10189 results about "Mixed solution" patented technology

The invention relates to a method for preparing a lithium iron phosphate / carbon composite material of a lithium ion battery, which belongs to the technical field of lithium ion batteries. The method for preparing the lithium iron phosphate / carbon composite material of the lithium ion battery comprises the following steps of: 1) preparing a suspending graphene-dispersed aqueous solution system, namely, crushing graphite to 1 to 5 microns, adding the crushed graphite into distilled water or purified water, adding 0.1 to 5 percent of surfactant, heating with stirring the mixed solution to 180 to 250 DEG C in a sealing way, performing stirring for 2 to 6 hours and reducing the temperature; 2) crushing lithium iron phosphate to the particle size of 1 to 5 microns, adding the crushed lithium iron phosphate into the distilled water or the purified water, adding with stirring 0.01 to 1 percent of coupling agent, performing uniform stirring, adding the graphene-dispersed aqueous solution, and performing stirring and filtration; and 3) vacuum-drying solid powder obtained by the filtration, and calcinating the dried solid powder for 2 to 12 hours to obtain the graphene-coated lithium iron phosphate cathode material. The method has the advantages of simple process, high material performance, high conductivity, high bulk density, high compacted density and the like.

The invention belongs to the technical field of aerogel materials, and particularly relates to antistatic aerogel for 3D printing as well as a preparation method and application of the antistatic aerogel. The preparation method comprises the following steps: (1) dispersing inorganic nanoparticles modified by a silane coupling agent containing epoxy groups and an aniline monomer in an acidic solvent to obtain a monomer mixed solution; (2) stirring and dissolving polyamide in the monomer mixed solution; (3) initiating a reaction to obtain a polyaniline modified polyamide solution; and (4) freeze-drying to obtain the antistatic aerogel for 3D printing. By controlling synthesis conditions, a core-shell structure of acid-doped polyaniline coated inorganic nanoparticles is formed, and a good conductive path is formed in polyamide with a small addition amount of polyaniline. The antistatic aerogel for 3D printing can be applied to technologies such as photocuring molding and fused deposition of polyurethane resin in a 3D printing technology, and the antistatic property and the mechanical property of a 3D printed product are improved.

The invention discloses a composite electrode material for removing uranium through photoelectrocatalysis and a preparation method and application of the composite electrode material, and belongs to the technical field of catalytic materials and wastewater treatment.The preparation method of the composite electrode material comprises the following steps that a ZIF-8 material, copper salt and ferric salt are mixed, and a first metal composite material is prepared; reacting the first metal composite material with a KOH solution to prepare a second metal composite material; carrying out carbonization treatment on the second metal composite material, and then carrying out acid treatment by using acid to obtain a bimetallic atom catalytic material; the preparation method comprises the following steps: dispersing a bimetallic atom catalytic material and a g-C3N4 material in a mixed solution containing phytic acid and a Nafion solution to obtain catalyst ink; and coating the catalyst ink on a substrate, and carrying out illumination drying to obtain the composite electrode material. According to the composite electrode material, under the synergistic effect of the bimetallic single atomic cluster catalyst and g-C3N4, respective advantages are fully exerted, and efficient deposition removal of uranium is achieved.

The invention provides a method for recovering a BHET monomer from a waste polyester textile alcoholysis solution, and is characterized in that the recovery method comprises the following steps: (1) filtering: mixing the waste polyester textile alcoholysis solution with water under a stirring condition, and filtering at 55-70 DEG C; and (2) cooling crystallization: under a stirring condition, carrying out primary cooling on the filtrate obtained by filtering in the step (1) from 55-70 DEG C to 45-55 DEG C, then adding a BHET seed crystal, then carrying out secondary cooling to 5-15 DEG C, and maintaining the temperature for 20-60 min to obtain the BHET monomer. The mixed solution cooling crystallization method is developed on the basis of complexity of components of the waste polyester textile fabric, the problems that in the conventional production process, a BHET crystal product is low in quality, prone to scaling, difficult to filter and dry and the like are solved, and the obtained BHET product is large in particle size, narrow in particle size distribution, high in purity, good in fluidity and high in stability.

The invention discloses an A-site high-entropy solid oxide fuel cell cathode material as well as a preparation method and application thereof, and provides an A-site high-entropy solid oxide fuel cell cathode material Pr < 0.2 > M < 0.2 > La < 0.2 > Ba < 0.2 > Sr < 0.2 > Co < 0.8 > Fe < 0.2 > O < 3-delta > with a perovskite phase. The preparation method comprises the following steps: S1, weighing multi-element metal nitrates, and mixing to obtain a first mixed solution; s2, dissolving ethylenediamine tetraacetic acid in ammonia water to obtain a second mixed solution; mixing the first mixed solution, the second mixed solution and citric acid to form a mixed precursor solution; s3, carrying out second heating treatment on the mixed precursor solution, and adjusting the pH value to form a gel precursor; and S4, carrying out pre-sintering treatment, third heat treatment and calcination treatment on the gel precursor to obtain a high-grade powder precursor, and carrying out ball milling and sieving treatment to obtain the A-site high-entropy solid oxide fuel cell cathode material. The cathode material is high in stability and good in chemical compatibility with a barrier layer GDC, provides high-quality mass transfer channels and active sites for O2 / O- / O2-, and has good electrochemical performance at medium and low temperatures.

The invention provides a sample pretreatment automation method for flow cytometry, and belongs to the technical field of sample pretreatment for flow cytometry. A biological sample to be detected is collected and placed in a collection tube containing an EDTA-K2 anticoagulant for pretreatment; an automatic pipetting system is used for carrying out incubation reaction on an anticoagulant whole blood sample and an intelligent matching fluorescence labeling antibody mixed solution, and a double-layer game optimization verification system is used for verifying the rationality of an antibody adding proportion and reaction condition parameters; carrying out fluorescence characteristic readability index prediction on the incubated cell suspension by adopting an intelligent dilution parameter regulator model, dynamically adjusting hemolysis parameters and suspension conditions, and adding 1 * hemolysin working solution by using an automatic liquid adding device to carry out hemolysis treatment so as to finish pretreatment; the technical problems that in the pretreatment process of flow cytometry detection samples, parameters are often based on artificial experience, and the reproducibility and standardization degree of detection results are insufficient are solved.

The invention relates to an anion exchange membrane based on isopropyl piperidone and biphenyl and a preparation method of a membrane electrode, the preparation method comprises the following steps: respectively dissolving an aromatic monomer and IPD in a first solvent, and mixing to obtain a mixed solution, the aromatic monomer being BP or TP; dropwise adding an acidic initiator into the mixed solution for reaction at the reaction temperature of-5 DEG C to 0 DEG C to obtain a nitrogen heterocyclic ring polymer intermediate; adding a quaternization reagent into the nitrogen-containing heterocyclic ring polymer intermediate to realize quaternization modification of nitrogen atoms to obtain a quaternization ionomer; and forming a film to obtain the AEM film. The preparation method of the membrane electrode comprises the following steps: respectively forming a cathode catalyst layer and an anode catalyst layer on two opposite sides of an AEM membrane through ultrasonic spraying to obtain the MEA. The AEM membrane and the MEA obtained according to the invention have the characteristics of excellent stability and high water electrolysis performance, can significantly improve the efficiency and durability of AEMWE, and are suitable for the fields of hydrogen production by water electrolysis and the like.

The invention provides a method for synthesizing 1, 2-bis (4-vinyl phenyl) ethane, which comprises the following steps: adding a first solvent, methyl triphenyl phosphine halide and strong alkali into a reaction flask, and uniformly stirring to obtain a first mixed solution; heating the first mixed solution and carrying out reflux reaction for 1 hour; dropwise adding a 1, 2-bis (p-formaldehyde phenyl) ethane solution until the reflux reaction is finished to obtain a second mixed solution; reducing the temperature of the second mixed solution to room temperature, and adjusting the pH value of the second mixed solution to obtain a first solution; layering the first solution, and taking an organic layer; adding a polymerization inhibitor into the organic layer to obtain a second solution; concentrating the second solution to obtain a 1, 2-bis (4-vinyl phenyl) ethane crude product; adding a poor solvent into the crude product, stirring and crystallizing; filtering the crystal to obtain a filter cake, adding a second solvent into the filter cake, and washing and drying the filter cake to obtain 1, 2-bis (4-vinyl phenyl) ethane; the method for synthesizing the BVPE is simple and low in raw material cost, and the synthesized BVPE is high in purity and free of product isomeride.

The invention provides a preparation method of a cell culture three-dimensional scaffold and cell culture meat, which comprises the following steps: firstly, preparing a gelatin-carrageenan mixed solution and a gel precursor solution of transglutaminase, dividing into two parts, incubating at constant temperature to obtain two parts of composite hydrogel, randomly freeze-drying one part to obtain aerogel, and freeze-drying the aerogel to obtain the cell culture three-dimensional scaffold. Stacking on the other part and incubating at constant temperature again to obtain the prefabricated double-layer gel. The prefabricated double-layer gel is directionally frozen, ice crystals grow upwards from the bottom, freezing is stopped after the temperature is reduced to the set temperature, and the cell culture three-dimensional scaffold is obtained through drying. The stent adopts an ordered-disordered partition design, parallel micro-channels are formed in the lower layer by using a directional ice template method, and muscle fiber arrangement is simulated; a porous spongy structure is constructed on the upper layer by using a random ice template method, and is adapted to adipocyte proliferation. Two layers of interfaces are interpenetrated and communicated, natural mechanical gradients are combined, natural tissue characteristics are re-engraved, the traditional limitation is broken through, the cell co-culture efficiency and the cultured meat quality are improved, and industrialization is promoted.

The invention relates to a preparation method of antibacterial gamma-polyglutamic acid superabsorbent hydrogel. The preparation method comprises the following steps: (1) preparing a gamma-polyglutamic acid solution; (2) dissolving an antibacterial agent in the gamma-polyglutamic acid solution, and fully stirring and uniformly mixing to obtain a mixed solution 1; adjusting the pH value of the mixed solution 1, heating the mixed solution 1 to 60 DEG C, and continuously reacting for 1-2 hours to obtain a mixed solution 2; cooling the mixed solution 2 to room temperature, adding a cross-linking agent, and uniformly mixing to obtain a mixed solution 3; standing the mixed solution 3 at room temperature for 1-3 hours and then carrying out gradient heating reaction to obtain an antibacterial gelatinous product; and (3) dehydrating the antibacterial gelatinous product, and carrying out vacuum negative pressure drying to obtain a dried hydrogel product, namely the antibacterial gamma-polyglutamic acid super absorbent hydrogel. The antibacterial gamma-polyglutamic acid superabsorbent hydrogel prepared by the invention has good biocompatibility, is safe and non-toxic, also has excellent water absorption performance and antibacterial performance, and has a good application prospect.

The invention discloses preparation of a bionic copper-based MOF nano-enzyme and application of the bionic copper-based MOF nano-enzyme in hydroquinone detection, and the bionic copper-based MOF nano-enzyme is prepared by the following method: dissolving terephthalic acid H2BDC and L-histidine His in N, N-dimethylformamide DMF to obtain a solution A; adding copper chloride CuCl2. 2H2O into the solution A obtained by C1, and stirring to form a uniform mixed solution; carrying out hydrothermal reaction on the mixed solution obtained from C2 for a certain time, centrifuging to obtain a solid precipitate, cleaning the solid precipitate, and drying to obtain the bionic Cu / His-MOF nano-enzyme; the invention also discloses an application of the sensor in hydroquinone detection. The bionic copper-based MOF nano-enzyme has the advantages of being simple and convenient to synthesize, high in substrate affinity, high in catalytic capacity and the like, and meanwhile, a rapid, sensitive and reliable HQ detection method is provided.

The invention provides a preparation method of prismatic titanium diboride powder, and belongs to the technical field of titanium diboride powder. The preparation method comprises the steps of titanium source preparation, boron source preparation, material mixing, cold isostatic pressing and carbon thermal reduction reaction. The step of preparing the titanium source comprises the following steps: heating TiO2 powder body liquid, raising the temperature to 52-55 DEG C, adding a tetrabutyl titanate solution, uniformly stirring, adding an ammonia water solution to adjust the pH value to 7.0, and carrying out heat preservation stirring for 2.7-3.2 hours to obtain the titanium source; the step of preparing the boron source comprises the following steps: adding B4C powder into absolute ethyl alcohol, carrying out ultrasonic dispersion, then adding a mixed solution, controlling the adding rate of the mixed solution to be 0.8-1.2 g / min, heating to 34-37 DEG C, and carrying out heat preservation and stirring for 3.8-4.2 hours to obtain the boron source; the titanium diboride powder obtained through the method is in a prism shape and is uniform in particle, high in density and purity and poor in high-temperature oxidation resistance.

The invention relates to a preparation technology of a gel polymer lithium ion battery cell electrolyte, and belongs to the field of battery preparation technologies, the preparation technology comprises the following steps: mixing methacrylate monomers and silane monomers according to a mass ratio of 3: 1-5: 1, adding 1-3% of an initiator, and carrying out prepolymerization at 60-80 DEG C for 1-3 h to prepare a prepolymer solution; mixing with a non-aqueous solvent containing lithium hexafluorophosphate according to a mass ratio of (1: 4)-(1: 6) to form a precursor mixed solution, and controlling the injection rate to be 1.5-2.5 g / Ah to a gap between a battery cell pole piece and a diaphragm; after standing for 2-4 hours at the vacuum degree of less than or equal to-0.08 MPa, curing for 3-6 hours at the temperature of 60-70 DEG C to form a gel polymer electrolyte; the wettability is improved through pole piece surface hydrophilic treatment, 1-5% of vinylene carbonate is added to optimize an SEI film, the prepolymerization temperature fluctuation is controlled to be smaller than or equal to + / -2 DEG C through microwave-assisted heating, the pressure of 0.2-0.5 MPa is applied after injection to promote uniform permeation, a polyvinylidene fluoride coating of 5-10 microns is coated after curing to enhance protection, and the interface performance is ensured through an alternating-current impedance test.

The invention provides a high-hydrophobicity anti-pollution flashover coating and a preparation method thereof, and relates to the field of coatings. The silicone rubber composition is prepared from the following raw materials in parts by weight: 80 to 100 parts of hydroxyl-terminated polydimethylsiloxane; 5 to 15 parts of modified nano silicon dioxide; 10 to 30 parts of a composite self-repairing microcapsule; 10 to 25 parts of a flame retardant; 3-8 parts of a cross-linking agent; 0.5-2 parts of a catalyst; 1-5 parts of an accelerant; 40 to 100 parts of a solvent; the modified nano silicon dioxide is fumed silica subjected to surface treatment by a fluorine-containing silane coupling agent and a platinum catalyst; the capsule wall of the composite self-repairing microcapsule is a polylactic acid-glycolic acid copolymer, and the capsule core of the composite self-repairing microcapsule is a mixed solution of a hydroxyl-terminated polydimethylsiloxane oligomer and methyltris (methylethylketoximino) silane. The coating has excellent hydrophobicity, weather resistance and targeted repair function.

The application discloses an organic sulfur hydrolysis catalyst, a preparation method and application, and adds a water-soluble titanium-containing compound and a surfactant to obtain titanium-containing pseudo-boehmite; finally, the titanium-containing pseudo-boehmite is formed to obtain the organic sulfur hydrolysis catalyst; and in the carbonization method reaction process, the pH is slowly changed by adjusting the flow of the CO2, the pH change value of the mixed solution is less than 1 in 30 min, and the final pH value of the reaction solution is controlled to be 7.0-9.5. In the preparation of the pseudo-boehmite, the titanium element is highly dispersed in the pseudo-boehmite powder by adding the titanium element and the surfactant and controlling the pH change rate, the catalyst fully plays the hydrolysis effect of each titanium active site on the organic sulfur, and a higher organic sulfur hydrolysis rate is realized under the condition that the titanium content is lower.

The invention belongs to the technical field of medicine and health care, and particularly relates to a preparation method of an American ginseng root water extract rich in rare ginsenoside and application of the American ginseng root water extract in improving the immune and anti-tumor direction. The preparation method comprises the following steps: step 1, carrying out superfine grinding on American ginseng, and sieving; step 2, adding the American ginseng powder into water, and then adding compound enzyme for enzymolysis to obtain enzymatic hydrolysate; s3, after the enzymolysis is finished, heating the enzymatic hydrolysate, extracting twice, and mixing after the extraction is finished; and S4, inoculating compound lactic acid bacteria into the mixed solution, fermenting to obtain a fermentation solution, blending, and sterilizing to obtain the American ginseng afterbiogen beverage. According to the invention, a new physical-biological combined process is adopted, and crushing, enzymolysis, extraction, fermentation and blending are carried out, so that the American ginseng metagen beverage rich in rare ginsenoside is obtained, and the rare ginsenoside has a remarkable anti-tumor effect and higher activity.

The invention provides a preparation method of a nickel-based composite oxygen evolution anode for alkalescent electrolyte. According to the invention, nickel-based alloy is used as substrates, two same substrates are respectively used as a working electrode and an auxiliary electrode, two-electrode system electrochemical oxidation reduction treatment at room temperature is carried out in a mixed solution of phosphate, carbonate and chloride, and two reconstructed nickel-based composite oxygen evolution electrodes are obtained at the same time. In the electrochemical oxidation process, nickel ions and other metal (Fe, Co, Cr and Mn) ions are dissolved out from the nickel-based alloy under the etching assistance of chloride ions; in the electrochemical reduction process, water on the electrode is reduced to form hydroxyl. Under continuous oxidation reduction, substance reconstruction is carried out to generate a composite catalyst layer of phosphate, carbonate and hydroxide of nickel and other metals, so that not only can the oxygen evolution activity be improved, but also metal dissolution and corrosion passivation when the catalyst is used in a weakly alkaline solution can be inhibited, and the durability of the electrode is greatly improved.

The invention belongs to the technical field of electrode foil formation treatment, and particularly relates to an electrode foil and a preparation method thereof and an aluminum electrolytic capacitor, the preparation method of the electrode foil comprises the steps of performing multi-stage formation treatment on a corrosion foil, the number of stages of the formation treatment is at least two, and the formation treatment at least comprises first-stage formation and second-stage formation, first heat treatment is carried out after the second-stage formation; a formation liquid used in the second-stage formation is a mixed solution containing adipate and monopotassium phosphate. According to the preparation method provided by the invention, the formation liquid used in secondary formation is the mixed solution containing adipate and monopotassium phosphate, the limitation of traditional single formation liquid is broken through, and synchronous optimization of the structure, hydration resistance and electrochemical performance of the aluminum oxide film is realized through multi-stage formation, mixed solution synergy and the synergistic effect of formation and heat treatment; meanwhile, production cost is reduced, and environmental load is relieved.

The invention provides high-filling silver powder and a preparation method thereof, and belongs to the field of metal powder.The preparation method comprises the steps that a nano-silver solution is prepared, a dispersing agent and a first reducing agent are mixed to obtain a mixed solution, the nano-silver solution and the mixed solution are mixed in a constant-temperature stirring state to obtain a base solution, a second reducing agent solution and a silver nitrate solution are prepared respectively, and the high-filling silver powder is prepared. And under the constant-temperature stirring state, the second reducing agent solution and the silver nitrate solution are synchronously added into the base solution, a silver powder solution is obtained through reaction, the silver powder solution is subjected to washing, solid-liquid separation, drying and depolymerization shaping treatment, and the high-filling silver powder is obtained. Controllable preparation of the large-size sphericity silver powder is achieved by controlling the particle size and the adding amount of the nano-silver, regulating and controlling heterogeneous nucleation and growth sites of silver ions and inhibiting formation of multistage dendritic crystals, surface charges and steric hindrance effects of silver particles are optimized through the surface adsorption effect of the dispersing agent, the agglomeration phenomenon of the silver powder in the growth process is reduced, and the silver powder is prepared. And meanwhile, the silver powder is endowed with excellent flowability.

The invention discloses a screen cloth enhanced polybenzimidazole porous membrane as well as a preparation method and application thereof. The preparation method comprises the following steps: fully mixing polybenzimidazole, a polar solvent and a template to obtain a mixed solution, coating a base material with the mixed solution, placing a polymer mesh on the previous base material, and carrying out in-situ compounding, polar solvent removal and film formation to obtain a compact mesh reinforced polybenzimidazole film; and then carrying out in-situ etching treatment to prepare the screen cloth enhanced polybenzimidazole porous membrane. The size and connectivity of ion channels in the membrane can be regulated and controlled by regulating and controlling the type and content of templates in the membrane casting process, and the polybenzimidazole porous layer can be ultrathin by combining the effect of enhancing the mechanical property of the polymer mesh cloth, so that the mass transfer resistance of the polybenzimidazole porous separation layer is remarkably reduced, and the performance of the membrane is improved. The mesh-reinforced polybenzimidazole porous membrane has good dimensional stability and pore uniformity, and has the characteristics of high ion selectivity, high ion conductivity and high stability.

The invention relates to the technical field of chemical engineering, and discloses nylon powder for a hydrogen storage bottle inner container and a preparation method thereof, the hydrogen storage bottle inner container and a forming process thereof.The method comprises the following steps that S1, nylon resin, an antioxidant and an organic solvent are mixed, heat preservation is conducted for 15 min to 120 min at the temperature of 140 DEG C to 160 DEG C, and a mixed solution A is formed; s2, the mixed solution A is cooled to 25-60 DEG C, nylon resin is separated out, and slurry B is formed; and S3, removing the organic solvent in the slurry B, and drying to obtain the product. According to the preparation method, the nylon resin and the antioxidant are jointly dissolved in the organic solvent at the specific temperature, the cooling and precipitation conditions are controlled, reconstruction and optimization of the particle size and morphology of the powder are effectively achieved, the obtained powder has the high sphericity degree, uniform particle size distribution and good fluidity, and the preparation method is suitable for industrial production. The melt consistency and the spreading performance in the rotational molding process are improved, the integrity and the air tightness of the hydrogen storage bottle liner structure are improved, and the problems that existing nylon powder is poor in particle size control, insufficient in fluidity and the like are solved.

The invention provides a Pt-Sn bimetallic catalyst and a preparation method and application thereof.The preparation method comprises the steps that 1, a Y molecular sieve is placed in a mixed solution of KOH and methyl alcohol, centrifugation and washing are conducted till the Y molecular sieve is neutral after stirring, drying and roasting are conducted, and a non-acid KY molecular sieve is obtained; the silica-alumina ratio of the Y molecular sieve is 3-100; 2) taking the non-acidic KY molecular sieve as a carrier, and loading Sn by adopting an atomic layer deposition technology to obtain a Sn-modified non-acidic KY molecular sieve; and 3) loading Pt by using the Sn-modified non-acidic KY molecular sieve as a carrier and adopting an atomic layer deposition technology to obtain the Pt-Sn bimetallic catalyst. According to the preparation method provided by the invention, spatial distribution of Pt and Sn is accurately regulated and controlled by combining an atomic layer deposition technology, so that the electronic state of Pt species is adjusted, alkane is promoted to be dehydrogenated into an olefin intermediate, and the aromatization catalytic activity and the aromatic hydrocarbon selectivity of alkane are improved.

The invention discloses a real-time feedback method and system for a hydrogen peroxide production process, and relates to the technical field of intelligent feedback. The real-time feedback method and system for the hydrogen peroxide production process comprises the following steps: S1, preprocessing production process data and historical process data; s2, self-adaptive time sequence prediction feedback regulation and control analysis is carried out, the rotating speed of a servo motor is adjusted, and a sampling flow error value is corrected; s3, performing regulation and control characteristic attribution analysis, and performing mixed solution transfer; s4, performing process equipment self-diagnosis for efficient emulsion separation and multi-parameter mahalanobis distance discrimination; and S5, carrying out process parameter optimization and risk early warning. The problems that an existing system is difficult to achieve automatic continuous sampling and flow self-adaptive regulation and control in the hydrogen peroxide production process, and high-precision real-time monitoring and intelligent early warning are difficult to achieve are solved.

The invention belongs to the technical field of contact lenses, and provides a moisturizing contact lens containing a hyaluronic acid coating and a preparation method of the moisturizing contact lens. The preparation method comprises the following steps: carrying out ultrasonic mixing on a hydrophilic monomer, a siloxane monomer, a cross-linking agent and an initiator, injecting the mixed solution into a contact lens mold, and carrying out polymerization reaction to obtain a contact lens material; mixing the chitosan solution, the shellac acid solution, the hyaluronic acid solution and the vitamin E succinate solution to obtain a hyaluronic acid mixed solution; and soaking the contact lens material in the hyaluronic acid mixed solution, adding a cross-linking agent, curing, and drying to obtain the moisturizing contact lens containing the hyaluronic acid coating. The contact lens disclosed by the invention has excellent moisture retention, good light transmission performance, swelling performance and excellent mechanical property, the wearing comfort is remarkably improved, and the contact lens is suitable for being worn for a long time; the preparation method disclosed by the invention is environment-friendly and easy to industrialize.

The invention relates to a method for quickly depositing and modifying the surface of a polypropylene base material and the polypropylene base material subjected to surface deposition modification. The method comprises the following steps: pretreating the surface of the polypropylene base material; dissolving with a Tris-HCl buffer solution to prepare a dopamine solution and a NaIO4 solution; the preparation method comprises the following steps: mixing a prepared dopamine solution and a prepared NaIO4 solution according to a preset proportion, uniformly stirring to form a mixed solution, immersing a polypropylene base material, and reacting for preset time to form a deposition layer on the surface of the polypropylene base material. By optimizing an oxidizing agent system, the reaction time can be shortened to be within 30 minutes as soon as possible, meanwhile, the excellent performance of a deposition layer is kept, synergistic improvement of surface roughness, hydrophilicity and active functional group density is achieved, a theoretical foundation is laid for expanding application of the method in the fields of automobiles, packaging, medical instruments and the like, and the method is worthy of popularization and application. The technology can also be applied and popularized to surface functionalization of other non-polar polymers, and has great industrial application significance.

The invention provides a preparation method and application of a mineral oral liquid containing fat-soluble vitamins, the fat-soluble vitamins are dissolved in an oil phase, then the oil phase is mixed with a water phase containing an emulsifier, and high-shear and high-pressure homogenization treatment is performed to obtain emulsified fat-soluble vitamins; dispersing the sweetening agent, the suspending aid, the pH regulator and the insoluble mineral substances to obtain a mixed solution; adding the emulsified fat-soluble vitamins and the flavor regulator into the mixed solution, adding water to a constant volume, and uniformly stirring to obtain a material solution; and canning the feed liquid, sealing, and sterilizing at high temperature to obtain the oral liquid. The fat-soluble vitamins in the oral liquid provided by the invention are small in particle size after being subjected to high-shear and high-pressure homogenization treatment, can tolerate high-temperature sterilization, is small in loss rate, good in dispersity and high in stability within the shelf life, and can maintain the actual content of the fat-soluble vitamins in the oral liquid and ensure the nutritional effect of the fat-soluble vitamins.

The invention discloses a preparation method of a carbon-coated single-crystal sodium ferric pyrophosphate positive electrode material, which is specifically implemented according to the following steps: step 1, dissolving sodium salt, ferric salt and phosphate in deionized water in proportion, then adding a carbon source into the solution, and uniformly stirring to obtain a mixed solution; step 2, fully drying the mixed solution obtained in the step 1 to obtain precursor powder; and 3, carrying out heat treatment on the precursor powder in a protective atmosphere, and cooling to obtain the carbon-coated single-crystal sodium ferric pyrophosphate positive electrode material. The invention also discloses a coating prepared by the method, a single-crystal structure is combined with uniform carbon coating, grain boundary defects are eliminated, conductivity is improved, high specific capacity and long cycle life are realized, single-crystal growth and carbon layer in-situ coating are synchronously realized by a synthesis process, and structural integrity and efficient conductive network construction can be ensured.

The invention discloses a liquid chromatography determination method for a mixed solution of glyoxylic acid, glycollic acid and oxalic acid and application. The method comprises the following steps: (1) preparing standard solutions with different concentrations; (2) detecting the standard solutions with different concentrations by using high performance liquid chromatography; (3) establishing a linear regression equation of each acid according to the relationship between the concentration of the standard solution and the corresponding peak area; (4) pre-treating a sample to be detected, detecting under the same condition as that in the step (2) by using high performance liquid chromatography, and recording the peak area of each acid in the sample to be detected; and (5) substituting the peak area of each acid in the to-be-detected sample into the corresponding linear regression equation, and calculating to obtain the concentrations of glyoxylic acid, glycollic acid and oxalic acid in the to-be-detected sample. The method is a liquid chromatographic determination method which is simple and convenient to operate, excellent in separation effect, mild in chromatographic condition and compatible with various detectors, can accurately quantify three strong-polarity mixed acids of glyoxylic acid, glycollic acid and oxalic acid, and has important practical application value.

The invention relates to a textured KCu7S4 thermoelectric material and a preparation method thereof, and the method comprises the steps: sequentially adding a prepared KOH aqueous solution, CuCl2. 2H2O and Na2S. 9H2O into a high-pressure kettle, and fully stirring for dissolving; dropwise adding an N2H4.H2O aqueous solution into the mixed solution, fully stirring, sealing, transferring to a microwave chemical synthesis instrument, heating, keeping stirring, and reacting at a target temperature and self-generated pressure to generate a KCu7S4 nanowire preferentially growing along a [001] crystal orientation; and after the reaction is finished and natural cooling is carried out, a product is collected through centrifugation, full cleaning and vacuum drying are carried out, and then the KCu7S4 thermoelectric material with [001] preferred orientation in the direction perpendicular to the pressure direction is obtained through spark plasma sintering. According to the method, a surfactant and an organic solvent are not used, and macro, rapid, efficient and controllable preparation of the KCu7S4 nanowire is realized through a low-temperature, low-cost and low-energy-consumption microwave-assisted hydrothermal process.

The invention relates to a sunken porous magnetic alloy ball wave-absorbing material and a preparation method and application thereof.The wave-absorbing material is prepared through the following steps that S1, citric acid, soluble ferric salt, soluble cobalt salt and soluble nickel salt are dissolved in a mixed solvent of ethylene glycol and water, and the mixture is fully stirred to form a uniform mixed solution; and S2, the mixed solution obtained in the step S1 is subjected to spray drying, obtained precursor powder is placed in the air atmosphere to be calcined to remove the carbon source, then the precursor powder is placed in the H2 / Ar atmosphere to be subjected to heating reduction, and the porous FeCoNi alloy balls with the surface pits are obtained and are the target product. The surface of the prepared alloy microsphere has an obvious concave structure, magnetic anisotropy and magnetic performance are enhanced, a small number of pores are generated in the reduction process, impedance matching of the material is optimized, and effective high-frequency electromagnetic absorption is achieved; and due to the synergistic effect of the recesses and the pores, the obtained alloy microspheres have obvious lightweight characteristic, and have good application prospects in the field of electromagnetic absorption.