The invention provides a
lithium manganate precursor with a
crystal face
induction effect, a preparation method of the
lithium manganate precursor, a positive
electrode material and a
lithium battery, and belongs to the technical field of
energy materials, the lithium
manganate precursor can play a
crystal face induction role in the subsequent lithium mixing
sintering process, the lithium manganate precursor is spherical-particle manganous-manganic
oxide, the particle size D50 is 3-15 microns, and the particle size D50 is 3-15 microns. The primary particles are uniform in size. The core
advantage of the method is that synchronous and uniform
doping of the element M and the element M'is realized at the precursor stage through a
coprecipitation method. The co-
precipitation doping technology not only ensures the atomic-scale uniform distribution of
doping elements in manganous-manganic
oxide, but also effectively stabilizes the
crystal structure of the lithium manganate positive
electrode material by utilizing the synergistic effect of the elements in the subsequent
sintering process, and realizes the selective induced growth of the crystal face. The unique crystal face
induction effect has significant contribution to improvement of the electrochemical performance, including
cycling stability, rate capability and safety, of the positive
electrode material.