2409 results about "Cerium oxide" patented technology

The invention relates to a denitration catalyst capable of resisting alkali metal, water and sulfur composite poisoning and a preparation method and application thereof, and belongs to the field of environment-friendly catalytic materials and air pollution control. An organic solvent is used as a template agent, cerium oxide, manganese oxide and tungsten oxide are used as active components, and a cerium-manganese-tungsten composite oxide active component with a porous structure and strong acidity is prepared by a coprecipitation-soft template method. The catalyst has a wide denitration temperature window, high denitration efficiency and excellent composite poisoning resistance stability. The catalyst component is environment-friendly, low in cost and simple in preparation method, and is particularly suitable for stable and efficient purification of NOx in complex flue gas in the cement industry.

The invention relates to the technical field of smashing, and discloses a cerium oxide airflow smashing device and a production technology.The cerium oxide airflow smashing device comprises a base, four supporting legs arranged at equal angles are arranged on the base, a first tank is connected to the supporting legs, and an air injection mechanism used for spraying high-pressure airflow and driving materials to collide with one another to be smashed is installed in the first tank; a feeding pipeline positioned above the air injection mechanism is mounted on the first tank body; the inner wall of the first tank body is provided with four cooling assemblies which are arranged at equal angles, the upper port of the first tank body is connected with a second tank body through a flange, the second tank body is provided with a grading mechanism and a discharging pipeline corresponding to the grading mechanism, and the upper port of the second tank body is provided with a top cover; according to the device, efficient production is achieved through multi-dimensional innovation, a double-layer S-shaped cooling flow channel dissipates heat quickly, and high-temperature agglomeration of materials is avoided so as to guarantee stable physicochemical properties; and the four groups of opposed nozzles form a vortex field, so that the particle size refining rate of the material is more than 90%, and the energy consumption is reduced by 35%.

The invention discloses a method for preparing nano cerium oxide through supergravity reinforcement, which comprises the following steps: 1) completely dissolving cerium chloride hexahydrate serving as a cerium source with deionized water to prepare a cerium chloride solution; (2) inputting the cerium chloride solution into a supergravity reactor through a peristaltic pump at normal temperature, then inputting ammonia water into the supergravity reactor through a constant-flux pump, and carrying out premixing reaction in the supergravity reactor to form mixed slurry; and 3) after the premixing reaction is finished, taking out the mixed slurry, and carrying out suction filtration, washing, drying and high-temperature oxidation calcination to obtain the nano cerium oxide. According to the method, the production efficiency can be improved, the particle size of the prepared nano cerium oxide is small, the particle size distribution is narrowed, and the crystallinity of crystals is improved.

The invention discloses a preparation method of a non-additive nitrogen-phosphorus-cerium synergistic flame-retardant polyurethane elastomer, and the polyurethane elastomer is prepared by taking isocyanate as a hard segment and poly (1, 4-butanediol adipate) as a soft segment, and compounding the hard segment and the soft segment with 2-amino-4-hydroxy-6-methylpyrimidine, a phosphorus reactive flame retardant and cerium oxide. The preparation method is simple, the process is easy to control, and the prepared polyurethane elastomer has good tensile strength; besides, the limit oxygen index of the polyurethane elastomer reaches 27.4, the polyurethane elastomer meets commercial standards of flame-retardant materials and UL-94 V-0 flame-retardant grade requirements, the ultraviolet band light transmittance is 0%, ultraviolet rays can be completely isolated, and the polyurethane elastomer has a good anti-oxidation function and can be applied to the industries of wires, cables, pipe profiles, films, general molding and the like.

The invention belongs to the technical field of ceramics, and discloses a preparation method of fracture-resistant and wear-resistant ceramics. The preparation method comprises the following steps: weighing the raw materials in parts by weight; the preparation method comprises the following steps: mixing 40 parts of potassium feldspar, 10 to 25 parts of albite, 1 to 10 parts of kaolin, 1 to 10 parts of serpentine, 5 to 25 parts of dolomite, 2 to 9 parts of nano zirconium oxide, 0.1 to 1 part of nano cerium oxide, 0.1 to 1 part of nano molybdenum disulfide, 0.1 to 0.8 part of silicon carbide fiber, 0.5 to 2.5 parts of polyethylene glycol, 0.1 to 0.6 part of fullerene trifluoromethyl derivative, 0.1 to 3 parts of sodium dodecyl sulfate, 0.1 to 2 parts of sodium tripolyphosphate and 10 to 60 parts of solvent to obtain slurry; and carrying out spray granulation to obtain a blank, carrying out compression molding to obtain a green body, and sintering to obtain the fracture-resistant and wear-resistant ceramic. The breaking strength of the breaking-resistant and wear-resistant ceramic can exceed 70 MPa, and the length of a grinding pit does not exceed 8.5 mm.

The invention relates to the technical field of aluminum alloys, in particular to a high-fluidity corrosion-resistant aluminum alloy material for laser cladding as well as preparation and application of the high-fluidity corrosion-resistant aluminum alloy material. The material comprises the following components in percentage by mass: 3.12%-5.34% of nickel, 4.24%-6.76% of molybdenum, 6.54%-8.12% of cobalt, 10.45%-14.49% of silicon, 5.65%-8.45% of a functional additive, 1.25%-2.45% of cerium oxide, 3.46%-7.42% of yttrium oxide, 3.45%-7.58% of lanthanum oxide and the balance of aluminum, the functional additive is titanium carbide doped with Ti < 3 + >. The aluminum alloy material has high flowability during laser cladding and is well combined with a matrix, and related properties such as wear resistance, high temperature resistance, corrosion resistance and oxidation resistance of a coating formed by the aluminum alloy material are sufficiently uniform due to the high flowability of the aluminum alloy material.

The invention relates to the technical field of carbon monoxide oxidation catalysts, and discloses a sulfur-tolerant noble metal-based CO oxidation catalyst as well as a preparation method and application thereof. The preparation method of the catalyst comprises the following steps: dipping a carrier in an aqueous solution containing a noble metal precursor and an auxiliary agent precursor, and then drying and roasting to obtain a catalyst matrix; carrying out pre-reduction treatment on the catalyst matrix in a hydrogen-containing atmosphere to obtain a catalyst intermediate; carrying out induced activation on the catalyst intermediate in an atmosphere containing CO and H2S; wherein the carrier is at least one of titanium dioxide, cerium dioxide, aluminum oxide and zirconium dioxide, and the metal element in the auxiliary agent precursor is at least one of Fe, Co and Ni. The catalyst prepared by the method provided by the invention can realize the high-selectivity oxidation process of H2S species, inhibits the adsorption of S species and the formation process of sulfate, and realizes the high-conversion-rate oxidation reaction of carbon monoxide in the presence of H2S.

The invention discloses an aerogel fire extinguishing agent for fire fighting, a fire extinguishing device and a releasing method.The aerogel fire extinguishing agent for fire fighting is prepared from, by mass, 8-12 parts of silicon dioxide aerogel powder, 40-45 parts of perfluorohexanone, 1.5-2 parts of zinc molybdate, 0.8-1.2 parts of nano cerium oxide, 2-3 parts of hyperbranched polysiloxane and 0.2-0.3 part of 18-crown-6 ether. Solid-phase silicon dioxide aerogel powder is matched with liquid-phase perfluorohexanone, zinc molybdate, nano cerium oxide, hyperbranched polysiloxane, 18-crown-6 ether and the like are compounded to serve as auxiliaries, efficient fire extinguishing can be conducted on precise electrical elements, residues are few, loss of instruments and equipment is small, and the fire extinguishing agent is suitable for being applied to the electrical field.

The invention relates to the field of aluminum materials, and provides an automobile corrosion-resistant aluminum material and a preparation method thereof.The automobile corrosion-resistant aluminum material is prepared from cerium oxide loaded aluminum oxide nanorods, scandium / boron nitride nanotubes, zirconium powder, magnesium powder, copper powder, manganese powder, silicon carbide nanoparticles, TiB2 nanoparticles, aluminum powder and stearic acid. Wherein the cerium oxide loaded aluminum oxide nanorod is composed of an aluminum oxide nanorod and cerium oxide nanoparticles loaded on the surface of the aluminum oxide nanorod, and the scandium / boron nitride nanotube is composed of a boron nitride nanotube and a scandium nanolayer uniformly coated on the surface of the boron nitride nanotube. The material is prepared through mechanical ball milling, cold isostatic pressing forming, vacuum sintering and aging treatment, and finally the aluminum-based composite material containing the Al3Sc nano precipitated phase and the boron nitride nanotube reinforced phase is formed. And an Al3Sc precipitated phase and an aluminum matrix form a coherent interface, so that the strength, the corrosion resistance and the wear resistance of the material are improved. Through nanostructure optimization, high performance of the aluminum alloy is achieved, and the aluminum alloy is suitable for the fields of automobiles, aerospace and the like.

The invention discloses low-migration UV ink-jet ink and a preparation method thereof, and belongs to the technical field of novel ink. Comprising the following components in parts by mass: 10-15 parts of a dynamic cross-linked polyurethane acrylate oligomer, 5-8 parts of an epoxy silicone resin oligomer, 2-3 parts of modified silicon dioxide, 4-5 parts of a photoinitiator, 15-20 parts of sorbic acid modified color paste, 1-2 parts of nano cerium oxide and 0.5-1 part of an antioxidant. The molecular chain of the dynamic cross-linked polyurethane acrylate oligomer prepared by the invention contains an active group capable of forming a cross-linked structure and a dynamic covalent bond. The groups and bonds promote molecular chain crosslinking when the ink is cured, a three-dimensional network is formed, and the molecular crosslinking density is improved. Through interaction of palmitic acid modified silicon dioxide and oligomer, the palmitic acid modified silicon dioxide is uniformly dispersed in a matrix and interferes molecular chain movement during curing, so that the crosslinking density is further improved, an ink film layer is more compact and firmer, the wear resistance and the scratch resistance are improved, and the tinting strength and the stability are indirectly enhanced.

The invention relates to cerium oxide-based polishing powder and a preparation method thereof, a polishing solution and application, the cerium oxide-based polishing powder comprises porous secondary particles assembled by a plurality of primary crystal grains, the primary crystal grain aperture is 2-30 nm, the pore volume is 0.10-0.50 cm < 3 > / g, the specific surface area is 10-80 m < 2 > / g, and the content of surface trivalent cerium accounts for 10-40% of the total surface cerium content. The microstructure of the cerium oxide-based polishing powder is porous cerium oxide-based particles assembled by nano primary particles, and the self-assembly structure enables the cerium oxide-based polishing powder to have higher specific surface area while having higher surface trivalent cerium content, so that higher polishing rate can be obtained; due to the submicron particle size, the dispersity of the polishing slurry is improved; the Young modulus of the polishing powder is reduced due to the porous structure, so that the polishing powder is not easy to break in the polishing process, the surface precision of a polished workpiece is improved, and the service life of the polishing powder is prolonged. Therefore, the cerium oxide-based polishing powder provided by the invention has excellent polishing rate and polishing precision at the same time, and has relatively long service life.

The invention discloses a high-weather-resistance bismuth vanadate coating and a preparation method thereof, and belongs to the technical field of inorganic pigment modification. The high-weather-resistance bismuth vanadate coating comprises bismuth vanadate matrix particles, and the surfaces of the bismuth vanadate matrix particles are sequentially coated with an amorphous aluminum oxide layer, a cerium oxide layer and a fluorinated silicon oxide layer. The amorphous aluminum oxide layer is formed in an atomic layer deposition mode; the cerium oxide layer is formed by hydrothermal treatment of a cerium source. The preparation technology has accurate and controllable technological parameters, is suitable for industrial production, can replace the traditional toxic pigment containing lead and cadmium, and meets the requirements of environmental regulations. The bismuth vanadate coating has excellent weather resistance and chemical stability, the service life of a product can be prolonged, the maintenance cost is reduced, and a reliable solution is provided for development of high-performance environment-friendly pigments.

The invention discloses a synergistic compound light stabilizer for an automobile coating and a preparation method of the synergistic compound light stabilizer, and belongs to the technical field of coating additives. The light stabilizer comprises the following components in percentage by mass: 30-50% of a hindered amine light stabilizer, 20-40% of an ultraviolet light absorber, 5-15% of surface modified nano cerium dioxide, 5-10% of a hyperbranched polyester anti-migration aid and the balance of a solvent, wherein the ultraviolet light absorber is a mixture of benzotriazole and triazine in a mass ratio of (1: 1)-(1: 3); the particle size of the nano cerium dioxide is 10-50nm, and the surface of the nano cerium dioxide is coated with a silane coupling agent; the preparation method comprises the following steps: modifying the surface of nano cerium dioxide, shearing and dispersing multiple components at a high speed, and adjusting and filtering a solvent; the weather resistance of the automobile coating is remarkably improved and the service life of the automobile coating is remarkably prolonged through the synergistic effect of a plurality of light stabilizing components and the combination of the photocatalytic degradation capability of the nano cerium dioxide and the anti-migration characteristic of the hyperbranched polyester.

The invention discloses a methyl paraoxon pesticide detection test strip based on oxygen vacancy-cerium dioxide and a preparation method of the methyl paraoxon pesticide detection test strip, and belongs to the technical field of biosensors. The test strip is characterized in that a large amount of oxygen vacancy-cerium dioxide is loaded. The oxygen vacancy-cerium dioxide nano enzyme can show simulated phosphatase activity under specific conditions, and the enzyme activity can cut off P-O and P-S bonds of organophosphorus pesticides and promote methyl paraoxon to be hydrolyzed into a yellow product p-nitrophenol. The detection limit of a nano-enzyme system is discussed, so that the portable visual quantitative detection of the paraoxon methyl pesticide is realized. The test strip established on the basis of the principle can quickly detect paraoxon methyl, has the advantages of simplicity and convenience in operation, high sensitivity, low cost and the like, and provides a new method for instant test of paraoxon methyl pesticide.

The invention discloses a passive radiation refrigeration coating and a preparation method thereof, and relates to the technical field of industrial coatings. Comprising a fluoroacrylate emulsion, hollow glass beads, nano titanium dioxide, flaky silicon dioxide aerogel powder, polytetrafluoroethylene micro powder, hydroxyl-terminated polydimethylsiloxane, a hydroxyl acrylic acid modified silane coupling agent, a super-hydrophobic modified fluorosilicone surface additive, nano cerium oxide, aluminum fluoride doped zinc oxide infrared enhancement powder and deionized water. The paint is prepared on the basis of the formula. According to the invention, a multi-scale spectrum regulation and control and surface self-cleaning system is constructed cooperatively, so that the synergistic effect of high reflection of a sunlight region and high emission of a middle infrared region is realized. The coating can maintain continuous passive refrigeration in a day and night period, the surface of the coating has self-cleaning capability and excellent ultraviolet aging resistance, and high reflectivity and high radiation emissivity can be maintained for a long time in a complex outdoor environment, so that the thermal management efficiency of buildings and equipment is remarkably improved.

The invention relates to the technical field of composite materials, in particular to a heat and sound insulation PVB intermediate film and a preparation method thereof. The problem that a PVB intermediate film is insufficient in heat insulation and aging resistance is solved. The preparation method comprises the following steps: pre-plasticizing PVB resin, shearing and mixing the pre-plasticized PVB resin and silane coupling agent modified enhanced nano cellulose, sequentially adding additives such as a plasticizer, molybdenum trioxide loaded lanthanum hexaboride, a composite light stabilizer and modified cerium oxide, and carrying out tape casting and hot pressing treatment to obtain the PVB intermediate film. Wherein the modified lanthanum hexaboride enhances infrared ray shielding, the composite light stabilizer and the modified cerium oxide synergistically improve the aging resistance, all the components are subjected to substance cooperation and process cooperation, comprehensive improvement of heat insulation, sound insulation and aging resistance of the PVB intermediate film is achieved, and the PVB intermediate film is suitable for the field of high-strength building glass.

The invention relates to the field of anticorrosive paint, in particular to anticorrosive paint containing lanthanum cerium oxide and a preparation method of the anticorrosive paint. The invention relates to an anticorrosive coating containing lanthanum cerium oxide. The anticorrosive coating is prepared from the following raw materials: 28 to 45 parts of ultraviolet stable composite film forming matter, 5 to 10 parts of composite rare earth filler, 6 to 12 parts of supported synergistic antirust agent, 18 to 30 parts of mixed solvent, 0.8 to 2.5 parts of dispersing agent, 2.7 to 5.3 parts of functional additive and 0.5 to 1.2 parts of nano montmorillonite, the composite rare earth filler is lanthanum cerium oxide-hydroxyapatite composite powder with a core-shell structure, wherein lanthanum cerium oxide is used as a core, hydroxyapatite is used as a shell, and the thickness of the shell layer is 10-20 nm; the ultraviolet stable composite film forming substance comprises epoxy resin and ultraviolet grafting modified polyurethane in a weight ratio of 1: (0.6-2.2); the supported synergistic antirust agent is a mixture of mesoporous silica supported benzotriazole and zinc molybdate. And the obtained coating is high in adhesive force and long in service life.

The invention discloses composite conductive powder for preparing conductive silver paste and the conductive silver paste, and particularly relates to the technical field of electronic materials.The composite conductive powder is of a double-shell core-shell structure composed of a silver metal inner core, a silicon dioxide middle coating layer and a silver nanoparticle self-assembled outer layer and is subjected to ultraviolet irradiation treatment; the conductive silver paste is based on the composite conductive powder and is matched with cerium oxide modified glass powder, graphene nanosheets, thermoplastic polyurethane resin and a dibasic acid ester solvent to form a low-temperature environment-friendly formula. The volume resistivity of the conductive silver paste is as low as 1.2 * 10 <-6 > omega.cm, the curing temperature is reduced to 120 DEG C, the content of volatile organic compounds meets the environmental protection standard, meanwhile, the tensile strength is improved by 50%, the conductive silver paste can bear 500 times of bending circulation without breakage, the adhesive force reaches the level 0 of a cross-cut method, the strict requirement of a high-performance electronic device for the conductive silver paste is effectively met, and the conductive silver paste has wide application prospects.

The invention discloses a warm-keeping fabric containing hollow polyester fibers as well as a preparation method and application thereof, and relates to the field of fabrics. When the thermal fabric containing the hollow polyester fibers is prepared, hollow mesoporous nano cerium oxide is selectively protected by molten paraffin and then reacts with chloromethyl trimethoxy silane and isocyanuric acid in sequence, paraffin is dissolved by chloroform, and then N-(3-trimethoxysilylpropyl) pyrrole is grafted to obtain modified hollow mesoporous nano cerium oxide; reacting terephthalic acid, a multifunctional monomer and ethylene glycol to obtain modified polyester particles; the preparation method comprises the following steps: granulating modified polyester, uniformly mixing modified hollow mesoporous nano cerium oxide and polyethylene glycol 10000, performing melt spinning, treating with a pyrrole solution, twisting, spinning and weaving, and treating with a sodium hypochlorite mixed solution to obtain the thermal fabric containing the hollow polyester fibers. The warm-keeping fabric containing the hollow polyester fibers prepared by the invention has excellent warm-keeping, antibacterial, anti-aging, flame-retardant, antistatic and mechanical properties.

The invention discloses preparation of a high-uniformity cerium oxide abrasive material and application of the high-uniformity cerium oxide abrasive material in a chemical mechanical polishing solution. According to a method, cerium nitrate or cerium oxalate is used as a cerium source, a cationic or nonionic surfactant is used as a structure-directing agent, and the high-uniformity cerium oxide abrasive material is prepared in a mixed solvent system formed by water and isopropanol or water and diethylene glycol according to a specific volume ratio. The preparation method comprises the following steps: regulating the particle size and the morphology structure through a solvothermal reaction, carrying out cleaning, drying and high-temperature calcination treatment on a reaction product to obtain sphere-like cerium oxide nano-particles with high particle size concentration ratio, moderate surface roughness and good dispersity, adding cerium oxide powder into deionized water, and carrying out ultrasonic dispersion to obtain the spherical cerium oxide nano-particles. And sequentially adding a dispersing agent and amino acid while stirring, uniformly stirring, fixing the volume, and adding a pH regulator to enable the solution to be weakly acidic, thereby obtaining the chemical mechanical polishing solution. The cerium oxide submicron powder which is different in surface appearance, particle size and distribution uniformity is prepared by adjusting the solvent ratio and other reaction conditions.

The invention provides an anti-ultraviolet composite particle, an anti-ultraviolet polyamide material and a preparation method and application of the anti-ultraviolet composite particle, the anti-ultraviolet composite particle comprises a nano-microsphere with a core-shell structure and a benzotriazole anti-ultraviolet agent adsorbed outside the nano-microsphere, the core of the nano-microsphere comprises zinc oxide and cerium oxide, and the core of the nano-microsphere comprises zinc oxide and cerium oxide. The shell layer comprises silicon dioxide; zinc oxide and cerium oxide are matched to serve as a core, silicon dioxide serves as a shell layer, and a benzotriazole anti-ultraviolet agent is adsorbed outside the shell layer, so that the obtained anti-ultraviolet composite particles have long-term and excellent anti-ultraviolet performance, and can be uniformly dispersed in polyamide resin; the obtained polyamide material also has long-term and excellent ultraviolet resistance, and meanwhile, the spinnability of the polyamide fiber is not influenced.

The invention discloses a high-performance double-slurry quick-setting grouting material and a preparation method thereof, and belongs to the field of building materials, the high-performance double-slurry quick-setting grouting material comprises a component A and a component B. The component A is base slurry, and the component B is a performance regulator of the component A; the component A is prepared from the following components in parts by weight: 30 to 35 parts of methacrylic anhydride gelatin modified sulphoaluminate cement, 5 to 8 parts of calcium powder, 0.25 to 0.45 part of lanthanum cerium oxide, 0.5 to 0.8 part of amino acid type surface activity exciting agent, 1 to 1.5 parts of polycarboxylic acid water reducing agent and water, and the water-cement ratio of the water to the modified sulphoaluminate cement is 0.35 to 0.45; and the component B is prepared from the following components: hydroxyethyl cellulose acrylamide modified bentonite, N-vinyl pyrrolidone / methacrylic acid / 2-hydroxy-3-methacryloyloxypropyl trimethyl ammonium chloride terpolymer, a double initiator, a cross-linking agent and deionized water. The bonding strength of the whole system of the grouting material can be enhanced, and the mechanical strength of the grouting material can also be improved.

The invention provides a method for synthesizing octahedral nano cerium oxide with a high Ce < 3 + > ratio and a chemical mechanical polishing solution, the polishing solution takes the synthesized octahedral cerium oxide as a grinding material, and the octahedral cerium oxide is prepared by the following specific steps: dissolving a certain amount of organic ligand and cerous nitrate in deionized water; controlling the ratio of the organic ligand to cerous nitrate to water to be (0.01-0.5): 1: (100-300), and stirring for 1-2 hours in a nitrogen atmosphere; dropwise adding a certain amount of alkali liquor into the solution at a certain speed in a nitrogen atmosphere, carrying out hydrothermal treatment on the mixture, controlling the reaction temperature to be 80-150 DEG C and the synthesis time to be 6-8 hours, centrifuging, drying and calcining the mixture after the reaction, calcining at the calcining temperature to be 400-600 DEG C and calcining for 4-8 hours, thereby obtaining the catalyst. The particle size of the octahedral nano cerium oxide is about 30-50nm, and the Ce < 3 + > ratio of the octahedral nano cerium oxide is high. The polishing solution taking the octahedral nano cerium oxide prepared by the method as the abrasive material has good dispersity and stability, high polishing rate and low surface roughness, and has wide popularization and application values.

The invention relates to the technical field of PET optical films, and particularly discloses a high-light-transmittance blue-light-resistant PET optical film and a preparation method thereof, and the high-light-transmittance blue-light-resistant PET optical film is prepared from the following raw materials by weight: 70-85% of a polyethylene glycol terephthalate resin matrix; 3%-8% of a benzotriazole anti-blue light agent; 5%-12% of a silicon dioxide nano anti-reflection agent; 2%-6% of nano zinc oxide or nano cerium oxide; 1.5% to 4% of a polycarbodiimide cross-linking agent; 0.5%-3% of an anti-blocking agent; 0.4%-1.5% of an antioxidant; 0.4%-1.0% of an ultraviolet light absorber; the balance is a processing aid; the preparation method comprises the following steps: S1, pretreating the raw materials; s2, a mixing procedure; and S3, extruding and coating. The PET optical film provided by the invention has high optical properties of high light transmittance, blue light resistance and low haze, and has the advantages of high light transmittance and blue light blocking rate of the optical film and improvement of the application range of the optical film.

The invention relates to the technical field of cables, and provides a high-temperature-resistant flame-retardant power cable and a preparation method thereof. A high-temperature-resistant flame-retardant power cable comprises a conductor and a high-temperature-resistant flame-retardant outer layer wrapping the conductor. The high-temperature-resistant flame-retardant outer layer is prepared from the following raw materials in parts by weight: linear low-density polyethylene, an ethylene-vinyl acetate copolymer, ethylene propylene diene monomer, chopped polyimide fibers, nano-coated magnesium hydroxide, zinc borate, zinc stannate, polyethylene grafted maleic anhydride, an anti-aging agent, dicumyl peroxide, an antioxidant, polyethylene wax, calcium stearate and cerium dioxide. According to the cable prepared in the invention, the reliability of an existing high-temperature-resistant flame-retardant power cable under thermal cycle is improved, and the problem of local temperature resistance difference caused by agglomeration and high-temperature migration of nanoparticles in a polymer matrix is improved.

The invention discloses a high-strength, high-conductivity and heat-resistant aluminum-based composite material. The aluminum-based composite material is formed by compounding and sintering 90-95 wt% of an aluminum alloy matrix and 5-10 wt% of a conductive fiber membrane. A trace amount of Zr, Hf and B elements are added into the aluminum alloy matrix, and the effects of refining grains, purifying impurities and improving the electric conductivity, heat resistance and comprehensive mechanical performance of the alloy matrix can be achieved. The conductive fiber membrane is a polyaniline / polyacrylonitrile composite conductive fiber membrane doped with nano-copper particles and cerium oxide particles, and polyaniline and polyacrylonitrile blended spinning can improve the strength and stability of the fiber membrane. And the conductivity of the fiber membrane and the bonding strength of the fiber membrane and an aluminum alloy matrix can be further improved through doping of the nano-copper particles and the cerium oxide particles. The aluminum-based composite material disclosed by the invention has good electrical conductivity and heat resistance and excellent comprehensive mechanical properties.

The invention relates to the technical field of stainless steel pneumatic cylinder barrels, and particularly discloses a wear-resistant stainless steel pipe for a pneumatic cylinder barrel and a preparation process thereof.The wear-resistant stainless steel pipe for the pneumatic cylinder barrel comprises the steps that firstly, a powder metallurgy method is adopted, tungsten carbide, cerium oxide, chromium nitride and other components are added into stainless steel powder, and the performance of a steel pipe base body is enhanced; the corrosion-resistant alloy layer is deposited on the surface of the steel pipe, so that the corrosion resistance, wear resistance and other properties of the steel pipe are enhanced, finally, a silicon nitride wear-resistant ceramic layer is sintered on the surface of the corrosion-resistant coating, and two lubricants of graphite and molybdenum sulfide are synthesized in gaps and holes of the wear-resistant ceramic layer. The defects on the ceramic surface are blocked; and the ceramic coating is endowed with a self-lubricating function.

The invention provides a cerium oxide photo-thermal synergistic catalytic material loaded with a metal promoter as well as a preparation method and application of the cerium oxide photo-thermal synergistic catalytic material. The cerium oxide photo-thermal synergistic catalytic material loaded with the metal promoter comprises a cerium oxide nanocrystal and the metal promoter loaded on the surface of the cerium oxide nanocrystal, the exposed crystal face of the cerium oxide nanocrystal comprises a {111} crystal face, and the area of the {111} crystal face accounts for more than 50% of the total area of the outer surface of the crystal face; the mass fraction of the metal cocatalyst is 0.1-2wt% of the mass of the cerium oxide. The catalytic material provided by the invention takes cerium oxide with a {111} crystal face as an exposed special crystal face as a carrier, photons can be captured and charges can be separated more efficiently, and phonons further promote deep trap state charge release. Meanwhile, the metal additive is added and cooperates with cerium oxide with exposed special crystal faces for catalysis, so that the catalytic effect is remarkably improved, and efficient catalytic combustion of methane is achieved under the mild condition.

The present invention belongs to the field of material preparation, and discloses a preparation method and application of a composite material of Pd, cerium oxide and silicon dioxide with a controllable hierarchical catalytic structure. Cerium oxide rich in oxygen vacancies is used as a carrier, and Pd species are loaded by impregnation, and then dispersed on the surface of acidic silicon dioxide with a high specific surface area. Finally, a Pd / CeO2 / SiO2 material with a controllable hierarchical catalytic structure is prepared by high-temperature calcination and reduction, and is used to catalyze the hydrogenation conversion reaction of furfural. The preparation method of the present invention is simple, green and environmentally friendly, highly active, stable, cheap and easy to obtain, and can efficiently catalyze the hydrogenation conversion of furfural, and has good industrial application prospects.

The invention provides a cerium oxide-loaded mesoporous carbon sphere material and a preparation method and application thereof, and belongs to the technical field of cerium oxide composite material preparation, and the preparation method comprises the following steps: carrying out a hydrothermal reaction on cerium salt under the action of an alkaline mesoporous carbon sphere aqueous solution to obtain a mixed solution; the mass fraction of the mesoporous carbon spheres in the mixed solution is 1-4 wt%, and the concentration of the cerium salt is 0.04-0.06 mol / L; and carrying out centrifugal washing on the obtained mixed solution, and carrying out vacuum drying to obtain the cerium oxide loaded mesoporous carbon sphere material. The mesoporous carbon sphere has a large specific surface area and a uniform pore structure, the pore structure of the mesoporous carbon sphere is very close to the diameter of the short rod type CeO, and the short rod type CeO can be embedded into the pore of the mesoporous carbon sphere due to the size matching, so that tight physical contact is formed; meanwhile, hydroxyl groups on the surfaces of the carbon spheres and oxygen vacancies on the surfaces of the CeO particles can form stable covalent bonds, so that the bonding strength of the cerium oxide-loaded mesoporous carbon spheres is improved, and the service life of the cerium oxide-loaded mesoporous carbon spheres is prolonged.