The invention discloses a preparation method of a
photonic crystal with an inverse opal structure, and belongs to the technical field of the
photonic crystal with the inverse opal structure. The preparation method comprises the following technological steps of: firstly adding
polymeric microspheres to colloidal
sol in proportions, and then dispersing the mixture for 10-60 minutes by using ultrasonic
waves so as to form a uniform stable suspension
emulsion; transferring the prepared suspended
emulsion to a
glass container, and vertically placing a clean substrate in the
glass container filled with the suspended
emulsion; then slantwise placing the
glass container on a heating platform, and heating so as to volatilize a
solvent; utilizing a binary synergistic effect for ensuring that
polymeric microspheres and the colloidal
sol grow on the substrate in a self-organizing manner to form a
polymer; after ending growth, taking out a sample, and heating in air under an appropriate temperature condition so as to decompose and volatize the
polymer; cooling and taking the sample to obtain the
photonic crystal with the inverse opal structure, which has good degree of
crystallinity and no defects and is large in area.