The invention discloses a one-stage low-temperature two-stage high-temperature high-
zinc high-iron solution
oxygen pressure kettle medium-temperature iron
precipitation separation method, which belongs to the technical field of lead-
zinc smelting, and comprises the following steps: one-stage and two-stage
oxygen pressure leaching, replacement
copper precipitation, pre-
neutralization,
indium precipitation, mineralization iron precipitation and
neutralization iron removal. According to the method, first-stage low-temperature countercurrent
oxygen pressure leaching and second-stage high-temperature countercurrent
oxygen pressure leaching are adopted, efficient leaching of various valuable metals such as
zinc,
copper and
indium is achieved, valuable elements such as silver, lead and elemental
sulfur are enriched in the second-stage
oxygen pressure leaching residues, the
sulfur content and the lead-silver
enrichment ratio in the second-stage
oxygen pressure leaching residues are increased, and the yield is increased. And the second-stage oxygen pressure leaching residues are conveyed to
sulfur flotation to produce qualified sulfur concentrate and sulfur
tailings rich in lead and silver, the sulfur concentrate is conveyed to a sulfur melting
system to produce sulfur, and the sulfur
tailings are conveyed to a
lead system to be subjected to pyrogenic treatment. According to the method, the
copper slag, the pre-
neutralization slag and the
indium precipitation
slag can be respectively produced;
hematite is produced after indium precipitation liquid is treated, zinc and iron are efficiently separated, and the slag amount is reduced; and treating the mineralized iron-precipitated solution to generate a neutralized iron-removed solution, and purifying and electrodepositing the neutralized iron-removed solution to produce
metal zinc.