst with good uniformity.

The invention discloses a nitrogen-doped carbon-supported transition metal monatomic material as well as a preparation method and application thereof, and belongs to the technical field of inorganic catalyst materials. The preparation method provided by the invention comprises the following steps: (1) grinding a mixture containing a transition metal precursor, a nitrogen source and a carbon source to obtain an initial mixture; and (2) pyrolyzing the initial mixture in an inert gas atmosphere to obtain the nitrogen-doped carbon-supported transition metal monatomic material. The material provided by the invention can efficiently catalyze carbon dioxide to be reduced into carbon monoxide in a carbon dioxide saturated potassium bicarbonate electrolyte, and the selectivity is higher than 90% or above. The preparation method provided by the invention has universality, is easy for large-scale production, and can be used for synthesizing other similar monatomic materials. The nitrogen-doped carbon-supported transition metal monatomic material prepared by the invention is applied to electrochemical carbon dioxide reduction as an electrocatalyst, and can show excellent catalytic activity, selectivity and stability.

The present invention discloses a high-nickel ternary positive electrode material containing an organic-inorganic composite coating and a preparation method thereof, and relates to the technical field of lithium-ion batteries. The high-nickel ternary positive electrode material containing an organic-inorganic composite coating includes inorganic lithium-containing fast ion conductor particles, which are randomly distributed on the surface of the high-nickel ternary positive electrode material in a point shape, and are embedded in an organic conductive polymer film. The active group at one end of the organic conductive polymer is chemically bonded to the transition metal on the surface of the high-nickel ternary positive electrode material to form an M-O bond, so that the organic conductive polymer is firmly compounded on the surface of the high-nickel ternary positive electrode material. The present invention also provides a preparation method thereof. The high-nickel ternary positive electrode material containing an organic-inorganic composite coating provided by the present invention can simultaneously improve the stability and conductivity of the high-nickel ternary positive electrode material, and effectively solve the problems of poor thermal stability, many surface side reactions and short cycle life of the existing high-nickel ternary material.

The invention provides an ultrahigh-temperature ceramic precursor, a preparation method thereof, a modified high-performance inorganic fiber and application, and relates to the technical field of high-temperature-resistant materials. The preparation of the ultra-high-temperature ceramic precursor comprises the following steps: placing a transition metal compound mixed solution in a low-temperature environment, standing, adding a coordination agent and an exchange agent, reacting, filtering in a low-temperature nitrogen atmosphere, adding a mixed solvent into the filtrate, heating and refluxing, and carrying out a polymerization reaction to obtain the ultra-high-temperature ceramic precursor. The superhigh-temperature ceramic precursor provided by the invention forms a high-temperature protective coating on the surface of a high-performance inorganic fiber and other materials, and meanwhile, a transition metal ion solution is placed under a low-temperature condition through a metal ion stabilization method, so that the internal structure of transition metal ions is more stable, and uniform dispersion at a molecular level is achieved; and the uniformity of the elements can be kept in the curing and cracking processes, and the phenomenon of coating stripping caused by mismatching of thermal shrinkage coefficients of a coating and a substrate material in an extreme environment is avoided.

The invention relates to the technical field of oxygen evolution catalysts, in particular to a preparation method and application of a monatomic doped ferronickel-based oxygen evolution electrocatalyst, and the preparation method comprises the following steps: growing a NiFe-LDH nanosheet substrate on the surface of a carbon-based carrier in situ through a hydrothermal method, and then precisely regulating and controlling transition metal monatomic doping in combination with an electrochemical deposition technology. The monatomic doped ferronickel-based oxygen evolution electrocatalyst prepared by the preparation method has the advantages of excellent catalytic activity, low cost, greenness and no toxicity.

The invention discloses a 3d transition metal M-rare earth metal R bi-component doped carbon-supported Pt catalyst as well as a preparation method and application thereof, relates to a catalyst taking doped carbon as a carrier to support Pt as well as a preparation method and application thereof, and aims to solve the problem that the existing Pt / C catalyst is poor in catalytic activity and stability. Wherein M is Fe, Co, Ni or Zn, and R is Ce, Nd or Gd. The preparation method comprises the following steps: carrying out complexing growth on M and R ions and a nitrogen source ligand on the carbon surface, and then carrying out high-temperature carbonization to obtain an M-R bi-component doped carbon carrier; the preparation method comprises the following steps: preparing an M-R two-component doped carbon-carbon supported Pt catalyst by using a microwave reduction method, then loading Pt by using a microwave reduction method to obtain the M-R two-component doped carbon-carbon supported Pt catalyst, the mass activities of Pt / Fe-Ce-NC and Pt / Co-Ce-NC are respectively 0.27 A / mgPt and 0.22 A / mgPt and are 2.8 times and 2.3 times that of Pt / C, and the M-R two-component doped carbon-carbon supported Pt catalyst can be used in the field of proton exchange membrane fuel cells.

The invention discloses a preparation method of a low-temperature high-air-velocity VOC (volatile organic compound) catalyst and the catalyst, belongs to the field of industrial waste gas treatment, and aims to solve the problems that volatile organic compounds VOCs as main atmospheric pollutants cause photochemical smoke and harm human health; a VOCs catalyst in the prior art cannot meet catalytic combustion treatment process conditions at a high space velocity of 30000 h <-1 >. The high airspeed VOCs noble metal catalyst is developed aiming at a complex volatile organic compound VOCs catalytic combustion technology and meets industrial requirements, and the maximum airspeed of the catalyst is 30000 h <-1 >. The catalyst is an integral honeycomb catalyst formed by taking a double-effect synergistic two-component noble metal precursor, a transition metal oxide and a rare earth oxide as active components, so that the oxygen vacancy of a carrier and the acidity of a catalyst Bronsted acid are enhanced, and the capabilities of oxygen vacancy flow on the surface of the catalyst and adsorption and oxidative dissociation of functional groups on the surface of VOCs (Volatile Organic Compounds) are enhanced.