1555 results about "Molybdenum" patented technology

The invention discloses a multi-component composite oxide dispersion strengthening molybdenum alloy and a preparation method thereof, and relates to the technical field of refractory metal powder metallurgy preparation. The molybdenum alloy comprises a molybdenum matrix and a Y-X-O composite oxide nano precipitated phase dispersed and distributed in the molybdenum matrix. The molybdenum alloy comprises the following components in percentage by mass: 1%-2% of Y2O3, 0.3%-1.2% of an active element X, 96.5%-98.7% of molybdenum and inevitable impurities, wherein X is selected from one of Ti, Zr and Hf; the Y-X-O composite oxide nano precipitated phase and the molybdenum matrix form a coherent or semi-coherent interface, and the interface mismatch degree is less than or equal to 5%. The molybdenum alloy has excellent high-temperature strength and creep resistance, and can be applied to the high-temperature fields of nuclear industry, aerospace and the like.

The invention discloses a method for preparing a carbon monoxide oxidation catalyst by using red mud and tungsten-molybdenum smelting slag, which comprises the following steps of: uniformly stirring and mixing the red mud and the tungsten-molybdenum smelting slag at a high speed, mixing with inorganic strong acid, and performing ultrasonic-assisted stirring to obtain acid leaching slag; the acid leaching residues are subjected to low-temperature plasma activating treatment and then microwave activating treatment, and microwave activated plasma residues are obtained; weighing tricalcium phosphate and microwave activated plasma slag, and uniformly stirring to obtain phosphorus-calcium doped activated slag; weighing an ammonium sulfide solution and the phosphorus-calcium doped activated slag, uniformly stirring, transferring the obtained sulfur-phosphorus-calcium doped activated slag into a hydrothermal reaction kettle, carrying out hydrothermal reaction, carrying out compression molding on the obtained hydrothermal composite material, and carrying out pyrolysis carbonization treatment in an inert gas atmosphere to obtain the phosphorus-calcium doped activated slag. The obtained pyrolysis composite material is soaked with a silane coupling agent solution and then roasted again, and the carbon monoxide oxidation catalyst is obtained. The catalyst prepared by the invention can realize efficient oxidation photocatalysis of carbon monoxide under the conditions of normal temperature and normal pressure.

This invention belongs to the field of catalyst technology, specifically relating to a selective reduction catalyst for the production of sulfur from sulfur dioxide and its application method. The selective reduction catalyst for sulfur production from sulfur dioxide contains 1-2 wt% cobalt (CoO), 4-10 wt% molybdenum (MoO3), and 2-4 wt% zinc (ZnO), with TiO2-Al2O3 as the support. This invention exhibits good wide-temperature reaction performance, heat resistance, and water vapor resistance; the single-pass yield of elemental sulfur is higher than 80%, and the reaction process has high efficiency, showing promising application prospects.

The invention discloses an injection molding high-density alloy steel sintering integrated preparation process, which comprises the steps of alloy raw material proportioning, feed preparation, injection molding, continuous thermal desorption sintering treatment and enhanced heat treatment, and comprises the following steps: selecting gas atomization pure iron powder subjected to vacuum reduction treatment, and matching with chromium, nickel, molybdenum, vanadium, carbon, silicon, manganese and iron powder multi-component alloy proportioning; a phenolic resin-polyformaldehyde composite binder is adopted, 0.5-1.5% of a lubricating additive is added, internal mixing parameters are controlled under the protection of inert gas according to the powder-to-rubber ratio of 72-77%: 23-28%, and the problem that the compatibility of a single binder and alloy powder is poor is solved; three-section gradient temperature control injection molding and a continuous atmosphere furnace sectional degreasing-sintering integrated process are combined, and strengthening heat treatment is matched, so that sufficient diffusion of elements and densification of a green body are realized, and defects are avoided. The technology effectively solves the technical problems that traditional raw materials are high in impurity content and insufficient in element diffusion, and therefore the alloy steel sintering preparation efficiency can be improved.

The invention discloses a copper-molybdenum alloy component and a manufacturing method thereof, and belongs to the technical field of alloy manufacturing. Mo powder is sequentially subjected to vacuum drying treatment, oxidation-reduction treatment and coating treatment, so that the Mo powder has good flowability and powder laying uniformity; under the preset 3D printing condition, the porous Mo framework which is stably formed and complex in structure can be obtained, the problems that an existing rolling composite method is complex in technological process, strict in technological requirement and the like are solved, and the method is suitable for manufacturing parts with small sizes or complex shapes; the porous Mo framework is subjected to vacuum thermocuring and Cu infiltration treatment, and the obtained copper-molybdenum alloy component is excellent in compactness, high-temperature stability, interface bonding strength, heat conduction, electrical conductivity and the like. The problems that a copper-molybdenum alloy obtained in the prior art is poor in wettability and low in density and uniformity, and the mass content of copper is lower than 30%, so that the heat conductivity, the electric conductivity, the air tightness and other performance are low are solved.

The invention relates to a nickel-molybdenum anode electrode based on a crack induced self-passivation mechanism and a preparation method of the nickel-molybdenum anode electrode. The method comprises the following steps that 1, a substrate is soaked in a solution A for 1-25 min and then taken out; 2, immersing the substrate treated in the step 1 into a solution B for 10 minutes to obtain a precursor; and 3, putting the precursor into a Joule ultrafast heating device, heating the precursor to 380-450 DEG C at a heating rate greater than or equal to 100 DEG C / min in an air or inert atmosphere, carrying out heat preservation for a certain time, and cooling to obtain the nickel-molybdenum anode electrode. According to the method, the foam nickel three-dimensional framework is free of structural damage through short-time chemical soaking, the original high porosity and interconnection network of the foam nickel three-dimensional framework are perfectly reserved, and the loss rate of the specific surface area is reduced. According to the prepared nickel-molybdenum anode electrode, by means of the self-passivation effect of the crack edge and the component storage function of the thick layer, the Mo dissolution rate is reduced by one order of magnitude, and thousand-hour-level stable operation under the low current density can be achieved.

The invention belongs to the technical field of catalysts, and particularly relates to a selective reduction catalyst for preparing sulfur from sulfur dioxide and an application method of the selective reduction catalyst. The selective reduction catalyst for preparing sulfur from sulfur dioxide contains 1-2wt% of cobalt (in terms of CoO), 4-10wt% of molybdenum (in terms of MoO3) and 2-4wt% of zinc (in terms of ZnO), and a carrier is TiO2-Al2O3. The method has good wide-temperature reaction performance, heat resistance and water vapor resistance, the single-pass yield of elemental sulfur is higher than 80%, the efficiency of the reaction process is high, and the method has good application prospects.

The invention relates to the technical field of mineral processing, and particularly provides a combined reagent system for flotation and magnesium reduction of talc-containing copper-molybdenum ore and application of the combined reagent system. The combined reagent system comprises a flotation collecting agent (faint yellow to orange transparent liquid, 40%-50% of active ingredients and less than or equal to 3% of free alkali) with active ingredients in the formula 1 and a flotation depressing agent (light yellow powder, extracellular polysaccharide extract of xanthomonas, the weight-average molecular weight of 1000-1500000 Daltons and rich in hydroxyl, carboxyl and pyruvic acid groups) with a structural formula in the formula 2, and the flotation depressing agent comprises extracellular polysaccharide extract of xanthomonas, the weight-average molecular weight of xanthomonas and the weight-average molecular weight of xanthomonas and is rich in hydroxyl, carboxyl and pyruvic acid groups. Through the synergistic adsorption effect of the combined reagent, the flotation grade and the recovery rate of the copper sulfide molybdenum ore are remarkably improved under the condition that the pH is 8-11. The combined reagent system has the advantages of being high in flotation efficiency, high in selectivity, low in reagent cost, environmentally friendly, high in industrial applicability and the like.

The application provides a glass structure and an electronic device. The glass structure comprises a glass substrate and a first optical scratch-resistant layer, a second optical scratch-resistant layer and a first superhard layer which are sequentially stacked on one side of the glass substrate, the first optical scratch-resistant layer is formed by alternately stacking two layers of materials with different refractive indexes, the second optical scratch-resistant layer is formed by stacking three layers of materials with different refractive indexes, and the first superhard layer is a diamond-like layer doped with at least one element selected from silicon, aluminum, titanium, zirconium, molybdenum and nitrogen. The glass structure has good scratch resistance and optical properties which change little compared with the glass substrate, and can better meet the long-term use requirements of the electronic device shell.

A beneficiation method for improving a grade of a magnesium-containing copper sulfide ore concentrate includes: crushing and grinding an ore to a fineness degree allowing 55% to 65% of particles to pass through a 0.074 mm sieve, adding an adjusting agent lime, collecting agents butylxanthate and kerosene, and a foaming agent methyl isobutyl carbinol (MIBC) to obtain a copper-molybdenum-sulfur mixed concentrate; re-grinding the copper-molybdenum-sulfur mixed concentrate to a fineness degree allowing 75% to 82% of particles to pass through a 0.048 mm sieve, adding lime, a magnesium-containing silicate inhibitor, a collecting agent 1, and MIBC to obtain a copper-molybdenum mixed concentrate; and adding sodium sulfide, kerosene, and MIBC to the copper-molybdenum mixed concentrate to obtain a high-grade copper concentrate. The beneficiation method adopts mixed flotation of copper-molybdenum, regrinding for separating copper and molybdenum from sulfur, and magnesium removal from a copper concentrate to allow quality improvement for the copper concentrate.

Acrolein is produced by selectively oxidizing allyl alcohol over a first mixed metal oxide catalyst in the presence of oxygen in the vapor phase. The first mixed metal oxide catalyst comprises oxides of molybdenum and bismuth. Acrylic acid is produced by selectively oxidizing the acrolein over a second mixed metal oxide catalyst in the presence of oxygen in the vapor phase. The second mixed metal oxide catalyst has a different composition from the first mixed metal oxide catalyst.

The invention relates to a preparation method of bainite steel with high toughness and strength at low temperature, and the strength and toughness of the bainite steel at low temperature are improved by designing process parameters and steel ingot components. The bainite steel with high toughness and strength at low temperature is finally obtained by designing the components of the steel ingot, avoiding the addition of elements such as nickel, molybdenum and vanadium, reducing the material cost and the processing difficulty and accurately controlling the cooling rate of heat treatment. The prepared bainite steel is composed of strip-shaped bainite and thin strip-shaped retained austenite, and the volume fraction of the retained austenite is 5-10%. The tensile strength is not lower than 1240 MPa, the normal-temperature impact is not lower than 120 J, and the impact toughness at-40 DEG C is not lower than 80 J.

Provided herein are low resistance metallization stack structures for 3D-NAND applications and related methods of fabrication. In some embodiments, thin metal oxynitride nucleation layers are deposited on dielectric material followed by deposition of a pure metal conductor using process conditions that increase non-molybdenum component element content at the oxynitride-dielectric interface. Certain embodiments of the methods described below convert less than all of the metal oxynitride nucleation layer to a pure metal layer, further lowering the resistivity.

The invention discloses a method for preparing a NaFeO2 material and leaching copper, zinc and molybdenum from copper slag, and relates to the technical field of metallurgical solid waste resource utilization. The method comprises the following steps: grinding the copper slag, mixing the ground copper slag with a sodium salt, roasting the mixture in a muffle furnace at a proper temperature, and finally carrying out ultrasonic washing and filtering on the roasted product to obtain filter residues and filtrate; and drying filter residues to obtain a high-purity NaFeO2 material, and recovering valuable metals such as copper, zinc and molybdenum from filtrate. In the washing process, valuable metal elements copper, zinc and molybdenum in the copper slag are efficiently leached into the solution, the leaching rate reaches 96% or above, and synchronous recovery of the valuable elements is achieved; according to the method, the industrial waste residue copper slag is successfully converted into the NaFeO2 product with the high additional value, meanwhile, valuable metal is efficiently extracted, the method has the advantages of being simple in process, low in cost, high in recycling degree and environmentally friendly, a new way is opened up for high-value utilization of the copper slag, and the method has good industrial application prospects.

The invention belongs to the technical field of new energy materials and bioelectrochemistry, and particularly relates to an iron-based multi-metal sulfide composite carbon anode material and a preparation method of the iron-based multi-metal sulfide composite carbon anode material. The preparation method is simple in process flow, convenient to operate, easy for large-scale production, wide in raw material source, low in cost and environment-friendly, and can be used for preparing the three-dimensional porous carbon matrix which is formed by foaming and carbonizing polyvinylpyrrolidone and is provided with interconnected carbon nanosheets. Through reasonable composition design and structural regulation, and optimization of metal ratio and vulcanization conditions, accurate regulation of material performance can be realized, electrochemical performance and biocompatibility are significantly improved, electricity generation performance and operation stability of a microbial fuel cell are improved, and good industrial application prospects are achieved.

Metal carbide films and related devices and related methods are provided herein. A device comprises a substrate and a metal carbide film located on the substrate. The metal carbide film comprises at least one of a molybdenum, a tungsten, or any combination thereof. The metal carbide film comprises a residual chlorine component. The metal carbide film has a carbon content of at least 10% based on a total composition of the metal carbide film.

The invention discloses a powder metallurgy brake shoe for a locomotive and a preparation method, and relates to the technical field of metallurgy brake shoes, the powder metallurgy brake shoe comprises the following raw materials by mass percentage: 50%-70% of a matrix component, 10%-18% of a reinforcing component, 10%-16% of a lubricating component and 10%-16% of a friction component; the matrix component comprises electrolytic copper powder; the reinforcing components comprise reduced iron powder, superfine iron powder, atomized nickel powder, molybdenum powder and zinc powder; the lubricating component comprises artificial graphite and sulfide. According to the invention, the performance reduction of the brake shoe and the decline of a matrix at high temperature are effectively inhibited, the stability of a friction coefficient is kept, the abrasion is reduced, and the service life is prolonged.

The invention belongs to the technical field of rhenium alloy materials, and particularly relates to a high-strength rhenium alloy material and a preparation method thereof. The rhenium alloy material is prepared from the following raw materials in percentage by mass: 12 to 24 weight percent of molybdenum, 6 to 9 weight percent of niobium, 2 to 5 weight percent of cobalt, 1 to 3 weight percent of tungsten, 0.5 to 1.2 weight percent of modified tantalum carbide, 3 to 6 weight percent of high-entropy rare earth and the balance of rhenium and other inevitable impurities. The modified tantalum carbide is prepared by the following preparation process: adding tantalum chloride, zirconium oxychloride and phenolic resin into a mixed solution of acetylacetone and n-butyl alcohol, stirring for 1-2 hours under a heating condition, dropwise adding ammonia water, continuously stirring for 0.5-1 hour, and drying to obtain a precursor; calcining the precursor, and cooling to obtain the modified tantalum carbide. The rhenium alloy prepared through the method has high hardness, good bending strength and excellent high-temperature mechanical property.

The invention relates to the technical field of research and development of low-temperature bolt steel, and discloses a low-temperature impact performance control process for low-temperature bolt steel. Comprising the steps that S1, in the steelmaking refining stage, purity and uniformity control is conducted, S2, casting blank homogenization treatment is conducted, stress relief and structure regulation are conducted, S3, a heat treatment core process is conducted, structure and toughness balance regulation is conducted, and S4, online detection and dynamic feedback are conducted, and performance stability is guaranteed. By accurately controlling the element proportion of carbon (C), silicon (Si), manganese (Mn), chromium (Cr) and molybdenum (Mo) in steel and combining with an optimized heat treatment process (such as 860 DEG C oil quenching and 640-650 DEG C high-temperature tempering, and the heat preservation time is prolonged to 120 minutes or more), the V-shaped notch impact energy of the material in the environment of-101 DEG C stably reaches 35 J or more, the impact energy of part of samples can reach 50 J or more, and the impact energy of the part of samples can reach 50 J or more. The problem that the low-temperature impact performance is insufficient after wire hardening and tempering is thoroughly solved, and it is ensured that the brittle failure resistance of the bolt is remarkably improved in the ultralow-temperature environment.

The invention discloses a high-calcium suspension fertilizer as well as a preparation method and application thereof, and relates to the technical field of chemical fertilizer production, the high-calcium suspension fertilizer comprises the following components in parts by weight: 20-30 parts of a macroelement fertilizer, 10-15 parts of a medium element fertilizer, 3-5 parts of a microelement fertilizer, 0.5-3 parts of an auxiliary agent and 30-50 parts of deionized water; the macroelement fertilizer is prepared from 30-50 parts of nitrogen fertilizer, 20-30 parts of phosphate fertilizer and 15-20 parts of potash fertilizer; the medium element fertilizer is modified nano calcium carbonate and magnesium carbonate; the trace element fertilizer is prepared from zinc amino acid, sodium tetraborate, ferric sodium ethylenediaminetetraacetate, molybdenum sodium ethylenediaminetetraacetate, manganese sulfate monohydrate and copper sulfate pentahydrate. Therefore, the nano calcium carbonate can be quickly absorbed by the plants, so that calcium ions can be supplemented in time in the growth process of the plants, and the growth of the plants is accelerated.

A process produces high-purity vanadium chemicals from vanadium raw materials having high molybdenum contents. Molybdenum is selectively precipitated via vanadium from alkaline vanadate solutions using the following process steps: providing a molybdenum-containing alkaline vanadate solution, adding calcium hydroxide as a precipitant in portions while keeping the pH constant between 6 and 7 using acid, mixing the solution, solid-liquid separation of the resulting suspension, and further processing the low-molybdenum alkaline vanadate solution to produce a high-purity vanadium chemical having a molybdenum content of at most 500 ppm.

The invention discloses a copper-based catalyst for catalyzing partial hydrogenation of nitrocyclohexane to prepare cyclohexanone-oxime as well as a preparation method and application of the copper-based catalyst. The catalyst comprises a main active component and an auxiliary active component, the main active component is copper, the auxiliary active component is selected from one or more of titanium, vanadium, chromium, molybdenum, zirconium, cadmium, indium, tin, antimony, niobium, silver, iron, zinc, magnesium, aluminum, bismuth, manganese, lanthanum, gold or lead, the total molar ratio of the copper to the auxiliary active component is (100-1): 1, and the catalyst is prepared by adopting a coprecipitation method or a supported impregnation-coprecipitation method. And the process is simple and green. Under mild conditions, the catalyst can realize the conversion rate gt of nitrocyclohexane; the selectivity of cyclohexanone-oxime is greater than or equal to 99%, and the method is obviously superior to the existing non-noble metal system, and is low in cost, good in stability and suitable for industrial production of green synthesis of caprolactam.

The present invention provides an alumina particle containing molybdenum (Mo) and an inorganic coating part provided on the surface of the alumina particle.

This invention relates to a vermicular cast iron alloy with high mechanical strength and thermal conductivity requirements to replace the conventional gray and vermicular cast irons and introduces a manufacturing process for high mechanical strength and thermal conductivity vermicular cast iron alloy and internal combustion engine parts produced from said alloy. The alloy includes carbon, manganese, tin, copper, molybdenum, silicon, magnesium, rare earths, chromium, titanium, niobium, vanadium, tungsten, phosphorus, sulfur, aluminum, and nickel. The alloy has a graphite microstructure consisting of up to 70% of vermicular particles and up to 30% of nodular particles in area, with a matrix in area up to 80% pearlitic and up to 20% ferritic, with presence of segregating carbides of up to 1%.

Valves with a coated surface are described. A surface of the valve can include a surface coating. For example, the surface coating can include many different materials and may include a metal or metal alloy such as, for example, a molybdenum alloy or a nickel alloy or a nickel molybdenum alloy. Systems and devices including the valves are also described.

The invention relates to a multi-conductive-agent composite conductive paste for a lithium battery and a preparation method of the multi-conductive-agent composite conductive paste, and belongs to the technical field of lithium battery conductive pastes.The multi-conductive-agent composite conductive paste is characterized in that an iron-molybdenum catalyst is loaded on expanded graphite, then vertical orientation carbon nanotubes and transverse graphene blades are grown in situ, the specific surface area is increased, and the expanded graphite serves as a layered carrier; a metal alloy catalyst can be uniformly loaded in natural pores of the carbon nanotube, a layered framework is kept from collapsing at a high temperature, support is provided for directional growth of a carbon material, electrons can be rapidly transmitted along the carbon nanotube when the composite conductive paste is prepared, gaps of the carbon nanotube are filled by graphene blades, a breakpoint-free conductive network is formed, and the composite conductive paste is prepared. And meanwhile, abundant pores provide channels for lithium ion diffusion, so that the conductive efficiency is improved from the source of the structure, and abundant specific surface area and subsequent nitrogen and sulfur loading provide sufficient sites.

The invention discloses a sulfur-resistant non-noble metal catalyst for removing carbon monoxide and a preparation method thereof. The preparation method comprises the following steps: step 1, dissolving aluminum oxide, cerium-containing metal salt and a precipitator in a solvent, fully mixing, and dispersing to obtain a colloidal dispersion system; a hydrothermal product is obtained after the hydrothermal reaction, and solid powder A is obtained after the hydrothermal product is roasted; step 2, dropwise adding a copper-containing metal salt solution into the solid powder A under a ball-milling condition to obtain a turbid liquid; carrying out heat preservation roasting to obtain solid powder B; 3, roasting the molybdenum-containing metal salt, and performing thermal decomposition to obtain solid powder C; and 4, adding the solid powder C obtained in the step 3 into the turbid liquid of the solid powder B, dispersing, and roasting to obtain the required catalyst. The obtained catalyst is stable in overall structure and can still keep good catalytic performance in a sulfur-containing environment.

The invention relates to the technical field of dissimilar material connection, in particular to a method for regulating and controlling molybdenum steel brazed joint intermetallic compounds based on transition elements. According to the technical scheme, the method comprises the following steps that a transition element coating is deposited on the surface of a molybdenum matrix, transition elements are selected from one or more of Ti, V, Nb, Zr, Hf and Ta, and the molybdenum matrix and a steel matrix are brazed through boron-containing Ni-based brazing filler metal; in the brazing process, the transition element and the boron element preferentially react to generate a transition element boride, and therefore generation of MoNiBintermetallic compounds is inhibited. According to the method, the transition element coating is introduced, a brazing interface reaction path is actively intervened and reconstructed from the thermodynamic angle, and the problem of continuous generation of the brittle MoNiBintermetallic compound in the molybdenum / steel brazing joint is fundamentally solved.

The present application relates to the field of nonferrous metallurgy, and particularly relates to a method for extracting molybdenum from refractory molybdenum ore by mechanical activation. The method comprises the following steps: step S1: mechanically crushing colloidal sulfur molybdenum ore to below 2 mm; step S2: adding an activation agent and water in a predetermined ratio to the molybdenum ore particles with a particle size of 2 mm or less after crushing, and ball-milling and activating to obtain activated ore; step S3: adding a leaching solution to the activated ore according to a solid-liquid ratio, controlling the leaching temperature at 20-100 DEG C, and leaching for 1-12 hours; and step S4: after leaching, separating the solid and liquid to recover molybdenum in the leaching solution. The present application can efficiently leach molybdenum in colloidal sulfur molybdenum ore into a solution, and the process is simple, environmentally friendly, and can realize efficient utilization of refractory colloidal sulfur molybdenum ore and associated minerals.

The invention discloses a metalized diamond particle, a diamond / gallium-based liquid metal composite material and a preparation method thereof, and belongs to the field of composite thermal interface materials. The metallized diamond particle comprises a diamond particle, the surface of the diamond particle is coated with an immiscible alloy layer, the immiscible alloy layer contains a diffusion barrier component and a reaction wetting component, and the content of the diffusion barrier component in the immiscible alloy layer is not higher than 15 at% of the total content of the diffusion barrier component and the reaction wetting component; wherein the diffusion barrier component is one or more of tungsten, molybdenum and tantalum, and the reaction wetting component is one or more of silver and copper. The metallized diamond particles and the gallium-based liquid metal are combined to form the composite material, so that the diamond / gallium-based liquid metal composite material has more excellent thermal conductivity.