The invention discloses a method for preparing electrodes of a dissymmetric super capacitor based on nickel foam. The method comprises the steps: washing the nickel foam, soaking the nickel foam into a graphene oxide aqueous solution to obtain nickel foam in which graphene oxide deposits, serving the nickel foam in which the graphene oxide deposits as precursor materials, and respectively adopting a three-electrode method for preparaing a positive electrode and a negative electrode of the dissymmetric super capacitor, wherein the positive electrode is composed of composite materials of graphene, a carbon nanometer tube and the nickel foam, and the negative electrode is composed of composite materials of graphene, manganese dioxide and the nickel foam. The invention further discloses some other methods for preparing the electrodes of the super capacitor based on the similar principle, and products which correspond to the methods. By means of the methods and the products, respective high-ratio capacitance characteristics of the composite materials are fully played, and energy density of the super capacitor is improved. In addition, usage of various combined reagents can be avoided, and accordingly large-batch industrial production is conducted in a mode of convenient control, low cost and low energy consumption.