5932 results about "Aluminium oxides" patented technology

The invention discloses a preparation process of an aluminum oxide ceramic material, which comprises the following steps: S1, pretreatment of aluminum oxide powder: taking alpha-Al2O3 powder as a raw material, adding a dispersion medium, carrying out ball milling, transferring into an ultrasonic dispersion machine, dispersing, and further carrying out vacuum drying to obtain pretreated aluminum oxide powder; s2, chemical activation treatment: weighing pretreated aluminum oxide, magnesium oxide, nano silicon dioxide, calcium oxide, zirconium dioxide, titanium dioxide and modified nano silicon carbide in parts by weight, mixing, sequentially adding a dispersing agent absolute ethyl alcohol and a KH550 silane coupling agent, stirring at a high speed, adding a polyvinyl alcohol binder, and continuously stirring to obtain ceramic slurry; s3, sieving the ceramic slurry, filling the ceramic slurry into a mold, and performing isostatic pressing to obtain a ceramic green body; and S4, putting the ceramic green body into a box-type sintering furnace, sintering step by step, and cooling to room temperature along with the furnace to obtain the aluminum oxide ceramic material. The prepared aluminum oxide ceramic material has high compactness, excellent dielectric strength and mechanical property, low energy consumption and great application potential.

The invention discloses a fluoride salt-free nitrate-free cast iron enamel semitransparent glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, sodium carbonate, potassium carbonate, calcium carbonate, potassium feldspar, zinc oxide, lithium carbonate, zirconium silicate, titanium dioxide, aluminum oxide, trisodium phosphate, antimony oxide, magnesium carbonate and barium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for cast iron matrixes, the firing temperature is 740-760 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.

The invention relates to a modified chrome corundum ramming material and a preparation and construction process thereof, and belongs to the technical field of chrome corundum ramming materials. The ramming material comprises a material A, a material B and a material C, wherein the material A comprises chrome corundum aggregate, titanium dioxide coated aluminum oxide microspheres, calcium sulfide dehydrate and silicon carbide porous microspheres; the material B comprises chromium oxide-zirconium oxide composite nano powder, sodium thiosulfate pentahydrate, tricalcium phosphate and hexagonal boron nitride flaky crystals; and the material C comprises an aluminum dihydrogen phosphate-magnesium hydroxide compound, a calcium fluoride-aluminum oxide co-melt and a silane coupling agent. The preparation process comprises the steps of pretreatment of all the components, preparation of composite powder and layered preparation. The construction process comprises the steps of pretreatment, wet-process mixing, layered ramming, negative-pressure permeation, medium-temperature reaction, spraying curing, integral firing and the like. Generation of hexavalent chromium can be effectively inhibited, the thermal shock resistance, the mechanical strength and the heat-conducting property of the material are remarkably improved, and the material has the advantages of being good in environment friendliness, long in service life, excellent in construction performance and the like.

The invention discloses a high-weather-resistance bismuth vanadate coating and a preparation method thereof, and belongs to the technical field of inorganic pigment modification. The high-weather-resistance bismuth vanadate coating comprises bismuth vanadate matrix particles, and the surfaces of the bismuth vanadate matrix particles are sequentially coated with an amorphous aluminum oxide layer, a cerium oxide layer and a fluorinated silicon oxide layer. The amorphous aluminum oxide layer is formed in an atomic layer deposition mode; the cerium oxide layer is formed by hydrothermal treatment of a cerium source. The preparation technology has accurate and controllable technological parameters, is suitable for industrial production, can replace the traditional toxic pigment containing lead and cadmium, and meets the requirements of environmental regulations. The bismuth vanadate coating has excellent weather resistance and chemical stability, the service life of a product can be prolonged, the maintenance cost is reduced, and a reliable solution is provided for development of high-performance environment-friendly pigments.

The invention provides a carbon ceramic resistor and a preparation method thereof, and relates to the technical field of special material production of power systems and electrical equipment. The preparation method comprises the steps that carbon-containing electric conductor raw materials are mixed to obtain a first mixed raw material, and the carbon-containing electric conductor raw materials comprise, by mass, 15 parts of gluconic acid, 10 parts of aluminum oxide and 55 parts of deionized water; performing hydrothermal reaction on the first mixed raw material to obtain a carbon-containing conductor precursor; the carbon-containing conductor precursor is carbonized in a protective atmosphere, a carbon-containing conductor of a core-shell structure is obtained, and the carbon-containing conductor takes aluminum oxide as an inner core and takes a conductive carbon material formed by gluconic acid as a conductive outer shell; mixing the carbon-containing electric conductor with the core-shell structure with a carbon ceramic matrix raw material to obtain a resistor blank; and sintering the resistor blank to obtain the carbon ceramic resistor. The uniformity, the stability and the reliability of the carbon ceramic resistor are improved, so that the carbon ceramic resistor can better meet the application requirements of ultrahigh-voltage and extra-high-voltage alternating-current power transmission systems.

The invention discloses high-toughness ultrathin flexible glass and a preparation method thereof, and relates to the technical field of glass manufacturing. The ultrathin flexible glass is prepared from the following raw materials: silicon dioxide, aluminum oxide, lithium oxide, sodium oxide, magnesium oxide, a modified nano reinforced phase, a high-temperature melting regulator and cerium dioxide. The modified nano reinforced phase is prepared by the following steps: pre-treating silicon carbide and silicon nitride with hydrochloric acid, and mixing with nano zirconium oxide to obtain a mixture; and modifying the mixture with a silane coupling agent to obtain the modified nano reinforced phase. The high-temperature melting regulator is a mixture of lithium borate, sodium sulfate and lithium fluoride. The preparation method of the ultra-thin flexible glass comprises the following steps: preparing the modified nano reinforced phase, melting and homogenizing the glass, forming the glass substrate, and preparing the ultra-thin flexible glass. The ultra-thin flexible glass prepared by the invention has relatively high fracture toughness and structural rigidity, excellent flexibility and bending fatigue durability, and excellent thermal shock resistance.

The invention provides a low-compression-stress low-density heat-conducting gasket and a preparation method thereof.The heat-conducting gasket is prepared from, by weight, 100-300 parts of vinyl silicone oil, 1-3 parts of end chain hydrogen-containing silicone oil, 2-6 parts of side chain hydrogen-containing silicone oil, 0.2-0.6 part of platinum catalyst, 300-700 parts of heat-conducting filler, 0.1-0.5 part of coupling agent and 0.1-0.5 part of inhibitor. Wherein the vinyl silicone oil is prepared by matching two kinds of vinyl-terminated polydimethylsiloxane with different viscosities and vinyl contents; and the heat-conducting filler is a ternary combination of spherical aluminum oxide, spherical boron nitride and beta-type silicon nitride with a lubricating function. The preparation method comprises the following steps: adding the raw materials into stirring equipment, controlling the vacuum degree during stirring by adopting staged negative pressure, stirring under the conditions that the negative pressure is less than or equal to-0.095 MPa,-0.06 to-0.07 MPa and less than or equal to-0.095 MPa in sequence, fully mixing the materials, clustering, transferring to a calender, and carrying out high-temperature vulcanization molding at 120-140 DEG C. The heat-conducting gasket has the characteristics of low compression stress and low density, and the production efficiency is remarkably improved.

The invention belongs to the technical field of electrode foil formation treatment, and particularly relates to an electrode foil and a preparation method thereof and an aluminum electrolytic capacitor, the preparation method of the electrode foil comprises the steps of performing multi-stage formation treatment on a corrosion foil, the number of stages of the formation treatment is at least two, and the formation treatment at least comprises first-stage formation and second-stage formation, first heat treatment is carried out after the second-stage formation; a formation liquid used in the second-stage formation is a mixed solution containing adipate and monopotassium phosphate. According to the preparation method provided by the invention, the formation liquid used in secondary formation is the mixed solution containing adipate and monopotassium phosphate, the limitation of traditional single formation liquid is broken through, and synchronous optimization of the structure, hydration resistance and electrochemical performance of the aluminum oxide film is realized through multi-stage formation, mixed solution synergy and the synergistic effect of formation and heat treatment; meanwhile, production cost is reduced, and environmental load is relieved.

The invention belongs to the field of synthesis of inorganic non-metallic materials, and particularly relates to an equimolar-ratio seven-element high-entropy oxide and a preparation process thereof. The preparation process comprises the following steps: putting seven oxide powder Al2O3, Y2O3, TiO2, ZrO2, NiO, CuO and CeO2 into a ball milling tank according to a molar ratio of 1: 1: 2: 2: 2: 2: 2: 2, adding absolute ethyl alcohol and zirconium oxide grinding balls, performing ball milling in a ball mill, and fully drying and sieving after ball milling to obtain mixed powder; carrying out tabletting treatment on the mixed powder to obtain a to-be-sintered green body; and putting the to-be-sintered green body into an alumina crucible, and putting the alumina crucible into a microwave oven for microwave sintering. According to the method, the equimolar-ratio seven-element high-entropy oxide (AlYTiZrNiCuCe) Ox with good solid solution is obtained, the crystallinity and element uniformity of the seven-element high-entropy oxide are improved, all the raw materials react completely, meanwhile, the process efficiency is high, and energy consumption is low.

The invention is suitable for the technical field of electrical measurement and state monitoring, and provides an aluminum electrolysis cell power distribution system regionalization independent blanking control method based on pseudo resistance monitoring, and the method comprises the steps: collecting the anode current and the cell voltage of each measurement point; dividing the plurality of measurement points into a plurality of control areas, and calculating a pseudo resistance value of each control area; screening control areas meeting conditions from all the control areas to form a reference area set; determining an aluminum oxide concentration reference state of each control region in the reference region set through a preset concentration state mapping relation; with the reference region set as a starting point, according to the proximity relation between the control region with the undetermined state and the reference region set in space and the similarity of pseudo resistance values, the aluminum oxide concentration state is propagated to all the control regions through iterative matching; according to the aluminum oxide concentration states of all the control areas, independent discharging control instructions of all the control areas are generated; and the regionalized independent control on the concentration of aluminum oxide in the aluminum electrolysis cell is realized.

The invention discloses a method for preparing a light-transmitting gradient multicolor zirconium oxide material through photocuring, which comprises the following steps: preparing modified aluminum oxide which is formed by attaching a strontium element and a chromium element to the surface of aluminum oxide; preparing bottom-layer slurry, middle-layer slurry and upper-layer slurry from the zirconium-aluminum powder; the bottom layer slurry comprises zirconium aluminum powder and a coloring agent; the middle layer slurry comprises zirconium-aluminum powder, a light-transmitting auxiliary agent and a coloring agent; the upper-layer slurry comprises zirconium-aluminum powder, a light-transmitting auxiliary agent and a coloring agent; preparing a bottom layer green body by using the bottom layer slurry through 3D printing by using the photocuring slurry, preparing a middle layer green body on the surface of the bottom layer green body by using the middle layer slurry, and preparing an upper layer green body on the surface of the middle layer green body by using the upper layer slurry, so as to obtain a zirconium oxide material green body; the light-transmitting gradient multicolor zirconia material with gradient light transmission and gradient color is directly prepared through 3D printing, the color of the light-transmitting gradient multicolor zirconia material is closer to that of real teeth, and the strength and toughness are not reduced.

The invention provides a wastewater advanced oxidation catalyst and a preparation method and application thereof, the wastewater advanced oxidation catalyst is of a core-shell structure, the core is activated carbon containing copper oxide and optional ferrous sulfide, and the shell is a silicon oxide-aluminum oxide compound containing nano ferrous sulfide. The invention further provides a preparation method of the wastewater advanced oxidation catalyst and application of the wastewater advanced oxidation catalyst in organic wastewater treatment. The wastewater advanced oxidation catalyst has the characteristics of high catalytic degradation capability on organic pollutants and the like, solves the problem of copper dissolution, and improves the long-term effectiveness of the catalyst.

The invention provides a low-cost high-specific-surface-area cerium-aluminum composite oxide, a preparation method and application thereof, and relates to the technical field of catalysts, the preparation method comprises the following steps: step S1, adding 10-40% of cerium salt, 50-90% of aluminum salt and 0-10% of lanthanum source or zirconium source into deionized water, stirring and mixing, filtering, and washing to be neutral to obtain a cerium-containing solution; step S2, impregnating an alumina carrier in the cerium-containing solution prepared in the step S1, and standing to enable the cerium-containing solution to be impregnated on the alumina carrier, so as to obtain impregnated slurry; and S3, drying the dipping slurry, and then roasting in an inert atmosphere to obtain the cerium-aluminum composite oxide. The stable cerium-aluminum composite material is formed by doping one of lanthanum and zirconium with different masses into aluminum oxide or cerium oxide, the problem that the adsorption capacity of a traditional ammonia trapping method is limited is effectively solved, and the adsorption capacity of the material to ammonia is remarkably improved.

The application provides a method for grading diesel deep hydrodesulfurization catalysts, which comprises the following steps: loading catalysts containing AlPO4-5 phosphorus aluminum molecular sieves and catalysts containing ETS-10 titanium silicon molecular sieves in the upper and lower parts of a fixed bed hydrogenation reactor respectively according to a loading mass ratio of 1:3-3:1, so that diesel is subjected to hydrodesulfurization reaction through catalysts containing AlPO4-5 phosphorus aluminum molecular sieves first and then through catalysts containing ETS-10 titanium silicon molecular sieves; the carrier of the catalysts containing AlPO4-5 phosphorus aluminum molecular sieves comprises AlPO4-5 phosphorus aluminum molecular sieves and aluminum oxide powder, the carrier of the catalysts containing ETS-10 titanium silicon molecular sieves comprises ETS-10 titanium silicon molecular sieves and aluminum oxide powder, and the active components of the two kinds of catalysts respectively comprise a combination of two or three of nickel oxide, molybdenum oxide and cobalt oxide. The sulfur content of the hydrogenated diesel obtained through the method can be as low as 10 μg / g or below.

The invention relates to a preparation method and system for an atomic gas chamber for sapphire coating, and the preparation method comprises the steps: S1, placing a cleaned atomic gas chamber on a heating base station of a reaction chamber, and filling the reaction chamber with replacement gas to discharge residual gas in the reaction chamber; s2, filling aluminum source gas into the reaction chamber, and carrying out chemical adsorption on the wall surface of the atomic gas chamber to form a first film layer; s3, filling replacement gas into the reaction chamber to discharge residual aluminum source gas in the reaction chamber; s4, filling oxide gas into the reaction chamber to oxidize the first film layer and convert the first film layer into an aluminum oxide film layer; s5, filling replacement gas into the reaction chamber to discharge residual oxide gas in the reaction chamber; and S6, repeating the steps S2 to S5 to form a preset number of aluminum oxide film layers with a preset thickness on the wall surface of the atomic gas chamber so as to form the atomic gas chamber with the sapphire coating film. The anti-shielding capability of the alkali metal atomic gas chamber can be enhanced, and the electromagnetic wave precision measurement performance of the atomic gas chamber is improved.

The invention relates to the technical field of catalyst carriers, and discloses reticular porous spherical aluminum oxide as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) mixing an aluminum source, acid, a pore-forming agent, a surfactant and water to obtain pseudo sol; (2) performing ultrasonic treatment and oil ammonia column forming treatment on the pseudo sol obtained in the step (1) to obtain gamma-Al2O3 spherical gel beads; and (3) aging, washing, drying and calcining the gamma-Al2O3 spherical gel beads obtained in the step (2) to obtain the reticular porous spherical alumina. The spherical aluminum oxide prepared by the method has abundant communicated reticular pore channels, is obviously distributed in mesopore and macropore ranges, is beneficial to obviously improving dispersion and loading of a catalyst in an aluminum oxide carrier and improving the performance of petroleum reforming and propane dehydrogenation, and has industrial production utilization value and commercial value.

According to the emulsion mixing equipment applied to the mixing field and used for aluminum oxide composite fiberboard production, through a guide cylinder which forms an annular gap with the inner wall of a tank body in an enclosing mode and a stirring assembly arranged on the lower portion of the guide cylinder, raw materials circularly flow between the annular gap and an inner cavity of the guide cylinder, and the stirring assembly and a shearing assembly act synergistically; firstly, raw materials fully flow, components are promoted to be uniformly dispersed, local concentration difference is avoided, a foundation is laid for stable emulsification, agglomeration and precipitation are reduced, the emulsification efficiency and quality are improved, meanwhile, by means of a plurality of heat exchange structures such as a tank shell wall cooling clamping cavity, a spiral heat exchange pipe, an emulsification stator inner heat exchange channel and a guide cylinder shell wall spiral channel, sufficient heat exchange is achieved, and the emulsification efficiency and quality are improved. The raw material temperature is effectively controlled, heat accumulation and overheating are reduced, and the gelation probability is reduced.

The invention discloses a polyetherketoneketone high-temperature-resistant wear-resistant non-stick coating and a preparation method thereof. The coating is prepared from the following components in parts by mass: 13 to 30 parts of a resin matrix group (containing 12 to 25 parts of titanium modified polyether ketone ketone resin, 1 to 5 parts of fluorine-free viscous resin and 0.65 to 6 parts of aluminum oxide), 0.5 to 3 parts of a nano reinforced group (containing 0.5 to 3 parts of KH-550 modified nano titanium dioxide, 0.025 to 0.6 part of cerium dioxide and 0.5 to 3 parts of boron nitride) and 62 to 71 parts of an auxiliary agent group. The preparation method comprises the following steps: 1) taking diphenyl ether, paraphthaloyl chloride and isophthaloyl chloride as monomers, and synthesizing titanium modified polyether ketone ketone resins with different viscosities through segmented polymerization (1.5-2.0 hours or 3.0-4.0 hours); 2) respectively preparing a smooth bottom layer water dispersion slurry and a wrinkled surface layer water dispersion slurry; and (3) forming a compact bottom layer and a micro-wrinkle surface layer on the base material by adopting a layered spraying and stepped sintering process (280-320 DEG C, 10-20 minutes). The whole system of the coating is fluorine-free and has temperature resistance gt; the coating has the characteristics of high temperature resistance (350DEG C), wear resistance (Taber wear rate of 3-5mg / 1000r), non-sticking (contact angle gt, 100 DEG C) and heavy corrosion resistance, and is suitable for cooking utensils and chemical equipment.

The invention discloses a polytetrafluoroethylene compensator with good corrosion resistance and a preparation method thereof.The polytetrafluoroethylene compensator is composed of a corrugated pipe, a pipe connecting flange and an end flange, the pipe connecting flange and the end flange are located at the two ends of the corrugated pipe, the corrugated pipe is composed of a lining layer and a base material layer, and the base material layer is made of stainless steel; the preparation method comprises the following steps: firstly, carrying out surface grafting on nano aluminum oxide by using isocyanate silane, and introducing an active reaction group; then part of active groups react with benzotriazole, so that the corrosion inhibition and adhesion enhancement functions are realized; finally, enabling the residual active groups to react with hydroxylated polytetrafluoroethylene activated by alkali treatment, and coating a chemical inert layer on the surface of the residual active groups; the obtained core-shell structure functional filler is dispersed in epoxy resin to prepare a coating, and after the coating is coated on a stainless steel base material and cured, a high-performance compensator with high hardness, strong adhesive force, excellent corrosion resistance and weather resistance is formed.

The invention discloses fluoride-salt-free and nitrate-free high-temperature acid-resistant translucent glaze for steel plate enamel as well as a preparation method and application of the translucent glaze, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, titanium dioxide, trisodium phosphate, potassium carbonate, lithium carbonate, aluminum oxide, zinc oxide and sodium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and firing adaptability, is suitable for a steel plate matrix, has the firing temperature of 840-880 DEG C and the firing time of 820-830 minutes, and is suitable for a steel plate. The method can be used for producing green and environment-friendly enamel products.

A component for use in a semiconductor processing chamber is provided. A metal or metal alloy component body has a process-facing surface. An intermediate aluminum oxide coating is disposed on the process-facing surface, the intermediate aluminum oxide coating being at least 99% pure by weight and having a porosity of less than 0.1% by volume, the intermediate aluminum oxide coating having a first thickness. A process-exposed layer is disposed on the intermediate aluminum oxide coating, the process-exposed layer comprising at least one of yttrium, hafnium, zirconium, lanthanum, magnesium, and a lanthanide, the process-exposed layer being at least 99% pure by weight, having a porosity of less than 0.1%, and having a second thickness, the second thickness being less than or equal to the first thickness.

The invention discloses a preparation method of low-temperature rapid densification silicon nitride ceramic based on an aluminum oxide-yttrium oxide composite sintering aid, and aims to solve the problems of high temperature, high energy consumption, difficult densification and the like in the existing Si3N4 ceramic preparation. The preparation method comprises the following steps: 1, mixing alpha-Si3N4 powder, Y2O3 powder and Al2O3 powder, and carrying out ball milling dispersion to obtain mixed powder; 2, carrying out rotary evaporation drying on the mixed powder under a vacuum condition; 3, carrying out heat preservation treatment under the conditions of 1600-1700 DEG C and 40-60 MPa through a spark plasma sintering process; and 4, demolding after cooling. Under the action of the Al2O3-Y2O3 composite sintering aid, phase transformation from alpha-Si3N4 to beta-Si3N4 is remarkably promoted, the relative density of the ceramic reaches 97%-99%, the fracture toughness of the ceramic is 5.21 MPa.m < 1 / 2 >, and the bending strength of the ceramic is 924.99 MPa.

The invention relates to the technical field of thermal insulation materials, in particular to an aerogel felt and a preparation method thereof.The aerogel felt is composed of a composite fiber base material and multi-component aerogel loaded in the composite fiber base material, the composite fiber base material comprises 65%-75% of alkali-free glass fibers, 15%-20% of modified polyimide fibers, 4%-6% of nanoscale carbon fibers and 8%-12% of basalt fibers, and the multi-component aerogel is loaded in the composite fiber base material. According to the multi-component aerogel, 78%-82% of tetraethoxysilane, 12%-14% of methyltrimethoxysilane, 4%-6% of dimethyldimethoxysilane and 2%-4% of vinyltrimethoxysilane serve as precursors, 1.5%-2.5% of aluminum oxide, 0.8%-1.5% of titanium oxide nanoparticles and 3%-4% of zinc borate are added, a multi-stage reinforced structure is formed, the mechanical property and flexibility of the aerogel felt are remarkably improved, the tensile strength reaches 400 kPa or above, and the tensile strength reaches 400 kPa or above. The flexibility is excellent.

The invention discloses a negative electrode active material and a preparation method thereof, a negative electrode pole piece and a secondary battery, the negative electrode active material provided by the invention comprises a silicon-carbon composite material and an aluminum oxide layer coated on the surface of the silicon-carbon composite material, and the silicon-carbon composite material is a composite material of nitrogen-fluorine co-doped porous carbon and nano silicon particles. By optimizing and regulating the porosity and pore size distribution of the porous carbon, the ion transmission kinetics and the structural stability are improved, and the problems of poor rate capability, short cycle life and the like caused by single pore size of the traditional porous carbon are solved. By adopting the nitrogen and fluorine co-doped porous carbon skeleton, the conductivity of the electrode material is enhanced, and the cycling stability of the battery is improved. The nano silicon component uniformly deposited through a chemical vapor phase method provides high specific capacity, the aluminum oxide coating layer can effectively inhibit the decomposition reaction of the solid electrolyte, and the long-term stability and cycle performance of the electrode structure are jointly guaranteed through the dual effects.

The invention belongs to the technical field of aluminum electrolysis, and particularly relates to an electrolytic aluminum oxide concentrated phase conveying solid-gas ratio monitoring system and method, and the system comprises a control system, a material tank system, a compressed air system and a concentrated phase conveying system; the output end of the charging bucket system is connected with the input end of the concentrated phase conveying system; the output end of the compressed air system is connected with the charging bucket system and the concentrated phase conveying system; an air flow meter is mounted on the compressed air system, a weighing sensor is mounted on the charging bucket system, and the control system calculates and controls the solid-gas ratio through the air flow meter and the weighing sensor; the solid-gas ratio is calculated and controlled through the control system, and the working efficiency is improved.

The invention relates to the technical field of functional ceramic materials, and discloses complex-phase gradient isomeric zinc spinel-based composite activated zinc oxide, a preparation method thereof and a ceramic glaze, and the preparation method comprises the following steps: mixing zinc oxide, aluminum oxide, silicon oxide, magnesium oxide and rare earth oxide in proportion to obtain a mixture, adding the mixture and an alkoxy compound into a solvent, and dispersing to form nano precursor slurry; carrying out reduction-oxidation calcination treatment on the obtained nano precursor slurry to obtain a calcined product; and carrying out hydration treatment on the obtained calcined product to obtain the complex-phase gradient isomeric zinc spinel-based composite activated zinc oxide. By implementing the preparation method, the obtained complex-phase gradient isomeric zinc spinel-based composite activated zinc oxide contains a zinc oxide phase and a spinel phase, is low in high-temperature lattice distortion rate and has super wear resistance, and a rare earth element R is introduced, so that the catalytic activity of the zinc oxide is improved, the degradation rate of the zinc oxide to formaldehyde and toluene is increased, and the antibacterial property of the zinc oxide is also improved.

The invention discloses fluoride salt-free and nitrate-free low-temperature matte glaze for steel plate enamel as well as a preparation method and application of the low-temperature matte glaze, and belongs to the technical field of enamel. The matte glaze is prepared from quartz, borax pentahydrate, sodium carbonate, titanium dioxide, magnesium oxide, monopotassium phosphate, calcium carbonate, zinc oxide, magnesium carbonate, lithium carbonate, aluminum oxide and zirconium silicate according to a specific mass ratio. The preparation method comprises the following steps: mixing the raw materials, melting at 1300 + / -10 DEG C in a pure oxygen environment, and quenching after wiredrawing to detect a molten state. The matte glaze completely avoids the use of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are eliminated from the source, the fluorine content of the product is not detected through detection, and the limit value requirements of European Union REACH regulations are met. Zinc oxide and ZnO / TiO2 are added, so that the liquid phase viscosity is reduced, ion diffusion is accelerated, and the opacity (opacification performance) and gloss of the porcelain glaze are enhanced.

The invention discloses a fluoride-salt-free and nitrate-free cast iron enamel zirconium white glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The zirconium white glaze is prepared from quartz, borax pentahydrate, magnesium carbonate, potassium carbonate, potassium feldspar, zinc oxide, aluminum hydroxide, calcium carbonate, zirconium silicate, sodium tripolyphosphate and lithium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The zirconium white glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, and meanwhile, the zirconium white glaze has good porcelain surface, luster and firing adaptability, is suitable for cast iron matrixes, has the firing temperature of 740-760 DEG C and the firing time of 87-87 hours, and can be widely applied to cast iron substrates. The method can be used for producing green and environment-friendly enamel products.

The invention discloses high-temperature-resistant fluorine-modified estersil and a preparation method thereof, and relates to the technical field of organosilicon materials.The high-temperature-resistant fluorine-modified estersil comprises a group A and a group B. The group A serves as a main base material and functional filler and is used for providing a film-forming framework and the high-temperature-resistant characteristic; the group B is a cross-linking curing unit and is used for regulating and controlling the reaction rate and the final cross-linking density; the component A comprises the following raw materials: a fluorine-terminated vinyl estersil prepolymer, a vinyl estersil diluent, surface fluorinated nano silicon dioxide, spherical aluminum oxide, an antioxidant and a defoaming agent; the component B comprises the following raw materials: a hydrogen-containing silyl ester cross-linking agent, a platinum catalyst and an inhibitor. A fluorine-terminated structure is introduced into a vinyl estersil prepolymer, and surface fluorinated nano silicon dioxide and spherical aluminum oxide are adopted for synergistic filling, so that the thermal stability and interface bonding force of the material are improved; the obtained high-temperature-resistant fluorine-modified estersil can still keep excellent mechanical strength and electrical insulation performance under the condition of 250-300 DEG C, and has the characteristics of low surface energy and pollution resistance at the same time.

The invention discloses an efficient separation and purification method of MLnM type medium-chain and long-chain triglyceride, and belongs to the technical field of separation and purification. The efficient separation and purification method comprises the following steps: S1, preparing a crude product; s2, mixing the crude product with an adsorbent for static adsorption; and S3, performing column chromatography elution on the static adsorption product, and performing dynamic chromatography to separate the MLnM type triglyceride. According to the efficient separation and purification method of the MLnM type medium-long-chain triglyceride, a neutral aluminum oxide static adsorption and dynamic column chromatography coupling process is adopted, the purity of the MLnM type triglyceride can be greatly improved and is far higher than that of other adsorbents, the whole process steps are clear, the steps of raw material preparation, static adsorption, dynamic chromatography and the like are included, and the method is suitable for industrial production. The operation process is easy for standardized and large-scale production, and does not need to depend on complex equipment such as molecular distillation, supercritical CO2 extraction and the like.