8209 results about "Manganese" patented technology

The invention discloses a 500MPa-grade supercritical CO2 corrosion-resistant pipeline coil plate and a manufacturing method thereof, and the 500MPa-grade supercritical CO2 corrosion-resistant pipeline coil plate comprises the following chemical components: 0.05 to 0.10 percent of C, 0.6 to 0.9 percent of Si, 1.50 to 1.70 percent of Mn, less than or equal to 0.010 percent of P, less than or equal to 0.002 percent of S, 0.10 to 0.30 percent of Cr, 0.35 to 0.45 percent of Mo, 0.03 to 0.05 percent of Nb, 0.01 to 0.03 percent of Ti, 0.02 to 0.05 percent of Al, 0.20 to 0.30 percent of Co, less than or equal to 0.008 percent of N, 1.2 to 4.3 percent of Mo / Cr, 0.75 to 0.92 percent of Mo + Cr + Co, 2.8 to 3.9 percent of Si / Co and the balance of Fe and inevitable elements. The manufacturing method comprises the steps of smelting, slab continuous casting, continuous casting slab heating, rolling, cooling and coiling. In the transverse direction of the rolled plate, Rt0.5 is larger than or equal to 540 MPa, Rm is larger than or equal to 640 MPa, Rt0.5 / Rm is smaller than or equal to 0.87, A50 mm is larger than or equal to 36%,-40 DEG C impact energy KV8 is larger than or equal to 220 J, and-20 DEG C drop weight DWTT is larger than or equal to 95%; in the longitudinal direction, Rt0.5 is larger than or equal to 520 MPa, Rm is larger than or equal to 630 MPa, Rt0.5 / Rm is smaller than or equal to 0.86, and A50mm is larger than or equal to 38%; the average corrosion rate in a 14.5 MPa supercritical CO2 environment is 1t; and 0.05 mm / a. The low-carbon medium-manganese molybdenum-chromium-cobalt-containing alloy design is adopted, the low-temperature toughness of a weld joint is guaranteed, the CO2 corrosion resistance and the oxidation resistance are improved, and higher safety is achieved in pipeline engineering.

The invention discloses a non-contact magnetoelectric composite current sensor with magnetism gathering and magnetic shielding. A sensor core is composed of a magnetoelectric sensing element, a magnetofluid layer, a magnetism gathering structure and a magnetic shielding layer. The magnetoelectric sensing element is made of manganese-doped lead magnesium niobate and amorphous alloy film composite materials, the outer side of the sensing element is coated with a magnetofluid layer made of soft magnetic composite materials, the magnetism gathering structure is made of permalloy materials with high magnetic conductivity and is divided into an upper part and a lower part, the upper part accommodates the sensing element and the magnetofluid layer, and the lower part accommodates the magnetic gathering structure. And the lower part is provided with a standardized groove for placing a conductor to be tested. The outermost layer is a magnetic shielding layer composed of multiple layers of nanocrystalline alloy strips, the vertical split type design is also adopted, and it is ensured that the magnetic shielding layer is tightly matched with the magnetic gathering structure through precision machining. The upper magnetic shielding layer and the lower magnetic shielding layer are detachably connected, and field installation is facilitated. The overall structure is compact, a circuit does not need to be disconnected during installation, and the device is especially suitable for on-line current monitoring requirements in the fields of smart grids, industrial automation and the like.

The invention relates to the technical field of filling materials, and particularly discloses an ardealite-based high-strength anti-seepage filling material and a preparation process thereof, the ardealite-based high-strength anti-seepage filling material comprises 50%-65% of pretreated ardealite, 15%-25% of Portland cement, 5%-15% of superfine slag powder, 5%-10% of electrolytic manganese residues, 5%-8% of silica fume, 3%-6% of metakaolin, 2%-4% of a composite alkali activator and 0.5%-1.2% of a polycarboxylic acid water reducer, 0.3%-0.8% of an organic silicon water repellent and 0.05%-0.1% of cellulose ether; according to the invention, through chemical reaction of Mn < 2 + > in the electrolytic manganese residue and SO4 < 2-> in the phosphogypsum, micron-sized manganite crystals (MnAl2 (SO4) 4. 22H2O) are generated to actively fill internal micro-cracks of the material, so that a filling body is endowed with a self-repairing function and the impermeability is improved, and a composite alkali activator composed of NaOH and water glass is used for synergistically activating potential gelling activity of the superfine slag powder and the silica fume, so that the self-repairing filling material is prepared. And the formation of hydration products is accelerated, and 0.3-0.5 T of pulsed magnetic field is applied in the stirring process, so that the manganite crystals are guided to orderly grow along the expected stress direction of the filling body, and the compressive strength is improved.

The invention relates to a Bayesian optimization-based ruthenium, tin and indium doped lithium-rich manganese-based electrocatalyst screening method, electronic equipment and a storage medium, and the method comprises the following steps: generating a uniform ruthenium, tin and indium doped lithium-rich manganese-based material data set based on Dirac distribution, and generating a doped structure through element replacement; calculating hydroxyl adsorption energy and extracting descriptors to construct a data set to train a machine learning model; performing cell expansion operation on the initial electrocatalyst structure, predicting hydroxyl adsorption energy of each adsorption site, and mapping adsorption energy deviation into current density characterization component activity in combination with Boltzmann distribution; selecting an initial component based on the obtained component activity information, and constructing an agent model by utilizing Bayesian optimization; and determining a to-be-sampled component through an expectation improvement strategy, sampling and updating the agent model, and outputting an optimal doping proportion. Compared with the prior art, the method has the advantages that the ruthenium, tin and indium doped lithium-rich manganese-based electrocatalyst with excellent catalytic performance can be efficiently screened out, and the experiment cost is reduced.

The invention relates to the technical field of high-entropy oxide and electrocatalyst synthesis, in particular to a double-phase hollow high-entropy oxide catalyst and a preparation method and application thereof, the double-phase hollow high-entropy oxide catalyst comprises metal elements and non-metal elements, the metal elements comprise ruthenium, nickel, cobalt, iron, manganese and chromium; the non-metallic element is oxygen; the chemical formula of the double-phase hollow high-entropy oxide catalyst is NiCoFeMnCrRuO. The invention further discloses a preparation method of the catalyst. The double-phase hollow high-entropy oxide catalyst has a multi-shell hollow structure, provides a larger specific surface area and exposes a large number of reaction active sites, so that the double-phase hollow high-entropy oxide catalyst has lower overpotential, higher reaction efficiency and good electrochemical stability; meanwhile, the preparation method of the double-phase hollow high-entropy oxide catalyst is simple in process, low in cost, high in repeatability and suitable for industrial mass production, and has a wide application prospect.

A double cold rolled non-oriented electrical steel sheet having a composition including: 0.0001%≤Carbon≤0.007%, 0.1%≤Manganese≤0.2%, 3.1%≤Silicon≤3.6%, 0.8%≤Aluminum≤1.1%, Phosphorus≤0.15%, Sulfur≤0.006%, Nitrogen≤0.09%, and can contain various optional elements. The remainder composition being iron and unavoidable impurities caused by processing, the microstructure is made of ferrite and has in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, is from 35% to 45% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000 A / m (J50) from 1.64 T to 1.66 T.

The invention discloses an electricity meter terminal temperature anomaly identification method, system and device and a storage medium, and relates to the technical field of intelligent electricity meter monitoring and anomaly detection.The method comprises the steps that currents of a live line loop and a zero line loop of an intelligent electricity meter are sampled, and the deviation rate of the live line current relative to the zero line current is calculated; estimating the temperature of the terminal of the electric energy meter based on the deviation rate and by using the resistance characteristic metering error change trend of the manganese-copper shunt; and when the terminal temperature estimated value of the electric energy meter exceeds a preset threshold value, determining that the temperature of the live wire terminal is abnormal, and recording an alarm event. The method realizes real-time acquisition of current difference characteristics, provides a reliable data basis for subsequent terminal temperature estimation, realizes a method of indirectly reflecting terminal temperature rise through electrical characteristics, ensures that alarm can be triggered and a complete tracing chain can be formed when temperature abnormity occurs, and improves the accuracy of terminal temperature estimation. Therefore, the controllability of the operation safety of the electric energy meter and the completeness of post analysis are improved.

The invention provides an in-situ modified lithium-rich manganese-based precursor and a preparation method and application thereof.The preparation method comprises the following steps that a nickel-cobalt-manganese mixed metal salt solution, a precipitator solution and a complexing agent solution are introduced into a base solution for a first coprecipitation reaction, and after the first coprecipitation reaction is finished, feeding is stopped; and introducing a doped nickel-cobalt-manganese mixed metal salt solution, a precipitant solution, a complexing agent solution and a carbon source solution into a system after the first coprecipitation reaction is finished, and carrying out a second coprecipitation reaction to obtain the in-situ modified lithium-rich manganese-based precursor. According to the preparation method, doping elements and a carbon source are introduced when the lithium-rich manganese-based precursor is prepared through the coprecipitation reaction, in-situ uniform construction of oxygen vacancies and a carbon coating layer on the surface of the material is synchronously achieved, the in-situ modified lithium-rich manganese-based precursor is obtained, the treatment step of subsequent secondary coating can be reduced, the production cost can be reduced, and the method is suitable for industrial production. The technological process is shortened.

A double cold rolled non-oriented electrical steel sheet having a composition including, expressed in percentage by weight: 0.0001%≤Carbon≤0.007%, 0.15%≤Manganese≤0.3%, 3.2%≤Silicon≤3.8%, 0.8%≤Aluminum≤1.1%, Phosphorus≤0.15%, Sulfur≤0.006%, Nitrogen≤0.09%, and can contain various optional elements. The remainder composition being iron and unavoidable impurities caused by processing, the microstructure is made of ferrite and has in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less than 30% when calculated in accordance of Bertotti method and simultaneously having a magnetic polarization at 5000 A / m (J50) from 1.66 T to 1.69 T.

The invention relates to a high-strength stable solid waste-based composite cementing material and a preparation method and application thereof in the field of building materials. The high-strength stable solid waste-based composite cementing material is prepared from the following raw materials in parts by weight: 70-85 parts of composite solid waste micro powder; 10 to 20 parts of Portland cement clinker; 3-8 parts of a composite activator; 0.5 to 2 parts of a nano-scale function regulator; wherein the composite solid waste micro powder is prepared by mixing and grinding the following raw materials in parts by weight: 40-60 parts of blast furnace slag powder; 20 to 30 parts of fly ash; 10-20 parts of chemically modified electrolytic manganese residue powder; and 5-15 parts of steel slag powder. According to the preparation method, sodium metasilicate is adopted to assist medium-temperature calcination to chemically modify the electrolytic manganese residues, so that not only is the gelation activity of the electrolytic manganese residues effectively excited, but also free-state manganese, cadmium and other heavy metal ions in the electrolytic manganese residues are fixed in situ in newly formed zeolite-like silicate mineral lattices through thermochemical reconstruction; and a brand new technical path is opened up for safe and high-value utilization of the typical hazardous waste, namely the electrolytic manganese residues.

The invention relates to a preparation method of a high-purity manganese target material, which belongs to the technical field of metallurgy, and comprises the following steps: firstly, drying manganese powder, then pouring the manganese powder into a graphite mold, and putting the graphite mold into a Joule hot sintering furnace for sintering, during sintering, a strategy of two-stage prepressing and four-stage gradient pressing of prepressing forming, low-pressure degassing, medium-pressure densification and high-pressure sintering is implemented, and low-temperature sintering is realized; through two-stage cooling after sintering, stress and cracking in the cooling process are avoided; by accurately controlling the temperature and time of each stage, the defects that high heating temperature and long heat preservation time are needed are overcome. The production process is integrally simplified, the internal stress is controlled to be effectively and gradually released at different temperatures, the porosity is reduced, and sintering cracking is avoided; by optimizing the sintering atmosphere of each stage, the influence of impurities such as oxygen in the air on the purity of the sintered manganese target material is avoided, and the purpose of preparing the high-purity manganese target material with low energy consumption, high efficiency and high quality is achieved.

The invention provides a manganese-silicon alloy and a production method thereof, and the production method comprises the following steps: respectively crushing a manganese-containing material, silica and coke in proportion, mixing with a dephosphorizing agent, adding a binder and a proper amount of water to prepare a premix, pressing the premix into smelted pellets, and drying; the dried smelting pellets are put into a closed electric furnace to be smelted, and alloy melt is obtained; transferring the alloy melt into a steel ladle, and blowing magnesium powder for desulfurization; the desulfurized alloy melt is subjected to slagging-off, and manganese-silicon alloy molten iron is obtained; and the manganese-silicon alloy molten iron is poured into a mold for ingot casting, and a manganese-silicon alloy finished product is obtained after cooling. According to the method, the raw materials such as the manganese material, the silica, the coke and the dephosphorizing agent are crushed respectively and then mixed, briquetted and smelted, so that the dephosphorizing and desulfurizing effects can be improved, and sulfur in the alloy can be further removed by spraying magnesium powder outside the furnace for desulfurization, so that the quality of the manganese-silicon alloy is improved.

A non-oriented electrical steel sheet having a composition including of the following elements, expressed in percentage by weight: 0.0001%≤Carbon≤0.007%,, 0.15% ≤Manganese≤0.2%, 3%≤Silicon≤3.6%, 0.7%≤Aluminum≤1.3%, Phosphorus≤0.15%, Sulfur≤0.006%, Nitrogen≤0.09%, with 3.85%≤Si+Al+Mn ≤5.5%, and can contain various optional elements, the remainder composition being composed of iron and unavoidable impurities caused by processing, the microstructure of the steel sheet being made of ferrite and including in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, of 35 to 55% when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000 A / m (J50) from 1.635T to 1.670T.

A double cold rolled non-oriented electrical steel sheet having a composition including of the following elements, expressed in percentage by weight: 0.0001%≤Carbon≤0.007%, 0.1%≤Manganese≤0.3%, 3.1%≤Silicon≤3.8%, 0.6%≤Aluminum≤0.8%, Phosphorus≤0.15%, Sulfur≤0.006%, Nitrogen≤0.09%, and can contain various optional elements. The remainder composition is iron and unavoidable impurities caused by processing. The microstructure ferrite and has in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, of 40 to 50% when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000 A / m (J50) from 1.66T to 1.7T.

A non-oriented electrical steel sheet having a composition including of the following elements, expressed in percentage by weight: 0.0001%≤Carbon≤0.007%, 0.15%≤Manganese≤0.25%, 3.2%≤Silicon≤3.8%, 0.7%≤Aluminum≤1.3%, Phosphorus≤0.15%, Sulfur≤0.006%, Nitrogen≤0.09%, and various optional elements. The remainder composition is iron and unavoidable impurities caused by processing. The microstructure is ferrite and has in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, less than 33% when calculated in accordance with Bertotti method and simultaneously having a magnetic polarization at 5000 A / m (J50) from 1.630T to 1.65T.

Disclosed herein is a catalytic comprising a hexacyano metal compound; wherein the hexacyano metal compound comprises a metal selected from the group consisting of cobalt, iron, copper, manganese, nickel, zinc, and combinations thereof; wherein the hexacyano metal compound comprises coordinatively unsaturated metal (II)—N—C centers for; and wherein the hexacyano metal compound is anchored onto an inorganic substrate. Also disclosed are a system including the catalytic material and a process for treating wastewater using the catalytic material.

The invention provides a high-stability lithium-rich manganese-based positive electrode material and a preparation method thereof, and relates to the technical field of lithium-rich manganese-based positive electrode materials, and the method comprises three steps of preparation of a homogeneous precursor, solid-state mechanical fusion doping and coating, and high-temperature sintering; a lithium-rich manganese-based precursor is prepared by adopting a homogeneous coprecipitation process, uniform distribution of metal ions is ensured, then an aluminum source, a zirconium source and a fluorine source are introduced as doping agents, phosphate and a titanate coating agent are combined, doping and coating integrated treatment is realized through mechanical ball milling, and the lithium-rich manganese-based composite material is obtained. And finally, mixing with a lithium source in an argon atmosphere, and carrying out high-temperature sintering of temperature programming and staged heat preservation to form a stable composite coating layer in situ. Therefore, manganese ion migration is effectively inhibited through lattice doping, a layered structure is prevented from being converted into spinel or rock salt phase, meanwhile, a nanoscale ion / electron transmission channel is constructed, interface impedance is reduced, and the charging and discharging efficiency under high voltage is improved.

Systems and methods described herein may include pumps and pump components including carbon-manganese-chromium (C—Mn—Cr)-based steel alloys for enhanced resistance to wear or corrosion. A pump component may include one or more components formed of a C—Mn—Cr-based ferrous alloy, which may result in enhanced wear or corrosion resistance. The C—Mn—Cr-based ferrous alloy may include a carbon content ranging from about 0.1 weight percent (wt. %) to about 2 wt. %, a manganese content ranging from about 10 wt. % to about 30 wt. %, and a chromium content ranging from about 0.1 wt. % to about 20 wt. %.

The invention belongs to the technical field of aluminum alloy production, and particularly discloses a low-carbon environment-friendly method for producing a 3104 alloy blank with a high secondary aluminum proportion, which comprises the procedures of smelting, melt purification, online degassing filtration, continuous casting and triple continuous rolling, and is characterized in that alloy components are optimized, secondary aluminum waste is used in a large proportion, the Fe content is increased, and the production cost is reduced. Iron and elements such as manganese in the aluminum alloy form intermetallic compounds, the intermetallic compounds can serve as heterogeneous nucleation, obviously refine alloy grains during casting and increase Fe content, the performance of the 3104 alloy blank is improved, meanwhile, aluminum is replaced with iron, the main material cost can be reduced, in addition, due to the fact that the rolling temperature of an inlet of each rack is high, and meanwhile the finish rolling temperature is also high, the service life of the 3104 alloy blank is prolonged. The self-tempering effect is achieved, internal dislocation of materials is eliminated, the blank edge cracking condition is improved, strip breakage caused by the edge cracking problem in the subsequent rolling process is avoided, safe production is guaranteed, the main material cost is reduced, meanwhile, the blank performance is improved, the 3104 alloy blank is efficiently produced in a high-quality mode, and the purposes of low carbon and environment protection are achieved.

A steel sheet has a chemical composition including in wt % C: 0.2-0.4%, Mn: 0.8-2.0%, Si: 0.1-0.5%, Al: 0.01-0.1%, Ti: 0.01-0.1%, B: 0.0005-0.005%, P≤0.040%, Ca≤0.01%, S≤0.006%, N≤0.01%. The steel sheet includes from the bulk to the surface of the coated steel sheet a bulk and a skin layer occupying the outermost 10% of the thickness on either side of the bulk. The bulk includes an inclusion population in which the sum of clustering indexes of MnS and TiN / Ti(C,N) inclusions is less than or equal to 300 μm / mm2. This allows to manufacture hot pressed parts having a tensile strength equal to or greater than 1300 MPa and a bending anisotropy equal to or lower than 7°.

The invention relates to the technical field of aluminum alloy materials, in particular to a high-temperature-resistant and high-strength aluminum alloy material and a preparation method thereof. The problems that an existing aluminum alloy material is insufficient in mechanical property and poor in high temperature resistance are solved. A plurality of strengthening elements with synergistic effects, including copper, magnesium, scandium, zirconium, nickel, manganese and titanium, are introduced into an aluminum alloy matrix, meanwhile, multiple layers of graphene nanosheets are added for step-by-step smelting, and under argon protection, hexachloroethane refining and lithium salt complexing agent grain refinement are performed to prepare a smelted alloy; and by combining the multi-stage refined smelting, the staged heat treatment process, the three-stage aging treatment and the surface modification process, the microstructure is optimized, and meanwhile the surface performance is improved. According to the prepared aluminum alloy material, through multi-element cooperation and multi-process optimization, the mechanical property, the high temperature resistance and the surface oxidation resistance of aluminum alloy are remarkably improved, and the aluminum alloy material is suitable for the field of aerospace.

The invention provides a modified lithium-rich manganese-based positive electrode material, a preparation method thereof and a lithium ion battery, and relates to the technical field of new energy. According to the modified lithium-rich manganese-based positive electrode material disclosed by the invention, multi-element point position doping is carried out on a base material to enhance the structural stability of a polycrystalline material, inhibit transition metal ion migration and interlayer dislocation, improve the internal lattice strength and manufacture a stable base material core; the heterostructure layer can greatly improve the surface structure phase change and transition metal dissolution of the material surface under high voltage, the stability of the surface of the matrix material is improved, and the rate capability of the material can be improved by the in-situ generated three-dimensional ion channel; the coating layer can effectively reduce side reaction of a solid-liquid interface, improve dissolution of metal ions on the surface and improve the cycle performance of the material; in a word, the internal structure and the surface of the material are effectively modified mainly through three means of doping, interface structure design and coating, the multiplying power of the material can be greatly improved, and the long-term service life of the material can be greatly prolonged.

The invention discloses ultra-thick L360 pipeline steel with excellent low-temperature toughness, which belongs to the technical field of materials and metallurgy and comprises the following components in percentage by weight: 0.050%-0.058% of C, 0.10%-0.20% of Si, 1.0%-1.1% of Mn, 0.040%-0.050% of Nb, 0.019%-0.021% of Ti, 0.18%-0.24% of Cr, 0.15%-0.20% of Ni, less than or equal to 0.015% of P, less than or equal to 0.003% of S, less than or equal to 0.004% of N, 0.118%-0.130% of Pcm and the balance of Fe and inevitable impurities. The low-carbon, low-manganese and low-Pcm alloy design is adopted, Nb and Ti are added to improve the strength, an acicular ferrite structure is obtained through the synergistic effect of Cr and Ni and a proper cooling system, and good obdurability matching is achieved.

A non-oriented electrical steel sheet having a composition including of the following elements, expressed in percentage by weight: 0.0001%≤Carbon≤0.007%, 0.21%≤Manganese≤0.7%, 3%≤Silicon≤3.6%, 0.7%≤Aluminum≤1.3%, Phosphorus≤0.15%, Sulfur≤0.006%, Nitrogen≤0.09%, with 3.85%≤Si+Al+Mn≤5.5%, and can contain various optional elements. The remainder composition being composed of iron and unavoidable impurities. The microstructure is ferrite and has in area fraction, 80% to 100% recrystallized microstructure, 0% to 20% non-recrystallized microstructure wherein the average grain size of recrystallized microstructure is from 20 microns to 110 microns and having a percentage of eddy current losses in total iron losses, measured at 1 T and 400 Hz according to IEC 60404-2 standards, from 35% to 45% and simultaneously having a magnetic polarization at 5000 A / m (J50) from 1.63T to 1.66T.

The invention discloses an acetonitrile hydrogenation catalyst and a preparation method and application thereof. The acetonitrile hydrogenation catalyst is a transition metal modified Pt supported catalyst. A transition metal precursor adopted in the transition metal improvement is an oxide containing transition metal elements; the transition metal element is selected from at least one of titanium, vanadium, manganese, iron, cobalt, nickel and copper; the acetonitrile hydrogenation catalyst also comprises a carrier; the carrier is selected from at least one of gamma-Al2O3, SiO2, an MOR molecular sieve and a ZSM-5 molecular sieve. The catalyst can effectively catalyze acetonitrile hydrogenation to prepare ethylamine under mild reaction conditions. The supported catalyst provided by the invention has excellent reaction performance such as high acetonitrile conversion rate in acetonitrile hydrogenation reaction, the reaction condition is mild, the operation is simple, and the catalyst is easy to prepare and can be recycled.

A phosphor composition includes a red phosphor material having a red decay rate and a green phosphor material having a green decay rate. The red phosphor material includes a Mn4+ doped phosphor of Formula I and a Eu3+ doped uranium phosphor, and a difference between the red decay rate and the green decay rate is no more than 7 ms, AxMFy:Mn4+ (I), wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is an absolute value of a charge of the MFy ion; and y is 5, 6 or 7. A device is also provided.

The invention belongs to the technical field of denitration catalyst preparation, and discloses a meerscham-TiO2 composite carrier loaded manganese cerium medium and low temperature denitration catalyst and a preparation method and application thereof, the preparation method comprises the following steps: (1) mixing meerschaum and nitric acid, then heating and stirring for reaction, then carrying out suction filtration and washing, and drying to obtain a meerschaum-TiO2 composite carrier loaded manganese cerium medium and low temperature denitration catalyst; after the treated sepiolite is drained, drying and screening are conducted, and nitric acid acidified sepiolite is obtained; and (2) mixing the meerschaum acidified by nitric acid and TiO2, then adding the manganese source precursor solution into the acidified meerscham-TiO2, then dipping and stirring, dropwise adding a potassium permanganate solution into the solution, then adding a cerium nitrate solution, stirring and then carrying out suction filtration, drying, grinding and screening the obtained filter cake, and then calcining to obtain the catalyst. According to the invention, the acidified sepiolite and TiO2 are compounded, so that complementary advantages of the two carrier materials are realized, and the obtained catalyst not only has good denitration efficiency, but also can significantly reduce the production cost.

The invention belongs to the field of nickel-based alloy materials, and discloses a precipitation hardening type nickel-based alloy welding wire and a preparation method thereof.The precipitation hardening type nickel-based alloy welding wire comprises, by mass, 50%-60% of nickel, 15%-20% of chromium, 15%-20% of iron, 2%-4% of molybdenum, 2%-5% of niobium, 0.01%-2% of tantalum, 0.2%-2% of aluminum, 0.5%-1.2% of titanium, 0.03%-0.08% of carbon, 0.1%-0.5% of manganese, 0.1%-0.5% of silicon, 0.01%-0.05% of magnesium, 0.01%-0.05% of yttrium, 0.5%-2% of tungsten, 0.1%-0.6% of cobalt, 0.001%-0.02% of boron and the balance impurities; according to the precipitation hardening type nickel-based alloy welding wire and the preparation method thereof, through component optimization and process innovation, the nickel-based alloy welding wire with high-temperature strength, excellent hot crack resistance and welding toughness is provided.

The invention relates to the technical field of hydrometallurgy, in particular to a method for selectively leaching and separating cobalt and manganese from crude cobalt hydroxide leaching residues. The separation method provided by the invention comprises the following steps: S1, pre-reduction treatment; and S3, cobalt is leached through selective oxidation, and manganese is precipitated. According to the separation method, the synergistic effect of ORP and pH is regulated and controlled, proper reducing agents and oxidizing agents are selected, cobalt is selectively leached through step-by-step oxidation, dissolution of manganese is inhibited, manganese circularly entering a leaching and extraction system is reduced, the leaching and extraction operation cost is reduced, meanwhile, a selective complexing agent is introduced, impurity co-dissolution is reduced, the subsequent purification process is simplified, and the method is suitable for industrial production. The preparation method is simple to operate and easy for industrial production, and has a good application prospect.

The invention discloses an iron alloy electrode paste and a preparation process, and belongs to the technical field of electrode paste preparation, the iron alloy electrode paste comprises a composite aggregate system and a composite binder system, the composite aggregate system comprises the following components by mass: 40-60% of anthracite aggregate, 15-25% of artificial graphite flake, and 3-8% of silicon carbide whisker; the composite binder system comprises the following components in percentage by mass: 70-80% of medium-temperature modified coal pitch, 10-15% of furan resin and 5-10% of dispersion liquid containing nano boron carbide, and the composite binder system is combined with the composite aggregate system through a gradient permeation process to form a three-dimensional conductive network and an enhanced interface; the composite aggregate system and the composite binder system are optimally proportioned, and gradient permeation and gradient kneading processes are combined, so that the comprehensive performance of the electrode paste is remarkably improved, the thermal shock resistance is greatly improved and the linear shrinkage rate is reduced while low resistivity is maintained, the electrode paste is suitable for smelting ferroalloys such as silicomanganese and ferrochromium, and the service life is remarkably prolonged.