The invention discloses an
imidazole derivative molecule modified
solar cell and a preparation method thereof, and belongs to the technical field of solar cells. The
cell sequentially comprises an ITO (
Indium Tin Oxide) conductive glass layer, a
nickel oxide passivation layer, a [4-(3, 6-dimethoxy-9H-
carbazole-9-yl) butyl] phosphonic acid
hole transport layer, an ITO (
Indium Tin Oxide) conductive glass layer and a
nickel oxide passivation layer from bottom to top, the
thin film solar cell is characterized in that the
thin film solar cell comprises a substrate, a
metal Ag electrode layer, a Cs0.05 (FA0. 95MA0. 05) 0. 95Pb (I0. 95Br0. 05) 3 narrow-
band gap perovskite thin film PVSK modified by 2-(2 ', 6'-dichloroanilino)-2-imidazoline, a (6, 6)-phenyl-C61-
butyric acid methyl ester
electron transport layer, a 2, 9-dimethyl-4, 7-
biphenyl-1, 10-
phenanthroline hole
blocking layer and a
metal Ag electrode layer; according to the scheme,
perovskite defects are passivated through
imidazole derivative molecules, double-interface
passivation and
crystallization regulation are achieved, the film quality is improved, and the
crystal quality of the
perovskite film is remarkably improved; due to effective passivation of the double interfaces,
ion migration is obviously inhibited, the carrier transmission efficiency is effectively improved, and the
moisture resistance of the perovskite thin film and the device stability are improved.