2251results about "Paper coating" patented technology

The invention discloses a polyhydroxyalkanoate water-based barrier coating composition and application, and belongs to the technical field of packaging materials. The composition takes water as a dispersion medium and comprises polyhydroxyalkanoate, a plasticizer, an emulsifier and an inorganic nano filler. The stable emulsion with the volume average particle size of 400-700nm is prepared under specific proportioning and process conditions. After the emulsion is applied to a paper substrate according to the dry film coating weight of 10-12 g / m, the obtained coating shows good comprehensive performance: the oxygen permeability is not higher than 580 cm / m.d, the water vapor permeability is not higher than 290 g / m.d, and the heat sealing strength at 130 DEG C is not lower than 5.0 N / 15 mm. The biodegradable paper-based packaging film does not contain fluorine compounds, can be completely biodegraded, and provides a technical path for sustainable paper-based packaging.

The invention discloses a PHA / PVA nano-scale paper-based barrier emulsion as well as a preparation method and application thereof. The water-based emulsion comprises PHA particles with the average particle size ranging from 100 nanometers to 300 nanometers and PVA, the PHA and the PVA are blended according to a specific proportion, and the PVA serves as a main film forming component and a barrier property contribution component and is blended with the PHA to form the nano-emulsion. The preparation method comprises the following steps: mixing PHA particles with an initial average particle size of 1-100 microns with a PVA aqueous solution, and carrying out high-pressure homogenization and other nanocrystallization means to obtain the nano-emulsion. The emulsion can be coated on the surfaces of paper-based materials such as paper and paperboards, and a barrier coating is formed after the emulsion is dried. The obtained emulsion is small in particle size, good in stability and good in leveling property, a uniform and compact barrier film is easily formed on a paper base, the film has excellent water vapor, oxygen and grease barrier performance, and the material is bio-based, biodegradable and environmentally friendly.

The present invention relates to the technical field of water-based coatings, and specifically to a PHA water-based coating, a preparation method and application thereof. The PHA water-based coating comprises the following raw materials: a PHA water-based dispersion, an emulsifier, a thickener, a film-forming aid and a leveling agent; wherein the PHA water-based dispersion is obtained by a PHA fermentation broth through a wall-breaking treatment. The present invention directly prepares the PHA water-based coating by using the PHA water-based dispersion obtained by fermentation and wall-breaking treatment upstream, and can prepare a PHA water-based coating that is not easy to settle, has good storage stability, is uniformly dispersed and has a small particle size.

The invention discloses a pure bio-based PHA aqueous dispersion as well as a preparation method and application thereof, and belongs to the technical field of pure bio-based polymer aqueous dispersion. According to the dispersion, polyhydroxyalkanoate is used as a unique film forming matter, Pickering solid particles and a natural surfactant are adopted for synergistic stabilization, and a bio-based plasticizer can be selected. The emulsion or slurry with the polyhydroxyalkanoate content of 40-85wt% and the particle size of 0.2-3m is prepared through a melting high-pressure homogenization method, a low-temperature wet grinding method or a solvent replacement method. The coating does not contain petrochemical polymer protective colloid and perfluorinated and polyfluoroalkyl substances, and the bio-based content is greater than or equal to 99%. Due to the excellent stability, rheological property and film-forming property of the modified starch, the modified starch becomes an ideal basic material for constructing a multi-layer programmable controlled release and degradation functional coating system, can be used in the fields of paper-based barrier coatings, adhesives, advanced crop seed coats and the like, realizes excellent barrier, bonding and controlled release properties, meets the industrial compost and repulping property standards, and has wide application prospects. The method has green, environment-friendly and industrial potential.

The invention discloses a double-PHA barrier system for a paper-based container and a paperboard as well as a preparation method and application of the double-PHA barrier system, and belongs to the technical field of paper-based material surface engineering and green packaging. The system sequentially comprises a paper base material, a water-based PHA dispersion hole sealing layer and a PHA extrusion compact layer from inside to outside. According to the invention, the micron-sized PHA dispersoid without cell debris is utilized, so that an efficient hole sealing effect which is difficult to achieve by a high coating amount in a traditional process can be achieved by only needing an extremely low coating amount, and the pinhole defect of an extrusion layer is eliminated from the source. And in cooperation with the modified PHA extrusion layer with the specific crystallinity, the problem of micro-cracking of a single coating during edge rolling forming is cooperatively solved. According to the system, excellent barrier performance is achieved through a thinner bio-based structure, and meanwhile the system has a wide heat sealing window and excellent repulp recycling performance. Compared with the prior art, on the premise that high performance is guaranteed, the consumption amount of packaging materials and the environmental burden are remarkably reduced.

The present invention discloses a PHA / PVA nanoscale paper-based barrier emulsion, and its preparation method and application. The aqueous emulsion comprises PHA particles with an average particle size of 100 nanometers to 300 nanometers and PVA, wherein PHA and PVA are blended in a specific ratio, and PVA is blended with PHA as the main film-forming component and barrier performance contributing component to form the nanoemulsion. The preparation method comprises mixing PHA particles with an initial average particle size of 1 micron to 100 microns with a PVA aqueous solution, and processing the nanoemulsion by nano-processing means such as high-pressure homogenization. The emulsion can be applied to paper-based materials, such as paper and cardboard surfaces, and forms a barrier coating after drying. The emulsion obtained by the present invention has small particle size, good stability, good leveling properties, and is easy to form a uniform and dense barrier film on the paper base. The film has excellent water vapor, oxygen and grease barrier properties, and the material is bio-based, biodegradable, and environmentally friendly.

The present invention is directed to a biodegradable container in combination with a liquid personal care composition comprising: a biodegradable vessel having at least one opening and a biodegradable cover for the opening wherein the container, a liquid personal care composition comprising from about 14% to about 50% water; from about 20% to about 70% of a humectant; wherein there is a Water Activity (Aw) of about 0.40 to about 0.90.

The invention discloses degradable coated paper and a preparation method thereof, and belongs to the field of high polymer materials. Aiming at the problem of single function of the existing coated paper, the invention provides the degradable coated paper, the degradable coated paper comprises backing paper and a coated layer, and the coated layer comprises the following components in parts by weight: 50-80 parts of polylactic acid and 10-25 parts of poly (ethylene terephthalate) succinate; the plastic is prepared from the following components in parts by weight: 1-5 parts of biodegradable chitosan, 10-20 parts of modified talcum powder, 0.3-1.0 part of a plasticizer, 0.2-1.0 part of a lubricant, 0.2-0.5 part of an antioxidant and 0.2-0.5 part of a compatilizer. The antibacterial purpose is achieved by selecting the degradable chitosan, and meanwhile the mechanical performance of the coated paper is not affected; the purposes of heat preservation, cost reduction and efficiency improvement are achieved through the modified talcum powder, so that the finally prepared degradable coated paper has multiple functions of degradability, heat preservation and antibiosis; meanwhile, all the used raw materials are biodegradable, so that the environment-friendly significance is higher. The operation is simple, the convenience and the efficiency are higher, and the use prospect is higher.

The invention discloses a large-size green packaging carton and a preparation process thereof, and relates to the field of packaging box preparation. The environment-friendly composite material comprises the following raw materials in parts by weight: 50-80 parts of plant fiber slurry, 10-25 parts of a modified starch-based adhesive, 5-15 parts of a nanoscale inorganic reinforcing filler, 1-5 parts of a degradable water repellent agent, 0.5-3 parts of a cross-linking agent and 2-8 parts of starch and plant fiber composite buffer microspheres. According to the preparation method, full-environment-friendly raw materials such as plant fiber slurry and a modified starch-based adhesive are selected and matched with starch and plant fiber composite buffer microspheres, and optimized processes such as segmented temperature control pressurization molding, adhesive gelatinization treatment, stirring speed reduction and microsphere structure protection are combined; and through coating of the degradable polymer coating and micron-sized hydrophobic texture imprinting, synergistic improvement of high compressive strength, excellent buffering performance, excellent hydrophobic and damp-proof effects and high degradation rate of the carton is achieved.

The invention relates to the technical field of papermaking, and particularly provides high-strength tipping base paper for cigarettes and a preparation process of the high-strength tipping base paper. The tipping paper base paper for the cigarettes comprises a fiber raw material; functionalizing the nano cellulose; a cellulase; a dry strength agent; a wet strength agent; and a sizing agent. Nano cellulose is functionalized and a synergistic stepped enhancement mechanism is constructed, so that the synergistic breakthrough of the high-strength raw tipping paper for cigarettes in the aspects of strength, wet strength and air permeability is realized; after the functionalized nanocellulose is subjected to carboxylation treatment, the hydrogen bond and electrostatic adsorption between the functionalized nanocellulose and the fiber are enhanced, and the bonding strength in a dry state and a wet state is remarkably improved; meanwhile, the wet strength agent is added in stages, and the adsorption sequence of the dry strength agent is optimized, so that the reinforcing agent constructs a stable three-dimensional network framework in the paper sheet, and the end breaking risk under high-speed winding is effectively reduced.

The present invention relates to a packaging unit (2) for a moulded pulp material and a manufacturing process therefore. The packaging unit according to the invention comprises a product receiving or carrying compartment having a product contact surface, wherein the product contact surface comprises a peelable laminate layer (10). In a presently preferred embodiment the moulded pulp material comprises an amount of a bio-degradable aliphatic polyester.

A dispersion coated paperboard (1) for food packaging applications, the coated paperboard comprising a paper or paperboard substrate (2) having a first side (2a) and a second side (2b). The paper coated paperboard (1) further comprises a first layer (3) coated with a PHA dispersion, the first layer (3) being coated on at least one side (2a, 2b) of the paperboard substrate (2); and a second layer (4) coated with a PHA dispersion, said second layer (4) being coated on at least one of said first layers (3) wherein the crystallinity of the second layer (4) is higher than the crystallinity of the first layer (3).

A polyhydroxyalkanoate (PHA) water-based coating, a preparation method therefor, and a use thereof. The coating comprises a PHA suspension and an auxiliary agent, wherein the melting point of PHA is 100-120°C, and the PHA is a copolymer containing at least two polymerization monomers. By selecting the PHA meeting specific conditions, the obtained coating is environment-friendly and degradable, and the prepared coated paper can be directly pulped and recycled. The coated paper has good comprehensive performance in terms of stable standing, temperature resistance, oil resistance, environment friendliness, and coating flatness, and can meet the requirement for containing high-temperature liquids.

The invention discloses environment-friendly high-barrier packaging paper and a preparation method thereof, and belongs to the technical field of paper product manufacturing. The method comprises the following steps: dispersing bleached sulfate softwood pulp in an aqueous solution of TEMPO and NaBr, adding a NaClO solution, adjusting the pH value, carrying out a reaction, washing the product obtained by the reaction, and carrying out high-pressure homogenization to obtain TEMPO oxidized nanocellulose (TOCNF); mixing the bleached sulfate softwood chemical pulp, hardwood pulp and viscose fibers, pulping, papermaking and the like to obtain original paper; then, TOCNF and waterborne epoxy modified acrylic emulsion are mixed, and a mixed coating is prepared; and finally, coating the surface of original paper with the coating according to a certain mass ratio, and carrying out hot-pressing curing to obtain the environment-friendly high-barrier packaging paper. The packaging paper is excellent in mechanical property, high in barrier property, good in surface uniformity and printing property, environment-friendly and degradable in raw materials, simple to prepare and low in cost.

The invention discloses a bio-based PHA oil-resistant and moisture-permeable coating for hamburger paper, coated paper and a preparation method, and belongs to the technical field of bio-based high polymer materials and paper-based food packaging. The coating is a PHA aqueous dispersion, and mainly comprises a semi-crystalline matrix PHA and a low-crystallinity or amorphous toughening PHA. The core of the coating is that after the coating is dried to form a film, a functional gradient structure can be spontaneously formed in the thickness direction of the coating: an interface layer close to a paper base is rich in toughening PHA so as to enhance toughness and adhesive force; and the surface layer of the coating is rich in matrix PHA so as to maximize the oil resistance. By means of the functional gradient structural design, the packaging material integrates oil resistance, moisture permeability and flexibility of the packaging material, has the degradable environment-friendly characteristic and is suitable for packaging high-grease food.

The present invention relates to a method of making a PHA (polyhydroxyalkanoate) coated fiber-based substrate, the method comprising the steps of: a) providing a fiber-based substrate having a first major surface and a second major surface; b) forming a first PHA layer by applying a foamed first aqueous coating composition comprising a first PHA and a blowing agent on the first major surface and drying the foamed first aqueous coating composition, wherein the foamed first aqueous coating composition is a foam having a foam density of 0.75 g / cm3 or less; c) forming a second PHA layer by applying a second aqueous coating composition comprising a second PHA on the first PHA layer and drying the second aqueous coating composition The invention also relates to a PHA coated fiber-based substrate and a packaging container comprising a PHA coated fiber-based substrate.

The invention relates to the field of food packaging, in particular to food packaging barrier transfer paper with high damage resistance. The food packaging barrier transfer paper comprises a base paper layer 1, and an adhesive layer 2, a composite barrier layer and a composite heat sealing layer from bottom to top. Wherein the composite barrier layer comprises a metal dielectric layer 3, a buffer layer 4, a metal dielectric layer 5, a barrier layer 6 and a transfer layer 7 from bottom to top. And the composite heat-sealing layer comprises a double-layer structure including a heat-sealing layer 8 and an isolating layer 9 from bottom to top. The transfer paper provided by the invention has the characteristics of no plastic, high barrier, heat sealability, degradability and direct food contact, meanwhile, the barrier layer of the food packaging barrier transfer paper has higher damage resistance due to the design of the multi-layer barrier structure and the buffer layer, and the temperature resistance and weather resistance of the paper are improved due to the addition of the isolation layer; the factors are superposed, so that the food packaging barrier transfer paper has stable quality performance.

The invention relates to the field of packaging materials, and discloses low-temperature heat-sealing water-based coated paper and a preparation method and application thereof.The water-based coated paper comprises a base paper layer and a water-based coating, and the water-based coating comprises water-based ethylene-acrylic acid copolymer emulsion, modified nano-silica, a coalescing agent and water; a cardanol derivative is introduced into the water-based ethylene-acrylic acid copolymer emulsion as a functional component; the cardanol derivative is prepared by reacting epoxidized cardanol with 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and then grafting with acryloyl chloride. The preparation method comprises the following steps: reacting epoxidized cardanol with 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide; the modified nano silicon dioxide is prepared by mixing aminated nano silicon dioxide and chitosan and adding a cross-linking agent prepared by grafting phytic acid and ethylene glycol diglycidyl ether. The water-based coating paper prepared by the invention overcomes the defects that the existing BOPP film is not environment-friendly, and the conventional coating paper is high in heat sealing temperature and easy to stick; meanwhile, good mechanical properties, water resistance and flame retardance are achieved.

The invention relates to the technical field of packaging bags, and discloses a moisture-proof medical packaging bag material and a preparation method thereof. The moisture-proof medical packaging bag material comprises a paper layer and a plastic layer, the paper layer comprises modified kraft paper, and the plastic layer comprises the following raw materials in parts by weight: 70-100 parts of polybutylene terephthalate adipate, 30-50 parts of polypropylene carbonate, 5-7 parts of modified mica and 1.5-3 parts of cellulose acetate oleate. The moisture-proof medical packaging bag material prepared by the invention has good water resistance and mechanical properties, also has good degradability, and has a good application prospect.

The invention provides a coated paper for packaging and a preparation method thereof. The coated paper comprises the following raw material components: 20-25 parts of modified corn starch citrate, 75-80 parts of alginic acid, 20-25 parts of polypropylene carbonate, 20-25 parts of polylactic acid, 1-3 parts of glycerol, 1-3 parts of polyhydroxystearic acid and 2-2.5 parts of carboxymethyl cellulose. The preparation method of the modified corn starch citrate comprises the following steps: in a reaction kettle, preparing a citric acid solution with a mass percentage of 0.8-1.2% by using distilled water, and heating the solution to 35-38 DEG C; starting stirring; adding corn starch to the citric acid solution while stirring, and reacting for 2.5-3 hours; then, adjusting the pH value of the solution in the reaction kettle to be alkaline with sodium hydroxide, cooling the solution to 26-28 DEG C, adding octenyl succinic anhydride and sodium alginate, and continuing stirring and reacting for 30-50 minutes; after the reaction, standing and filtering; drying and grinding the filtered solid to 80-100 meshes. The coated paper prepared by the invention is environmentally friendly, safe and easily degradable.

Disclosed are multi-ply tissue products, particularly creped and through-air dried tissue products, having cloth like properties, such as good drapability and durability. For example, the products generally comprise two plies and have a geometric mean slope (GM Slope) less than about 10.0 kg and a geometric mean tensile energy absorption (GM TEA) of about 15 g·cm / cm2 or greater. In certain instances, the tissue products also have a low degree of stiffness, such as a Stiffness Index less than about 5.00. The tissue products may be prepared from webs manufactured by a print-crepe process that deposits a latex polymer on at least one of the outer surfaces of the tissue web.

The invention discloses a compostable and reslurrable mineral-based dual-scale barrier coating as well as preparation and application thereof, and belongs to the technical field of water-based and reslurrable barrier materials. In order to overcome the defects of high coating weight, large color difference or difficulty in recovery in the prior art, a compact barrier is constructed through double-scale collaborative design of interlayer intercalation of layered double hydroxides and interparticle metal micro-networks. The method has the prominent advantage that high-efficiency water-oxygen barrier better than that of a conventional scheme can be realized only by using an extremely low coating amount. Meanwhile, the coating strictly controls color difference to maintain high whiteness of the paper, has pH responsiveness, can be quickly unlapped and dispersed under an acidic condition, and is easy to re-pulp. The coating does not contain PFAS and PVDC, and unification of high barrier, high whiteness and recoverability is achieved.

The invention discloses a water-based paper barrier coating and a method for improving the barrier property of a packaging material. The packaging material includes a substrate having a coating to provide a packaging material having tailored water vapor permeability, oxygen permeability or permeability, grease resistance properties, and light properties.

The invention relates to a paper substrate bio-based high-barrier Pickering emulsion coating and a preparation method and application thereof, and belongs to the technical field of paper coatings, the prepared coating has excellent waterproof and oil-proof performance and is suitable for surface coating of substrates such as paper, the emulsion is prepared by taking glycerol as a plasticizer and chitosan as an oil-proof agent, and the emulsion is prepared by taking the chitosan as an oil-proof agent. The cellulose nanocrystal is used as an emulsifier, and the alkyl ketene dimer AKD and palm wax are used as an oil phase. After the emulsion is coated on the surface of paper, a high-barrier coating with a core-shell structure is formed, and the core-shell structure is clear through electron microscope observation; the hydrophobic angle of the coating can reach 130 degrees to the maximum, and the coating shows remarkable hydrophobicity and oil resistance. The coating is composed of bio-based materials, has the advantages of environmental protection and sustainability, is suitable for application requirements of degradable and green packaging, is simple in preparation process and excellent in performance, and can provide efficient barrier performance for paper packaging materials.

The invention discloses a production process of high-folding-resistance corrugated base paper, and particularly relates to the technical field of corrugated paper production. The process comprises the following steps: mixing and hydraulically pulping different types of waste paper raw materials to obtain original waste paper pulp with the concentration of 2.5-2.8%; original waste paper pulp enters a classifying screen after being subjected to high-concentration sand removal, coarse screening and low-concentration sand removal, and fibers in the waste paper pulp are screened into long fibers and short fibers; mixing the long fiber pulp and the short fiber pulp in proportion, and carrying out papermaking and surface sizing treatment; wherein the papermaking comprises the steps of forming a net part, squeezing and dehydrating, and drying in a pre-drying part to obtain initial corrugating base paper with the dryness of 90-92%, then carrying out surface sizing treatment on the initial corrugating base paper by using a boiled glue solution, drying at 60-100 DEG C until the dryness is 85-92%, and curling and slitting to obtain the high-folding-resistance corrugating base paper. Stable production of the high-folding-resistance corrugated base paper is achieved through raw material diversification, fiber refining treatment, papermaking process flexible regulation and control and glue solution accurate preparation.

Document (100) with a security feature, comprising: a first substrate layer (103) having a first substrate layer region (105), wherein the substrate layer region (105) is impregnated with a black fluid over the entire thickness of the first substrate layer (103), the black fluid having carbon particles; a second substrate layer (107) with a second substrate layer region (109), wherein the second substrate layer (107) is arranged above the first substrate layer (103), the second substrate layer region (109) having a light reflection characteristic which differs from a light reflection characteristic of the first substrate layer region (105), wherein the first substrate layer region (105) and the second substrate layer region (109) form a composite security feature.

The present invention relates to a method of manufacturing a surface-modified material wherein the method comprises the steps of applying a coating composition onto at least one surface of a substrate to form a porous coating thereon wherein the coating composition comprises mineral particles selected from the group consisting of calcium carbonate, calcium phosphate, hydromagnesite and mixtures thereof and a binder, and impregnating the porous coating with at least 150% by weight of an impregnating liquid composition based on the total weight of the porous coating to form a constraining liquid layer within and on the porous coating wherein the impregnating liquid composition is chemically inert to the substrate and the porous coating. Furthermore, the invention relates to a corresponding surface-modified material, an article comprising the same and the use of such a material.

There is provided a multi-layered paperboard (200, 300) comprising a first cellulose fibre-based layer (201, 301) and a second cellulose fibre-based layer (202, 302), which second layer (202, 302) has an inner surface facing in the direction of the first layer (201, 301) and an outer surface facing in the opposite direction, wherein the density of the second layer (202, 302) is below 550 kg / m3 and lower than the density of the first layer (201, 301) and wherein an additive (204, 304) selected from the group consisting of starch, fines, MFC, CMC and PVOH is added to the outer surface of the second layer (202, 302), with the proviso that no further cellulose fibre-based layer is provided on the outer surface of the second layer (202, 302).

A PHA water-based paint, and a preparation method therefor and the use thereof. The PHA water-based paint comprises the following raw materials: a PHA water-based dispersion liquid, an emulsifier, a thickening agent, a film-forming auxiliary agent and a leveling agent, wherein the PHA water-based dispersion liquid is obtained by wall-breaking treatment of a PHA fermentation liquid. The PHA water-based dispersion liquid obtained by means of fermentation and wall breaking treatment is used for directly preparing the PHA water-based paint, and the PHA water-based paint which is not easy to settle, good in terms of storage stability, uniform in terms of dispersion and small in terms of particle size can be prepared.

The invention discloses a paper base-PHA double-sided composite soil biodegradable agricultural mulching film as well as a preparation method and application thereof, and belongs to the technical field of agricultural mulching materials and green high polymer materials. The mulching film comprises a paper base layer and a homologous polyhydroxyalkanoate covering layer arranged on the surface of the paper base layer. Through double-sided synergy of the water-based PHA coating on the soil sticking surface and the thermoplastic PHA extrusion film layer on the windward and rainy surface, and in combination with a'wet-to-heat 'integrated composite process and trace anhydride grafting, super-strong combination of a paper-plastic interface fiber tearing level is realized, and the problem that traditional paper-plastic is easy to layer is solved. Compared with a traditional fluorine-containing product, on the premise that total organic fluorine is not detected, the excellent barrier and moisture conservation performance is achieved with the thinner coating thickness by means of double barriers. The product has excellent mechanical laying adaptability and long-season weather resistance, is fully biodegradable, thoroughly solves the hidden dangers of micro-plastic residues and persistent organic pollutants, and is an ideal green agricultural covering material.