5791results about "Paper/cardboard" patented technology

The present invention discloses a water-based emulsion of PHA, PBAT and PVOH and its application in paper-based barrier coatings. This emulsion is prepared by first melt-blending PHA and PBAT at 150-170 °C and then dispersing them into an aqueous PVOH solution at 80-95 °C. Plasticizers, cross-linking agents and surfactants can be added to improve the performance. After coating on paper and drying at 80-150 °C, a barrier film with a Cobb value of 10-15 g / m² and a Kit ≥ 10 grade is formed. Compared with traditional PE film laminating or fluorine-containing coatings, this system is more environmentally friendly and recyclable; PVOH dissolves in pulping water, PHA and PBAT are easily separated, and fibers can be efficiently recovered; in composting, soil and marine environments, PHA and PBAT have extensive biodegradability and are superior to PLA which is difficult to recycle and requires industrial composting. It is applicable to food, industrial, special packaging and agricultural paper products.

The invention discloses a polyhydroxyalkanoate water-based barrier coating composition and application, and belongs to the technical field of packaging materials. The composition takes water as a dispersion medium and comprises polyhydroxyalkanoate, a plasticizer, an emulsifier and an inorganic nano filler. The stable emulsion with the volume average particle size of 400-700nm is prepared under specific proportioning and process conditions. After the emulsion is applied to a paper substrate according to the dry film coating weight of 10-12 g / m, the obtained coating shows good comprehensive performance: the oxygen permeability is not higher than 580 cm / m.d, the water vapor permeability is not higher than 290 g / m.d, and the heat sealing strength at 130 DEG C is not lower than 5.0 N / 15 mm. The biodegradable paper-based packaging film does not contain fluorine compounds, can be completely biodegraded, and provides a technical path for sustainable paper-based packaging.

A composite can include cellulose fiber and foam binding the cellulose fiber. A method for manufacturing a composite can comprise mixing a plurality of ingredients to form a pre-foam mixture, foaming the pre-foam mixture to produce a foam, mixing the foam with cellulose fiber to form a composite material, and curing the composite material.

Sanitary tissue products of the present disclosure may comprise at least about 70% short fibers and / or having a weight weighted mean fiber length of less than about 1.4, and may have one or a combination of premium performance parameter(s). One or more of said sanitary tissue products may form part of an array of sanitary tissue products.

A method of making an absorbent structure including mixing ultra-high molecular weight (“UHMW”) glyoxalated polyvinylamide adducts (“GPVM”) and / or high molecular weight (“HMW”), glyoxalated polyacrylamide and / or high cationic charge glyoxalated polyacrylamide (“GPAM”) copolymers and high molecular weight (“HMW”) anionic polyacrylamide (“APAM”) with the furnish during stock preparation of a wet laid papermaking process.

The invention discloses a PHA (polyhydroxyalkanoate), PBAT (poly (butyleneadipate-co-terephthalate)) and PVOH (polyvinyl alcohol) blended water-based emulsion and application thereof in a paper-based barrier coating. The emulsion is prepared by performing melt blending on PHA and PBAT at 150-170 DEG C and then dispersing the mixture into a PVOH aqueous solution at 80-95 DEG C, and a plasticizer, a cross-linking agent and a surfactant can be added to improve the performance. And after coating paper, drying at the temperature of 80-150 DEG C to form the barrier film with the Cobb value of 10-15g / m and the Kit greater than or equal to grade 10. Compared with a traditional PE film or fluorine-containing coating, the system is more environmentally friendly and recyclable; pVOH is dissolved in pulping water, PHA and PBAT are easy to separate, and fibers are efficiently recycled; in compost, soil and marine environments, PHA and PBAT have wide biodegradability and are superior to PLA which is difficult to recycle and re-slurry and needs industrial compost. The method is suitable for food, industrial, special packaging and agricultural paper products.

Paper towel rolls that exhibit novel combinations of physical properties, such as Basis Weight, Roll Density, and Roll Diameter, such that the paper towel rolls meet consumers' needs, and method for making such novel paper towel rolls and marketing such novel paper towel rolls are provided.

An absorbent retail paper product comprised of cellulosic fibers having a concentration of 1, 3-dichloro-2-propanol that is not detected to 50 ppb, as measured using the ACOC official method 2000.0150, a concentration of 3-monochloro-1, 2-propanediol that is not detected to 1000 ppb, as measured using the ACOC official method 2000.0150, as measured by the "adipic acid test", as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150, as measured by the ACOC official method 2000.0150. Polyaminoamide-epihalohydrin at a concentration of not detected to 0.09% has a lateral wet strength of from 80 n / m to 200 n / m wherein all of the cellulosic fibers contained in the absorbent paper product are non-synthetic, the cellulosic fibers and the absorbent paper product are substantially free of formaldehyde.

The invention discloses a double-PHA barrier system for a paper-based container and a paperboard as well as a preparation method and application of the double-PHA barrier system, and belongs to the technical field of paper-based material surface engineering and green packaging. The system sequentially comprises a paper base material, a water-based PHA dispersion hole sealing layer and a PHA extrusion compact layer from inside to outside. According to the invention, the micron-sized PHA dispersoid without cell debris is utilized, so that an efficient hole sealing effect which is difficult to achieve by a high coating amount in a traditional process can be achieved by only needing an extremely low coating amount, and the pinhole defect of an extrusion layer is eliminated from the source. And in cooperation with the modified PHA extrusion layer with the specific crystallinity, the problem of micro-cracking of a single coating during edge rolling forming is cooperatively solved. According to the system, excellent barrier performance is achieved through a thinner bio-based structure, and meanwhile the system has a wide heat sealing window and excellent repulp recycling performance. Compared with the prior art, on the premise that high performance is guaranteed, the consumption amount of packaging materials and the environmental burden are remarkably reduced.

Disclosed is a coreless roll of a tissue paper product having a first end and a second end, and a web of tissue paper product being wound such as to define a central inner hole with the first end located on the outer side and the second end located at the inner hole, the product including a bonded first ply and a second ply, a grammage of the product being 35 to 55 g / m2, and having a Geometric Mean Tensile strength of at least 200 N / m, the first ply and the second ply being made of Conventional Wet Press (CWP) paper and embossed to be nested, the coreless roll having an outer diameter of 95 to 150 mm, an inner hole diameter of 20 to 50 mm, and a density of the coreless roll of 70 to 90 kg / m3, a caliper ratio of the roll of 40% to 70%.

Creped fibrous structures having pillows and knuckles, wherein the creped fibrous structures may exhibit improved knuckle properties, such as Knuckle Roughness Ra, Knuckle Roughness Rq, and Knuckle Creping Frequency and methods for making same are provided, and / or may comprise elongate knuckles comprising discrete pillows and / or elongate pillows between first and second elongate knuckles.

The invention discloses a large-size green packaging carton and a preparation process thereof, and relates to the field of packaging box preparation. The environment-friendly composite material comprises the following raw materials in parts by weight: 50-80 parts of plant fiber slurry, 10-25 parts of a modified starch-based adhesive, 5-15 parts of a nanoscale inorganic reinforcing filler, 1-5 parts of a degradable water repellent agent, 0.5-3 parts of a cross-linking agent and 2-8 parts of starch and plant fiber composite buffer microspheres. According to the preparation method, full-environment-friendly raw materials such as plant fiber slurry and a modified starch-based adhesive are selected and matched with starch and plant fiber composite buffer microspheres, and optimized processes such as segmented temperature control pressurization molding, adhesive gelatinization treatment, stirring speed reduction and microsphere structure protection are combined; and through coating of the degradable polymer coating and micron-sized hydrophobic texture imprinting, synergistic improvement of high compressive strength, excellent buffering performance, excellent hydrophobic and damp-proof effects and high degradation rate of the carton is achieved.

The invention relates to the technical field of papermaking, in particular to a papermaking filler wrapping agent and a preparation method and application thereof. The papermaking filler wrapping agent comprises a cationic polyester polyacrylamide emulsion and a high molecular weight water-soluble polymer. The papermaking filler wrapping agent has the advantages that the papermaking filler wrapping agent is insensitive to shearing action, the retention rate of filler such as calcium carbonate is high, the paper strength is not reduced, and produced paper products are good in batch stability.

The present disclosure relates to a method for manufacturing a multiply paperboard on a paperboard machine. The method comprises the steps of - forming a middle-ply web from a first furnish comprising at least 20 wt% of CTMP on a first forming wire, - dewatering the middle-ply web on the first forming wire in a first dewatering zone, - dewatering the middle-ply web (3) between the first forming wire (1) and a second forming wire (6) in a second dewatering zone (5), which second dewatering zone (5) comprises at least one suction unit (7) and dewatering blades (8), which dewatering blades (8) are in contact with the second forming wire (6), and at least two loadable dewatering blades (9a, 9b, 9c, 9d) in contact with the first forming wire (1), wherein the loading pressure applied by each of the loadable dewatering blade (9a, 9b, 9c, 9d) is in the range of between 0.1 – 25 kPa -kPa, - forming a top-ply web from a second furnish and a back-ply web from a third furnish, - couching the said webs to form a three-ply web wherein the middle ply web is arranged between the top- and back ply web, - pressing the three-ply web in a press section, - drying the pressed web in a drying section and - reeling the web. The paperboard manufactured according to the present invention exhibits an excellent formation and a high z-strength.

Disclosed is a coreless roll of a tissue paper product having a first end and a second end, and a web of tissue paper product being wound such as to define a central inner hole with the first end located on the outer side and the second end located at the inner hole, the product including a bonded first ply and a second ply, a grammage of the product being 35 to 55 g / m2, and having a Geometric Mean Tensile strength of at least 200 N / m, the first ply and the second ply being made of Conventional Wet Press (CWP) paper and embossed to be nested, the coreless roll having an outer diameter of 95 to 150 mm, an inner hole diameter of 20 to 50 mm, and a density of the coreless roll of 70 to 90 kg / m3, a caliper ratio of the roll of 40% to 70%.

Multi-ply tissue products, particularly tissue products prepared from two or more wet pressed tissue plies that have been recreped using a print-crepe process that deposits a latex polymer on at least one of the outer surfaces of each tissue ply. The tissue products have improved strength and softness, such as a geometric mean tensile strength (GMT) greater than about 1,400 g / 3″, a geometric mean tensile energy absorption (GM TEA) of about 20 g·cm / cm2 or greater and a TS7 value less than about 16.0. In certain instances, the tissue products also have a low degree of stiffness and a relatively smooth surface, such as a Stiffness Index less than about 8.00 and a TS750 value less than about 20.0.

The invention discloses a biomass-based reinforcing agent for paper and application of the biomass-based reinforcing agent. The reinforcing agent comprises a biomass-based material, the biomass-based material comprises a micron-sized structure and a nano-sized structure distributed on the micron-sized structure. The reinforcing agent prepared by the invention has abundant nanostructures, is beneficial to physical crosslinking such as entanglement and bridging of fibers in paper pulp, and improves the wet strength of paper; the preparation of the reinforcing agent is a simple physical process, and a complex synthesis chemical process for synthesizing a polymer in a traditional organic reinforcing agent is avoided; the reinforcing agent is prepared by a dissolution regeneration method, so that the energy consumption is low, the solvent can be recycled and reused, no chemicals are consumed, and the reinforcing agent is environment-friendly; the reinforcing agent prepared by the invention can achieve a satisfactory wet strength effect at a lower content.

The invention discloses a bio-based barrier coating for fresh-keeping of paper-based beverages as well as a preparation method and application of the bio-based barrier coating, and belongs to the technical field of paper-based packaging materials for foods and beverages. The coating is a water-based emulsion, and the core solid components of the coating comprise polyhydroxyalkanoate, polyethylene furandicarboxylate, aliphatic polyester, a polyisocyanate cross-linking agent, a nanofiller, a surfactant and a plasticizer. An emulsion is prepared through melt crosslinking and high-shear emulsification, and a dry film is formed through curtain coating and orientation. The film has excellent oxygen and water vapor barrier properties, can be heat-sealed and re-pulpified, and can be biodegraded in industrial compost, household compost and marine environments. According to the preferred embodiment, the bio-based content can be higher than 99%, aluminum foil can be replaced to be used for 60-day fresh-keeping beverage packaging, carbon footprint is reduced, and the recovery value is improved.

The invention discloses a straw paper mulching film based on thermo-mechanical pulp as well as a green preparation method and application of the straw paper mulching film. The invention belongs to the field of biomass resource utilization. Aiming at the defects in the prior art, the invention provides a green preparation method of a straw paper mulching film based on thermo-mechanical pulp. According to the method, the staged hydrothermal grinding technology is adopted, washing is not needed, the acidic paper pulp is directly obtained, and the technological process is simplified. Meanwhile, the invention innovatively develops a green sizing agent taking chitosan as a main material. The sizing agent can be directly fused with acidic paper pulp, and acid and alkali do not need to be additionally added for adjusting the pH value. The dry tensile index of the straw paper mulching film is larger than or equal to 15 N.m / g, the wet tensile index is larger than or equal to 5 N.m / g, the burst index is larger than or equal to 3.5 kPa.m < 2 > / g, the contact angle is larger than or equal to 105 degrees, and the 2-hour water absorption rate is smaller than or equal to 50%.

There is provided a method of producing a paper- or linerboard having a grammage measured according to ISO 536:2019 of 170-310 g / m2 and comprising a print layer, a middle layer and a back layer, wherein the middle layer is formed from a middle layer furnish comprising at least 25% by dry weight CTMP and the back layer is formed from a back layer furnish comprising an unbleached pulp, such as an unbleached kraft pulp, said method comprising the step of subjecting a multi-layered web at a speed of at least 600 m / min to pressing in a press section comprising a first and a second double-felted shoe press nip arranged in series, wherein the total press impulse of the double-felted shoe press nips is at least 95 kPa*s, preferably at least 100 kPa*s.

The invention discloses a cationic core-shell PHA nano-emulsion reinforcing agent as well as preparation and application thereof, and belongs to the technical field of papermaking chemicals. The problems that a traditional wet strength agent is poor in environmental protection property and difficult to recycle, and a conventional bio-based material needs high-temperature curing and is high in energy consumption are solved. According to the reinforcing agent, low-MFFT bio-based polyhydroxyalkanoate is used as a core, and a positive ion shell layer with strong positive charges is wrapped outside the core. The method has the core advantages that extra high-temperature curing is not needed, the film can be efficiently formed under the conventional 105 DEG C drying condition, and the energy consumption is remarkably reduced; meanwhile, high dry and wet strength and water resistance are achieved, the treated paper has excellent re-pulping recycling suitability, and the industrial pain point that traditional wet strength paper is difficult to recycle is solved.

A dispersion coated paperboard (1) for food packaging applications, the coated paperboard comprising a paper or paperboard substrate (2) having a first side (2a) and a second side (2b). The paper coated paperboard (1) further comprises a first layer (3) coated with a PHA dispersion, the first layer (3) being coated on at least one side (2a, 2b) of the paperboard substrate (2); and a second layer (4) coated with a PHA dispersion, said second layer (4) being coated on at least one of said first layers (3) wherein the crystallinity of the second layer (4) is higher than the crystallinity of the first layer (3).

The invention relates to the technical field of packaging materials, in particular to a high-strength corrugated carton based on polymer fiber material processing, and particularly relates to a corrugated carton achieving high strength and high waterproofness through polymer fiber material modification and special structural design. A polymer fiber material is soaked in a sodium hydroxide solution with a certain concentration, hydroxyl groups are introduced to the surface of the fiber, and the interface bonding force between the fiber and base materials such as starch is remarkably improved. According to detection, the bonding strength of the treated fibers and starch is improved by 30%-50%, so that the overall performance of the polymer fiber material layer is enhanced, in addition, compared with traditional corrugated waveforms, the UV composite waveforms are adopted, the compressive strength is improved by 20%-30%, the buffering performance is improved by 15%-20%, external impact force can be dispersed more effectively, and objects in the carton can be protected.

Paper towel rolls that exhibit novel combinations of physical properties, such as Basis Weight, Roll Density, and Roll Diameter, such that the paper towel rolls meet consumers' needs, and method for making such novel paper towel rolls and marketing such novel paper towel rolls are provided.

A method of making an absorbent structure including mixing ultra-high molecular weight (“UHMW”) glyoxalated polyvinylamide adducts (“GPVM”) and / or high molecular weight (“BMW”), glyoxalated polyacrylamide and / or high cationic charge glyoxalated polyacrylamide (“GPAM”) copolymers and high molecular weight (“BMW”) anionic polyacrylamide (“APAM”) with the furnish during stock preparation of a wet laid papermaking process.

Disclosed are multi-ply tissue products, particularly wet pressed facial tissue products that have been recreped. For example, disclosed are tissue products prepared from wet pressed tissue webs that have been recreped using a print-crepe process that deposits a latex polymer on at least one of the outer surfaces of the tissue web. The tissue products have improved strength and softness, such as a geometric mean tensile strength (GMT) greater than about 1,400 g / 3", a geometric mean tensile energy absorption (GM TEA) of about 20 gocm / cm2 or greater and a TS7 value less than about 16.0. In certain instances, the tissue products also have a low degree of stiffness and a relatively smooth surface, such as a Stiffness Index less than about 8.00 and a TS750 value less than about 20.0.

The invention discloses a PHA-acrylic acid structural unit water-based dispersion based on interface engineering regulation and control, a preparation method thereof and application of a paper-based barrier coating, and belongs to the technical field of high polymer materials, interface engineering and water-based coatings. The stable interface layer is constructed in situ between the crystalline PHA and the acrylic resin through the amphiphilic polymer, so that the problems of poor compatibility and film forming defects of a bio-based material are effectively solved. The dispersion can realize excellent waterproof, oil-proof and gas barrier effects by only needing a relatively low coating weight, and the material consumption is remarkably reduced. The unique gradient structure of the coating has excellent mechanical adhesive force and efficient re-pulping and recycling characteristics, and the technical defect that a traditional barrier coating is difficult to recycle is overcome. And an ideal solution with high performance and high safety is provided for green packaging.

The present invention discloses a tensile and wear-resistant washed kraft paper and its preparation process, which relates to the technical field of kraft paper. The process includes the following steps: Step 1: Add color paste, waterborne acrylic resin, preservative, reinforcing agent, softening agent, curing agent, and waterproofing agent into a solvent in sequence and stir evenly to obtain a sizing slurry; Step 2: Coat the sizing slurry on the base paper, and successively perform extrusion, ultraviolet light irradiation, first drying, ironing, and second drying to obtain the tensile and wear-resistant washed kraft paper. In this application, by preparing specific reinforcing agent and waterproofing agent and introducing them into the sizing slurry for sizing, the interfacial action between the sizing slurry and the base paper is effectively improved, thereby improving the tensile and wear resistance of the washed kraft paper while enhancing the flame retardant performance; it can achieve the purpose of replacing plastic, leather, and cloth with paper.

The invention discloses environment-friendly high-barrier packaging paper and a preparation method thereof, and belongs to the technical field of paper product manufacturing. The method comprises the following steps: dispersing bleached sulfate softwood pulp in an aqueous solution of TEMPO and NaBr, adding a NaClO solution, adjusting the pH value, carrying out a reaction, washing the product obtained by the reaction, and carrying out high-pressure homogenization to obtain TEMPO oxidized nanocellulose (TOCNF); mixing the bleached sulfate softwood chemical pulp, hardwood pulp and viscose fibers, pulping, papermaking and the like to obtain original paper; then, TOCNF and waterborne epoxy modified acrylic emulsion are mixed, and a mixed coating is prepared; and finally, coating the surface of original paper with the coating according to a certain mass ratio, and carrying out hot-pressing curing to obtain the environment-friendly high-barrier packaging paper. The packaging paper is excellent in mechanical property, high in barrier property, good in surface uniformity and printing property, environment-friendly and degradable in raw materials, simple to prepare and low in cost.

The invention discloses a bio-based PHA oil-resistant and moisture-permeable coating for hamburger paper, coated paper and a preparation method, and belongs to the technical field of bio-based high polymer materials and paper-based food packaging. The coating is a PHA aqueous dispersion, and mainly comprises a semi-crystalline matrix PHA and a low-crystallinity or amorphous toughening PHA. The core of the coating is that after the coating is dried to form a film, a functional gradient structure can be spontaneously formed in the thickness direction of the coating: an interface layer close to a paper base is rich in toughening PHA so as to enhance toughness and adhesive force; and the surface layer of the coating is rich in matrix PHA so as to maximize the oil resistance. By means of the functional gradient structural design, the packaging material integrates oil resistance, moisture permeability and flexibility of the packaging material, has the degradable environment-friendly characteristic and is suitable for packaging high-grease food.