11904 results about "Aluminium oxides" patented technology

The invention relates to the technical field of nano ceramic materials, and discloses a high-strength nano aluminum oxide ceramic product and a preparation process thereof.The preparation process comprises the following preparation steps that aluminum oxide powder, a composite binder, composite gel, a plasticizer and a solvent are mixed and subjected to ball milling, and composite slurry is obtained; placing the composite slurry in a mold, and performing mold pressing and drying to obtain a green body; and putting the green body into a high-temperature sintering furnace, carrying out high-temperature sintering, and cooling to room temperature to obtain the nano aluminum oxide ceramic product. Nano zirconium oxide and nano magnesium oxide are formed on the surfaces of the pretreated silicon carbide whiskers, and can form a solid solution with nano aluminum oxide in the sintering process to serve as a bridge of the silicon carbide whiskers and nano aluminum oxide particles, so that the binding force of the silicon carbide whiskers in a nano aluminum oxide ceramic matrix is remarkably enhanced; phosphoric acid and aluminum ammonium sulfate are firmly combined on the surfaces of nanometer aluminum oxide particles through carboxymethyl cellulose, and the situation that phosphoric acid and aluminum ammonium sulfate are not firmly combined with the nanometer aluminum oxide particles is avoided.

The invention relates to a self-cleaning nano coating material and a preparation process thereof, and belongs to the technical field of functional coatings. The coating material is prepared from nano silicon dioxide, nano aluminum oxide, graphene nanosheets, nitrogen-doped titanium dioxide, fluorinated silane, polyurethane, polydimethylsiloxane, a microcapsule repairing system, ethanol and deionized water according to a specific proportion through a multi-layer composite structure. The preparation process comprises the steps of base material surface pretreatment, reinforced particle surface modification, base material dissolution, functional additive introduction and multi-layer coating preparation. Through bottom layer enhancement, middle layer flexible buffering and surface layer functional design, excellent mechanical strength, wide-spectrum photocatalytic performance, self-repairing capacity and environmental adaptability are achieved. The problems that in the prior art, a self-cleaning coating is insufficient in mechanical performance, low in photocatalytic efficiency, lack of a self-repairing function and poor in weather resistance are solved, the service life of the coating is remarkably prolonged, and the functional stability of the coating is remarkably improved.

The invention relates to the technical field of ceramic substrates, and provides a low-dielectric-loss multilayer ceramic substrate and a preparation method thereof. The low-dielectric-loss multilayer ceramic substrate is prepared from, by weight, 90-100 parts of aluminum oxide, 1-3 parts of plasticizer, 3-5 parts of sintering aid, 6-10 parts of binder, 1-3 parts of dispersing agent and 50-60 parts of water, the aluminum oxide is composed of first aluminum oxide and second aluminum oxide, and the first aluminum oxide and the second aluminum oxide are different in form. According to the technical scheme, the problem of high dielectric loss of the multilayer ceramic substrate in the prior art is solved.

The invention belongs to the technical field of battery materials, and particularly relates to a method for preparing a porous carbon structure containing a sub-nanoscale ionic conduction improvement layer by utilizing atomic layer deposition and application. The invention discloses a porous carbon-silicon negative electrode structure, which is characterized in that a sub-nano-scale ion conduction improvement layer is added between a porous carbon substrate and silicon particles, and the sub-nano-scale ion conduction improvement layer comprises silicon carbide, aluminum phosphide, aluminum nitride, aluminum oxide, lithium phosphate, aluminum phosphate and lithium aluminum phosphate. Meanwhile, the invention also discloses a preparation method of the porous carbon-silicon negative electrode structure, namely, a sub-nano-scale ion conduction improvement layer is deposited on the porous carbon substrate through an atomic layer deposition method, so that the binding force between the sub-nano-scale ion conduction improvement layer and silicon particles and an ion transport channel are increased, and the ion conduction of a vapor deposition silicon-carbon negative electrode material is improved; the polarization of the material is effectively reduced, so that the rate capability of the battery is improved, and the cycling stability of the porous carbon structure battery is improved.

The invention provides an anode foil and a preparation method thereof, and relates to the technical field of capacitors. The preparation method comprises the following steps: preparing mixed aluminum slurry which comprises spherical aluminum powder, spherical aluminum oxide powder, a solvent, a binder and a dispersing agent; coating the surface of an aluminum foil substrate with the mixed aluminum slurry, and drying the aluminum foil substrate containing the mixed aluminum slurry to obtain a powder layer aluminum foil blank; sintering the powder layer aluminum foil green body to obtain a sintered foil; performing shot blasting treatment on the sintered foil to obtain an initial anode foil; cleaning and boiling the initial anode foil; and performing formation treatment on the boiled initial anode foil to obtain a target anode foil. According to the preparation method disclosed by the invention, the bending strength of the anode foil can be improved, and large-scale application of the anode foil can be realized.

The present invention belongs to the technical field of glass preparation, and specifically relates to an ultra-white glass and a preparation method thereof. The ultra-white glass of the present invention is composed of the following raw materials by weight: 110 parts of quartz sand, 18-20 parts of sodium carbonate, 14-16 parts of colemanite, 4.5-5.5 parts of magnesia, 2.6-2.8 parts of calcined alumina, 1.1-1.3 parts of potassium oxide, 0.8-1.0 parts of zinc oxide, 1.5-1.7 parts of phosphorus pentoxide, 0.15-0.20 parts of strontium chloride, 0.3-0.34 parts of calcium fluoride, 0.25-0.27 parts of barium nitrate, and 0.16-0.18 parts of zirconium oxide. The ultra-white glass of the present invention has a synergistic effect between the raw materials to ensure that the prepared ultra-white glass has excellent whiteness and visible light transmittance.

The invention relates to the technical field of ceramic substrates, and provides an aluminum oxide multilayer ceramic substrate and a preparation method thereof. The aluminum oxide multilayer ceramic substrate comprises the following raw materials in parts by weight: 80-90 parts of pretreated aluminum oxide, 1-4 parts of a sintering aid, 1-2 parts of a dispersing agent, 6-12 parts of a binder and 85-95 parts of a solvent, the preparation method of the pretreated aluminum oxide comprises the following steps: performing wet ball milling, drying, sintering and crushing on aluminum oxide, manganese sesquioxide, magnesium oxide and zirconium oxide to obtain the pretreated aluminum oxide. According to the technical scheme, the problem that the bending strength of the aluminum oxide multilayer ceramic substrate prepared from the aluminum oxide raw material with the purity of 95% in the related technology is low is solved.

The invention relates to the technical field of electronic ceramic materials, and particularly discloses a high-purity aluminum oxide ceramic substrate and a preparation process thereof. The high-purity aluminum oxide ceramic substrate is prepared from the following raw materials in parts by weight: 0.20 to 0.25 part of magnesium oxide, 0.35 to 0.55 part of zirconium oxide, 1.2 to 1.5 parts of dispersing agent, 60 to 65 parts of ethanol, 99.7 to 99.8 parts of aluminum oxide, 12 to 15 parts of adhesive, 6 to 9 parts of plasticizer and 50 to 55 parts of n-butyl alcohol, the adhesive is a mixture of polyvinyl butyral, water glass and modified paraffin. The prepared high-purity aluminum oxide ceramic substrate has excellent chemical stability and mechanical strength, and the obtained aluminum oxide ceramic substrate has better density, mechanical property and thermal stability by mixing various raw material components, and is not easy to break when subjected to bending load.

The invention discloses a lithium battery diaphragm coating based on a nano material and application thereof, and relates to the technical field of lithium battery diaphragms. The coating comprises the following raw materials in parts by weight: 15-25 parts of polystyrene maleic anhydride copolymer modified polyvinylidene fluoride, 10-20 parts of polystyrene, 2-4 parts of nano silicon nitride, 3-6 parts of a boehmite / aluminum oxide and silicon dioxide composite material, 1-2 parts of a dispersing agent and 65-90 parts of a solvent, according to the lithium battery diaphragm coating provided by the invention, the wettability and absorptivity of a diaphragm to an electrolyte are remarkably improved, meanwhile, the lithium battery diaphragm coating also has excellent thermal stability, and the diaphragm can be effectively prevented from thermal shrinkage or melting under a high-temperature condition, so that the safety performance of a battery is remarkably enhanced.

The invention relates to the technical field of textiles, and discloses a cool and washable bio-based nylon 56 fabric and a preparation method thereof. The preparation method of the cool and washable bio-based nylon 56 fabric comprises the following steps: loading modified nano aluminum oxide on modified aluminum nitride microchips to obtain a composite cool material; nylon 56, an ethylene-methyl acrylate-glycidyl methacrylate terpolymer, polypentamethylene guanidine hydrochloride and a composite cool feeling material are subjected to blending extrusion and melt spinning, and then the bio-based nylon 56 fabric is woven. Mixing the composite modified boron nitride and ethanol to obtain finishing liquid; spraying the finishing liquid on one side of the bio-based nylon 56 fabric, and drying to obtain the cool washable bio-based nylon 56 fabric. The cool and washable bio-based nylon 56 fabric disclosed by the invention has excellent cool feeling, antibacterial property, washable property, moisture absorption property and unidirectional perspiration property.

The invention discloses a preparation process of an aluminum oxide ceramic material, which comprises the following steps: S1, pretreatment of aluminum oxide powder: taking alpha-Al2O3 powder as a raw material, adding a dispersion medium, carrying out ball milling, transferring into an ultrasonic dispersion machine, dispersing, and further carrying out vacuum drying to obtain pretreated aluminum oxide powder; s2, chemical activation treatment: weighing pretreated aluminum oxide, magnesium oxide, nano silicon dioxide, calcium oxide, zirconium dioxide, titanium dioxide and modified nano silicon carbide in parts by weight, mixing, sequentially adding a dispersing agent absolute ethyl alcohol and a KH550 silane coupling agent, stirring at a high speed, adding a polyvinyl alcohol binder, and continuously stirring to obtain ceramic slurry; s3, sieving the ceramic slurry, filling the ceramic slurry into a mold, and performing isostatic pressing to obtain a ceramic green body; and S4, putting the ceramic green body into a box-type sintering furnace, sintering step by step, and cooling to room temperature along with the furnace to obtain the aluminum oxide ceramic material. The prepared aluminum oxide ceramic material has high compactness, excellent dielectric strength and mechanical property, low energy consumption and great application potential.

The invention discloses a wear-resistant high-strength composite polyurethane sieve plate and a preparation method thereof, and belongs to the technical field of polyurethane sieve plate processing.The preparation method comprises the following steps that modified polyurethane is added into xylene, the temperature of a reaction system is increased to 90-100 DEG C, stirring is conducted till the system is dissolved and clarified, and a polyurethane sieve plate is obtained; the preparation method comprises the following steps: adding olefin double bond modified aluminum oxide powder and a catalyst into a reaction system, taking composite polyurethane prepared from modified aluminum powder reinforced modified polyurethane as a polyurethane sieve plate base material, and carrying out reinforced crosslinking on the composite polyurethane by using o-cresol formaldehyde epoxy resin and modified nylon fiber; the strong acid and alkali corrosion resistance of the composite polyurethane sieve plate is effectively improved, and the service life of the composite polyurethane sieve plate is effectively prolonged.

The invention relates to the technical field of ceramic substrates, and provides a high-toughness multilayer ceramic substrate and a preparation method thereof. Raw materials of the high-toughness multilayer ceramic substrate comprise the following components in parts by weight: 90-95 parts of aluminum oxide, 13-17 parts of a sintering aid, 2-5 parts of a plasticizer, 1-3 parts of a dispersant, 3-5 parts of a binder, 10-12 parts of an aid and 55-65 parts of water, the auxiliaries comprise boron carbide, copper-tin alloy powder and graphene oxide. According to the technical scheme, the problem of poor toughness of the multi-layer ceramic substrate in the prior art is solved.

The invention provides a high-barrier fresh-keeping low-temperature heat-sealing composite film and a manufacturing process and application thereof, the composite film sequentially comprises a heat-sealing layer, a barrier layer, a reinforcing layer and a surface treatment layer from the inner layer to the outer layer, and the layers are bonded through bonding layers. The heat-sealing layer is prepared from modified polyethylene, polypropylene and a heat-sealing auxiliary agent, and the barrier layer is made of a composite material of nano aluminum oxide, polyvinylidene fluoride and an ethylene-vinyl alcohol copolymer. The enhancement layer is a polyester film, and the surface treatment layer is subjected to corona treatment. The composite film is prepared through a specific manufacturing process, and the specific manufacturing process comprises the steps of preparation of the heat sealing layer and the blocking layer, compounding, curing treatment, surface treatment and the like. The composite film disclosed by the invention has excellent barrier property and low-temperature heat-sealing capability, is suitable for vacuum packaging or modified atmosphere packaging of foods, and effectively prolongs the fresh-keeping period and the shelf life of the foods.

The invention belongs to the technical field of sodium-ion batteries, and relates to sodium-ion battery positive electrode slurry and a preparation method thereof, and the sodium-ion battery positive electrode slurry comprises a positive electrode active material, a conductive agent, a binder, a dispersant, a slurry stabilizer and a solvent; the positive electrode active material is a transition metal layered oxide material, the conductive agent is one or a combination of more of conductive carbon black, ketjen black, conductive graphite and a carbon nanotube, the binder is polyvinylidene fluoride, the dispersant is polyvinylpyrrolidone, the slurry stabilizer is one or a combination of more of iron oxide, aluminum oxide, zirconium oxide and titanium boride, and the positive electrode active material is a positive electrode active material. The solvent is N-methyl pyrrolidone; in the slurry preparation step, a binder and a solvent are mixed and dissolved to prepare a glue solution; adding a conductive agent and a dispersing agent for dispersing to obtain a conductive adhesive; adding a positive active material and a slurry stabilizer, and dispersing to obtain final slurry; the invention can effectively solve the problem of slurry flocculation in the homogenizing process of the sodium ion battery positive electrode material.

The invention provides a composite granular desulfurizer and a preparation method thereof. The desulfurizer comprises the following components: zinc oxide, calcium oxide, iron oxide, coke, activated carbon, modified attapulgite, a pore-enlarging agent and aluminum oxide. The preparation method comprises the following steps: uniformly mixing the components, feeding into a calcining furnace, roasting at 350-450 DEG C for 2-4 hours to obtain a calcined material, crushing, extruding and forming, and screening by using a vibrating screen to obtain the desulfurizing agent. The desulfurizer is prepared by loading calcium oxide with aluminum oxide, and ferric oxide is added to further catalyze the desulfurization reaction, so that the desulfurization reaction process is changed, and the desulfurization efficiency is improved. The pore-enlarging agent is used for pore-forming of desulfurizer particles, the adsorption performance of the active substance calcium oxide in the desulfurizer is improved, meanwhile, the mechanical performance of the desulfurizer particles is changed, the desulfurizer particles can be repeatedly used, and the regeneration performance of the desulfurizer is improved.

The invention relates to the technical field of solar cells, in particular to a film layer structure for improving UV attenuation of a TOPcon cell. In order to improve the passivation effect of the front face of the TOPCon cell, an aluminum oxide passivation layer is generally arranged on the surface of a BSG layer on the front face of the TOPCon cell, but the aluminum oxide passivation layer is poor in ultraviolet resistance and prone to being damaged by ultraviolet light, and then the service life of the cell is affected. Aiming at the problem, the invention provides the film layer structure for improving UV attenuation of the TOPcon battery, the second silicon oxide layer and the first silicon oxide layer are respectively arranged above and below the aluminum oxide layer, and the silicon nitride layer is arranged on the surface of the second silicon oxide layer, so that the passivation effect of the front surface of the obtained TOPcon battery is remarkably improved, the attenuation speed of the battery is effectively reduced, and the service life of the battery is prolonged. And the service life of the battery is prolonged.

The invention relates to the field of friction materials, and discloses a high-reliability friction material for an electromagnetic brake and a preparation method of the high-reliability friction material. Raw materials of the friction material comprise benzoxazine, phenolic resin, butyronitrile rubber powder, modified basalt fibers, PBO pulp, ceramic fibers, plant fibers, carbon fiber powder, potassium titanate lamellar crystals, barite, light calcium carbonate, friction particles, wollastonite powder, aluminum-titanium powder, feldspar powder, aluminum oxide, zircon powder, garnet powder, crystalline flake graphite, artificial graphite, flexible graphite and composite metal sulfide. And polymer lubricating material micro powder. The friction material provided by the invention is suitable for a high-temperature and high-humidity environment, the stability of the braking performance of a brake is improved, and the phenomenon that the brake slips due to attenuation of braking torque is reduced.

A core-shell particle having an organic polymer core which is completely covered by a first inorganic oxide shell, wherein the first inorganic oxide shell has a silica (SiO2), an alumina (Al2O3), or a titania (TiO2); wherein the first inorganic oxide shell has a layer of a magnetic material which is disposed directly on the polymer core; further having a mesoporous second inorganic oxide shell, wherein the mesoporous second inorganic oxide shell covers the first inorganic oxide shell; wherein the mesoporous second inorganic oxide shell has silica (SiO2), alumina (Al2O3), or a titania (TiO2).

The invention discloses a fluoride salt-free nitrate-free cast iron enamel semitransparent glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, sodium carbonate, potassium carbonate, calcium carbonate, potassium feldspar, zinc oxide, lithium carbonate, zirconium silicate, titanium dioxide, aluminum oxide, trisodium phosphate, antimony oxide, magnesium carbonate and barium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for cast iron matrixes, the firing temperature is 740-760 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.

The invention discloses a heat-insulating ceramic fiber board and a preparation method thereof. The heat-insulating ceramic fiber board comprises the following raw materials in parts by mass: 96-114 parts of aluminum silicate fiber mixed cotton, 4-6 parts of zirconium oxide fiber, 9-12 parts of alkaline silica sol, 12-15 parts of a water-based resin dispersant, 8-10 parts of aluminum oxide fine powder and 5-8 parts of high-temperature ceramsite sand. Wherein the aluminum silicate fiber mixed cotton is a mixture composed of aluminum silicate fiber raw cotton, aluminum silicate fiber broken cotton and aluminum silicate short fibers. The heat insulation ceramic fiber board is high in strength, long in service life, low in heat conductivity coefficient and good in heat insulation performance.

The invention relates to an aluminum oxide CMP polishing solution for rough polishing of silicon carbide wafers and a polishing method of the aluminum oxide CMP polishing solution, and the aluminum oxide CMP polishing solution comprises the following components in percentage by weight: 2-10wt% of nano aluminum oxide abrasive; 0.2 to 2 wt.% of a dispersant; 0.001 to 0.01 wt% of a pH regulator; the concentration of the oxidizing agent is 1-5wt.%. By adopting the compound oxidant, potassium permanganate is utilized to oxidize a reduction product manganese dioxide on the surface of the silicon carbide wafer to activate potassium persulfate, so that a large amount of sulfate free radicals are generated in the polishing solution, the oxidability of the sulfate free radicals is extremely high, the polishing solution can be promoted to generate chain oxidation reaction, and the surface of the silicon carbide wafer is further oxidized; and an oxide layer with low hardness is formed on the surface of the silicon carbide and is finally removed under the mechanical action of the aluminum oxide abrasive, so that the ultra-smooth and damage-free surface of the silicon carbide wafer is formed. The surface roughness of the obtained optimal silicon carbide wafer is 0.125 nm, and the material removal rate is 3.5 [mu] m / h. Compared with an existing aluminum oxide polishing solution, the polishing solution has the advantage that the surface quality and the polishing efficiency of the silicon carbide wafer are remarkably improved.

The invention discloses reflection-heat insulation dual-functional aluminum oxide ceramic and a preparation method and application thereof.The method comprises the steps that after surface silanization treatment is conducted on nanoscale hollow oxide filler, surface-modified nanoscale hollow oxide filler is prepared; and then adding the surface-modified nanoscale hollow oxide filler into a high-molecular polymer and a mixed polar solvent to obtain the thermal insulation coating. The method comprises the following steps: coating the surface of aluminum oxide ceramic with a heat insulation coating to form a primary coating, and carrying out gradient heating curing to obtain aluminum oxide ceramic with a functionalized heat insulation coating; and coating the surface of the thermal insulation coating functionalized aluminum oxide ceramic with an infrared reflection coating, and carrying out annealing treatment in a nitrogen atmosphere to prepare the reflection-thermal insulation dual-functionalized aluminum oxide ceramic. By constructing a double-layer composite structure, enhancing interface thermal resistance through chemical bonding, directionally distributing the nanofiller and designing a low-radiation layer structure, heat conduction and radiation heat transfer of the aluminum oxide ceramic-based material are synergistically reduced, and the high-temperature heat insulation performance of the aluminum oxide ceramic-based material is improved.

The invention relates to a nanometer aluminum oxide polishing solution for a silicon carbide substrate slice as well as a preparation method and application of the nanometer aluminum oxide polishing solution. The nano aluminum oxide polishing solution is prepared from the following components in percentage by weight: 0.5 to 6.0 percent of alpha-Al2O3 abrasive, 0.5 to 5.0 percent of oxidant, 0.1 to 1.0 percent of pro-oxidant, 0.05 to 0.50 percent of pH (Potential of Hydrogen) regulator, 0.10 to 0.50 percent of dispersing agent and the balance of water, the D10 of the alpha-Al2O3 grinding material ranges from 0.100 to 0.140 [mu] m, the D50 of the alpha-Al2O3 grinding material ranges from 0.180 to 0.230 [mu] m, the D90 of the alpha-Al2O3 grinding material ranges from 0.240 to 0.300 [mu] m, the D100 of the alpha-Al2O3 grinding material ranges from 0.340 to 0.420 [mu] m, and The preparation method of the alpha-Al2O3 abrasive material comprises the following steps: preparing alpha-Al2O3 powder into alpha-Al2O3 slurry, adding potassium citrate, grinding, and carrying out particle classification on the alpha-Al2O3 slurry after grinding, so as to obtain the alpha-Al2O3 abrasive material. Compared with the prior art, graded alpha-Al2O3 is selected as abrasive particles for silicon carbide polishing, potassium permanganate with higher oxidability is selected as an oxidizing agent, and the prepared nanometer aluminum oxide polishing solution is applied to chemical mechanical polishing of a silicon carbide substrate slice; the surface roughness of the silicon carbide substrate slice is reduced while the removal rate of the silicon surface material of the silicon carbide substrate slice is improved, and the atomic-scale smooth surface quality is obtained.

The invention relates to the technical field of carbon monoxide oxidation catalysts, and discloses a sulfur-tolerant noble metal-based CO oxidation catalyst as well as a preparation method and application thereof. The preparation method of the catalyst comprises the following steps: dipping a carrier in an aqueous solution containing a noble metal precursor and an auxiliary agent precursor, and then drying and roasting to obtain a catalyst matrix; carrying out pre-reduction treatment on the catalyst matrix in a hydrogen-containing atmosphere to obtain a catalyst intermediate; carrying out induced activation on the catalyst intermediate in an atmosphere containing CO and H2S; wherein the carrier is at least one of titanium dioxide, cerium dioxide, aluminum oxide and zirconium dioxide, and the metal element in the auxiliary agent precursor is at least one of Fe, Co and Ni. The catalyst prepared by the method provided by the invention can realize the high-selectivity oxidation process of H2S species, inhibits the adsorption of S species and the formation process of sulfate, and realizes the high-conversion-rate oxidation reaction of carbon monoxide in the presence of H2S.

The invention discloses an enamel ceramic glaze tile with a metal spot bionic effect and a preparation method thereof, and relates to the technical field of ceramics. The enamel porcelain glaze tile comprises a bottom blank, a metal ground glaze layer and a semi-opaque cover glaze layer, the metal ground glaze layer is prepared from a first ground glaze formula or a second ground glaze formula, and the first ground glaze formula comprises, by mass, potassium feldspar, quartz, calcite, kaolin, talc, zinc oxide, ferric oxide and manganese dioxide; the formula of the second ground glaze comprises the following components in percentage by mass: potassium feldspar, quartz, calcite, kaolin, talc, zinc oxide, ferric oxide and chromic oxide; the semi-opaque surface glaze layer is prepared from the following raw materials in percentage by mass: albite, calcite, talc, burnt soil, zircon powder, oriental zirconium, calcined zinc oxide, black clay powder and calcined aluminum oxide. Through a double-layer glaze structure and a black mud powder glaze breaking mechanism, the stereoscopic visual effect that metal spots are randomly generated on an opacifying substrate is achieved, and meanwhile the Moh's hardness of the ceramic tile is improved.

According to the Pt cluster catalyst, the preparation method and the application, an aluminum oxide composite metal oxide carrier is prepared by adopting a pH swing method, a defect oxide nano island is formed through high-temperature reduction treatment, and oxygen vacancies contained on the surface can firmly anchor a subsequently loaded Pt cluster, so that the coking phenomenon of the Pt-based catalyst is reduced, and the catalytic activity of the Pt-based catalyst is improved. The catalytic activity and the stability of the Pt cluster catalyst are obviously improved. Meanwhile, Pt clusters are prepared through a heating reflux method, so that the Pt clusters have high dispersity and rich active sites, the finally prepared Pt cluster catalyst is small in Pt particle size and high in atom utilization rate, and when the Pt cluster catalyst is used for catalyzing a dehydrogenation reaction of a liquid organic hydrogen carrier, the Pt cluster catalyst is weak in adsorption capacity to a product, and the catalytic activity of the liquid organic hydrogen carrier is improved. The catalyst can show high conversion rate and hydrogen release rate at low temperature, can still keep stable structure at high temperature, and provides an efficient and reliable solution for engineering application of an LOHC dehydrogenation link.

The invention discloses a spherical nano aluminum oxide polishing solution for silicon carbide wafer polishing, and relates to the technical field of preparation of semiconductor silicon carbide wafer polishing materials, and the spherical nano aluminum oxide polishing solution comprises the following raw materials by weight: 0.5-55% of aluminum oxide, 0.05-25% of an oxidant, 0.1-10% of an inhibitor, 0.01-12% of a surfactant, 0.01-15% of a dispersant, 0.1-10% of a pH regulator, and the balance of high purity water. The preparation process comprises the following steps: (1) preparing materials; (2) grinding material pretreatment; (3) mixing; (4) adjusting the pH value; and (5) high-pressure homogenization. The CMP polishing solution has the characteristics of high removal rate, good suspension dispersion performance, no damage to the surface of the silicon carbide wafer, extremely low surface roughness value, long cycle service life, easiness in cleaning, good universality and the like, and is suitable for CMP polishing of semiconductor silicon carbide wafers.

The invention relates to the field of aluminum materials, and provides an automobile corrosion-resistant aluminum material and a preparation method thereof.The automobile corrosion-resistant aluminum material is prepared from cerium oxide loaded aluminum oxide nanorods, scandium / boron nitride nanotubes, zirconium powder, magnesium powder, copper powder, manganese powder, silicon carbide nanoparticles, TiB2 nanoparticles, aluminum powder and stearic acid. Wherein the cerium oxide loaded aluminum oxide nanorod is composed of an aluminum oxide nanorod and cerium oxide nanoparticles loaded on the surface of the aluminum oxide nanorod, and the scandium / boron nitride nanotube is composed of a boron nitride nanotube and a scandium nanolayer uniformly coated on the surface of the boron nitride nanotube. The material is prepared through mechanical ball milling, cold isostatic pressing forming, vacuum sintering and aging treatment, and finally the aluminum-based composite material containing the Al3Sc nano precipitated phase and the boron nitride nanotube reinforced phase is formed. And an Al3Sc precipitated phase and an aluminum matrix form a coherent interface, so that the strength, the corrosion resistance and the wear resistance of the material are improved. Through nanostructure optimization, high performance of the aluminum alloy is achieved, and the aluminum alloy is suitable for the fields of automobiles, aerospace and the like.

The invention discloses a half-piece solar cell passivation method, which comprises the following steps that a plurality of half-piece solar cells are placed in a cavity of atomic layer deposition equipment, cutting surfaces of the plurality of half-piece solar cells are exposed, other surfaces are not exposed, and the cutting surfaces of the half-piece solar cells are parallel or in the same plane; the cutting surface is parallel to the direction of airflow arranged in the cavity; the cavity is heated to a preset reaction temperature, an aluminum source and an oxygen source are alternately introduced into the cavity in a pulse mode, an aluminum oxide film is deposited on the cutting faces of the multiple half solar cells so as to achieve passivation, the aluminum source comprises trimethyl aluminum steam, the oxygen source comprises ozone or water vapor, and the airflow inflow direction of the aluminum source and the oxygen source is parallel to the cutting faces; and annealing and cooling the plurality of half-piece solar cells to obtain the passivated half-piece solar cells. According to the method, the passivation uniformity can be improved, the passivation rate is increased, and the passivation duration, raw material consumption and cost are reduced.