242 results about "Silanol" patented technology

The invention discloses a phosphate ester type composite binder for a sulfide battery, the phosphate ester type composite binder comprises a solute and a solvent, the solute comprises the following components in percentage by mass: 49.75%-88.5% of a binder, 9.5%-49.75% of phosphate ester and 0.45%-1.96% of silanol; the solvent is a non-polar solvent, and the mass ratio of the solute to the solvent is 1%: (10%-90%); the preparation method comprises the following steps: S1, placing the binder in a non-polar solvent, and heating and stirring until the binder is completely dissolved to obtain a solution A; s2, mixing a silane coupling agent with absolute ethyl alcohol, adjusting the pH value with acetic acid, and stirring to generate silanol; s3, silanol is added into the solution A, so that one end of silanol reacts with active hydrogen of the binder for bonding; and S4, adding phosphate into the solution A, so that the other end of the silanol is combined with a group of the phosphate to obtain a reaction solution with a binder-silanol-phosphate structure. According to the invention, stable combination of the binder and phosphate is realized through a silanol-mediated grafting structure, and the interface stability, the ionic conductivity and the mechanical strength are improved.

The invention relates to the technical field of high-molecular compound preparation, in particular to a high-molecular compound preparation method and system.The method comprises the steps that distilled water and boron nitride are added into a container containing silane monomers, stirring reaction is conducted for 3-5 h, and a hyperspectral image of a mixed solution in the container in the stirring reaction process is collected; the method comprises the following steps: acquiring spectral similarity factors of matched pixels in a hyperspectral image, judging the fullness degree of a stirring reaction according to the distribution characteristics of the spectral similarity factors of the pixels, completing the stirring reaction, mixing the prepared boron nitride modified organic silicon resin, silanol, polyester resin and a crosslinking catalyst, continuously reacting for 2-4 hours at 110-130 DEG C, adding an organic solvent, and uniformly stirring to obtain the boron nitride modified organic silicon resin. The solid content of the modified polyester resin is 62-66%. The invention aims to improve the performance and prolong the service life of the prepared modified polyester resin, and realizes the preparation method of the high-molecular compound.

The invention discloses vinyl fluorine-containing polysiloxane and a preparation method thereof, and relates to the technical field of organic silicon materials. According to the invention, high-activity fluorine-containing potassium hydroxide silanolate is used as a catalyst to realize high-efficiency catalysis; d3F serves as a main monomer, D3Vi serves as a comonomer, deionized water is introduced for the first time to serve as a retarder, and implosion is effectively inhibited; vinyl dimethyl ethyoxyl silane is used as an end-capping reagent for the first time, end group vinylation is synchronously realized, and end group and side chain divinyl polysiloxane is prepared; through cooperation of ring-opening polymerization and condensation polymerization, the reaction process is mild and controllable, the product viscosity is controllable, the crosslinking activity is high, and the application range is remarkably widened.

Methods and compositions including a CO2 foam treatment fluid having a plurality of functionalized silanol group silica nanoparticles the silanol group selected from the group consisting of an isolated silanol group, a vicinal silanol group, a geminaol silanol group, and any combination thereof; and a surfactant. The CO2 foam treatment fluids can be used for stimulation of subterranean formations for hydrocarbon production.

The invention discloses a solid electrolyte membrane for constructing a grain boundary bridge based on an APTES coupling agent and a preparation method of the solid electrolyte membrane, and belongs to the technical field of lithium batteries. According to the composite film, a gallium-doped lithium ion conductor is used as an inorganic phase, a polymer is used as an organic phase, APTES is added for ball milling, an APTES siloxane group is hydrolyzed to generate silanol, the silanol and hydroxyl on the surface of inorganic filler LGLZO are subjected to condensation, terminal amino and the polymer form a hydrogen bond, and a grain boundary bridge is successfully constructed. By adding the APTES coupling agent, the organic-inorganic interface compatibility can be enhanced, the growth of lithium dendrites can be inhibited, the interface impedance can be reduced, the interface stability and the lithium ion transmission efficiency can be improved, and the structural integrity and the electrochemical performance of the battery in the cycle process can be guaranteed; and important theoretical guidance and experimental basis are provided for structural design and performance optimization of the composite solid electrolyte membrane.

To provide a surface treatment agent composition comprising a silicone-based compound and capable of achieving both durable water repellency and resistance to peeling, and to provide a water / oil-repellent fiber product and a method for producing the same.SOLUTION: A surface treatment agent composition comprises: a silicone resin (A); and an organopolysiloxane (B) containing silanol groups, wherein the silicone resin (A) includes, as a component, at least one selected from MQ, MDQ, MTQ, and MDTQ {M, D, T, and Q respectively represent (R'')3SiO0.5 units, (R'')2SiO units, R''SiO1.5 units and SiO2 units, and R'' represents a monovalent aliphatic hydrocarbon group having 1 to 10 carbon atoms or a monovalent aromatic hydrocarbon group having 6 to 15 carbon atoms}.SELECTED DRAWING: None

The invention belongs to the field of catalyst preparation, and particularly relates to a platinum-based bimetallic propane dehydrogenation catalyst and a preparation method thereof. The method comprises the following steps: firstly, weighing beta molecular sieve powder, adding into a concentrated nitric acid solution, stirring and refluxing at high temperature, centrifugally washing, and drying to obtain a dealuminated beta molecular sieve; then calcining the metal additive oxide powder and the dealuminated beta molecular sieve in a reducing atmosphere to obtain composite beta molecular sieve powder; then weighing platinum precursor salt, dissolving the platinum precursor salt in ultrapure water to form a solution, and then adding ethylenediamine for coordination; and finally, impregnating the composite beta molecular sieve with a platinum precursor solution, and carrying out aging, drying and high-temperature treatment to obtain the dealumination beta molecular sieve loaded platinum-based bimetallic catalyst. According to the method provided by the invention, the metal is spontaneously and highly dispersed on the carrier by utilizing the capturing effect of the beta molecular sieve silanol nest on the metal and combining the dynamic migration behavior of the metal under high-temperature reduction. The prepared catalyst shows extremely high propane conversion activity and selectivity at 600 DEG C, and is excellent in stability.

The invention discloses an Ectoin and hydrolyzed collagen silanol composition as well as a preparation method and application thereof. The preparation method comprises the following steps: preparing a hydrolyzed collagen silanol derivative: hydrolyzing a silane coupling agent in an acidic organic solvent aqueous solution to obtain silanol hydrolysate; the preparation method comprises the following steps: dissolving hydrolyzed collagen in deionized water, adjusting the pH value to 8-10, stirring, adding silanol hydrolysate for reaction, cooling to room temperature, and freeze-drying to obtain hydrolyzed collagen silanol derivative powder; the preparation method comprises the following steps: preparing an Ectoine and hydrolyzed collagen silanol composition: dissolving hydrolyzed collagen silanol derivative powder and Ectoine in pure water together, and carrying out ultrasonic treatment to obtain the Ectoine and hydrolyzed collagen silanol composition, the prepared composition can inhibit skin heat injury, inhibit skin inflammatory response, promote skin collagen regeneration and repair skin barrier, and can be applied as a raw material of skin care products or medical beauty products.

The invention belongs to the technical field of coatings, and particularly relates to a water-based woodware varnish as well as a preparation method and application thereof. The water-based wood top-coat comprises a water-based emulsion, an organosilicon compound, a functional additive, a thickening agent, a wetting agent and water, the water-based emulsion comprises a self-crosslinking acrylic copolymer emulsion and an emulsion A; the emulsion A is selected from any one of self-crosslinking acrylic acid homopolymerized emulsion and polycarbonate modified polyurethane emulsion; the organosilicon compound comprises at least one of silane and silanol; the functional auxiliary agent comprises any one of a functional auxiliary agent 1 and a functional auxiliary agent 2; the functional additive 1 comprises a mildew preventive A and a mildew preventive B; the functional auxiliary agent 2 comprises a mildew preventive C, an ultraviolet light absorber and an ultraviolet light stabilizer; the thickeners include high shear, medium shear, and low shear polyurethane thickeners. The water-based woodware varnish disclosed by the invention has good comprehensive properties such as mildew resistance, weather resistance, chemical resistance and blocking resistance, and can be used for coating outdoor woodware or semi-outdoor woodware.

The purpose of the present invention is to provide a filler for a chromatography column, a chromatography column, a method for producing a chromatography column, a chromatography device, and an analysis method, which are suitable for separation or the like of a mixture containing various analytes. The column filler for chromatography is characterized in that the silanol group of silica contained in the filler is modified with a group represented by chemical formula (I). [Formula I]

The invention belongs to the technical field of organic silicon synthesis, and particularly relates to low-ring-content silicone oil and a preparation method thereof, and the silicone oil comprises the following components in percentage by mass: 92-97% of DMC, 0.2-0.8% of crown ether, 0.5-2% of a phosphazene alkali silicon alkoxide catalyst, 0.4-2% of a phosphosilyl ester neutralizer and 0.35-3.5% of divinyl tetramethyl disiloxane. The novel phosphazene alkali silicon alkoxide catalyst and the phosphoric acid silicon ester neutralizer are adopted, so that the'back-biting 'cyclization phenomenon is greatly restrained in the polymerization process, and the reaction conversion rate and efficiency are improved; the Fe3O4-beta-cyclodextrin composite material is selected as an adsorbent of a ring body, so that the content of cyclosiloxane is reduced, the magnetic recovery rate is high, the thermal stability is high, and the biological safety is better; the volatile component content of the prepared low-ring-content silicone oil is less than 0.2% (150 DEG C / 3h), the ring content (D3-D10) is less than 200ppm, and the ring content meets the requirements of electronics, food and medical levels.

The application discloses a preparation method of a composite antioxidant and application thereof, and belongs to the field of high polymer materials. In the application, a ring octene and a silicon-containing cyclic olefin monomer are subjected to metathesis copolymerization under the action of a metathesis catalyst, a silicon-containing polymer is obtained after chemical hydrogenation, and then the composite antioxidant is obtained after hydrolysis and mixing with lignin. The main chain of the composite antioxidant is a saturated hydrocarbon chain, the compatibility with polyethylene is high, the silicon-containing polymer is hydrolyzed to generate active silanol, the active silanol is efficiently bonded with lignin, and the lignin provides natural polyphenol antioxidant function. The application realizes efficient antioxidant of the composite material, high compatibility and long-term durability, and provides a new idea for high-performance environment-friendly high polymer composite materials.

Provided is a film-attached article 10 comprising a substrate 1 and a film 2 containing a silicon oxide on the substrate 1, wherein the film-attached article satisfies any one of the following (a) to (c). (a) Film thickness: less than or equal to 150 nm; Si–OH ratio: between 0.03 and 0.2, inclusive (b) Film thickness: greater than 150 nm and less than or equal to 400 nm; Si–OH ratio: between 0.07 and 0.3, inclusive (c) Film thickness: greater than 400 nm and less than or equal to 700 nm; an Si–OH ratio: between 0.15 and 0.5, inclusive The Si-OH ratio is the ratio of the peak intensity near 950 cm-1 attributed to a silanol group to the peak intensity near 1100 cm-1 attributed to a siloxane bond in Fourier transform infrared spectroscopy of the film.

A method for improving drug solubility and a drug composite material having improved solubility. The method comprises preparing a silica colloidal suspension from silica nanoparticles having a diameter between 2 nm and 100 nm; rapidly evaporating a solvent by means of controlling the temperature and pressure, so as to obtain a porous surface material with ultra-high density silanol groups retained on the surface; and loading drug molecules. By controlling the size of nanoparticles and the density of silanol groups, drug molecules can be effectively adsorbed under anhydrous conditions, and rapidly desorbed and released in an aqueous environment.

Provided is a laminated optical film in which at least a retardation film and an optical film other than a polyvinyl alcohol film are laminated via a molecular adhesive layer, the molecular adhesive layer being a cured product layer of a molecular adhesive having at least one reactive group selected from the group consisting of silanol groups and alkoxysilyl groups, and the molecular adhesive layer being a cured product layer of a molecular adhesive having at least one reactive group selected from the group consisting of silanol groups and alkoxysilyl groups. When the smoothness of a laminate of the entire laminated optical film is set as beta, beta < 0.45 arcmin is satisfied. The optical film is preferably a phase difference film. The thickness of the molecular adhesive layer is preferably 1 nm or more and 100 nm or less. The thickness of the retardation film is preferably 5 [mu] m or less.

A method of making an oven cavity of a cooking appliance, and a cooking appliance made therewith, are provided. The method includes forming a composite sheet via sheet molding compound. The composite sheet includes glass fiber impregnated with silicone polymer. An intermediate assembly is formed by disposing a layer comprising an insulative material onto a first layer of the composite sheet. The intermediate assembly is inserted into a mold. A compression load is applied to the intermediate assembly in the mold to obtain a molded piece. One or more of the molded piece forms a composite body that defines the oven cavity of the cooking appliance. The silicone polymer may include one or more of poly dimethylsiloxane, poly methylphenyl silanol, poly diphenyl silanol, and poly vinyl functional backbone silicones having methyl hydrosilane crosslinkers. The insulative material may include ceramic foam, hollow glass microspeheres, or recycled glass powder.

The invention discloses an electrochemical method of deuterated silane. The method comprises the following steps: in a protective atmosphere, mixing substituted silane, an electrolyte, a nickel catalyst, a ligand and deuterium water in a solvent, carrying out an electrochemical deuterization reaction under a constant current condition, and carrying out post-treatment to prepare the deuterated silane compound. The method takes deuterium water as a deuterium source, and is green, economical, cheap and easy to obtain; a catalytic amount of nickel and silane form a silicon-nickel intermediate, so that the polarity of silicon is reversed, and the generation of a silane self-coupling product and a silanol byproduct is effectively avoided; the electrochemical synthesis method has the characteristics of mild reaction conditions, cleanness, greenness and simplicity in reaction operation. The electrochemical synthesis method provided by the invention realizes successful preparation of the natural product post-modified deuterated silane, and has important significance in the aspects of drug development and deuterated compound research; the electrochemical synthesis method disclosed by the invention can resist high current to prepare the ten-gram-grade deuterated silane, and has a wide industrial application prospect. In addition, the deuterated silane synthetic product can be used as a silicon deuteration reagent, the practicability of the deuterated silane synthetic product in unsaturated bond reduction reaction is proved, and the deuterated silane synthetic product has a wide development prospect.

A water repellent and oil repellent member which has a functional film layer serving as the first layer on at least one surface of a base material, while having a primer layer serving as the second layer on the outer surface of the functional film layer and additionally having a water repellent and oil repellent layer serving as the third layer on the outer surface of the primer layer, wherein: the primer layer is formed of a layer that has a film thickness of 10-500 nm, while being mainly composed of an organosilicon compound which has a plurality of silanol groups in each molecule; and the water repellent and oil repellent layer is formed of a layer that has a film thickness of 0.5-50 nm, while being mainly composed of a cured product of a hydrolyzable fluorine-containing compound. This water repellent and oil repellent member has excellent rubber eraser abrasion resistance, while exhibiting excellent antistatic properties. In addition, the present invention is capable of forming a water repellent and oil repellent layer having excellent rubber eraser abrasion resistance and excellent antistatic properties on various base materials.

The invention discloses an antibacterial composite coated fabric suitable for a physiological period, a swimsuit and a preparation process, and belongs to the field of textile fabrics, a C = N Schiff base covalent bond is formed through a coating-fiber interface, o-quinone generated by oxidation of tannic acid and cotton hydroxyl / chitosan amino are subjected to a Schiff base reaction to generate irreversible C = N crosslinking, and through hydrolytic condensation of KH-550, the antibacterial composite coated fabric suitable for the physiological period, the swimsuit suitable for the physiological period and the preparation process of the swimsuit suitable for the physiological period are obtained. Silanol and cellulose hydroxyl are dehydrated to form hydrolysis-resistant ether bonds, so that a water molecule insertion path of a coating-fiber interface is blocked, and high hydrophobicity is provided; the prepared antibacterial composite coating fabric has the advantages of super-hydrophobicity, antibiosis, self-repairing and one-way moisture conduction, and is suitable for the fields of female bathing suit cushion layers, medical nursing clothes, protective clothing, washable medical clothing and the like.

The invention relates to the field of skin care products, and discloses an unsaturated silanol composition and application thereof in skin care, the composition comprises organosilanol, plant essential oil microcapsules, glycerin, hyaluronic acid, caprylic / capric polyethylene glycol glyceride and purified water; the general formula of the organosilanol is X-Si (OH) 2-Y; wherein: X is a vinyl group, an allyl group, a linear or branched C1-C4 alkyl group; y is a vinyl group, an allyl group,-OCH3,-OCH2CH3,-OCH2OH,-OCH2CH2OH, a linear or branched C1-C4 alkyl group; the plant essential oil microcapsule is prepared by using modified agar prepared by reacting octenyl succinic anhydride with agar, modified beta-cyclodextrin prepared by grafting mono-6-p-toluenesulfonyl-beta-cyclodextrin with chitosan and sodium alginate as wall materials, plant essential oil as a core material and calcium chloride as a cross-linking agent through an extrusion method and a freeze-drying method. And the composition with good antibacterial and antiseptic capabilities, skin barrier reparability and moisturizing and water locking effects is prepared.

The invention provides a waterproof heat-resistant mold coating which comprises the following components: modified acrylic resin, modified silicon dioxide, epoxy resin, kaolin, talcum powder, hexagonal boron nitride, zinc stearate, graphite, a solvent and an auxiliary agent, wherein the modified acrylic resin is obtained by polymerizing acrylic acid and butyl methacrylate and then grafting 2-fluoro-5-(trifluoromethyl) benzyl alcohol and triisopropyl silanol; the modified silicon dioxide is obtained by grafting perfluorooctyl ethylene, phenyl methacrylate, hydroxyethyl methylacrylate and oleic acid after silicon dioxide and a silane coupling agent react with each other. According to the waterproof heat-resistant mold coating disclosed by the invention, a silicon-oxygen bond, a benzene ring, a long fluorine chain and an organic chain segment are introduced into the modified silicon dioxide, and the silicon-oxygen bond, the benzene ring, the fluorine chain and the organic chain segment are introduced into the modified acrylic resin, so that the heat resistance, hydrophobicity and other properties of the coating are improved, and the waterproof heat-resistant mold coating has a good application prospect.

The invention discloses a performance improvement mechanism and a preparation method of a modified Aga soil material, a silane coupling agent and hydraulic lime are added into traditional Aga soil (Aga soil, water, elm bark juice and clear oil), and the modified Aga soil material is formed by combining a Tibetan ramming process. The modification principle is as follows: a silane coupling agent is dissolved in water to form a silanol solution, the silanol solution permeates into Aga soil along with ramming after being sprayed, and the hydraulic lime and the Aga soil are subjected to a pozzolanic reaction to generate a gelling product mainly comprising hydrated calcium silicate, so that the bonding and overall mechanical properties among particles of the Aga soil are improved; silanol and hydroxyl groups on the surface of the gelling product are subjected to dehydration condensation to form siloxane covalent bonds and enhance the structural stability; then, the silanol molecules are subjected to cross-linking polymerization, an organosilane polymer hydrophobic membrane is formed on the surfaces of the Aga soil and the gelling product, moisture is effectively blocked, and the water resistance and the impermeability of the Aga soil material are improved. The preparation method disclosed by the invention is simple, convenient, green and environment-friendly, can obviously improve the mechanical and durability of Aga soil, and has a good engineering application prospect.

The present invention provides a non-fluorine-based (i.e., a non-fluorine-based, non-fluorine-based, non-fluorine-based, non-fluorine-based, non-fluorine-based, non-fluorine-based, non-fluorine-based, non-fluorine-based, non-fluorine-based, non-fluorine-based, non-fluorine-based, non-fluorine-based, non-fluorine- ), an article surface-treated with the surface treatment agent, and a method for forming a coating film by applying the surface treatment agent on a substrate. A non-fluorine-based surface treatment agent containing: (A) a non-fluorine-based hydrocarbon terminal group-containing compound having at least one C4-32 linear, branched or cyclic monovalent hydrocarbon group at a molecular chain terminal and having at least one reactive silyl group at another molecular chain terminal, and / or a partial reaction condensate thereof; and (B) a compound having a functional group and a silanol group or a hydrolyzable silyl group at a molecular chain terminal, or a compound having a silanol group or a hydrolyzable silyl group at both molecular chain terminals: 1-50 mass% of the total of component (A) and component (B).

The application belongs to the field of aerospace coating, and particularly relates to a primer for the outer protective coating of a spacecraft, a preparation method and a use method. The primer comprises the following raw materials in parts by weight: tackifier 2-8 parts, alkyl silicone oil 5-10 parts and diluent 80-90 parts. The primer contains a large amount of inorganic / organic groups, can form a strong chemical bond with the substrate, and improve the adhesion of the coating. Meanwhile, the primer can also have interpenetration synergy with the silicone resin in the coating to form a PIN network structure, further improving the adhesion. In addition, the primer can also be activated to generate silanol under the condition of water molecules, and hydrolysis and bonding with inorganic media to form a firm silicon-oxygen bond. That is, the primer has inorganic / organic dual properties, is applied between organic and inorganic materials, and forms a micro organic-inorganic interface between the two, thereby enhancing the adhesion.

To address the problem that conventional technology lacks satisfactory sealing performance for a penetration hole formed when a foreign object such as a nail penetrates a tread portion.SOLUTION: A sealant composition is a two-component curable system comprising: (i) a silanol-terminated polydimethylsiloxane having at least two hydroxyl functional groups per molecule; (ii) a crosslinking agent; (iii) a condensation catalyst selected from the group consisting of titanate and / or zirconate; (iv) a filler; and (v) a hollow body having a true specific gravity of 0.3 or less and an average particle diameter of 20 μm to 200 μm, wherein an amount of the hollow body is 0.1 to 100 pts.mass relative to 100 pts.mass of the component (i) silanol-terminated polydimethylsiloxane.SELECTED DRAWING: Figure 1

A method for producing hydrophobic dry surface-modified fibrillated cellulose to improve dispersion in hydrophobic matrices includes: providing micro-fibrillated cellulose suspension of 5-30 wt % in water; adding a surfactant to the suspension with a mass ratio of surfactant to micro-fibrillated cellulose suspension of 0.1-2.0 wt %; adding a surface modifier to the suspension with a mass ratio of surface modifier to micro-fibrillated cellulose dry matter of 20-300 wt %, with the surface modifier obtained through a chemical reaction of a silane compound with a phenolic compound to create covalent bonds between the silane compound and the phenolic compound; covalently binding the surface modifier to the micro-fibrillated cellulose via (i) hydrolysis of the surface modifier to form reactive silanol groups and (ii) condensation of the silanol groups with available OH-groups of the micro-fibrillated cellulose; adding a plasticizer to the suspension of surface modified micro-fibrillated cellulose; drying the suspension.

The application relates to the field of organic chemistry, in particular to a method for photocatalytic synthesis of silanol or silyl ether. The application provides a method for photocatalytic synthesis of silanol or silyl ether compound, in which, under the condition of existence of an iridium catalyst and an organic solvent, hydrosilane is reacted with any one of water, alcohol or phenol under light to obtain silanol or silyl ether. The synthesis method has high yield and selectivity, low catalyst consumption, mild reaction condition and high environmental protection and efficiency.

Embodiments of the present disclosure relate to a method of making a silanol-functional polyolefin, the method comprising combining starting materials comprising A) a silyl hydride-functionalized polyolefin, optionally B) a solvent, C) a peroxy acid, optionally D) a neutralizing agent, under thermal conditions for effecting synthesis of a silanol moiety, thereby forming a reaction mixture, the reaction mixture produces the silanol functional polyolefin having the silanol moiety under the thermal conditions.

This invention provides a water-based paint composition that exhibits rust-preventive properties on hot-dip galvanized surfaces even in harsh environments such as salt spray tests. [Solution] An aqueous paint composition comprising the following components (A) to (C). (A) Ingredients: (meth)acrylic emulsion (B) Ingredients: Phosphate-based rust inhibitor (C) Component: Particles having silanol groups on their surface

The invention provides a long-acting bionic antimicrobial functional coating as well as a preparation method and application thereof, and relates to the technical field of marine coatings, the long-acting bionic antimicrobial functional coating comprises a component A and a component B, the component A is prepared from the following raw materials: silanol-terminated polydimethylsiloxane, methyl phenyl polysiloxane, a methylhydrosiloxane-dimethyl siloxane copolymer, an auxiliary agent and an organic solvent a; and the component B comprises the following raw materials: ethyl silicate and an organic solvent b. According to the long-acting bionic antimicrobial functional coating provided by the invention, marine organisms cannot be attached to the surface of a ship body or easily fall off, so that the antifouling effect is achieved, and the pollution path of antifouling paint to the marine environment is fundamentally cut off.