1695results about "Paper coating" patented technology

The invention discloses a polyhydroxyalkanoate water-based barrier coating composition and application, and belongs to the technical field of packaging materials. The composition takes water as a dispersion medium and comprises polyhydroxyalkanoate, a plasticizer, an emulsifier and an inorganic nano filler. The stable emulsion with the volume average particle size of 400-700nm is prepared under specific proportioning and process conditions. After the emulsion is applied to a paper substrate according to the dry film coating weight of 10-12 g / m, the obtained coating shows good comprehensive performance: the oxygen permeability is not higher than 580 cm / m.d, the water vapor permeability is not higher than 290 g / m.d, and the heat sealing strength at 130 DEG C is not lower than 5.0 N / 15 mm. The biodegradable paper-based packaging film does not contain fluorine compounds, can be completely biodegraded, and provides a technical path for sustainable paper-based packaging.

The invention discloses a PHA / PVA nano-scale paper-based barrier emulsion as well as a preparation method and application thereof. The water-based emulsion comprises PHA particles with the average particle size ranging from 100 nanometers to 300 nanometers and PVA, the PHA and the PVA are blended according to a specific proportion, and the PVA serves as a main film forming component and a barrier property contribution component and is blended with the PHA to form the nano-emulsion. The preparation method comprises the following steps: mixing PHA particles with an initial average particle size of 1-100 microns with a PVA aqueous solution, and carrying out high-pressure homogenization and other nanocrystallization means to obtain the nano-emulsion. The emulsion can be coated on the surfaces of paper-based materials such as paper and paperboards, and a barrier coating is formed after the emulsion is dried. The obtained emulsion is small in particle size, good in stability and good in leveling property, a uniform and compact barrier film is easily formed on a paper base, the film has excellent water vapor, oxygen and grease barrier performance, and the material is bio-based, biodegradable and environmentally friendly.

The invention discloses a pure bio-based PHA aqueous dispersion as well as a preparation method and application thereof, and belongs to the technical field of pure bio-based polymer aqueous dispersion. According to the dispersion, polyhydroxyalkanoate is used as a unique film forming matter, Pickering solid particles and a natural surfactant are adopted for synergistic stabilization, and a bio-based plasticizer can be selected. The emulsion or slurry with the polyhydroxyalkanoate content of 40-85wt% and the particle size of 0.2-3m is prepared through a melting high-pressure homogenization method, a low-temperature wet grinding method or a solvent replacement method. The coating does not contain petrochemical polymer protective colloid and perfluorinated and polyfluoroalkyl substances, and the bio-based content is greater than or equal to 99%. Due to the excellent stability, rheological property and film-forming property of the modified starch, the modified starch becomes an ideal basic material for constructing a multi-layer programmable controlled release and degradation functional coating system, can be used in the fields of paper-based barrier coatings, adhesives, advanced crop seed coats and the like, realizes excellent barrier, bonding and controlled release properties, meets the industrial compost and repulping property standards, and has wide application prospects. The method has green, environment-friendly and industrial potential.

The invention discloses a double-PHA barrier system for a paper-based container and a paperboard as well as a preparation method and application of the double-PHA barrier system, and belongs to the technical field of paper-based material surface engineering and green packaging. The system sequentially comprises a paper base material, a water-based PHA dispersion hole sealing layer and a PHA extrusion compact layer from inside to outside. According to the invention, the micron-sized PHA dispersoid without cell debris is utilized, so that an efficient hole sealing effect which is difficult to achieve by a high coating amount in a traditional process can be achieved by only needing an extremely low coating amount, and the pinhole defect of an extrusion layer is eliminated from the source. And in cooperation with the modified PHA extrusion layer with the specific crystallinity, the problem of micro-cracking of a single coating during edge rolling forming is cooperatively solved. According to the system, excellent barrier performance is achieved through a thinner bio-based structure, and meanwhile the system has a wide heat sealing window and excellent repulp recycling performance. Compared with the prior art, on the premise that high performance is guaranteed, the consumption amount of packaging materials and the environmental burden are remarkably reduced.

The present invention discloses a PHA / PVA nanoscale paper-based barrier emulsion, and its preparation method and application. The aqueous emulsion comprises PHA particles with an average particle size of 100 nanometers to 300 nanometers and PVA, wherein PHA and PVA are blended in a specific ratio, and PVA is blended with PHA as the main film-forming component and barrier performance contributing component to form the nanoemulsion. The preparation method comprises mixing PHA particles with an initial average particle size of 1 micron to 100 microns with a PVA aqueous solution, and processing the nanoemulsion by nano-processing means such as high-pressure homogenization. The emulsion can be applied to paper-based materials, such as paper and cardboard surfaces, and forms a barrier coating after drying. The emulsion obtained by the present invention has small particle size, good stability, good leveling properties, and is easy to form a uniform and dense barrier film on the paper base. The film has excellent water vapor, oxygen and grease barrier properties, and the material is bio-based, biodegradable, and environmentally friendly.

The invention discloses a large-size green packaging carton and a preparation process thereof, and relates to the field of packaging box preparation. The environment-friendly composite material comprises the following raw materials in parts by weight: 50-80 parts of plant fiber slurry, 10-25 parts of a modified starch-based adhesive, 5-15 parts of a nanoscale inorganic reinforcing filler, 1-5 parts of a degradable water repellent agent, 0.5-3 parts of a cross-linking agent and 2-8 parts of starch and plant fiber composite buffer microspheres. According to the preparation method, full-environment-friendly raw materials such as plant fiber slurry and a modified starch-based adhesive are selected and matched with starch and plant fiber composite buffer microspheres, and optimized processes such as segmented temperature control pressurization molding, adhesive gelatinization treatment, stirring speed reduction and microsphere structure protection are combined; and through coating of the degradable polymer coating and micron-sized hydrophobic texture imprinting, synergistic improvement of high compressive strength, excellent buffering performance, excellent hydrophobic and damp-proof effects and high degradation rate of the carton is achieved.

The invention relates to the technical field of papermaking, and particularly provides high-strength tipping base paper for cigarettes and a preparation process of the high-strength tipping base paper. The tipping paper base paper for the cigarettes comprises a fiber raw material; functionalizing the nano cellulose; a cellulase; a dry strength agent; a wet strength agent; and a sizing agent. Nano cellulose is functionalized and a synergistic stepped enhancement mechanism is constructed, so that the synergistic breakthrough of the high-strength raw tipping paper for cigarettes in the aspects of strength, wet strength and air permeability is realized; after the functionalized nanocellulose is subjected to carboxylation treatment, the hydrogen bond and electrostatic adsorption between the functionalized nanocellulose and the fiber are enhanced, and the bonding strength in a dry state and a wet state is remarkably improved; meanwhile, the wet strength agent is added in stages, and the adsorption sequence of the dry strength agent is optimized, so that the reinforcing agent constructs a stable three-dimensional network framework in the paper sheet, and the end breaking risk under high-speed winding is effectively reduced.

A dispersion coated paperboard (1) for food packaging applications, the coated paperboard comprising a paper or paperboard substrate (2) having a first side (2a) and a second side (2b). The paper coated paperboard (1) further comprises a first layer (3) coated with a PHA dispersion, the first layer (3) being coated on at least one side (2a, 2b) of the paperboard substrate (2); and a second layer (4) coated with a PHA dispersion, said second layer (4) being coated on at least one of said first layers (3) wherein the crystallinity of the second layer (4) is higher than the crystallinity of the first layer (3).

The invention discloses environment-friendly high-barrier packaging paper and a preparation method thereof, and belongs to the technical field of paper product manufacturing. The method comprises the following steps: dispersing bleached sulfate softwood pulp in an aqueous solution of TEMPO and NaBr, adding a NaClO solution, adjusting the pH value, carrying out a reaction, washing the product obtained by the reaction, and carrying out high-pressure homogenization to obtain TEMPO oxidized nanocellulose (TOCNF); mixing the bleached sulfate softwood chemical pulp, hardwood pulp and viscose fibers, pulping, papermaking and the like to obtain original paper; then, TOCNF and waterborne epoxy modified acrylic emulsion are mixed, and a mixed coating is prepared; and finally, coating the surface of original paper with the coating according to a certain mass ratio, and carrying out hot-pressing curing to obtain the environment-friendly high-barrier packaging paper. The packaging paper is excellent in mechanical property, high in barrier property, good in surface uniformity and printing property, environment-friendly and degradable in raw materials, simple to prepare and low in cost.

The invention discloses a bio-based PHA oil-resistant and moisture-permeable coating for hamburger paper, coated paper and a preparation method, and belongs to the technical field of bio-based high polymer materials and paper-based food packaging. The coating is a PHA aqueous dispersion, and mainly comprises a semi-crystalline matrix PHA and a low-crystallinity or amorphous toughening PHA. The core of the coating is that after the coating is dried to form a film, a functional gradient structure can be spontaneously formed in the thickness direction of the coating: an interface layer close to a paper base is rich in toughening PHA so as to enhance toughness and adhesive force; and the surface layer of the coating is rich in matrix PHA so as to maximize the oil resistance. By means of the functional gradient structural design, the packaging material integrates oil resistance, moisture permeability and flexibility of the packaging material, has the degradable environment-friendly characteristic and is suitable for packaging high-grease food.

The present invention relates to a method of making a PHA (polyhydroxyalkanoate) coated fiber-based substrate, the method comprising the steps of: a) providing a fiber-based substrate having a first major surface and a second major surface; b) forming a first PHA layer by applying a foamed first aqueous coating composition comprising a first PHA and a blowing agent on the first major surface and drying the foamed first aqueous coating composition, wherein the foamed first aqueous coating composition is a foam having a foam density of 0.75 g / cm3 or less; c) forming a second PHA layer by applying a second aqueous coating composition comprising a second PHA on the first PHA layer and drying the second aqueous coating composition The invention also relates to a PHA coated fiber-based substrate and a packaging container comprising a PHA coated fiber-based substrate.

The invention relates to the field of packaging materials, and discloses low-temperature heat-sealing water-based coated paper and a preparation method and application thereof.The water-based coated paper comprises a base paper layer and a water-based coating, and the water-based coating comprises water-based ethylene-acrylic acid copolymer emulsion, modified nano-silica, a coalescing agent and water; a cardanol derivative is introduced into the water-based ethylene-acrylic acid copolymer emulsion as a functional component; the cardanol derivative is prepared by reacting epoxidized cardanol with 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and then grafting with acryloyl chloride. The preparation method comprises the following steps: reacting epoxidized cardanol with 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide; the modified nano silicon dioxide is prepared by mixing aminated nano silicon dioxide and chitosan and adding a cross-linking agent prepared by grafting phytic acid and ethylene glycol diglycidyl ether. The water-based coating paper prepared by the invention overcomes the defects that the existing BOPP film is not environment-friendly, and the conventional coating paper is high in heat sealing temperature and easy to stick; meanwhile, good mechanical properties, water resistance and flame retardance are achieved.

Disclosed are multi-ply tissue products, particularly creped and through-air dried tissue products, having cloth like properties, such as good drapability and durability. For example, the products generally comprise two plies and have a geometric mean slope (GM Slope) less than about 10.0 kg and a geometric mean tensile energy absorption (GM TEA) of about 15 g·cm / cm2 or greater. In certain instances, the tissue products also have a low degree of stiffness, such as a Stiffness Index less than about 5.00. The tissue products may be prepared from webs manufactured by a print-crepe process that deposits a latex polymer on at least one of the outer surfaces of the tissue web.

The invention discloses a compostable and reslurrable mineral-based dual-scale barrier coating as well as preparation and application thereof, and belongs to the technical field of water-based and reslurrable barrier materials. In order to overcome the defects of high coating weight, large color difference or difficulty in recovery in the prior art, a compact barrier is constructed through double-scale collaborative design of interlayer intercalation of layered double hydroxides and interparticle metal micro-networks. The method has the prominent advantage that high-efficiency water-oxygen barrier better than that of a conventional scheme can be realized only by using an extremely low coating amount. Meanwhile, the coating strictly controls color difference to maintain high whiteness of the paper, has pH responsiveness, can be quickly unlapped and dispersed under an acidic condition, and is easy to re-pulp. The coating does not contain PFAS and PVDC, and unification of high barrier, high whiteness and recoverability is achieved.

The invention discloses a water-based paper barrier coating and a method for improving the barrier property of a packaging material. The packaging material includes a substrate having a coating to provide a packaging material having tailored water vapor permeability, oxygen permeability or permeability, grease resistance properties, and light properties.

The invention discloses a production process of high-folding-resistance corrugated base paper, and particularly relates to the technical field of corrugated paper production. The process comprises the following steps: mixing and hydraulically pulping different types of waste paper raw materials to obtain original waste paper pulp with the concentration of 2.5-2.8%; original waste paper pulp enters a classifying screen after being subjected to high-concentration sand removal, coarse screening and low-concentration sand removal, and fibers in the waste paper pulp are screened into long fibers and short fibers; mixing the long fiber pulp and the short fiber pulp in proportion, and carrying out papermaking and surface sizing treatment; wherein the papermaking comprises the steps of forming a net part, squeezing and dehydrating, and drying in a pre-drying part to obtain initial corrugating base paper with the dryness of 90-92%, then carrying out surface sizing treatment on the initial corrugating base paper by using a boiled glue solution, drying at 60-100 DEG C until the dryness is 85-92%, and curling and slitting to obtain the high-folding-resistance corrugating base paper. Stable production of the high-folding-resistance corrugated base paper is achieved through raw material diversification, fiber refining treatment, papermaking process flexible regulation and control and glue solution accurate preparation.

Document (100) with a security feature, comprising: a first substrate layer (103) having a first substrate layer region (105), wherein the substrate layer region (105) is impregnated with a black fluid over the entire thickness of the first substrate layer (103), the black fluid having carbon particles; a second substrate layer (107) with a second substrate layer region (109), wherein the second substrate layer (107) is arranged above the first substrate layer (103), the second substrate layer region (109) having a light reflection characteristic which differs from a light reflection characteristic of the first substrate layer region (105), wherein the first substrate layer region (105) and the second substrate layer region (109) form a composite security feature.

The invention discloses a paper base-PHA double-sided composite soil biodegradable agricultural mulching film as well as a preparation method and application thereof, and belongs to the technical field of agricultural mulching materials and green high polymer materials. The mulching film comprises a paper base layer and a homologous polyhydroxyalkanoate covering layer arranged on the surface of the paper base layer. Through double-sided synergy of the water-based PHA coating on the soil sticking surface and the thermoplastic PHA extrusion film layer on the windward and rainy surface, and in combination with a'wet-to-heat 'integrated composite process and trace anhydride grafting, super-strong combination of a paper-plastic interface fiber tearing level is realized, and the problem that traditional paper-plastic is easy to layer is solved. Compared with a traditional fluorine-containing product, on the premise that total organic fluorine is not detected, the excellent barrier and moisture conservation performance is achieved with the thinner coating thickness by means of double barriers. The product has excellent mechanical laying adaptability and long-season weather resistance, is fully biodegradable, thoroughly solves the hidden dangers of micro-plastic residues and persistent organic pollutants, and is an ideal green agricultural covering material.

The invention discloses a mineral-based easily-recyclable compostable water-based barrier coating and a preparation method thereof, and belongs to the technical field of paper-based packaging materials. The coating takes water as a carrier, and is composed of a biodegradable film forming system and a designed graded lamellar mineral system composed of three minerals with different sizes and morphologies. The mineral system comprises flaky kaolin with specific morphology and size, non-asbestos grade flaky talc and fully stripped sodium montmorillonite. A mineral sheet layer forms a compact parallel spreading barrier path in a coating through a specific coating and drying curing process, and excellent water vapor and oxygen barrier, water resistance and oil resistance are realized under the low dry weight of 8-15g / m by combining with a pH value response type reversible cross-linking system. The coating system does not contain polyvinylidene chloride and perfluoroalkyl and polyfluoroalkyl substances. The paper-based material coated with the coating is easy to defibrillate and recover under the standard alkaline warm water condition, the fiber recovery rate is high, and meanwhile, the whole material meets the industrial composting requirement.

This invention discloses a bio-based PHA oil-blocking and moisture-permeable coating for hamburger paper, the coated paper, and its preparation method, belonging to the fields of bio-based polymer materials and paper-based food packaging technology. The coating is an aqueous dispersion of PHA, mainly comprising semi-crystalline matrix PHA and low-crystallinity or amorphous toughening PHA. Its core feature is that after the coating dries and forms a film, it spontaneously forms a functional gradient structure along the coating thickness direction: the interfacial layer near the paper substrate is rich in toughening PHA to enhance toughness and adhesion; while the surface layer is rich in matrix PHA to maximize oil-blocking performance. Through this functional gradient structure design, this invention balances the oil-blocking, moisture-permeable, and flexible properties of the packaging material, and possesses biodegradable environmental characteristics, making it suitable for high-oil food packaging.

To provide an aqueous coating agent having superior heat sealability of a paper base material, particularly superior heat sealability even for a packaging body having a seal portion of a paper base material to which a content (more specifically, a powder) adheres.SOLUTION: Disclosed is an aqueous coating agent comprising: (A) thermally expandable microcapsule; and (B) a thermoplastic resin, wherein the aqueous coating agent comprises the component (A) in an amount less than 15 pts.mass based on 100 pts.mass of the total of the components (A) and (B).SELECTED DRAWING: None

The present invention provides an aqueous polyhydroxyalkanoate coating, a preparation method therefor, and a use thereof. The preparation method for the aqueous polyhydroxyalkanoate coating comprises: subjecting a polyhydroxyalkanoate fermentation solution to cell wall breaking and extraction, to obtain an aqueous polyhydroxyalkanoate dispersion, and then mixing the aqueous polyhydroxyalkanoate dispersion with an additive to obtain the aqueous polyhydroxyalkanoate coating, a dispersant and talcum powder being added during the cell disruption process. By means of using talcum powder to replace a portion of a dispersant as a protective additive for PHA particles, the present invention can prevent the aggregation of PHA particles at high purity, and the resulting aqueous PHA coating exhibits good coating water resistance.

The invention relates to a method for producing an oxygen barrier material, comprising: providing a support layer comprising paper and a first coating, applying a second coating on the support layer by extrusion technique, thereby forming a second coating on the support layer, the second coating having a gram weight of between 5 and 50 g / m2, where the second coating is compostable and / or biodegradable in industrial compost, the first coating is made to be at least 90% biodegradable within 6 months, the polymeric material in the first coating is biodegradable, the oxygen barrier material is compostable, and the oxygen barrier material has an oxygen barrier value of less than 70 cc / m2 * day. The invention also relates to an oxygen barrier material.

The invention relates to the technical field of agricultural paper, in particular to double anti-mite fruit cultivating bag paper and a preparation method thereof. The preparation method comprises the following steps: pulping: respectively pulping natural-color bamboo pulp and natural-color softwood pulp, then mixing, adding water, and uniformly mixing to obtain pulp; papermaking: sequentially adding iron oxide yellow, aluminum sulfate, rosin size and a wet strength agent into the pulp, adding water for dilution, and drying after papermaking to obtain fruit cultivating bag body paper; sizing: taking oxidized cassava starch, adding water, preparing starch slurry, heating, continuously stirring until the starch is completely gelatinized, taking starch gelatinized liquid, adding neem oil, putting into a high-speed homogenizing emulsifying machine, emulsifying to obtain neem oil anti-mite emulsion, uniformly mixing the neem oil anti-mite emulsion with wax emulsion to obtain anti-mite glue liquid, immersing the fruit cultivating bag body paper into the anti-mite glue liquid, and drying to obtain the fruit cultivating bag. And taking out and drying to obtain the double anti-mite fruit cultivating bag paper. The composite material has physical barrier and long-acting anti-mite functions, and the risk of insect attack invasion is greatly reduced.

The invention discloses a reversible cross-linked paper coating and a repulping switching process, and belongs to the technical field of paper coatings. The coating is composed of an acrylate emulsion, a polyhydroxyalkanoate dispersion and a dynamic cross-linking system, wherein the system is one of carbonyl-hydrazine, imine, Diels-Alder, ester exchange, borate or polyvalent metal-carboxylate. The coating is coated with 6-15 g / m, the use state is that Cobb60 is smaller than or equal to 18 g / m, Kit is larger than or equal to 10, WVTR is smaller than or equal to 80 g / (m.d) at the temperature of 38 DEG C and the RH of 90%, OTR is smaller than or equal to 200 cm / (m.d) at the RH of 23 DEG C / 80%, the initial sealing temperature is smaller than or equal to 180 DEG C, and the sealing strength is larger than or equal to 6.0 N / 15 mm. In the re-pulping stage, net releasing is triggered through alkali, acid (containing CO2 injection), a chelating agent or ultrasonic assistance, and according to CEPI V3 / PTS-RH 021: 2012, the fiber recovery rate is measured to be larger than or equal to 98%, the coarse slag rate is measured to be smaller than or equal to 1.0%, and the adhesion matter is measured to be smaller than or equal to grade 1. The formula does not contain PFAS, and high bio-based carbon content can be realized.

The present invention relates to a method for manufacturing a barrier-coated substrate web, coated with a layer of reduced graphene oxide. The invention further relates to laminated packaging materials comprising the barrier-coated substrate web, in particular intended for liquid carton food packaging, and to liquid carton packaging containers comprising the laminated packaging material.

A wrapper for use on a smoking article. The wrapper has low grease permeability or visual staining and can be utilized with an aerosol-generating substrate. The aerosol-generating article (10) includes an aerosol-generating substrate (12) containing nicotine and a gel composition. The wrapper is positioned around and in contact with the aerosol-generating substrate. The wrapper includes a paper layer (50) that includes a surface treatment such that the paper has a negative result to at least one kit oil sample according to Method Tappi 559cm-02, Classical Method 2002.

Multi-ply structures incorporating adhesive compositions, products produced from such structures, and methods of producing the structures.

The application discloses a mineral-based easily-recyclable compostable water-barrier coating and a preparation method thereof, and belongs to the technical field of paper-based packaging materials. The coating is formed by a biodegradable film-forming system and a hierarchical lamellar mineral system containing three different scales and morphologies. The mineral system contains specific morphology and size of lamellar kaolin, non-asbestos grade lamellar talc and fully exfoliated sodium montmorillonite. The mineral lamella forms a dense parallel spread barrier path in the coating through a specific coating and drying solidification process, and combines a pH value responsive reversible cross-linking system to achieve excellent water vapor and oxygen barrier properties, water resistance and oil resistance at a low dry weight of 8-15 g / m2. The coating system does not contain polyvinylidene chloride and perfluoro and polyfluoro alkyl substances. The paper-based material coated with the coating is easily defibered and recycled under standard alkaline warm water conditions, and the fiber recovery rate is high, and meanwhile, the whole material meets the industrial composting requirements.

The invention discloses a straw fiber-based antibacterial mulching film with temperature and humidity response performance and a preparation method, and belongs to the technical field of agricultural mulching films, the straw fiber-based antibacterial mulching film with temperature and humidity response performance comprises a bottom film layer, a slow release layer and a barrier layer in sequence from bottom to top; the slow-release layer is obtained by coating the base film layer with a mixed solution of acetic acid, a bactericide, gelatin and a plasticizer; the barrier layer is obtained by coating palm wax emulsion on the surface of the slow release layer. According to the invention, palm wax, a bactericide (carbendazim), gelatin and a wheat straw fiber-based mulching film are combined to construct the wheat straw fiber-based temperature and humidity response type bacteriostatic mulching film. The straw fiber-based antibacterial mulching film can respond according to the change of environmental temperature and humidity to realize accurate release of pesticides, so that diseases are accurately regulated and controlled.