3056results about "Monocomponent polyesters artificial filament" patented technology

The present invention relates to water-dispersible materials (e.g. fibers or films) and to a method of producing same. The materials of the invention comprise a water soluble component, for example, a sulfonated polycondensate thermoplastic, and a modifying auxiliary component, for example, a low melt temperature thermoplastic.

A process is disclosed for forming a synthetic fiber including providing a first component of an aliphatic polyester polymer a second component of a multicarboxylic acid, mixing the first component aliphatic polyester polymer and the second component multicarboxylic acid to form an unreacted specified thermoplastic composition, and melt blending the unreacted specified thermoplastic composition in an extruder or a mixer. The second component multicarboxylic acid lubricates the extruder and provides a nucleating agent for crystallizing the specified thermoplastic composition to form a mean crystal size less than about 120 Angstroms. Fiber composed of the specified thermoplastic composition has a mean crystal size less than about 120 Angstroms. The fiber has a glass transition temperature (Tg) less than about 55 DEG C. In one aspect, a first component of polylactic acid and a second component of adipic acid provide synthetic fibers in a nonwoven structure used in a biodegradable and compostable disposable absorbent product for the absorption and removal of body fluids.

A nanofibrillar structure for cell culture and tissue engineering is disclosed. The nanofibrillar structure can be used in a variety of applications including methods for proliferating and/or differentiating cells and manufacturing a tissue. Also disclosed is an improved nanofiber comprising a lipid, lipophilic molecule, or chemically modified surface. The nanofibers can be used in a variety of applications including the formation of nanofibrillar structures for cell culture and tissue engineering.

Disclosed are improved polymer materials. Also disclosed are fine fiber materials that can be made from the improved polymeric materials in the form of microfiber and nanofiber structures. The microfiber and nanofiber structures can be used in a variety of useful applications including the formation of filter materials.

Provided is a method for the production of a reinforced polymer, which method comprises:(a) introducing carbon nanotubes into a polymer to provide a mixture of the polymer and the nanotubes;(b) stretching the mixture at or above the melting temperature (Tm) of the polymer to orient the carbon nanotubes; and(c) stretching the mixture in the solid state to further orient the carbon nanotubes.

Non-woven fibrous scaffolds made by electrospinning from the synthetic biodegradable polymer such as, for example, poly(lactic-co-glycolic acid) (PLGA) and natural proteins, such as, for example, gelatin (denatured collagen) and elastin and a method of making thereof.

PCT No. PCT/EP97/04908 Sec. 371 Date Mar. 17, 1999 Sec. 102(e) Date Mar. 17, 1999 PCT Filed Sep. 19, 1997 PCT Pub. No. WO98/12242 PCT Pub. Date Mar. 20, 1998Biodegradable polyesters based on A) 95-99.99 mol % of at least one polyester A containing as monomeric building blocks of an acid component comprising a11) 20-95 mol % of at least one aliphatic or cycloaliphatic dicarboxylic acid or its ester-forming derivative and a12) 5-80 mol % of at least one aromatic dicarboxylic acid or its ester-forming derivative and at least one dihydroxy compound or at least one amino alcohol or their mixtures, and B) 0.01-5 mol % of a mixture comprising mono-, bi-, tri-, tetra- and higher-nuclear isocyanurates or corresponding compounds containing two, three or four functional groups capable of reacting with the end groups of polyester A, or mixtures of the isocyanurates and the corresponding compounds, as well as molding compositions comprising said polyesters, their manufacture and their use in the manufacture of moldings, filsm, fibers and coatings.

The invention is directed to compositions and methods for preparing electrospun matrices comprising at least one natural biological material component and at least one synthetic polymer material. The natural component makes the matrices highly biocompatible while the molecular weight polymer component can impart additional strength mechanical strength to the scaffold and/or improve ease of manufacture by increasing viscosity and spinning characteristics of the solution during electrospining.

The invention provides tissue engineering compositions and methods wherein three-dimensional matrices for growing cells are prepared for in vitro and in vivo use. The matrices comprise biodegradable polymer fibers capable of the controlled delivery of therapeutic agents. The spatial and temporal distribution of released therapeutic agents is controlled by use of defined nonhomogeneous patterns of therapeutic agents in the matrices.

The invention relates to a modified copolyester slice or fiber and a relative preparation, wherein the slice is copolymerized from terephthalic acid, ethandiol, isophthalate esters of sulfonic acid sodium (or potassium), and fatty group dibasic alcohol (or relative alkylate) with side chain. And the preparation comprises that (1), mixing the ethandiol and the fatty group dibasic alcohol (or relative alkylate) into a mixed alcohol, adding catalyzer and stabilizer to esterify the terephthalic acid under 220-260Deg. C, (2), adding 1-9%mol isophthalate esters of sulfonic acid sodium (or potassium) relative to the terephthalic acid for polycondensation at 250-300Deg. C, (3), drying, fusing, spinning, and drawing to obtain the modified copolyester filament. The inventive product can dye anion paint and disperse paint into deep color at normal pressure, with better feeling, high contraction, hidden micro coiled property, simple preparation, low cost and batch production support.

Fibers described herein comprise a composition including a polymer and graphene sheets. The fibers can be further formed into yarns, cords, and fabrics. The fibers can be in the form of polyamide, polyester, acrylic, acetate, modacrylic, spandex, lyocell fibers, and the like. Such fibers can take on a variety of forms, including, staple fibers, spun fibers, monofilaments, multifilaments, and the like.

A method for forming biodegradable fibers is provided. The method includes blending polylactic acid with a polyepoxide modifier to form a thermoplastic composition, extruding the thermoplastic composition through a die, and thereafter passing the extruded composition through a die to form a fiber. Without intending to be limited by theory, it is believed that the polyepoxide modifier reacts with the polylactic acid and results in branching of its polymer backbone, thereby improving its melt strength and stability during fiber spinning without significantly reducing glass transition temperature. The reaction-induced branching can also increase molecular weight, which may lead to improved fiber ductility and the ability to better dissipate energy when subjected to an elongation force. To minimize premature reaction, the polylactic acid and polyepoxide modifier are first blended together at a relatively low temperature(s). Nevertheless, a relatively high shear rate may be employed during blending to induce chain scission of the polylactic acid backbone, thereby making more hydroxyl and/or carboxyl groups available for subsequent reaction with the polyepoxide modifier. Once blended, the temperature(s) employed during extrusion of the blended composition can be selected to both melt the composition and initiate a reaction of the polyepoxide modifier with hydroxyl and/or carboxyl groups of the polylactic acid. Through selective control over this method, the present inventors have discovered that the resulting fibers may exhibit good mechanical properties, both during and after melt spinning.

The invention generally relates to dextran fibers which are preferably electrospun and devices formed from such fibers. In particular, such devices may include substances of interest (such as therapeutic substances) associated with the electrospun fibers. Upon exposure to a liquid the electrospun fibers dissolve immediately and the substances of interest are released into the liquid. Exemplary devices include bandages formed from electrospun dextran fibers and associated agents that promote hemostasis, such as thrombin and fibrinogen.

A biodegradable fiber that is formed from a thermoplastic composition that contains polylactic acid, a plasticizer, and a compatibilizer is provided. The compatibilizer includes a polymer that is modified with a polar compound that is compatible with the plasticizer and a non-polar component provided by the polymer backbone that is compatible with polylactic acid. Such functionalized polymers may thus stabilize each of the polymer phases and reduce plasticizer migration. By reducing the plasticizer migration, the composition may remain ductile and soft. Further, addition of the functionalized polymer may also promote improved bonding and initiate crystallization faster than conventional polylactic acid fibers. The polar compound includes an organic acid, an anhydride of an organic acid, an amide of an organic acid, or a combination thereof. Such compounds are believed to be more compatible with the generally acidic nature of the polylactic acid fibers.

The present invention relates to fiber compositions comprising gels or hydrogels. The invention further relates to the composition of a gel or hydrogel loaded biodegradable fiber and methods of fabricating such fibers. The present invention further provides tissue engineering and drug-delivery compositions and methods wherein three-dimensional matrices for growing cells are prepared for in vitro and in vivo use. The invention also relates to methods of manipulating the rate of therapeutic agent release by changing both the biodegradable polymer properties as well as altering the properties of the incorporated gel or hydrogel.

The invention provides a drawn and/or crimped fiber comprising a biodegradable polymer, such as polylactic acid, wherein the drawn and/or crimped fiber exhibits a storage-stable tenacity that does not decrease from an initial tenacity upon manufacture by more than about 10% after storage for 120 days in ambient conditions. The polymer composition used to form the fiber may comprise a softening agent. The fiber can be a drawn and crimped bicomponent fiber that is helically self-crimped and which comprises a first biodegradable polymer component and a second biodegradable polymer component, wherein the first polymer component and the second polymer component exhibit different polymer morphology such that each polymer component will undergo a different extent of longitudinal shrinkage upon application of heat. The outer surface of the fiber may carry a water-repellant coating. The invention also provides a method of forming a drawn and/or crimped fiber exhibiting storage-stable tenacity.

The polymeric composition of this invention can be used as a temporary support material in the additive manufacturing of three dimensional articles without compromising the quality of the ultimate product, reducing printing speed, increasing cost, increasing the incidence of printer jamming, or requiring printers of increased complexity. This invention more specifically discloses a polymeric composition which is particularly useful as a temporary support material for utilization in three-dimensional printing, said polymeric composition being comprised of a first polymeric component which is suitable for use as a modeling material and a second polymeric component which is immiscible with the first polymeric component, wherein the polymeric composition has a continuous phase, wherein the continuous phase is comprised of the second polymeric component, and wherein the polymeric composition has a Shore A hardness of at least 80.

The invention relates to a tobacco filter tip and relative preparation, wherein it is formed by spinning the lactic acid polymer resin, drawing, coiling and shaping, while the line density is 2-6dtex, the beam density is 3-6ktex, the coil number is 15-30n/25mm. And it uses the adhesive method similar acetate fabric. Therefore, its polymer structure and large specific area can support the adsorption on organic, and filter the solid particle.

Disclosed are water-dispersible fibers derived from sulfopolyesters having a Tg of at least 25° C. The fibers may contain a single sulfopolyester or a blend of a sulfopolyester with a water-dispersible or water-nondispersible polymer. Also disclosed are multicomponent fibers comprising a water dispersible sulfopolyester having a Tg of at least 57° C. and a water non-dispersible polymer. The multicomponent fibers may be used to produce microdenier fibers. Fibrous articles may be produced from the water-dispersible fibers, multicomponent fibers, and microdenier fibers. The fibrous articles include water-dispersible and microdenier nonwoven webs, fabrics, and multilayered articles such as wipes, gauze, tissue, diapers, panty liners, sanitary napkins, bandages, and surgical dressings. Also disclosed is a process for water-dispersible fibers, nonwoven fabrics, and microdenier webs. The fibers and fibrous articles have further applications in flushable personal care and cleaning products, disposable protective outerwear, and laminating binders.

The present invention provides a process for producing a polyester from a polyester composition comprising at least about 1 wt. % wollastonite, based on the total weight of the polyester composition, wherein the wollastonite is added at a temperature of about 240° C. or less. The present invention further provides a process for producing a polyester from a polyester composition comprising at least about 1 wt. % wollastonite, based on the total weight of the polyester composition, and about 0.01 wt. % other filler, based on total weight of the polyester composition, wherein the wollastonite is added at a temperature of about 240° C. or less. The invention is further directed to polyester products produced by said process and the shaped articles formed therefrom.

The invention relates to a preparation method of recycled polyester chip microfilaments and a usage thereof, belonging to the field of plastic modification and category of composite material/alloy promoter. The polyester chip microfilament is an ideal promoter which has excellent performance, environment-friendliness, high added value, wide application range and broad market prospect and can change the mechanical property of the composite material/alloy. Recycled blow molding polyester (RPET/RPBT) is taken as main raw material, and the following formula and process are adopted for preparing the microfilament according to parts by weight: 100 parts of recycled polyester (RPET/RPBT), 5-30 parts of wire-drawing high-density polyethylene (HDPE)/ polypropylene (PP)/ linear low-density polyethylene (LLDPE), 0.1-4 parts of crosslinking agent/ chain extender/anchoring agent, 0.1-0.8 part of antioxidant, 0.5-6 parts of nucleating agent, and 1-5 parts of nucleate accelerant, and other processing aids (such as lubricant and plasticizer)/functional aids (such as fire retardant and ultraviolet absorber) can be additionally and appropriately added. The microfilament is prepared through extrusion, cooling, drawing and granulating by the reaction under 90-260 DEG C under the action of mechanical shear. The recycled polyester (RPET/RPBT) microfilament prepared in the invention can endow the composite material/alloy with excellent mechanical property.

A spontaneously degradable fiber excellent in bulkiness, softness, stretchability and feeling, which comprises (A) a low heat-shrinkable fiber component comprising a high crystalline aliphatic polyester and (B) a high heat-shrinkable fiber component comprising an aliphatic polyester, e.g., a low crystalline or non-crystalline aliphatic polyester, and a block copolymer or a mixture the main component of which is an aliphatic polyester and which comprises a high-melting component and a low-melting component. Further, fibers excellent in self-crimpability or self-adhesion property and dividable fibers are obtained by suitably combining the fiber components (A) and (B) to form conjugated fibers or composite yarns.

Novel absorbable, semi-crystalline, polymer blend compositions are disclosed exhibiting enhanced crystallization and nucleation rates. Also disclosed are medical device constructs, such as fibers made from such blends. The blends have a first absorbable polymeric component having a first molecular weight distribution and a second absorbable polymeric component which has an ultrahigh molecular weight distribution. The first and second polymeric components may be the same polymer.

The invention discloses a biodegradable linear random copolyester, its preparation method and uses, wherein the copolyester has a structural unit of (1), wherein m is an integer of 2-10, n is an integer of 0-8, p is an integer of 2-10, m, n, p are identical or different, x is an integer of 1-10, y is an integer of 1-10, the average molecular weight Mw of the copolyester is 100,000-600,000g/mol, its molecular weight distribution is 1.2-3, which is measured through GPC method. The copolyester can be widely applied into section bar, film, fabric and coating.

The filter structures commonly known as a bag house or a filter bag or an air filter with a bag construction can be made by preparing the bag assembly, either in a tubular or a bi-fold construction by placing a layer of fine fiber on the upstream surface of the filter media structure. The filter assembly includes a filter cabinet with an interior component. The filter component is suspended within the filter cabinet interior. The filter component includes a frame or support for the filter media. The frame or support holds the filter bags such that the filter bags are suspended from the frame in the cabinet interior. The intake air enters the cabinet, passes through the filter assembly and exits the cabinet. The air must pass first into the fine fiber layer, the filter media and then the exterior of the cabinet.

Filter arrangements include a barrier media, usually pleated, treated with a deposit of fine fibers. The media is particularly advantageous at high temperature (greater than 140° F.) systems. Such systems may include engine systems and fluid compressor systems. Filter arrangements may take the form of tubular, radially sealing elements; tubular, axial sealing elements; forward flow air cleaners; reverse flow air cleaners; and panel filters.

The present invention relates to fibers having excellent responsiveness to magnetic fields and excellent conductivity, as well as articles made of the same. In particular, the present invention relates to fibers having magnetic properties and conductivity, which are excellent in resistance to heat and responsiveness to magnetic fields in a unit where a magnetic field is applied, as well as in stability of conductivity when the humidity varies. In addition, the present invention relates to textiles using such fibers, knitted articles and cloths, such as non-woven cloths, short fibers, brush rollers made of short fibers, and electro-photographic apparatuses using brush rollers. The fibers of the present invention are fibers having excellent responsiveness to magnetic field and conductivity, made of a polymer having fiber forming functions which contains magnetic material particles in spherical form having a saturation magnetic flux density of no less than 0.5 tesla. According to the preferred aspects of the present invention, (a) the average particle diameter of the above described magnetic material particles in spherical form is no greater than 5 μm, (b) the coercive force of the above described magnetic material particles in spherical form is no greater than 1000 A/m, and (c) the above described fibers are complex fibers which are made of magnetic layers that contain 20 wt % to 90 wt % of the above described magnetic material particles in spherical form, and protective layers where the content of the above described magnetic material particles in spherical form is less than 20 wt %.

A novel synthetic fiber is disclosed including a first component of an aliphatic polyester polymer, a second component of a multicarboxylic acid, an admixture of the first component aliphatic polyester polymer and the second component multicarboxylic acid to form an unreacted specified thermoplastic composition, and melt blending the unreacted specified thermoplastic composition in an extruder or a mixer. The second component multicarboxylic acid lubricates the extruder and provides a nucleating agent for crystallizing the specified thermoplastic composition to form a mean crystal size less than about 120 Angstroms. Fiber composed of the specified thermoplastic composition has a mean crystal size less than about 120 Angstroms. The fiber has a glass transition temperature (Tg) less than about 55° C. In one aspect, a first component of polylactic acid and a second component of adipic acid provide synthetic fibers in a nonwoven structure used in a biodegradable and compostable disposable absorbent product for the absorption and removal of body fluids.

A biodegradable, substantially continuous filament is provided. The filament contains a first component formed from at least one high melting polyester and a second component formed from at least one low melting polyester. The low melting point polyester is an aliphatic-aromatic copolyester formed by melt blending a polymer and an alcohol to initiate an alcoholysis reaction that results in a copolyester having one or more hydroxyalkyl or alkyl terminal groups. By selectively controlling the alcoholysis conditions (e.g., alcohol and copolymer concentrations, catalysts, temperature, etc.), a modified aliphatic-aromatic copolyester may be achieved that has a molecular weight lower than the starting aliphatic-aromatic polymer. Such lower molecular weight polymers also have the combination of a higher melt flow index and lower apparent viscosity, which is useful in the formation of substantially continuous filaments.

The invention relates to polyester conductive fibers and provides graphene conductive polyester fibers having good conductivity and lasting static resistance and a preparation method thereof. Through surface sulfonic acid group functionalization of graphene, graphene particles have sizes less than 1 micrometer and have good dispersibility, graphene, carbon nanotubes and a surfactant are stirred and mixed according to a mass ratio of 1-5: 1-5: 1-5: 1 and then are dispersed to form conducting particles, the conducting particles are added into polyester powder, the mixture is processed to form graphene superconducting masterbatches by a twin-screw granulation technology, and the graphene conductive polyester fibers are prepared by a spinning technology adopting a double-component composite spinning method or a single-component blending spinning method. The graphene conductive polyester fibers have the characteristics of simple production processes, low energy consumption, low labor and mass production feasibility.