3238 results about "Cathode material" patented technology

The invention relates to a method for preparing a lithium iron phosphate / carbon composite material of a lithium ion battery, which belongs to the technical field of lithium ion batteries. The method for preparing the lithium iron phosphate / carbon composite material of the lithium ion battery comprises the following steps of: 1) preparing a suspending graphene-dispersed aqueous solution system, namely, crushing graphite to 1 to 5 microns, adding the crushed graphite into distilled water or purified water, adding 0.1 to 5 percent of surfactant, heating with stirring the mixed solution to 180 to 250 DEG C in a sealing way, performing stirring for 2 to 6 hours and reducing the temperature; 2) crushing lithium iron phosphate to the particle size of 1 to 5 microns, adding the crushed lithium iron phosphate into the distilled water or the purified water, adding with stirring 0.01 to 1 percent of coupling agent, performing uniform stirring, adding the graphene-dispersed aqueous solution, and performing stirring and filtration; and 3) vacuum-drying solid powder obtained by the filtration, and calcinating the dried solid powder for 2 to 12 hours to obtain the graphene-coated lithium iron phosphate cathode material. The method has the advantages of simple process, high material performance, high conductivity, high bulk density, high compacted density and the like.

The invention discloses a zinc-iodine battery positive electrode material based on corn straw shell derived porous carbon and a preparation method of the zinc-iodine battery positive electrode material. According to the material, corn straw shells serve as the sole carbon source, an indigenous nitrogen-doped biomass charcoal carrier with a hierarchical pore structure is prepared through pre-carbonization and KOH activation processes, and the material is characterized in that the specific surface area is larger than or equal to 1500 m < 2 > / g, and the micropore proportion is larger than 90%. The iodine is loaded on the carrier (the iodine content is greater than or equal to 45wt%) through a vacuum sublimation method to form the indigenous nitrogen-doped biomass charcoal / iodine composite material. According to the positive electrode material, through the synergistic effect of physical confinement and pyridine nitrogen chemical adsorption, the multi-iodide shuttle effect is effectively inhibited, so that the capacity retention rate of the zinc-iodine battery is greater than or equal to 93% after 40000 cycles under the current density of 2A g <-1 >, and the capacity retention rate is greater than 45% under the rate of 10A / g. The method has double benefits of agricultural waste resource utilization and high-performance energy storage device development.

The invention discloses a modified carbon-coated sodium manganese ferric phosphate pyrophosphate / sodium ferric phosphate pyrophosphate positive electrode material as well as a preparation method and application thereof, and relates to the technical field of new energy materials. The preparation method comprises the following steps: preparing MnFe-MOF from a manganese source, a first iron source and a first organic ligand under a hydrothermal reaction; a second iron source, the MnFe-MOF and a second organic ligand are subjected to a hydrothermal reaction, and MnFe-MOF / Fe-MOF is obtained; uniformly mixing with a sodium source and a phosphorus source, and sintering to obtain a positive electrode material; and carrying out high-temperature gas-phase etching treatment to obtain the fluorine-doped carbon-coated modified sodium manganese ferric phosphate pyrophosphate / sodium ferric phosphate pyrophosphate positive electrode material. The material disclosed by the invention has a coating modified structure, so that an interface side reaction caused by direct contact between sodium ferromanganese phosphate and an electrolyte can be effectively avoided, a manganese dissolution phenomenon is reduced, and the structural stability of the material is improved; and meanwhile, the material has high conductivity, excellent structural stability, excellent long cycle life and excellent rate capability.

The invention discloses an A-site high-entropy solid oxide fuel cell cathode material as well as a preparation method and application thereof, and provides an A-site high-entropy solid oxide fuel cell cathode material Pr < 0.2 > M < 0.2 > La < 0.2 > Ba < 0.2 > Sr < 0.2 > Co < 0.8 > Fe < 0.2 > O < 3-delta > with a perovskite phase. The preparation method comprises the following steps: S1, weighing multi-element metal nitrates, and mixing to obtain a first mixed solution; s2, dissolving ethylenediamine tetraacetic acid in ammonia water to obtain a second mixed solution; mixing the first mixed solution, the second mixed solution and citric acid to form a mixed precursor solution; s3, carrying out second heating treatment on the mixed precursor solution, and adjusting the pH value to form a gel precursor; and S4, carrying out pre-sintering treatment, third heat treatment and calcination treatment on the gel precursor to obtain a high-grade powder precursor, and carrying out ball milling and sieving treatment to obtain the A-site high-entropy solid oxide fuel cell cathode material. The cathode material is high in stability and good in chemical compatibility with a barrier layer GDC, provides high-quality mass transfer channels and active sites for O2 / O- / O2-, and has good electrochemical performance at medium and low temperatures.

Embodiments described herein relate to electrochemical cells with dendrite prevention mechanisms, and methods of producing and operating the same. In some aspects, an electrochemical cell can include an anode and a cathode material disposed on a cathode current collector, the cathode material and the cathode current collector forming a cathode. The electrochemical cell further includes a first separator disposed on the anode, a second separator disposed on the cathode, and an interlayer disposed between the first separator and the second separator, the interlayer including electroactive material, the interlayer including a source of lithium ions, the lithium ions configured to migrate toward the anode upon a voltage difference between the interlayer and the anode exceeding a threshold value. In some embodiments, the anode can include an anode material disposed on an anode current collector. In some embodiments, the anode material can include graphite, silicon, and / or hard carbon.

The invention discloses a preparation method of a carbon-coated single-crystal sodium ferric pyrophosphate positive electrode material, which is specifically implemented according to the following steps: step 1, dissolving sodium salt, ferric salt and phosphate in deionized water in proportion, then adding a carbon source into the solution, and uniformly stirring to obtain a mixed solution; step 2, fully drying the mixed solution obtained in the step 1 to obtain precursor powder; and 3, carrying out heat treatment on the precursor powder in a protective atmosphere, and cooling to obtain the carbon-coated single-crystal sodium ferric pyrophosphate positive electrode material. The invention also discloses a coating prepared by the method, a single-crystal structure is combined with uniform carbon coating, grain boundary defects are eliminated, conductivity is improved, high specific capacity and long cycle life are realized, single-crystal growth and carbon layer in-situ coating are synchronously realized by a synthesis process, and structural integrity and efficient conductive network construction can be ensured.

The invention discloses a lithium iron manganese phosphate positive electrode material and a preparation method thereof, a positive electrode plate and a secondary battery, and belongs to the technical field of lithium iron manganese phosphate batteries, the lithium iron manganese phosphate positive electrode material comprises a lithium iron manganese phosphate positive electrode active material and a solid electrolyte interface film located on the surface of the lithium iron manganese phosphate positive electrode active material, the solid electrolyte interface film contains C, N, F and O elements, and the ratio of the relative content of the C element to the relative content of the N element in the solid electrolyte interface film is (0.5-2): 1. According to the solid electrolyte interface film, the dissolution of manganese ions and the decomposition side reaction of the electrolyte at high voltage / high temperature are remarkably inhibited, the generation of gas is fundamentally reduced, the battery is free from flatulence phenomenon after being circulated at high temperature, and the safety and the reliability of the battery are greatly improved.

The invention discloses a KTP type sodium-rich phosphate positive electrode material and a preparation method and application thereof, the chemical formula of the phosphate positive electrode material is NaxV1-yTyPO4F1-zOz, 1 < x < = 2, 0 < y < = 1, and 0 < = z < = 1; the preparation method of the material comprises the following steps: adding a vanadium source, a T source, a phosphorus source and a fluorine source in a stoichiometric ratio into a reaction kettle containing a reaction solvent, adding an ammonium source to keep the pH value to be 6-10, maintaining the temperature to be 120-250 DEG C, and reacting for 2-24 hours; naturally cooling, and washing with clear water to obtain a (NH4) xV < 1-y > TyPO4F < 1-z > Oz precursor; the preparation method comprises the following steps: fully grinding an excessive sodium source and a (NH4) xV < 1-y > TyPO4F < 1-z > Oz precursor, carrying out Na < + > / NH4 < + > molten salt exchange in a tubular furnace at 60-400 DEG C for 1-48 hours, introducing inert gas during reaction, and washing an obtained product with a washing solvent after the reaction is finished to remove the excessive sodium source; and drying in a drying oven at 50-250 DEG C for 1-30 hours to obtain the KTP type sodium-rich phosphate positive electrode material. By utilizing the induction effect of KTP configuration on V-O or T-O bonds, the voltage of V and T transition metal related redox couple is increased, and the energy density is improved.

The invention relates to a solid-state battery positive electrode material layer and a solid-state battery, belongs to the technical field of solid-state batteries, and is used for solving at least one of the problems that an existing solid-state battery is easy to crack, poor in contact and large in resistance, and a solid-state electrolyte battery prepared by a physical vapor deposition method is thin in electrode thickness, low in capacity and the like. A plurality of holes are formed in the positive electrode material layer, the diameter of each hole is 0.1-10 [mu] m, the opening area of each hole in the unit area of the positive electrode material layer accounts for 20-60% of the total area, and each hole is of a through hole structure. The positive electrode material layer of the solid-state battery is provided with a plurality of holes with through hole structures, the solid electrolyte is embedded into the holes, the holes are filled with the solid electrolyte, the solid electrolyte covers the positive electrode material layer, and the holes have specific diameters and opening areas, so that the ionic conductivity is improved, and the service life of the solid-state battery is prolonged. The thickness of the prepared positive electrode material layer can be designed as required.

The invention discloses a high-performance lithium-rich manganese oxide positive electrode material, a preparation method thereof and application of the high-performance lithium-rich manganese oxide positive electrode material to an all-solid-state battery. The lithium-rich manganese oxide positive electrode material coats / composites a lithium-rich manganese positive electrode base material and a lithium ion conductor or a conductive agent in situ through a freeze-drying method. In-situ coating / compounding of a lithium ion conductor or a conductive agent on the lithium-rich manganese oxide positive electrode material is realized through freeze drying, the interface impedance is effectively reduced, the interface stability is improved, and the lithium ion and electron transmission efficiency is improved. The lithium-rich manganese oxide positive electrode material prepared by the invention can inhibit the release and side reaction of lattice oxygen in the cycle process, and improve the structural stability and cycle life of the material; meanwhile, the freeze-drying method can maintain the nano dispersity and uniformity of the material, full solid-solid contact between the lithium-rich manganese material and a lithium ion conductor or a conductive agent is realized, and the high specific capacity of the lithium-rich manganese positive electrode material in all-solid-state battery application is ensured. The prepared lithium-rich manganese-based all-solid-state battery has the reversible specific capacity as high as 273 mAh / g, the bottleneck that the capacity release of the lithium-rich manganese oxide positive electrode material in an all-solid-state battery system is limited is broken through, the strategy provides a new design thought and technical path for the construction of the high-specific-energy all-solid-state battery positive electrode material, the adopted process is simple and controllable, and the method is suitable for industrial production. The method is suitable for large-scale preparation.

The invention discloses a lithium iron manganese phosphate positive electrode material and a preparation method thereof, and belongs to the technical field of lithium ion batteries, the lithium iron manganese phosphate positive electrode material at least comprises lithium iron manganese phosphate particles and a coating layer coating the lithium iron manganese phosphate particles; the raw material of the coating layer comprises an aluminum fluoride embedded poly (ethylenedioxythiophene)-lithium polystyrene sulfonate compound. And the coating layer can be used as a physical barrier to form dynamic interface protection, so that dissolution of manganese and erosion of electrolyte are directly inhibited, and side reaction between the electrolyte and the positive electrode material is reduced. Meanwhile, a more flexible transmission channel is provided for lithium ions and electrons, the conductivity of the positive electrode material is enhanced while the transmission efficiency of the lithium ions is improved, and the lithium manganese iron phosphate positive electrode material with stable structure, high rate capability and cycling stability is obtained.

The invention belongs to the technical field of lithium ion battery positive electrode material preparation, and relates to a manganese-based positive electrode of an all-solid-state battery system, a preparation method and application of the manganese-based positive electrode, the general formula of the manganese-based positive electrode is Li < 1 + x > NiyCoyMn3yOz, the preparation method comprises the following steps: S1, grinding and mixing a lithium-rich manganese original material and lithium phosphate in an inert gas protective atmosphere to obtain a precursor mixture; s2, performing high-energy mechanical ball milling on the precursor mixture; s3, collecting the powder subjected to high-energy mechanical ball milling in an inert gas protective atmosphere to obtain a manganese-based positive electrode material; the manganese-based positive electrode material disclosed by the invention realizes mixed arrangement of part of cations and a double-phase synergistic heterostructure, and has high energy density and voltage, and a halide and sulfide-based all-solid-state battery assembled by using the manganese-based positive electrode material shows good cycling stability and rate capability.

The present invention discloses a method for preparing a composite sodium ferric pyrophosphate cathode material, which relates to the technical field of sodium batteries and includes the following steps: Step S1, preparing a precursor; Step S2, combining it with a carbon source; and Step S3, sintering it. The composite sodium ferric pyrophosphate cathode material disclosed in the present invention has excellent electrochemical performance, good electrical conductivity, strong cycle performance and rate performance, and high initial charge and discharge efficiency.

Embodiments described herein relate to electrochemical cells with multiple separators, and methods of producing the same. A method of producing an electrochemical cell can include disposing an anode material onto an anode current collector, disposing a first separator on the anode material, disposing a cathode material onto a cathode current collector, disposing a second separator onto the cathode material, and disposing the first separator on the second separator to form the electrochemical cell. The anode material and / or the cathode material can be a semi-solid electrode material including an active material, a conductive material, and a volume of liquid electrolyte. In some embodiments, less than about 10% by volume of the liquid electrolyte evaporates during the forming of the electrochemical cell. In some embodiments, the method can further include wetting the first separator and / or the second separator with an electrolyte solution prior to coupling the first separator to the second separator.

Embodiments described herein relate to electrochemical cells with multiple separators, and methods of producing the same. A method of producing an electrochemical cell can include disposing an anode material onto an anode current collector, disposing a first separator on the anode material, disposing a cathode material onto a cathode current collector, disposing a second separator onto the cathode material, and disposing the first separator on the second separator to form the electrochemical cell. The anode material and / or the cathode material can be a semi-solid electrode material including an active material, a conductive material, and a volume of liquid electrolyte. In some embodiments, less than about 10% by volume of the liquid electrolyte evaporates during the forming of the electrochemical cell. In some embodiments, the method can further include wetting the first separator and / or the second separator with an electrolyte solution prior to coupling the first separator to the second separator.

The invention discloses a lithium-rich positive electrode material, a preparation method thereof and a lithium ion battery, and relates to the technical field of lithium ion batteries. The chemical formula of the lithium-rich positive electrode material is Li < 1 + x > TM < 1-x-y > DyO2 (TM is at least two of Ni, Co and Mn, D is at least two of Mg, Ti, Al, Zr, Nb and Ta, 0 lt; xlt; 0 < y < = 0.06), material particles are a spinel phase and a bulk phase in sequence from outside to inside, the concentration of TM is gradually increased from outside to inside, and the concentration of N is gradually reduced from outside to inside. The preparation method adopts a liquid-phase mechanical fusion coating technology to realize gradient doping of doping elements, and combines high-temperature calcination to obtain a target product. The lithium-rich positive electrode material disclosed by the invention is used as a positive electrode of a lithium ion battery, a stable multi-stage modified surface can be constructed through element gradient doping and surface nano-composite structure coordinated regulation and control, material structure transformation and interface side reaction are inhibited, high voltage greater than or equal to 4.3 V is realized, the capacity retention rate greater than or equal to 90% of cycles greater than or equal to 100 times is realized, and voltage attenuation lt of each circle is realized; and the material has excellent performance of 1.5 mV, and is suitable for the fields of power batteries, energy storage and the like.

The invention provides a positive electrode material precursor, a preparation method thereof, a positive electrode material and a lithium ion battery. Wherein the positive electrode material precursor comprises a secondary particle with a core-shell structure, a core layer of the secondary particle comprises a plurality of first pores, and the long diameter D1 of the first pores is greater than or equal to 300nm; the porosity of the core layer of the secondary particle is 40%-60%, and the porosity of the shell layer of the secondary particle is 1%-10%. According to the positive electrode material precursor, the transmission rate of lithium ions can be improved, and the charge-discharge efficiency and the rate capability of the battery can be improved.

The present invention relates to the technical field of lithium-ion battery recycling and utilization, and specifically discloses a method for recycling and regenerating positive electrode materials from waste ternary lithium-ion batteries. The present invention uses a ternary deep eutectic solvent combined with microwave-assisted leaching to efficiently leach waste lithium-ion battery positive electrode materials, and then combines subsequent precipitation and adjustment of the molar ratio of metal elements to regenerate the positive electrode materials. The obtained recycled and regenerated positive electrode materials have good electrochemical properties. The technical solution provided by the present invention effectively solves the problems of high cost and complicated process flow of the existing method for recycling metals from waste ternary lithium-ion batteries, and the problem that when the recovered metals are used to prepare lithium battery positive electrode materials, the purity is insufficient, resulting in poor effect of the regenerated positive electrode materials. It provides a new idea for the treatment of waste ternary lithium-ion batteries.

The invention belongs to the technical field of lithium ion battery material recovery, and discloses a regeneration, repair and doping method of a waste lithium iron phosphate material and a regenerated positive electrode material. The method comprises the following steps: firstly, immersing waste LiFePO4 powder into a mixed solution of citric acid and ascorbic acid, oscillating to selectively dissolve out Fe < 3 + > impurities, and synchronously reducing Fe < 3 + > on the surface to Fe < 2 + >; then Li2CO3 is added into the leached powder for lithium bit compensation, and ball milling and uniform mixing are carried out; then Al2O3 and TiCl3 are added for aluminum-titanium co-doping, and ultrasonic dispersion is carried out uniformly; and finally, carrying out segmented sintering. In the first stage, sintering is carried out in an air atmosphere at 300-350 DEG C; in the second stage, sintering is performed at 600-700 DEG C in an inert gas atmosphere; and finally obtaining the regenerated positive electrode material. According to the method, waste lithium iron phosphate batteries can be turned into wealth, the lithium iron phosphate positive electrode material with good electrochemical performance is obtained, the complex and expensive impurity removal process is omitted, the cost is low, and possibility is provided for large-scale industrial regeneration and repair of waste lithium iron phosphate active substances.

The invention provides a method for preparing a high-voltage medium-nickel ternary positive electrode material by synergistic regeneration of a waste ternary lithium battery, which comprises the following steps: S1, taking a pretreated waste high-nickel and low-nickel ternary positive electrode material, calculating and supplementing a metal source and a lithium source according to the metal proportion of the actual content, and mixing the elements according to the total molar ratio of Li: (Ni + Co + Mn) = 1.0-1.1; s2, a composite fluxing agent containing lithium ion metal salt is added into the calibration mixture obtained in the S1, and two-stage sintering is carried out; and S3, coating the surface of the final product with a metal oxide aqueous solution corresponding to the lithium ion metal salt in the S2 as a coating agent to obtain the ternary positive electrode material. The nickel-rich characteristic of the high-nickel material and the manganese / cobalt-rich characteristic of the low-nickel material are utilized to form element complementation, so that the utilization rate of nickel, manganese and cobalt elements in the waste material is maximized, and the composition proportion limitation during regeneration of a single waste material is broken through.

The invention discloses a high-voltage single-crystal positive electrode material as well as a preparation method and application thereof, and belongs to the technical field of lithium ion batteries. The preparation method comprises the following steps: by taking MOFs (Metal Organic Frameworks) with a porous structure as a template, loading a ternary precursor in pore channels of the template by adopting a solvothermal method to prepare loaded MOFs; mixing the loaded MOFs with a lithium source, carbonizing and calcining in an inert atmosphere for high-temperature solid-phase reaction, carbonizing the template to form a nitrogen-doped porous carbon skeleton, and converting the ternary precursor into single-crystal NCM particles to prepare a calcined product; sequentially carrying out acid pickling, drying and airflow crushing treatment on the calcined product to obtain a composite material; the composite material is sequentially subjected to multi-section penetration type dry coating and sintering treatment, the high-voltage single-crystal positive electrode material is prepared, and the high-voltage single-crystal positive electrode material can balance the capacity, the cycle life and the safety under high voltage.

The invention belongs to the field of lithium recovery, and particularly relates to a method and a system for electrochemically recovering lithium ions in ternary lithium battery leachate. The method comprises the following steps: (1) leaching the cathode material of the waste ternary battery to obtain a ternary leachate; (2) performing lithium ion enrichment in a capacitive deionization device by taking the ternary leaching solution obtained in the step (1) as a lithium source to obtain a lithium-rich receiving solution and a lithium-removed recycling solution; (3) recovering the lithium-rich receiving liquid to obtain recovered lithium; and performing non-lithium metal element recovery on the lithium-removed recovery liquid. According to the technical scheme, the rocking chair type capacitive deionization RCDI system adopts a waste ternary battery cathode material (SNCM) as an electrode material, the extraction quantity of a single reaction cycle can reach 4.90 mM g <-1 >, continuous and selective lithium extraction is realized, and meanwhile, the cost and the environmental influence are reduced.

The invention discloses a device and a method for a circulating cooling water system, an electrophoresis device comprises an electrophoresis tank, a reaction tank and a sedimentation tank which are communicated in sequence, a cathode material is arranged in the electrophoresis tank, an electrophoresis anode tube group is inserted on the cathode material, the electrophoresis anode tube group is composed of a plurality of electrophoresis anode tubes which are arranged in parallel, and the electrophoresis anode tubes are arranged in the sedimentation tank. The electrophoresis anode tube is provided with an anode element, water inlet pipes, an anode tab and a water outlet pipe, the anode element is coated with an electrophoresis film, the top of the anode element is provided with a connecting pipe fitting, the water inlet pipes, the anode tab and the water outlet pipe penetrate through the connecting pipe fitting, and each water inlet pipe is communicated with a bypass water outlet of the circulating cooling water system; each water outlet pipe is communicated with a first water return port of the circulating cooling water system, a water inlet of the electrophoresis tank is communicated with the bypass water outlet, and a water outlet of the sedimentation tank is communicated with a second water return port. The electrophoresis method is implemented by adopting the electrophoresis device. According to the electrophoresis device and the electrophoresis method, the current density and the current efficiency can be improved, and descaling of medium and large circulating water systems is met.

The invention relates to the technical field of lithium ion batteries, in particular to a high-voltage lithium cobalt oxide positive electrode material and a preparation method thereof. According to the technical scheme, the chemical composition of the positive electrode material is at least two elements selected from Al, Mg, Ti and Zr. Through triple strategies of multi-element synergistic doping, core-shell structure design and surface defect regulation and control, breakthrough improvement of the performance of the high-voltage lithium cobalt oxide positive electrode material is achieved, and especially through the synergistic effect of a specific element combination Al + Mg + Ti and the coupling effect of the gradient-distributed F element and the nanometer defect structure, the performance of the high-voltage lithium cobalt oxide positive electrode material is improved. The structure phase change and the interface side reaction in the high-pressure circulation process are effectively inhibited, and the cycle life and the thermal stability of the material are remarkably improved.

The invention discloses a preparation method of a high-performance modified dry-method electrode and application of the high-performance modified dry-method electrode in a lithium metal battery, the method comprises the following steps: step 1, heating and hot-melting succinonitrile under a hydrothermal condition to obtain clear and transparent liquid, and then adding lithium salt into the clear and transparent liquid to complete preparation of a dry-method modified additive; 2, premixing a positive electrode material, vapor-phase growth carbon fibers and a dry-method modified additive; 3, adding an adhesive into the premixed material to obtain a modified dry-method electrode material; and step 4, pouring the modified dry-method electrode powder into a mortar, after preliminary film formation, gradually thinning to 60-75 m in thickness under a roller press, and finally performing hot rolling with a current collector to complete the preparation of the modified dry-method electrode. According to the invention, by adding the additive into the dry electrode, an excellent high-voltage-resistant electrode interface is constructed, and the lithium ion conduction rate of the electrode is improved, so that the electrochemical performance of the dry electrode is further improved, and the application of the dry electrode in a high-voltage lithium metal battery is promoted.

The invention relates to a method for selectively leaching and regenerating a positive electrode material from a waste lithium ion battery, and belongs to the technical field of lithium ion batteries. The method comprises the following steps: discharging, disassembling, crushing, calcining and screening the waste lithium ion battery, adding an obtained positive active material into an oxalic acid solution, and stirring and reacting at 60-80 DEG C under the irradiation of an ultraviolet lamp to obtain a leaching solution rich in metal elements and leaching residue iron phosphate; adding sodium carbonate into the leachate for reaction to obtain lithium carbonate; and ball-milling and mixing iron phosphate, lithium carbonate and a carbon source, drying and calcining to obtain the regenerated lithium iron phosphate positive electrode material. The oxalic acid system is catalyzed by ultraviolet light to generate hydroxyl free radicals with strong oxidizing property, so that the leaching efficiency of lithium is remarkably improved, and the dissolution of iron is inhibited, thereby realizing the efficient separation of lithium and iron. The leaching residue is high-purity iron phosphate, lithium in the leaching solution is recycled in the form of lithium carbonate, and the leaching residue and the lithium carbonate can be directly used for regenerating the lithium iron phosphate positive electrode material as precursors, so that the technological process is greatly simplified, and the production cost is reduced.

The invention discloses a battery positive electrode material particle automatic analysis method and system. The method comprises the following steps: inputting an SEM image into a deep learning model, carrying out instance segmentation on particles to obtain a particle contour area, carrying out multi-dimensional quantitative analysis, and extracting geometric and optical quantitative indexes of a particle contour; according to the geometric and optical quantitative indexes of the particle contour, particle quantitative index statistical characteristics are generated, the geometric and optical quantitative indexes and the statistical characteristics are input into a large language model for particle characteristic analysis, and an analysis report is generated. The method and the system can effectively solve the automation problem of particle identification and characteristic analysis in the SEM image, comprehensive particle characteristic data can be obtained without manual intervention, and the system is mainly used for high-precision quantitative analysis of morphological characteristics, size distribution and morphological parameters of battery positive electrode material particles. And key microstructure data support is provided for research and development, quality control and performance optimization of the positive electrode material of the lithium ion battery.

The present invention relates to a sodium ion battery comprising a positive electrode composition having improved battery performance and moisture and air stability. The positive electrode composition has the general formula NaxAzNiiMyMnjTikSbfO2, where A is an alkali metal or alkaline earth metal selected from Ca, Li, M is a divalent element or trivalent element selected from Fe, Mg, Zn, Cu, Al, Co, and Ni is a divalent element, Mn, Ti are tetravalent elements, and Sb is a pentavalent element / trivalent element, where (i + j + k + f + y = 1), 0.7 < = x < = 1, 0 < = z < = 0.2, 0.1 < = i < = 0.6, 0 < = y < = 0.5, 0.1 < = j < = 0.5, 0.05 < = k < = 0.4, and 0 < = f < = 0.2. The invention is suitable for energy storage application.

The application provides a coated layered oxide sodium ion battery positive electrode material with excellent cycle stability, the positive electrode material is coated with nano-aluminum oxide and nano-titanium oxide on the surface of Na 0.66 Ni 0.23 Cu 0.1 Mn 0.67 O2 material. The positive electrode material provided by the application exhibits excellent long cycle stability and has a wide commercial development prospect.

A rechargeable electrochemical cell (10) comprises an anode compartment (14) and a cathode compartment (15), the compartments being enclosed in part by metal plates (11, 12) that define end faces of the cell (10), the two compartments (14, 15) being separated by an impermeable, ion-conducting electrolyte element (13). The cell (10) is a molten sodium / metal chloride cell, and the plate (12) enclosing the cathode compartment defines a slightly concave end face surrounded by a flat rim. The volume change of the cathodic materials as the cell is heated up to its operating temperature are accommodated by flattening of the concave end face, so the overall thickness of the cell (10) does not change.