Patents
Literature
Eureka-AI is an intelligent assistant for R&D personnel, combined with Patent DNA, to facilitate innovative research.
Eureka AI

1108results about How to "High specific capacity" patented technology

Oxidized grapheme/polyaniline super capacitor composite electrode material and preparation method and application thereof

ActiveCN101527202AImprove double layer capacitanceExcellent supercapacitor performanceElectrolytic capacitorsHybrid capacitor electrodesPolyaniline compositeAniline
The invention discloses an oxidized grapheme/polyaniline super capacitor composite electrode material and the preparation method and the application thereof. The preparation method comprise the following steps: firstly, adding oxidized graphite to water for ultrasonic dispersion so as to form an oxidized grapheme solution with uniformly dispersed single pieces; at room temperature, dropping aniline to the obtained oxidized grapheme solution for continuous ultrasonic dispersion to from a mixed solution; at a low temperature condition, adding hydrogen peroxide, ferric trichloride and a hydrochloric acid solution dropwise to the mixed solution, and stirring the solution for polymerization; and after the reaction is finished, centrifugating, washing and roasting the obtained mixed solution in vacuum to obtain the oxidized grapheme/polyaniline super capacitor composite electrode material which is used as the electrode material of an electricity storage system of a super capacitor and a battery. The oxidized grapheme/polyaniline super capacitor composite electrode material with good electrochemistry performance is obtained by the method, and the specific capacity of the oxidized grapheme and the polyaniline is greatly improved. In addition, the addition of the oxidized grapheme improves the charge and discharge service life of the polyaniline.
Owner:NANJING UNIV OF SCI & TECH

Spinel nickel manganese acid lithium and layered lithium-rich manganese-based composite cathode material with core-shell structure and preparation method thereof

The invention relates to a spinel nickel manganese acid lithium and layered lithium-rich manganese-based composite cathode material with a core-shell structure and a preparation method thereof, which belongs to the technical field of material synthesis. The prepared lithium ion composite cathode material takes a layered lithium-rich manganese-based Li[Lia(NixCoyMnz)]O2 as a core material, takes spinel nickel manganese acid lithium LiNi0.5Mn1.5O4 as a shell material; a coprecipitation method is employed to obtain a core-shell precursor, the core-shell precursor and the lithium source are uniformly mixed and calcined to obtain the spinel nickel manganese acid lithium and layered lithium-rich manganese-based composite cathode material with the core-shell structure. According to the invention, the layered lithium-rich manganese-based is taken as the core material, and the spinel nickel manganese acid lithium is taken as the shell material; under the prerequisite that material gram capacity is kept, material structural stability is increased, material cycle, multiplying power and safety performances are improved, function composite and complementation of the core material and the shell layer material can be realized, and the problem that high capacity and high security can not be achieved simultaneously is solved. The composite cathode material has the advantages of simple process and obviously increased performance.
Owner:南京时拓能源科技有限公司

Nanometer lithium titanate/graphene composite negative electrode material and preparation process thereof

The invention relates to the field of negative electrode materials of lithium ion batteries, and specifically to a nanometer lithium titanate/graphene composite negative electrode material and a preparation process thereof. According to the invention, micron-sized lithium titanate prepared by the solid phase method is subjected to ultrafine ball milling to obtain nanometer powder, and the nanometer lithium titanate powder and graphene are uniformly compounded and subjected to heat treatment so as to obtain a high performance lithium ion battery negative electrode material; the invention is characterized in that uniform distribution of graphene in the nanometer lithium titanate powder is realized through in situ compounding; the weight of graphene in the composite negative electrode material accounts for 0.5 to 20%, and the weight of lithium titanate accounts for 80 to 99.5%. The lithium ion battery negative electrode material has good electrochemical performance, 1C capacity greater than 165 mAh/g, 30C capacity greater than 120 mAh/g and 50C capacity greater than 90 mAh/g. Nanometer lithium titanate in the lithium ion battery negative electrode material prepared in the invention has high phase purity; the preparation process of the material is simple and is easy for industrial production.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI

Synthesis and surface modification method of lithium excessive laminar oxide anode material

The invention relates to a synthesis and surface modification method of a lithium rich anode material Li1+xM1-xO2 (M is one or more of Ni, Co and Mn, and X is more than or equal to 0 and less than or equal to 1/3) for a lithium ion battery. The method comprises the following steps of: synthesizing a precursor by using a carbonate precipitation method, mixing the precursor and a lithium salt, and calcining for 2 to 20 hours at the temperature of between 800 and 1,100 EG C to obtain a lithium rich material, wherein the prepared lithium rich material has controllable particle size and higher reversible capacity; and dissolving persulfate or sulfate in an amount which is 5 to 80 mass percent of the lithium rich material into deionized water, adding the lithium rich material, stirring for 2 to 100 hours at the temperature of between 25 and 80 DEG C, heating the materials to the temperature of between 100 and 500 DEG C in a muffle furnace, calcining the materials for 2 to 20 hours, fully filtering the obtained materials, and washing off impurities to obtain the surface modified anode material Li1+x-yM1-xO2. The synthesized lithium rich material has controllable particle size; the first charge/discharge efficiency of the lithium rich material and the discharge specific capacity and the cyclical stability under high magnification can be improved; and the method is simple, low in cost, convenient for operation and suitable for industrialized production.
Owner:GUANGZHOU HKUST FOK YING TUNG RES INST

Preparation method of high density nickel cobalt lithium manganate positive electrode material

The invention discloses a preparation method of a high density nickel cobalt lithium manganate positive electrode material, LiNixCoyMnzO2. The preparation method comprises the following steps: firstly, mixing a nickel salt solution, a cobalt salt solution and a manganese salt solution according to a certain mol ratio, adding the mixed solution, a complexing agent solution and a precipitant solution together to a stirring reaction kettle with a base solution, fully reacting, carrying out solid-liquid separation, and washing and drying to obtain a globular nickel cobalt manganese oxyhydroxide precursor; calcining the precursor at the temperature of 350-900 DEG C for 2-20 hours to obtain a globular nickel cobalt manganese oxide precursor, and smashing the globular nickel cobalt manganese oxide precursor at high speed to obtain a mono-crystalline nickel cobalt manganese oxide precursor; mixing a lithium source and the mono-crystalline precursor according to a certain mol ratio, calcining at the temperature of 700-980 DEG C for 2-20 hours, and smashing and classing to obtain the mono-crystalline nickel cobalt lithium manganate positive electrode material. The preparation method provided by the invention has the advantages that the compacted density of the prepared nickel cobalt lithium manganate material is large, the specific capacity is high, the rate property and consistency are good, the preparation method is simple, and the preparation process is easy to control and operate.
Owner:HUNAN SOUNDDON NEW ENERGY

Method for preparing nitrogen-doped carbonaceous material by modifying polymer

The invention discloses a method for preparing a nitrogen-doped carbonaceous material by modifying polymer, which can be used for preparing the nitrogen-doped carbonaceous material with the nitrogen doping amount of 5 to 26 at%. The method disclosed by the invention is characterized by comprising the following steps of: selecting a nitrogen-containing organic compound as a nitrogen precursor and utilizing the nitrogen-containing organic compound to perform polymerization reaction on a carbonaceous material to form a compound of the nitrogen-containing polymer and carbonaceous material; and then carrying out heat treatment on the polymer/carbonaceous material compound in the inert atmosphere to carbonize nitrogen-containing polymer in the compound so as to implement the nitrogen doping on the carbonaceous material and prepare the nitrogen-doped carbonaceous material. According to the invention, when the carbonaceous material is subjected to effective nitrogen doping, the original intrinsic structure of the carbonaceous material can be ensured; moreover, the nitrogen-doped carbonaceous material with the nitrogen content of 5 to 26 at% can be prepared; the specific capacity of using a carbon material as an electrode material of a supercapacitor is obviously improved; and the method has the characteristics of simple technical process and wide applicability.
Owner:UNIV OF SCI & TECH LIAONING

Porous carbon electrode material based on chitosan and derivative of chitosan thereof as well as preparation method and application of porous carbon electrode material

The invention discloses a porous carbon electrode material based on chitosan and a derivative of chitosan as well as a preparation method and application of the porous carbon electrode material. According to a hard template carbonization method, by taking a hollow silicon oxide ball as a template and taking chitosan and a derivative of chitosan as carbon source precursors, liquid-phase impregnation, high-temperature carbonization, template removing and the like are carried out so as to obtain the porous carbon electrode material suitable for a lithium ion battery and a supercapacitor. The prepared porous carbon electrode material simultaneously has the characteristics of a nitrogen-doped structure and a macroporous-mesoporous-microporous graded pore structure, wherein the nitrogen-doped content can be controlled by using different types of chitosans; the graded pore structure can be controlled by changing the size of the particle diameter and the wall thickness of each silicon oxide ball and regulating the mass of the chitosan solution. Compared with the commercialized graphite, the porous carbon electrode material prepared according to the method disclosed by the invention has the advantages that the specific capacity is obviously increased and the rate performance of the obtained porous carbon electrode material is maintained well. The porous carbon electrode material is simple in preparation process, has no strict requirement to equipment and is suitable for industrial production.
Owner:HUBEI ENG UNIV

High-voltage lithium cobalt oxide cathode material for lithium-ion battery and preparation method of high-voltage lithium cobalt oxide cathode material

The invention discloses a high-voltage lithium cobalt oxide cathode material for a lithium-ion battery and a preparation method of the high-voltage lithium cobalt oxide cathode material. The high-voltage lithium cobalt oxide cathode material is prepared from a doped lithium cobalt oxide matrix and a coating on the surface of the doped lithium cobalt oxide matrix, wherein a general formula of the doped lithium cobalt oxide matrix is Li<x>Co<1-y>M<y>O<2-z>N<z>; the general formula of the coating is LiNi<x'>Co<y'>Al<z'>O<2>; and the preparation method comprises the following steps: firstly, obtaining the lithium cobalt oxide matrix Li<x>Co<1-y>M<y>O<2-z>N<z> through once sintering; secondly, preparing a lithium cobalt oxide cathode material precursor coated with Ni<x'>Co<y'>Al<z'>(OH)<2> on the surface by liquid-phase co-precipitation reaction; and finally obtaining the high-voltage lithium cobalt oxide cathode material through twice sintering. The high-voltage lithium cobalt oxide cathode material prepared by the method is good in processability and high in compaction density, has relatively high specific capacity and good cycle performance in a high-voltage state, and can be stably circulated at high voltage of 3.0V to 4.5V.
Owner:HUNAN CHANGYUAN LICO CO LTD +1

Method for producing iron lithium manganese phosphate composite positive electrode material used in lithium ion battery through carbon reduction

The invention discloses an iron lithium manganese phosphate composite positive electrode material used in a lithium ion battery, and a preparation method thereof. The method provided by the invention is mainly aimed at improving the performance of a lithium ion battery positive electrode material. The method comprises specific steps that: a lithium source is mixed with an iron source, a manganesesource, a phosphorous source, a reducing agent, and doped elements; the mixture is subject to a reaction, such that a compound of an iron lithium manganese phosphate precursor, a lithium source, manganese phosphate, ferric phosphate, phosphate and doped elements is prepared; the compound is mixed with a lithium source and a reducing agent carbon source; and the mixture is sintered under a protective atmosphere, such that the iron lithium manganese phosphate composite positive electrode material is obtained. The method provided by the invention is advantaged in simple technology, low material cost, low production cost, short production period, and low energy consumption. The method can be applied in large-scale productions. The product prepared with the method is advantaged in high bulk density, good conductivity and high specific capacity.
Owner:济宁市无界科技有限公司

Spherical silicon-oxygen-carbon negative electrode composite material and preparation method and application thereof

The invention discloses a spherical silicon-oxygen-carbon negative electrode composite material, which is of a three-layer structure comprising an inner layer, an intermediate layer and an outer layer, wherein the inner layer is an SiOx/graphite substrate; the intermediate layer is an amorphous carbon coating layer; the outer layer is a carbon nanotube coating layer; the mass of the inner layer SiOx/graphite substrate accounts for 80%-90% of total mass of the spherical silicon-oxygen-carbon negative electrode composite material; the mass of the intermediate layer amorphous carbon accounts for 5%-10% of total mass of the spherical silicon-oxygen-carbon negative electrode composite material; and the outer layer carbon nanotube accounts for 5%-10% of total mass of the spherical silicon-oxygen-carbon negative electrode composite material. The grain diameter of the adopted SiOx substrate is smaller than 5 microns; the grain diameter is relatively small; intercalation and deintercalation of active substances are facilitated; higher specific capacity can be obtained; meanwhile, a dispersing agent is added when an SiOx sample is ground; and condition that the SiOx with a relatively small grain diameter is agglomerated in quantity to affect the performance is prevented.
Owner:ZHONGTIAN ENERGY STORAGE TECH

Coprecipitation-combustion synthesis method for lithium nickel cobalt manganate

The invention discloses a process of coprecipitation-combustion synthesis of nickel cobalt manganese lithium carbonate. (1) Utilizing acetate or nitrate of nickel, cobalt, and manganese as transition metal source and ammonia as complexing agent and utilizing H2C2O4, (NH4)3C2O4, (NH4)2CO3 or NH4HCO3 as precipitator, compound carbonate contained Ni-Co-Mn or oxalate precursors is synthesized by coprecipitation method. (2) Directly drying the compound carbonate containing Ni-Co-Mn or the suspension liquid of the oxalate and adding lithium nitrate or lithium acetate or a small quantity of water or ethanol to adjust into rheological phase. (3) Laying the materials in rheological phase in an electric stove to perform burning synthesis reaction, wherein the electric stove heats the materials in rheological phase at temperature of 400-600DEG C and then keeps constant temperature. (4) Temper drawing the reaction product with temperature of 600-1200DEG C, and anode active materials of lithium ion battery LiNixCoyMn1-x-yO2 is obtained. The invention has the advantages of simple technique, easy operation, saving water and energy and environment-friendliness, further, the synthetic material is provided with the shape of sphere or near-sphere, high specific capacity and fine cycle performance.
Owner:GUILIN UNIVERSITY OF TECHNOLOGY

Water-based zinc-manganese single flow battery

ActiveCN105336971AIncrease the speed of mass transferEliminate deformationRegenerative fuel cellsWater basedManganese oxide
The invention relates to a water-based zinc-manganese single flow battery; a positive electrode active material is an oxide of manganese, a metal composite oxide, a metal oxide or a carbon material, a negative electrode is a zinc electrode, an electrolyte solution is a nearly neutral aqueous solution containing a zinc salt and a manganese salt, positive electrode active ions and negative electrode active ions can coexist in one electrolyte solution, and an ion exchange membrane is not required for separating the positive electrode and the negative electrode; in processes of charging and discharging, the electrolyte solution constantly flows between an electrolyte solution storage tank and an electric pile through a pipeline under pushing of a liquid pump. During charging, zinc ions are deposited onto a negative electrode current collector from the electrolyte solution, the zinc ions and manganese ions are co-embedded into the positive electrode active substance at the same time, and the manganese ions are subjected to oxidation deposition; during discharging, the negative electrode deposited zinc is dissolved into the electrolyte solution, and the positive electrode manganese oxide is partially reduced and dissolved and is extricated to the electrolyte solution with the zinc ions simultaneously. The battery has the outstanding characteristics of simple manufacture, relatively high specific energy and specific power, low cost, long cycle life, environmental friendly and the like, and is widely applied in electric power, transportation, electronics and other fields.
Owner:NO 63971 TROOPS PLA

Lithium manganate composite positive electrode material, a preparing method thereof and a lithium-ion battery

The invention provides a lithium manganate composite positive electrode material, a preparing method thereof and a lithium-ion battery. The composite positive electrode material is of a core-shell structure. The inner layer of the composite positive electrode material is an in-situ composite of lithium manganate and nickel-rich concentration gradient type nickel cobalt manganese/lithium aluminate LiMn2O4-LiNi1-x-yCox(Al/Mn)yO2, wherein x is more than 0 and less than or equal to 0.25, and y is more than 0 and less than or equal to 0.15; the outer shell of the composite positive electrode material is a metal oxide coated layer. According to the lithium manganate composite positive electrode material and the preparing method thereof, the in-situ composite of lithium manganate and nickel-rich concentration gradient type nickel cobalt manganese/lithium aluminate is obtained after in-site sintering of a manganese source, a nickel-rich concentration gradient type nickel cobalt manganese/lithium aluminate precursor, and a lithium source, then shell-layer metal oxide is cladded by using spray drying, and finally the composite positive electrode material is obtained by combining a microwave sintering process. The composite positive electrode material provided by the invention has relatively high specific capacity, and excellent high temperature cycling and storage performances.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products