The invention relates to the technical field of preparation of
printing ink, in particular to a preparation method of high-water-resistance
printing ink, which comprises the following steps: taking 50-80 parts of self-crosslinking waterborne
polyurethane resin, adding 3-8 parts of
silane coupling agent and 2-5 parts of hydroxyl-terminated
polydimethylsiloxane, stirring for 1.5-3 hours, adding 1-4 parts of amino modified
nano silicon dioxide, and carrying out
ultrasonic dispersion to obtain amphiphilic modified resin; adding 1-3 parts of a
titanate coupling agent into 15-30 parts of
pigment, stirring, and adding
mica powder and a dispersing agent to obtain a core-shell
pigment and filler dispersion liquid; adding 2-6 parts of perfluoroalkyl
ethyl acrylate copolymer into 5-12 parts of
polyvinylidene fluoride emulsion, stirring, and adding a defoaming agent and an
ultraviolet absorbent to obtain an interpenetrating network functional aid solution; adding the
pigment and filler dispersion liquid into the amphiphilic modified resin, stirring at 60-80 DEG C, introducing
nitrogen, and adding the auxiliary liquid for cross-linking in batches; and dropwise adding a
thickening agent, and filtering to obtain the high-water-resistance
printing ink. The ink prepared by the invention is excellent in
water resistance, and an ink layer is not easy to fall off and swell; the storage is stable and the
viscosity change is small; the device adapts to multiple scenes, and is resistant to
chemical corrosion and
ultraviolet aging; and printing is smooth, film forming is uniform,
environmental protection is achieved, and industrial production is facilitated.