240 results about "Cerium nitrate" patented technology

The invention discloses preparation of a high-uniformity cerium oxide abrasive material and application of the high-uniformity cerium oxide abrasive material in a chemical mechanical polishing solution. According to a method, cerium nitrate or cerium oxalate is used as a cerium source, a cationic or nonionic surfactant is used as a structure-directing agent, and the high-uniformity cerium oxide abrasive material is prepared in a mixed solvent system formed by water and isopropanol or water and diethylene glycol according to a specific volume ratio. The preparation method comprises the following steps: regulating the particle size and the morphology structure through a solvothermal reaction, carrying out cleaning, drying and high-temperature calcination treatment on a reaction product to obtain sphere-like cerium oxide nano-particles with high particle size concentration ratio, moderate surface roughness and good dispersity, adding cerium oxide powder into deionized water, and carrying out ultrasonic dispersion to obtain the spherical cerium oxide nano-particles. And sequentially adding a dispersing agent and amino acid while stirring, uniformly stirring, fixing the volume, and adding a pH regulator to enable the solution to be weakly acidic, thereby obtaining the chemical mechanical polishing solution. The cerium oxide submicron powder which is different in surface appearance, particle size and distribution uniformity is prepared by adjusting the solvent ratio and other reaction conditions.

The invention belongs to the technical field of denitration catalyst preparation, and discloses a meerscham-TiO2 composite carrier loaded manganese cerium medium and low temperature denitration catalyst and a preparation method and application thereof, the preparation method comprises the following steps: (1) mixing meerschaum and nitric acid, then heating and stirring for reaction, then carrying out suction filtration and washing, and drying to obtain a meerschaum-TiO2 composite carrier loaded manganese cerium medium and low temperature denitration catalyst; after the treated sepiolite is drained, drying and screening are conducted, and nitric acid acidified sepiolite is obtained; and (2) mixing the meerschaum acidified by nitric acid and TiO2, then adding the manganese source precursor solution into the acidified meerscham-TiO2, then dipping and stirring, dropwise adding a potassium permanganate solution into the solution, then adding a cerium nitrate solution, stirring and then carrying out suction filtration, drying, grinding and screening the obtained filter cake, and then calcining to obtain the catalyst. According to the invention, the acidified sepiolite and TiO2 are compounded, so that complementary advantages of the two carrier materials are realized, and the obtained catalyst not only has good denitration efficiency, but also can significantly reduce the production cost.

The invention discloses a cerium-modified manganese-based NH3-SCR (Selective Catalytic Reduction) denitration catalyst as well as a preparation method and application thereof. The catalyst is obtained by uniformly mixing and stirring manganous nitrate, cerous nitrate, polyvinylpyrrolidone, citric acid and deionized water, stirring and evaporating to a gel state, drying to form a precursor, and roasting the precursor in an air atmosphere. Ce is used for modifying MnOx, polyvinylpyrrolidone and citric acid are used as a surfactant and a complexing agent in the preparation process of the catalyst, the interaction between Ce and Mn is enhanced, the phase of the catalyst is adjusted, and under the conditions of high NOx concentration (1000 ppm) and high space velocity (GHSV = 120,000 mL h <-1 > g <-1 >), the catalyst can be used for preparing the catalyst, and the catalyst can be used for preparing the catalyst. The catalyst has excellent low-temperature catalytic activity, a wide working temperature window and good reaction stability, and has good water resistance and sulfur dioxide poisoning resistance.

The invention discloses a high-sulfur-tolerance SCR honeycomb denitration catalyst and a preparation method thereof, and belongs to the technical field of industrial catalysts.The preparation method comprises the steps that S1, anatase type TiO2 and NH4HCO3 are mixed for pulping, pre-drying and calcination are conducted after extrusion forming, and a green body is formed; s2, carrying out nitric acid treatment on the green body, dipping the green body in a mixed solution of copper nitrate hydrate and cerium nitrate hydrate, and carrying out vacuum dipping, microwave drying and two-stage calcination to obtain a desulfurization carrier; s3, depositing an ammonium metatungstate precursor on the surface of the desulfurization carrier through CVD, and calcining to form a WO3 transition layer; and S4, dipping the transition layer in an acid solution containing NH4VO3 and ammonium metatungstate, and calcining after ultrasonic treatment to obtain a finished product. According to the method, the pore structure of the carrier is optimized through chambering treatment, and the stability and denitration efficiency of the catalyst in high-sulfur flue gas are remarkably improved by combining a multistage sulfur-resistant mechanism that the desulfurization layer preferentially captures SO2, the WO3 transition layer obstructs sulfur penetration and the denitration layer is protected by active sites.

The invention discloses a method for preparing a carbon monoxide normal-temperature oxidation catalyst based on electrolytic manganese residues and landfill leachate. The method comprises the following steps: soaking and purifying the electrolytic manganese residues with deionized water to obtain preliminarily purified electrolytic manganese residues; mixing aryl alcohol dehydrogenase, the preliminarily purified electrolytic manganese residues and the landfill leachate, and standing to obtain enzymolysis electrolytic manganese residue slurry; mixing fly ash, red mud and the enzymolysis electrolytic manganese slag slurry, uniformly stirring, drying and grinding to obtain a multi-component composite raw material; placing the multi-component composite raw material in low-temperature plasma equipment for irradiation to obtain a plasma activated composite material; and carrying out hydrothermal reaction on the plasma activated composite material to obtain a hydrothermal structure composite material, dipping the hydrothermal structure composite material in a solution containing cerium nitrate, drying, and roasting to obtain the carbon monoxide normal-temperature oxidation catalyst. The carbon monoxide normal-temperature oxidation catalyst with high activity and high moisture resistance is prepared by utilizing industrial wastes and landfill leachate enzymolysis derivative liquid.

The invention discloses a high-temperature-resistant and salt-resistant fracturing fluid and a preparation method thereof, and relates to the technical field of oil field fracturing fluids. When the high-temperature-resistant and salt-resistant fracturing fluid is prepared, sodium 3-chloro-2-hydroxypropane sulfonate, N, N-dimethylacrylamide and ethylene glycol react to prepare a quaternized solid product, and then the quaternized solid product reacts with 1-bromooctadecane to prepare an amphoteric hydrophobic monomer; guar gum powder reacts with 3-(1-naphthyloxy)-1, 2-epoxypropane to prepare naphthyloxy functionalized guar gum, and then the naphthyloxy functionalized guar gum, acrylamide and an amphoteric hydrophobic monomer are subjected to initiated polymerization through ceric ammonium nitrate to prepare modified guar gum; enabling zirconium oxychloride octahydrate, titanium chloride, lactic acid, ethanediamine and glycerol to react to prepare an organic zirconium cross-linking agent; and finally, mixing the modified guar gum, an organic zirconium cross-linking agent, sodium thiosulfate, sodium bromate, a surfactant and water to prepare the high-temperature-resistant and salt-resistant fracturing fluid. The high-temperature-resistant and salt-resistant fracturing fluid prepared by the invention has excellent high-temperature resistance and salt resistance.

The invention provides an anti-ionizing radiation fiber with high filling amount, high strength and high elasticity and a preparation method and application thereof, and belongs to the field of functional fiber materials.The preparation method comprises the steps that rare earth nitrate and citric acid are dissolved in an acidic alcohol aqueous solution, heated and stirred, the pH value is adjusted, sol is obtained, the sol is subjected to secondary heating treatment to obtain gel, and the gel is dried to obtain the high-filling-amount high-strength high-elasticity anti-ionizing radiation fiber. Aging, drying, grinding and calcining the gel to obtain rare earth composite powder; wherein the rare earth nitrate is a mixture of gadolinium nitrate, dysprosium nitrate and cerium nitrate; adding polyurethane into a mixed solution of DMF and xylene, stirring, adding the rare earth composite powder, stirring, and defoaming to obtain a spinning solution; preparing nascent fibers from the spinning solution through wet spinning; and drawing, washing and drying to obtain the anti-ionizing radiation fiber. The anti-ionizing radiation fiber prepared by the invention has excellent shielding property, mechanical property and air permeability.

The invention relates to the technical field of anti-corrosion treatment, and provides anti-corrosion molding powder and a radiator anti-corrosion treatment technology.The anti-corrosion molding powder is prepared by taking polyethylene glycol terephthalate as a matrix and cooperating with a TGIC curing agent, phosphoric acid activated bamboo charcoal nanofibers, graphene modified zinc oxide, a lanthanum nitrate and cerous nitrate compound, a silane coupling agent and a functional additive; a composite resin system with a compact nano-structure is prepared through high-speed ball milling pre-activation and a twin-screw gradient extrusion process. The treatment process of the radiator comprises the steps of forming the ceramic substrate layer through micro-arc oxidation, performing dynamic temperature control impregnation with acrylic acid water-based paint, spraying anti-corrosion molding powder, performing microwave infrared gradient curing, and constructing a metal substrate-ceramic layer-organic coating multi-stage protection system. The permeability resistance of the coating is remarkably improved, a continuous and compact composite protection structure is formed, the problems of interface stripping, medium permeation and poor environmental adaptability of a traditional coating are solved, and the coating is suitable for the long-acting anti-corrosion requirement of the radiator under the high-corrosion working condition.

The invention relates to the technical field of nano titanium oxide preparation processes, and discloses a nano titanium oxide preparation method which comprises the following steps: dissolving cerium nitrate in deionized water to obtain a solution A; dissolving tetrabutyl titanate in absolute ethyl alcohol, adding the solution A, and uniformly stirring to obtain a solution B; dissolving glycerol and hydroxybenzophenone in deionized water, and uniformly stirring to obtain a solution C; slowly dropwise adding the solution B into the solution C, adding citric acid at the same time, and violently stirring to form a mixed solution; adjusting the pH value of the mixed solution to 9.0-10.0 to form a suspension; and carrying out reaction on the suspension at 160-200 DEG C for 6-10 hours. According to the nano titanium oxide prepared by the preparation method disclosed by the invention, the skin feeling of the nano titanium oxide can be remarkably improved, the problems of dryness, thickness, whitening and the like are reduced, and the use satisfaction of consumers is improved.

The invention relates to the technical field of water treatment, in particular to a rare earth composite antibacterial scale inhibitor and a preparation method thereof.The preparation method comprises the steps that glycidyl methacrylate, vinylphosphonic acid, N-vinylthiourea and acrylic acid are mixed, a mixed solvent of deionized water and ethyl alcohol is added, nitrogen is introduced after the mixture is stirred and dissolved, azodiisobutyronitrile is added, the mixture is stirred at the constant temperature for a reaction, and the rare earth composite antibacterial scale inhibitor is obtained; the preparation method comprises the following steps: preparing a quadripolymer solution, adding trimethylamine hydrochloride into the quadripolymer solution, carrying out heating and stirring reaction, adjusting the pH value to be neutral to obtain a cationized copolymer solution, dropwise adding the cationized copolymer solution into a cerous nitrate solution, carrying out stirring reaction at room temperature, carrying out centrifugal washing, and carrying out freeze drying to obtain the rare earth composite antibacterial scale inhibitor. The prepared antibacterial scale inhibitor is remarkable in effect, metal ions can be combined in scale inhibition, growth of scale crystals is prevented, the rare earth ions and the copolymer are synergistically antibacterial, and the antibacterial scale inhibitor is durable, stable, good in dispersity and capable of adapting to complex environments.

The invention provides an aluminum-doped NiCoCe catalyst, a preparation method thereof and application of the aluminum-doped NiCoCe catalyst in low-temperature CO2 hydrogenation methane preparation reaction, the preparation method comprises the following steps: (1) dissolving nickel nitrate, cobalt nitrate, cerium nitrate, aluminum nitrate and an alkaline precipitator in deionized water, and fully stirring the solution at room temperature to obtain a solution A; (2) putting the solution A into a reaction kettle, and crystallizing the mother liquid at a constant temperature for a certain time to obtain a solid-liquid mixture B; (3) centrifuging and washing the solid-liquid mixture B in the step (2) to obtain a precipitate C; (4) drying the precipitate C in the step (3) to obtain a precursor D; and (5) reducing and passivating the precursor D in the step (4) to obtain the catalyst. The catalyst prepared by the invention effectively solves the problem of low CO2 conversion rate in low-temperature CO2 methanation reaction, lattice distortion is promoted by introducing the Al element, the migration ability of lattice oxygen is increased, and the formation of a large number of oxygen vacancies is beneficial to improving the oxidation-reduction property of the catalyst.

The invention discloses a plant-based deodorant and a preparation method thereof, and relates to the technical field of high polymer materials. When the plant-based deodorant is prepared, beta-cyclodextrin reacts with paratoluensulfonyl chloride and then reacts with ethylenediamine, and amino modified cyclodextrin is prepared; the plant-based extract is subjected to inclusion with amino modified cyclodextrin, and a cyclodextrin inclusion compound is prepared; the preparation method comprises the following steps: reacting hydroxyethyl cellulose with methacrylic anhydride to prepare double-bond modified cellulose; carrying out hydrothermal reaction on titanium sulfate, the carboxylated multi-walled carbon nanotube, ammonium fluoride and cerous nitrate to prepare a co-doped titanium dioxide / carbon nanotube; coating the co-doped titanium dioxide / carbon nano-tubes with oleic acid to prepare modified nano-particles; and reacting the double-bond modified cellulose with the cyclodextrin inclusion compound, and then copolymerizing with the modified nanoparticles and the comonomer to obtain the plant-based deodorant. The prepared plant-based deodorant has the advantages of good deodorization effect, slow release and photocatalytic degradation.

The invention provides a synergistic flame retardant-reinforced integrated antimony trioxide substitute flame retardant and a preparation method thereof, and belongs to the technical field of flame retardants. The preparation method comprises the steps of preparing a nickel-iron compound, preparing functional composite powder and mixing. The step of preparing the nickel-iron compound comprises the following steps: heating deionized water to 60-65 DEG C, adding nickel nitrate and ferric nitrate, uniformly stirring, adding a cerium nitrate solution and citric acid, stirring for 30-35 minutes, adding ethylene glycol and a kH560 coupling agent solution, stirring for 1.5-2.0 hours, standing, aging, drying, keeping the temperature at 320-350 DEG C for 1.0-1.2 hours, and keeping the temperature at 620-630 DEG C for 3.5-4.0 hours to obtain the nickel-iron compound; the antimony trioxide substituted flame retardant disclosed by the invention can completely and equivalently replace antimony trioxide in the field, and is high in flame retardant property, mechanical property and stability.

This invention discloses a plant-mediated green synthesis method for silver-cerium oxide-attapulgite multifunctional composite nanoenzymes. The method involves mixing cerium nitrate and silver nitrate with an attapulgite suspension, adding honeysuckle extract, adjusting the pH, heating the reaction mixture, centrifuging, washing, drying, and then calcining under a nitrogen atmosphere to obtain the silver-cerium oxide-attapulgite multifunctional composite nanoenzyme. Cerium ions form a complex with the active ingredients in the honeysuckle extract and bind to attapulgite via hydrogen bonds. Calcination yields cerium oxide nanoparticles, while silver ions are reduced by the honeysuckle extract to obtain silver nanoparticles. This invention features a green and environmentally friendly preparation process, simple operation, and easy scale-up. The resulting nanocomposite material exhibits pH-responsive antibacterial and antioxidant multienzyme activity and can be used as an anti-drug-resistant nanomaterial in biomedicine and other fields.

The invention discloses a preparation method of an iron-doped cerium-based perovskite type high-selectivity Cu ion capture stabilizing agent and application of the stabilizing agent in heavy metal pollution remediation, and the stabilizing agent is prepared through a sol-gel method and comprises the steps that cerous nitrate and citric acid are dissolved in water, and the mixture is heated and stirred to be gel-shaped; standing the gel solution in a drying oven at a constant temperature to obtain a Fe-Ce-PVSK precursor; grinding the precursor into powder, putting the powder into a quartz boat, and calcining in an air atmosphere through a horizontal tube furnace to obtain a product; and finally, washing to be neutral to obtain the iron-doped cerium-based perovskite stabilizing agent. Due to the high oxygen vacancy concentration and rich active sites, the stabilizing agent has high selectivity and high adsorption capacity and has specific capturing capacity on Cu < 2 + >. The preparation method has mild reaction conditions. The stabilizing agent can effectively reduce the bio-availability of heavy metals in a polluted matrix, promote healthy growth of plants, and realize pollution restoration and ecological function recovery at the same time.

The invention relates to the technical field of high-performance polyester, and discloses a modified preparation method of functionalized antibacterial polyester fibers, which comprises the following steps: S1, graphene is treated by oxygen-argon mixed plasma to obtain hydroxylated graphene; s2, after hydroxylated graphene is dispersed, cerium nitrate and sodium citrate are added, and cerium-based metallized graphene is obtained; s3, carrying out a reaction on the cerium-based metallized graphene and 3-(2-aminoethylamino) propyltrimethoxysilane, so as to obtain aminated graphene; s4, aminated graphene dicyandiamide, ammonium chloride tetraethoxysilane and hexadecyl trimethyl ammonium bromide are subjected to a reaction, and guanidyl-meso-porous silicon-metal composite graphene is obtained; s5, reacting the product with epsilon-polylysine and polycaprolactone to obtain a modified composite antibacterial agent; s6, treating the polyester fibers with a mixed solution of alkali and a surfactant; s7, the polyester fibers react with a solution containing an antibacterial agent, tetrabutyl titanate, an initiator and a dispersing agent, and a finished product is obtained.

The invention discloses an iron-carbon composite material for heavy metal contaminated soil remediation and a preparation method of the iron-carbon composite material, and belongs to the field of heavy metal contaminated soil remediation. The iron-carbon composite material comprises rape straw, hydroxyapatite, zero-valent iron, sulfydryl functionalized magnetic cerium oxide and nitrogen-doped graphene quantum dot-sodium alginate. The sulfydryl-functionalized magnetic cerium oxide is prepared from cerium nitrate and ferric nitrate through precipitation, calcination and sulfhydrylation, and the nitrogen-doped graphene quantum dot-sodium alginate is prepared from citric acid and urea through microwave reaction, dialysis, mixing and freeze drying; the preparation method comprises the following steps: treating straws and hydroxyapatite to obtain ball-milled phosphorus-containing biochar, mixing the ball-milled phosphorus-containing biochar with zero-valent iron and two modifiers, and carrying out molding and high-temperature calcination to obtain the phosphorus-containing biochar-based composite material. The material has a remarkable remediation effect on the heavy metal contaminated soil, can effectively reduce the activity of heavy metals in the soil, has the characteristics of environmental friendliness and high stability, and is suitable for treating the soil compositely contaminated by the heavy metals such as cadmium and lead.

The invention discloses a preparation method of a pH response type core-shell structure cerium oxide abrasive, a chemical mechanical polishing solution and a chemical mechanical polishing process, and belongs to the technical field of chemical mechanical polishing process.The method comprises the following steps that S1, a cerous nitrate aqueous solution and a precipitator are mixed, and cerium oxide (CeO2) nanoparticles are prepared through a hydrothermal reaction; s4, polyacrylic acid-block-polyethylene glycol and the CeO2 (at) mSiO2-NH2 are subjected to a reaction, the reaction product is grafted to the surfaces of the particles through amido bonds, and CeO2 (at) mSiO2 (at) PAA-b-PEG is obtained; and S5, dispersing the obtained CeO2 (at) mSiO2 (at) PAA-b-PEG in a trivalent cerium salt solution, and enabling Ce < 3 + > to be loaded on a PAA chain through ion exchange, so as to obtain CeO2 (at) mSiO2 (at) PAA-b-PEG < 3 + >. The chemical mechanical polishing solution can achieve high removal in the sensing stage, the polishing early stage and the polishing middle stage and high protection in the polishing later stage.

This invention belongs to the field of catalyst technology, providing a CO purification oxygen-rich catalyst, its preparation method, and its application. The preparation method involves dispersing γ-alumina in water, then sequentially adding copper nitrate and cerium nitrate to obtain a reaction solution. The reaction solution is mixed with an inorganic base, followed by a substitution reaction and a crystallization reaction to obtain a catalyst precursor. The catalyst precursor is calcined under a reducing atmosphere to obtain the CO purification oxygen-rich catalyst; the reducing atmosphere includes hydrogen. This preparation method generates sufficient active sites through a copper-cerium binary system, and then utilizes the basic groups provided by the inorganic base to form a low-valence metal-hydroxyl composite structure under a reducing atmosphere. Through the combined action of metal atoms, hydroxyl groups, and active oxygen sites, the research goals of high efficiency, stability, high selectivity, and economy are achieved. Furthermore, this preparation method does not use precious metals, resulting in low cost.

The invention discloses preparation of a nickel and cerium doped cobalt-based catalyst and application of the nickel and cerium doped cobalt-based catalyst in catalytic decomposition of nitrous oxide. The nickel and cerium doped cobalt-based catalyst is of a Ni and Ce co-doped spinel type Co3O4 structure and has a mesoporous structure, and the molar ratio of cobalt to nickel to cerium is 1: 0.12: 0.04. The preparation method comprises the following steps: preparing a mixed solution in which the molar ratio of cobalt nitrate to nickel nitrate to cerium nitrate is 1: 0.12: 0.04 by adopting a coprecipitation method, adding sodium carbonate as a coprecipitator into the mixed solution, adjusting the pH value of the mixed solution to 9 while stirring, carrying out coprecipitation and aging, then washing and drying the precipitate, and roasting for 3 hours in an air atmosphere at 300-400 DEG C to obtain the nickel and cerium doped cobalt-based catalyst. The catalyst provided by the invention has good low-temperature nitrous oxide decomposition capability and anti-interference capability under complex working conditions.

The application relates to the technical field of magnetic materials, in particular to a preparation method of high-performance heavy-rare-earth-free neodymium iron boron magnets; the preparation method comprises the following steps: rapidly quenching a main phase alloy into a flake, obtaining coarse powder after hydrogen breaking; immersing the coarse powder in an ethanol mixed solution containing lanthanum nitrate and cerium nitrate, drying the pretreated coarse powder after ultrasonic-magnetic stirring cooperative treatment; adding an antioxidant and a lubricant into the pretreated coarse powder, preparing fine powder with an average particle size of 2-3.5 microns through airflow milling; performing magnetic field orientation compression molding on the fine powder under nitrogen protection, improving the density through cold isostatic pressing; finally, performing vacuum sintering and step-by-step tempering treatment to obtain the high-performance heavy-rare-earth-free neodymium iron boron magnets; wherein the main phase alloy is composed of the following components with mass percentage: 28-31wt.% Pr25Nd75, 0.88-1.2wt.% B, 0-0.1wt.% Al, 0.05-0.3wt.% Ti, 0.05-0.4wt.% Cu, 0.5-1.4wt.% Co, 0.1-0.4wt.% Ga, and the balance is Fe; the prepared neodymium iron boron magnet has the dual characteristics of high coercivity and high remanence, and effectively guarantees the performance and quality.

The invention relates to the technical field of ultraviolet shielding materials, in particular to a preparation method of an attapulgite-loaded cerium metal polyphenol network composite material and ultraviolet shielding application of the attapulgite-loaded cerium metal polyphenol network composite material. The preparation method comprises the following steps: mixing attapulgite with deionized water, and performing ultrasonic dispersion; mixing tea polyphenol and cerous nitrate, adding the mixture into the obtained attapulgite suspension, adding a sodium hydroxide solution, putting the mixture into an ultrasonic kettle, and carrying out ultrasonic treatment; and centrifuging and freeze-drying to obtain the attapulgite loaded cerium metal polyphenol network nano composite material. The attapulgite loaded cerium metal polyphenol network composite material obtained by the invention has a relatively high specific surface area after ultrasonic treatment, the cerium metal polyphenol network is uniformly distributed on the surface of the attapulgite in the form of nanoparticles, and the self-agglomeration phenomenon of the attapulgite is improved by the steric hindrance effect of the cerium metal polyphenol network; and the whole material shows good ultraviolet shielding performance.

The invention discloses a spinnable CeO2-ZrO2 sol and a preparation method of CeO2-ZrO2 ceramic fibers. The preparation method of the spinnable CeO2-ZrO2 sol comprises the following steps: preparing zirconium polyacetylacetonate; preparing a first mixed solution from a zirconium polyacetylacetonate solution and cerium nitrate; adding a pore-forming agent and a seed crystal into the first mixed solution to prepare a second mixed solution; the second mixed solution is concentrated and aged, and a spinnable CeO2-ZrO2 sol is obtained; the solid content of the CeO2-ZrO2 sol with the spinnability is 30 to 50 percent; the mass fraction of the CeO2 is 8.6 to 36.8 percent, and the mass fraction of the ZrO2 is 3.1 to 26.3 percent; the cerium catalyst is high in catalytic efficiency, is fibrous and can be recycled, treated and repeatedly used after being used.

The invention provides a tantalum capacitor dielectric layer gradient oxidation preparation method and an oxidation film and an anode block thereof, and the method employs a multi-stage gradient boost rate to carry out electrochemical oxidation on a tantalum anode, and controls the boost rate and the oxidation voltage at different stages. And the oxide film forms a grain size gradient structure from the compact layer at the bottom to the nanocrystalline layer at the top, and the film thickness is 400-900 nm. Meanwhile, an electrolyte formula is optimized, ammonium dihydrogen phosphate and cerous nitrate are added into a phosphoric acid solution, the compactness of the film is improved, and oxygen vacancies are inhibited; ozone bubbling treatment is introduced in the constant-pressure stage, and the defect concentration is further reduced. The prepared dielectric layer has high breakdown voltage, low leakage current and high specific capacitance performance, the reliability of the tantalum capacitor is remarkably improved, the service life of the tantalum capacitor is remarkably prolonged, and the dielectric layer is suitable for high-reliability electronic equipment.

The application provides a variable-price rare earth element doped black titanium dioxide catalyst and a preparation method and application thereof, and belongs to the technical field of environmental functional materials and water pollution treatment. The catalyst is prepared by a sol-gel method combined with calcination in a hydrogen-argon mixed atmosphere, with tetrabutyl titanate as a titanium source and lanthanum nitrate and cerium nitrate as rare earth doping sources. Lanthanum / cerium doping can effectively inhibit the generation of rutile phase in the black titanium dioxide, increase the specific surface area, narrow the band gap and construct oxygen vacancy defects, and significantly improve the photocatalytic activity. The preparation process is simple, the cost is controllable, the catalyst has a remarkable selective degradation effect on specific dyes, and an efficient solution is provided for dye wastewater treatment.

The application relates to a CuO-ZnO-ZrO2@CeO2 core-shell catalyst and a preparation method and application thereof in preparing methanol. The preparation method is as follows: copper nitrate and zinc nitrate are dissolved in deionized water to form a mixed solution, a precipitant is added, and hydrothermal reaction is carried out to obtain copper-zinc nanoscale dispersed particles; then the particles are dispersed in deionized water, a zirconium nitrate aqueous solution is added, and hydrothermal reaction is carried out to precipitate zirconium on the outer layer of the particles; then a cerium nitrate aqueous solution and a precipitant are added to the system, and hydrothermal reaction is carried out; after the reaction, the system is subjected to filtration, washing, drying, grinding and calcination to obtain the CuO-ZnO-ZrO2@CeO2 core-shell catalyst. In the application process, CO2 and H2 are used as raw materials, cyclohexanol is used as a solvent, hydrogenation reaction is carried out under the action of the core-shell catalyst at 190-210 DEG C, and methanol is prepared. The core-shell catalyst can be applied to hydrogen transfer hydrogenation for preparing methanol, and can exhibit excellent catalytic activity and stability and higher methanol selectivity.

This invention discloses a nickel or nickel oxide-supported cerium dioxide-doped lithium aluminum hydride hydrogen storage material, prepared by mechanical ball milling of a supported sample and lithium aluminum hydride. The supported sample is obtained by calcining a precipitate formed by mixing nickel nitrate as the nickel source and cerium nitrate as the cerium source with sodium hydroxide solution in a certain weight ratio and heating. The supported sample is either nickel-supported cerium dioxide or nickel oxide-supported cerium dioxide, named Ni@CeO2 and NiO@CeO2, respectively. The preparation method includes: step 1) preparation of nickel or nickel oxide-supported cerium dioxide; step 2) preparation of the nickel or nickel oxide-supported cerium dioxide-doped lithium aluminum hydride hydrogen storage material. For application in the field of hydrogen storage, the final system's hydrogen release temperature is reduced to 63.9 to 93.5℃, the hydrogen release amount reaches 6.7 to 7.1 wt%, and the hydrogen release rate is 88.94 to 96.03%. This invention achieves improved hydrogen storage material performance at lower temperatures.

The present application relates to the technical field of waste gas purification treatment, in particular to a kind of thermal induction self-activation volatile heavy metal control material of waste gas and its preparation method and application, the control material is composed of the microcapsule of inner core, intermediate layer and shell;Wherein the inner core is the sodium alginate-polyvinyl alcohol microcapsule containing ferrous sulfide, graphene and sodium bicarbonate, the intermediate layer is calcium sulfate isolation layer, and the shell is manganese dioxide, cerium nitrate oxide layer.The material prepared in the application can realize thermal induction self-activation reaction at high temperature, by generating elemental sulfur, iron oxide, manganese oxide and cerium oxide and other active components, simultaneously and efficiently remove volatile heavy metals such as mercury, arsenic, thallium and other volatile heavy metals in waste gas, with the advantages of multifunctional synergy, high heavy metal removal rate, good selectivity, fast response rate and the like.

The invention relates to the technical field of electrode material preparation, in particular to a supported iridium-based catalyst with a carrier surface rich in hydroxyl and a preparation method and application thereof.The preparation method comprises the steps that cerous nitrate, sodium hydroxide and water are mixed and subjected to a hydrothermal reaction, and a cerium dioxide precursor is obtained; mixing the cerium dioxide precursor, a hydrogen peroxide solution, a sulfuric acid solution and water, and reacting to obtain an intermediate of which the surface is loaded with hydroxyl; and mixing the intermediate of which the surface is loaded with hydroxyl, iridium metal salt and an alcohol solvent, and carrying out reduction reaction to obtain the supported iridium-based catalyst of which the carrier surface is rich in hydroxyl. The preparation method provided by the invention is a universal preparation method of a nanoparticle electrode material, the process is simple, the operation is convenient, the cost is low, and the prepared catalyst has good electrochemical activity and high stability, can show relatively excellent electrochemical performance in an electrolyzed water OER reaction, and is suitable for industrial production. And a new research scheme is provided for industrial application of electrolyzed water.

The invention relates to a preparation method of a novel corrosion-resistant coating for a metal material, and belongs to the technical field of metal corrosion-resistant coatings. The preparation method comprises the following steps: sequentially adding 3, 3-diamino-4, 4-dicarboxyl biphenyl and cerous nitrate into a reaction kettle with a mixed solvent, carrying out ultrasonic treatment and heating reaction, distilling to remove the mixed solvent, and cooling to room temperature to obtain a cerium-containing precursor; the preparation method comprises the following steps: adding epoxy resin and epoxy cyclohexyl-polyhedral oligomeric silsesquioxane into solvent oil, then adding a cerium-containing precursor, carrying out a heating reaction, and carrying out ultrasonic treatment; continuously adding a curing agent, and stirring to obtain the novel corrosion-resistant coating. Coating the cleaned metal hook by using a dip-coating method, and drying at room temperature; the novel corrosion-resistant coating prepared by the preparation method disclosed by the invention is good in humidity and heat resistance and excellent in corrosion resistance.