2398 results about "Kaolin clay" patented technology

The invention belongs to the technical field of building materials, and discloses a high-activity composite auxiliary cementing material based on carbonated steel slag-carbide slag as well as a preparation method and application of the high-activity composite auxiliary cementing material. The high-activity composite auxiliary cementing material is prepared from the following raw materials in parts by mass: 40 to 55 parts of carbonated steel slag-carbide slag composite micro powder, 30 to 40 parts of high titanium slag, 20 to 25 parts of metakaolin, 3 to 5 parts of ardealite, 3 to 5 parts of calcium carbonate, 3 to 5 parts of calcium carbonate and 3 to 5 parts of calcium carbonate. Wherein the carbonated steel slag-carbide slag composite micro powder is obtained by carrying out carbon sequestration reaction on steel slag and carbide slag in a solution consisting of a carbonization enhancer, an additive and water. On one hand, the CO2 storage amount of the steel slag and the carbide slag is increased, the stability and the activity are improved, on the other hand, the carbonized steel slag-carbide slag and other industrial solid waste are cooperated to achieve a composite superimposed effect, the cement mortar or the concrete can be improved in strength, stability and durability, the comprehensive performance is good, and the cost is low. And the method is green, low-carbon, energy-saving, environment-friendly and wide in popularization and application

The invention discloses a sulfur-manganese composite autotrophic denitrification filler as well as a preparation method and application thereof, and belongs to the technical field of environmental functional materials and polluted water treatment. The sulfur-manganese composite autotrophic denitrification filler contains manganese salt, a sulfur-based component and a cement-based component, the manganese salt comprises one or more of manganese carbonate, calcium manganese ore and rhodochrosite; the sulfur-based component comprises sulfur and sulfur manganese ore; the cement-based component comprises cement, fly ash pottery sand, silica fume, blast furnace slag and metakaolin; the cement comprises one or more of Portland cement, iron aluminate cement and sulphoaluminate cement. The nitrogen removal efficiency of the sulfur-manganese composite autotrophic denitrification filler is superior to that of a sulfur autotrophic denitrification system, the sulfate concentration and nitrite nitrogen accumulation in effluent are remarkably reduced, the service life of the filler is prolonged, and the efficient utilization rate of the material is improved.

The invention relates to the technical field of ceramics, in particular to a preparation method of a heat-resistant ceramic marmite. The heat-resistant ceramic marmite is composed of a green body and a glaze surface, and the green body is prepared from, by weight, 30-35 parts of fused quartz, 8-10 parts of petalite, 9-11 parts of kaolin, 19-21 parts of washed illite clay, 5-7 parts of sepiolite, 5-6 parts of andalusite, 7-9 parts of coal gangue, 0.2-0.7 part of zinc spinel and 2-3 parts of talc; the glaze surface is prepared from the following raw materials in parts by weight: 18 to 20 parts of fused quartz, 14 to 16 parts of petalite, 12 to 14 parts of kaolin, 5 to 6 parts of calcium oxide, 1.5 to 2 parts of zinc oxide, 1 to 1.5 parts of strontium oxide, 8 to 10 parts of spodumene, 0.6 to 0.8 part of lanthanum oxide, 8 to 10 parts of ZrSiO4 coated Al2O3 and 1.2 to 1.8 parts of pigment. The prepared ceramic marmite has the advantages of matt appearance, higher thermal stability, low water absorption rate and excellent comprehensive performance, and is not easy to crack and wear.

The invention relates to the technical field of filling materials, and particularly discloses an ardealite-based high-strength anti-seepage filling material and a preparation process thereof, the ardealite-based high-strength anti-seepage filling material comprises 50%-65% of pretreated ardealite, 15%-25% of Portland cement, 5%-15% of superfine slag powder, 5%-10% of electrolytic manganese residues, 5%-8% of silica fume, 3%-6% of metakaolin, 2%-4% of a composite alkali activator and 0.5%-1.2% of a polycarboxylic acid water reducer, 0.3%-0.8% of an organic silicon water repellent and 0.05%-0.1% of cellulose ether; according to the invention, through chemical reaction of Mn < 2 + > in the electrolytic manganese residue and SO4 < 2-> in the phosphogypsum, micron-sized manganite crystals (MnAl2 (SO4) 4. 22H2O) are generated to actively fill internal micro-cracks of the material, so that a filling body is endowed with a self-repairing function and the impermeability is improved, and a composite alkali activator composed of NaOH and water glass is used for synergistically activating potential gelling activity of the superfine slag powder and the silica fume, so that the self-repairing filling material is prepared. And the formation of hydration products is accelerated, and 0.3-0.5 T of pulsed magnetic field is applied in the stirring process, so that the manganite crystals are guided to orderly grow along the expected stress direction of the filling body, and the compressive strength is improved.

The invention belongs to the technical field of ceramics, and discloses a preparation method of fracture-resistant and wear-resistant ceramics. The preparation method comprises the following steps: weighing the raw materials in parts by weight; the preparation method comprises the following steps: mixing 40 parts of potassium feldspar, 10 to 25 parts of albite, 1 to 10 parts of kaolin, 1 to 10 parts of serpentine, 5 to 25 parts of dolomite, 2 to 9 parts of nano zirconium oxide, 0.1 to 1 part of nano cerium oxide, 0.1 to 1 part of nano molybdenum disulfide, 0.1 to 0.8 part of silicon carbide fiber, 0.5 to 2.5 parts of polyethylene glycol, 0.1 to 0.6 part of fullerene trifluoromethyl derivative, 0.1 to 3 parts of sodium dodecyl sulfate, 0.1 to 2 parts of sodium tripolyphosphate and 10 to 60 parts of solvent to obtain slurry; and carrying out spray granulation to obtain a blank, carrying out compression molding to obtain a green body, and sintering to obtain the fracture-resistant and wear-resistant ceramic. The breaking strength of the breaking-resistant and wear-resistant ceramic can exceed 70 MPa, and the length of a grinding pit does not exceed 8.5 mm.

The invention provides an ultrahigh-ductility cement-based composite material for ocean engineering and a preparation method of the ultrahigh-ductility cement-based composite material for ocean engineering. The concrete is prepared from the following raw materials in parts by weight: 250 to 500 parts of cement clinker, 400 to 600 parts of fly ash, 200 to 300 parts of mineral powder, 100 to 150 parts of silica fume, 160 to 240 parts of metakaolin, 600 to 900 parts of quartz sand, 10 to 20 parts of organic synthetic fiber, 20 to 30 parts of organic corrosion inhibitor, 180 to 240 parts of water and 1 to 8 parts of water reducing agent. The organic corrosion inhibitor provided by the invention can be combined with chloride ions to form a passive film, so that the corrosion of reinforcing steel bars and the invasion of the chloride ions into concrete are inhibited, and the durability of the concrete is improved; by regulating and controlling the mixing ratio of the four mineral admixtures and the mixing amount of the synthetic fiber component, the concrete can well consider high strength, high ductility, high durability, high flow state and excellent deformation resistance. The ultrahigh-ductility concrete for ocean engineering, which can meet the toughness requirements of high compression resistance, fracture resistance and impact resistance and the requirements of high chloride ion permeation resistance and steel bar corrosion resistance, can be obtained.

The invention discloses an enamel ceramic glaze tile with a metal spot bionic effect and a preparation method thereof, and relates to the technical field of ceramics. The enamel porcelain glaze tile comprises a bottom blank, a metal ground glaze layer and a semi-opaque cover glaze layer, the metal ground glaze layer is prepared from a first ground glaze formula or a second ground glaze formula, and the first ground glaze formula comprises, by mass, potassium feldspar, quartz, calcite, kaolin, talc, zinc oxide, ferric oxide and manganese dioxide; the formula of the second ground glaze comprises the following components in percentage by mass: potassium feldspar, quartz, calcite, kaolin, talc, zinc oxide, ferric oxide and chromic oxide; the semi-opaque surface glaze layer is prepared from the following raw materials in percentage by mass: albite, calcite, talc, burnt soil, zircon powder, oriental zirconium, calcined zinc oxide, black clay powder and calcined aluminum oxide. Through a double-layer glaze structure and a black mud powder glaze breaking mechanism, the stereoscopic visual effect that metal spots are randomly generated on an opacifying substrate is achieved, and meanwhile the Moh's hardness of the ceramic tile is improved.

The invention relates to an aluminum-based composite material, in particular to a preparation method of an in-situ micro-nano Al2O3 particle reinforced aluminum-based composite material. The preparation method comprises the following steps: carrying out ball-milling pre-dispersion on silica powder, calcined kaolin and aluminum powder according to a specified ratio, stirring an Al-Si alloy melt at a semi-solid temperature, adding ball-milling mixed powder, heating to a temperature above an Al-Si alloy liquidus, dispersing reactant powder by using a blade-tray integrated stirring device, heating, carrying out heat preservation, carrying out heat preservation, and carrying out vacuum drying to obtain the aluminum-silicon alloy. And reacting to generate in-situ micro-nano Al2O3 particles, cooling, supplementing alloy elements, refining, and pouring to obtain the in-situ micro-nano Al2O3 particle reinforced composite material. According to the blade-tray integrated stirring device, mechanical stirring and the rolling and impacting effects of the ceramic balls are combined, the problem of one-time dispersion of micro-nano reactant powder is effectively solved, meanwhile, passivation of edges and corners of micron particles is achieved, and the comprehensive performance of in-situ particle reinforced aluminum matrix composites is improved.

The invention belongs to the technical field of new building materials, and provides a low-alkalinity and early-strength ardealite filling and curing material and a preparation method thereof.The low-alkalinity and early-strength ardealite filling and curing material is prepared from ardealite, a curing agent and water, the curing agent comprises silica fume, limestone powder, superfine granulated blast furnace slag powder, metakaolin, calcium aluminate powder, Portland cement clinker powder, a suspension stabilizer and hydroxypropyl methyl cellulose ether. The problems of delayed coagulation, low early strength and high alkalinity of a common cement-based ardealite filling material can be solved, and the technical requirements of ardealite cemented filling are met.

The invention discloses high-strength concrete and a preparation method thereof in the field of concrete. The high-strength concrete is prepared from the following raw materials in parts by weight: superfine sulphoaluminate cement; coarse aggregate; quartz sand; silica fume; coal ash; nano metakaolin; silicon carbide whiskers; a graphene oxide; a pH responsive microcapsule; coating the steel fibers with liquid metal; a carbon nanotube; and a polycarboxylic acid water reducer. Release of the repairing agent is accurately regulated and controlled by adopting the pH response microcapsule, the interface performance is enhanced by combining with the liquid metal coating steel fiber, and the composite dispersion process of the nano material is optimized. Wherein the environment response efficiency of the microcapsule is remarkably improved through the collaborative design of a calcium oxide-slow release agent system and a methyl methacrylate / acrylic acid copolymerization shell layer; according to the gallium-based liquid metal coating, metallurgical bonding of fibers and a matrix is achieved through the low-melting-point characteristic, and traditional physical bonding limitation is broken through.

The invention discloses a radiation refrigeration exterior wall tile and a preparation process thereof, and relates to the technical field of ceramic tiles. The radiation refrigeration external wall tile comprises a green body, a ground coat layer, a pattern layer and a protective glaze layer from inside to outside, the ground glaze layer comprises the following components in parts by mass: 40-60 parts of ground glaze layer ceramic basic glaze, 15-35 parts of cooling powder, 6-12 parts of calcined talc, 4-8 parts of calcined zinc oxide, 3-6 parts of dolomite, 2-4 parts of fluorite, 3-6 parts of calcined kaolin, 0.2-0.5 part of sodium carboxymethyl cellulose, 0.2-0.5 part of sodium tripolyphosphate and 40-55 parts of clear water; the protective glaze layer comprises the following components in parts by mass: 60-70 parts of protective glaze layer ceramic basic glaze, 10-20 parts of cooling powder, 5-10 parts of albite, 3-5 parts of calcined talc, 2-4 parts of calcined zinc oxide, 0.2-0.5 part of sodium carboxymethyl cellulose, 0.2-0.5 part of sodium tripolyphosphate and 40-55 parts of clear water. By adjusting the component proportion of the ground coat layer and the protective glaze layer and adding the cooling powder for compounding, the basic performance of the wall brick can be ensured, and the reflection and radiance of the wall brick to infrared rays and visible light can be improved.

The invention discloses a preparation process of a soil conditioner and application of the soil conditioner in soil improvement, and the preparation process comprises the following steps: S1, preparation of pretreated biomass; s2, preparation of composite biochar; s3, preparation of sulfhydrylated biochar; s4, preparing the modified composite biochar; and S5, uniformly mixing the modified composite charcoal, kaolin, humic acid, fly ash, slaked lime and vermiculite to obtain the soil conditioner. According to the soil conditioner, modified composite biochar prepared through specific functionalization is blended with kaolin, humic acid, fly ash, slaked lime and vermiculite according to a certain proportion, and the prepared soil conditioner has unique advantages in the aspects of improving soil organic matter, fixing carbon, providing microelements and especially regulating and controlling the activity of soil microorganisms; advanced complementation and synergistic interaction of all the components are achieved, and the comprehensive treatment requirement of complex degraded soil can be better met.

The invention discloses high-performance fluid-state solidified soil for backfill based on composite ardealite of building residue soil, which is prepared by taking the building residue soil as a core raw material, taking a compound of a polycarboxylic acid water reducer and hydroxypropyl methyl cellulose as a fluidization regulator, and mixing the fluidization regulator and the building residue soil to prepare the high-performance fluid-state solidified soil for backfill. Superfine slag powder, fly ash, nano silicon dioxide, metakaolin and ardealite are used as curing agents, so that the fluid-state solidified soil with strong performance is obtained. Through the synergistic effect of all the components and innovative processes such as liquid nitrogen low-temperature grinding, nano material compounding and a segmented vacuum stirring process, the effect that the ultrahigh strength of the construction waste soil reaches 7.5 MPa within 14 days is achieved for the first time and is improved by 40% or above compared with that of conventional solidified soil, and the industrial problem that traditional waste soil is insufficient in solidification strength is solved; and collaborative optimization of strength and fluidity is realized. Meanwhile, efficient resource utilization of the construction waste is achieved, land occupation and environmental pollution caused by muck landfill are greatly reduced, and the requirement for green and sustainable development is met.

The invention belongs to the field of coal solid waste resource utilization, and relates to a method for preparing a NaP type molecular sieve by utilizing kaolinite rock type coal gangue. The method comprises the following steps: 1) crushing and grinding blocky kaolinite rock type coal gangue into powder; 2) roasting and activating the coal gangue powder to obtain metakaolin; 3) mixing and stirring metakaolin, sodium hydroxide, a silicon source and deionized water to obtain an initial solution; 4) standing and aging the initial solution to obtain a precursor solution; 5) performing dynamic hydrothermal crystallization treatment on the precursor solution to obtain crystals; and 6) washing, neutralizing, centrifuging and drying the crystal to obtain the NaP type molecular sieve. The kaolinite rock type coal gangue is used as a raw material to replace a traditional chemical raw material required by molecular sieve synthesis, and resource utilization of aluminosilicate solid waste is promoted. According to the method, seed crystals or guiding agents are not required to be added in the molecular sieve crystallization process, and special crystallization methods such as microwaves and ultrasound are also not required, so that the process is simple, the cost is low, and the method is environment-friendly.

The invention discloses a method for preparing a soil conditioner based on infrared activation of coal gangue. The method comprises the following steps: S1, preparing activated coal gangue; s2, mixing the activated coal gangue with a slow-release fertilizer and modified zeolite, performing extrusion granulation to obtain basic particles, diluting a long-acting composite microbial inoculum with deionized water to obtain a microbial inoculum suspension, spraying the microbial inoculum suspension on the surfaces of the basic particles in a low-temperature spraying manner, and performing low-temperature drying to obtain a core material; s3, mixing the activated coal gangue with kaolin, humic acid, calcium hydrogen phosphate, sodium alginate and water to obtain coating slurry, and coating the core material with the coating slurry to obtain a shell-core material; s4, mixing the modified activated coal gangue with polyvinyl alcohol, talcum powder, a composite additive and water to obtain outer coating slurry, and coating the outer coating slurry on the core-shell material to obtain the soil conditioner. According to the method, the coal gangue is subjected to infrared activation treatment and then prepared into the soil conditioner with a high additional value, and waste resource utilization is achieved.

The invention relates to the technical field of glazes, and particularly discloses an antifouling glaze with a snow velvet effect and a preparation method thereof. The glaze comprises the following raw materials in parts by weight: 35-45 parts of quartz stone, 4-6 parts of zinc oxide, 7-8 parts of strontium carbonate, 4-5 parts of barium carbonate, 7-9 parts of calcite, 8-10 parts of talc, 5-8 parts of kaolin, 0.01-0.1 part of titanium dioxide and 1-5 parts of a microcapsule repairing agent. According to the glaze, a large number of fine willemite crystals can be separated out, so that a flickering crystal flower effect is generated, and a glass phase between the crystals is very compact, so that the unification of a visual effect and an antifouling function is realized. Even if the surface is scrubbed to generate scratches, the surface can be recovered through self-repairing, so that the antifouling effect is further improved.

The invention relates to the technical field of ceramics, and discloses an aluminum oxide ceramic glaze based on domestic waste ceramics, and a preparation method and application thereof. The aluminum oxide ceramic glaze comprises the following raw materials in parts by weight: 28-42 parts of domestic waste ceramic, 25-30 parts of kaolin, 6-12 parts of calcined talc, 3-7 parts of borax, 6-14 parts of aluminum oxide, 3-5 parts of zirconium oxide, 1-3 parts of lanthanum oxide and 3-6 parts of self-repairing particles. The self-repairing particles comprise mesoporous alumina doped with Si and Zr, and V2O5-B2O3-TeO2 series glass which is filled in pores of the mesoporous alumina and has a softening point of 200-300 DEG C. After the glaze is applied to the surface of the aluminum oxide ceramic to form a glaze layer, the insulativity of the aluminum oxide ceramic can be effectively improved, meanwhile, the high bonding stability between the glaze layer and the aluminum oxide ceramic can be achieved, and the problems that the insulativity is greatly reduced and the glaze layer cracks during heat circulation are solved.

The invention relates to the technical field of porcelain, in particular to porous antioxidant composite porcelain and a preparation method thereof, and the preparation method comprises the following steps: weighing the following raw materials in parts by weight: 35-40 parts of clay, 10-15 parts of aluminum oxide, 6-10 parts of an aluminum nitride-doped modified homogenizing agent, 5-9 parts of kaolin and 5-8 parts of a sodium silicate blender. According to the porous anti-oxidation composite porcelain, clay is adopted as a matrix, aluminum oxide and kaolin are added to be matched with an aluminum nitride modified homogenizing agent and a sodium silicate blender, the raw materials are blended and synergized, compression molding is performed, and finally homogenizing sintering is performed, so that the porous anti-oxidation composite porcelain is obtained. The porous performance, the high-temperature oxidation resistance and the mechanical bending strength performance of the obtained composite porcelain are harmoniously improved, and meanwhile, the stability effect of the product is remarkable under different degrees of corrosion conditions.

The invention discloses a rapid concrete repairing material based on microbial mineralization as well as a preparation method and application of the rapid concrete repairing material. According to the method, hydrophobic modified porous particles are used as a carrier, microbial bacteria, nutrient substances and a calcium source with mineralization behaviors are soaked into pores of the porous particles through vacuum impregnation, the pores of the particles are properly sealed by adopting waterborne epoxy, and then the particles are packaged by using metakaolin and sodium silicate, so that the porous particles are obtained. And finally, compounding with fiber composite mortar to prepare the concrete rapid repairing material. The rapid concrete repairing material has the advantages of strong interface adhesion, environment friendliness, light weight, excellent surface compactness improvement effect, crack self-repairing and the like, and can be used for coating and repairing the defect surface of concrete.

The invention relates to the technical field of cables, and particularly discloses a high-performance halogen-free flame-retardant flexible power cable. The high-performance halogen-free flame-retardant flexible power cable comprises a core layer, an insulating layer, a flame-retardant layer, a shielding layer and a protective layer which are arranged in sequence, the flame-retardant layer is prepared from the following raw material components in parts by weight: 30 to 40 parts of ethylene-vinyl acetate copolymer, 10 to 20 parts of polyolefin elastomer, 8 to 10 parts of microencapsulated ammonium polyphosphate, 2.5 to 4.5 parts of pentaerythritol, 20 to 30 parts of inorganic flame retardant, 5 to 8 parts of expansible graphite, 2 to 3 parts of diatomite, 0.5 to 1.5 parts of nano kaolin, 2 to 3 parts of zinc borate, 0.1 to 0.5 part of antioxidant and 0.5 to 1.0 part of lubricant. The cable provided by the invention not only has good flame retardant property, but also has certain flexibility.

The invention provides a reflective thermal insulation coating based on three-dimensional porous resin as well as a preparation method and application of the reflective thermal insulation coating. The coating is prepared from the following raw materials in parts by weight: 15 to 60 parts of polymer resin emulsion, 1 to 15 parts of good solvent, 1 to 15 parts of poor solvent, 5 to 15 parts of reflective filler, 2 to 5 parts of nano kaolin and 1 to 5 parts of silicon dioxide aerogel. The reflective filler is hollow glass microspheres jointly modified by a silane coupling agent and titanium n-butoxide. The chemical reaction between the silane coupling agent and the surfaces of the glass microspheres can enhance the binding force between the silane coupling agent and the resin matrix, and avoids the problems of aggregation and sedimentation in the coating, thereby improving the uniformity and stability of the coating. Meanwhile, titanium n-butoxide is introduced, a TiO2 coating layer is generated through a hydrolysis reaction, heat can be effectively reflected through the high reflectivity of TiO2, heat absorption of the coating is reduced, and the heat insulation effect is improved. Therefore, the double-modified hollow glass microspheres can play a better heat insulation role in the coating, and the overall heat insulation efficiency of the coating is improved.

The invention discloses a circulating opposite-grinding type kaolin refining grinder which comprises a grinding box and opposite-grinding rollers rotationally mounted on the inner side of the top of the grinding box and further comprises an outer frame, the outer frame is arranged on the inner side of the top end of the grinding box, and a partition net of a grid-shaped structure is fixedly mounted on the inner side of the outer frame; the outer frame is installed on the inner side of the top end of the grinding box in an up-down sliding mode. The screen is obliquely arranged below the opposite grinding rollers, the bottom of the screen is detachably installed on the top face of a fixing frame, and the fixing frame is installed in the middle of the inner side of the grinding box in an up-down sliding mode; a second shaft rod rotationally connected to the middle of the grinding box is arranged below the fixing frame. According to the circulating opposite-grinding type kaolin refining grinder, blocky kaolin can be pre-crushed, circulating grinding and filtering of the kaolin are facilitated, automatic screening can be achieved, flying dust can be reduced, direct drying can be achieved, and the kaolin grinding treatment efficiency is improved.

The invention relates to the technical field of cables, and provides an anti-aging insulated power cable. A conductor layer and an anti-aging outer sheath layer are sequentially arranged from inside to outside. The anti-aging outer sheath layer is prepared from the following raw materials in parts by weight: 55 to 65 parts of PVC (Polyvinyl Chloride) resin, 20 to 30 parts of ethylene propylene diene monomer, 10 to 15 parts of ethylene-vinyl acetate copolymer, 10 to 12 parts of modified kaolin, 18 to 20 parts of diisononyl phthalate, 4 to 5 parts of calcium-zinc composite stabilizer, 1.5 to 2 parts of antioxidant, 0.5 to 1 part of polyethylene wax and 0.5 to 0.7 part of calcium stearate; the modified kaolin is obtained by coating the surface of kaolin with nano silicon dioxide to obtain SiO2-coated kaolin and grafting the SiO2-coated kaolin with an ultraviolet absorbent. According to the anti-aging insulated power cable prepared in the invention, the problem that the ultraviolet absorbent may be decomposed, volatilized or migrated to fail in long-term use is solved, and the anti-aging stability of the insulating material in long-term operation is improved.

The present invention discloses a composite conditioner for repairing acidified soil and a preparation method thereof, and belongs to the technical field of acidified soil repair. The present invention prepares a carrier for loading bacterial strains by mixing and calcining steel slag, straw and kaolin, and then loads the embedded bacterial strains in the carrier to prepare a soil conditioner, which can efficiently repair acidic soil and provide sufficient nutrients for the soil; the soil conditioner provided by the present invention can adjust the release rate according to the pH value of the acidic soil to be repaired, and can reduce the amount of the soil conditioner on the basis of improving the repair effect; the soil conditioner provided by the present invention has high stability and obvious slow-release effect; the raw materials used in the present invention are simple and easy to obtain, the preparation process is simple, and it is suitable for large-scale promotion and application.

The invention relates to the field of new materials, and discloses a red mud-based ceramic flat sheet membrane and a preparation method thereof. The red mud-based ceramic flat sheet membrane comprises a substrate and a separation layer integrally attached to the surface of the substrate, the matrix is prepared from the following raw materials in parts by weight: 2000 to 4000 parts of Al2O3 powder with the average particle size of 5000nm, 200 to 350 parts of corn starch, 300 to 500 parts of red mud, 400 to 600 parts of kaolin and 2 to 8 parts of polyvinyl alcohol; the separation layer is prepared from the following raw materials in parts by weight: 4-10 parts of Al2O3 powder with the average particle size of 5000nm, 1-3 parts of a dispersing agent, 0.1-0.3 part of a defoaming agent and 1-3 parts of polyvinyl alcohol. The red-mud-based ceramic flat sheet membrane has good physical properties, the preparation method is scientific and reasonable, and the red-mud-based ceramic flat sheet membrane has the characteristics of short production period, low raw material and sintering cost and the like.

The invention discloses a raw material multi-stage crushing device applied to glass fiber production, and relates to the technical field of glass fiber production, the raw material multi-stage crushing device comprises a multi-stage crushing mechanism and a filter screen cylinder mounted in the multi-stage crushing mechanism, one side of the multi-stage crushing mechanism is provided with a conveying and feeding mechanism, and the other side of the multi-stage crushing mechanism is provided with a conveying and feeding mechanism; the multi-stage crushing mechanism comprises a crushing box, a crushing motor is fixedly mounted on one side of the crushing box, a crushing driving gear is fixedly connected to the output end of the crushing motor, a plurality of crushing driven gears are connected to the outer side of the crushing driving gear in a meshed mode, and a plurality of crushing blades are fixedly mounted on the crushing driven gears. The outer side of a crushing driven gear is connected with a meshing gear ring in a meshing mode, one side of the meshing gear ring is fixedly connected with a first connecting rotating ring, and due to the fact that the diameters of a first crushing roller and a second crushing roller are different, the crushed particle sizes are different, and large-particle-size kaolin raw materials are crushed step by step; therefore, the kaolin raw material crushing effect is improved.

The invention discloses double-layer fancy glaze with chapped ground texture and a preparation method of the double-layer fancy glaze, and relates to the technical field of ceramic glaze. The double-layer fancy glaze is composed of a ground glaze layer and a cover glaze layer. The ground glaze raw materials comprise potassium feldspar, kaolin, calcite, quartz, dolomite, zinc oxide and pigment; the cover glaze raw materials comprise potassium feldspar, waste porcelain powder, blank powder, chinastone, limestone, sepiolite, quartz, zirconium silicate with the particle size D50 being less than or equal to 1.0 mu m and pigment. The preparation method comprises the following steps: respectively carrying out ball milling to prepare ground glaze slip (32-40 baume degrees) and cover glaze slip (51-53 baume degrees); spraying ground glaze on the green body, drying, and then soaking with cover glaze; and finally, sintering at the temperature of 1250-1270 DEG C in a reducing atmosphere. Through the synergistic effect of the sepiolite and other components, the cover glaze has high surface tension, forms a microcrack network during drying, generates controllable glaze shrinkage during firing, forms a three-dimensional chap texture with crack width of 1-5mm and strong curled and raised crack edges, and meanwhile, the ground glaze completely covers a green body, so that the product practicability is ensured.

The invention discloses multi-scale toughened full-solid-waste ultrahigh-ductility concrete, which is prepared from the following raw materials in parts by weight: 500 to 650 parts of full-solid-waste cementing materials, 110 to 150 parts of calcined coal gasification slag, 190 to 250 parts of calcined fly ash, 20 to 40 parts of silica fume, 10 to 30 parts of metakaolin, 780 to 930 parts of washed sand, 10 to 25 parts of fly ash fibers, 0.6 to 0.9 part of hydroxypropyl methyl cellulose, 20 to 30 parts of polycarboxylic acid water reducing agents and 300 to 400 parts of water. The calcined coal gasification slag is subjected to gradient heating to 800-960 DEG C, heat preservation is conducted for 30-60 min, then the calcined coal gasification slag is cooled to the room temperature at the cooling rate of 10-15 DEG C / min, and the calcined coal gasification slag is obtained after powder grinding. According to the multi-scale toughened full-solid-waste ultrahigh-ductility concrete provided by the invention, the toughness and the mechanical property of the concrete can be enhanced, the performance of the concrete in an extreme environment is improved, meanwhile, the solid waste utilization rate is increased, and the production cost of the concrete is reduced.

The invention relates to the technical field of ceramic materials, in particular to an anti-falling ceramic material, a preparation method and application of the anti-falling ceramic material in ceramic ornaments.The anti-falling ceramic material is prepared from, by weight, 25-30 parts of silicon carbide, 15-20 parts of kaolin, 8-12 parts of quartz, 5-8 parts of alumina silicate fiber doped zirconium oxide agent and 4-7 parts of boron nitride additive. According to the anti-falling ceramic material disclosed by the invention, the silicon carbide, the kaolin and the quartz are adopted, the zirconium oxide agent doped with the aluminum silicate fibers and the boron nitride additive are coordinated and optimized, the skid resistance, the strength and the toughness of the prepared ceramic material are coordinated, optimized and improved through coordination and enhancement of the raw materials, and meanwhile, the product is remarkable in solarization-resistant and water-resistant stability effects.

The invention relates to the field of ceramic production equipment, in particular to a ceramic preparation process for dechlorinating and activating water, which is characterized in that kaolin, quartz sand, feldspar and activated carbon powder are ground through a grinding device, the grinding device comprises a grinding bin, an inner separator is further mounted in a bin body of the grinding bin, and the inner separator is connected with the grinding bin; the inner separator guides grinding balls installed in the bin body to roll, the improved device treats the grinding balls through the inner separator and separates the grinding balls through the third baffle, the large-diameter grinding balls and the small-diameter grinding balls are made to move through the surface of the third baffle and the surface of the guide groove respectively, and under high-speed movement, the grinding balls are separated through the third baffle and the guide groove. And a track formed by a steering plate of a third baffle and a second guide plate enables the grinding balls to rapidly fall down, then the grinding balls can be crushed in a high-speed state, and in the high-speed rotating process, a second separation groove in the surface of the steering plate enables the small-diameter grinding balls to enter.