89 results about "Scandium oxide" patented technology

The invention relates to the technical field of ceramic substrates, and provides a high-toughness aluminum oxide ceramic substrate and a preparation method thereof, the high-toughness aluminum oxide ceramic substrate comprises the following raw materials by weight: 100 parts of aluminum oxide, 1-3 parts of a plasticizer, 4-6 parts of an auxiliary agent, 4-6 parts of a binder, 1-3 parts of a dispersant, and 55-65 parts of water; the auxiliary agent is composed of an auxiliary agent A and an auxiliary agent B, the auxiliary agent A comprises rare earth oxide, and the auxiliary agent B is composed of molybdenum boride, scandium oxide and zirconium oxide. According to the technical scheme, the problem of low toughness of the aluminum oxide ceramic substrate in the prior art is solved.

The invention provides a method for recovering scandium from scandium-containing lithium slag and a pretreatment method of the scandium-containing lithium slag. The method for recovering scandium from the scandium-containing lithium slag comprises the following steps: mixing the scandium-containing lithium slag with concentrated sulfuric acid, and heating and roasting to obtain a roasted product; the roasted product is subjected to water leaching, and scandium-containing leaching liquid and leaching residues are obtained; the scandium-containing leachate is extracted, and a scandium-containing organic phase and raffinate are obtained; washing the scandium-containing organic phase to obtain a purified scandium-containing organic phase and a washing solution; carrying out reverse extraction on the purified scandium-containing organic phase, and filtering to obtain a reverse extract; the reverse extract is subjected to acid dissolution, and a scandium-containing acid solution is obtained; adding oxalic acid into the scandium-containing acid solution for precipitation, filtering to obtain scandium oxalate precipitation, and roasting to obtain scandium oxide.

The invention discloses a multi-band high-stability ferrite magnetic material composite formula and a preparation process, and relates to the technical field of magnetic materials. The ferrite magnetic material composite formula comprises 38-42 parts of ferric oxide powder, 37-41 parts of ferroferric oxide powder, 6-12 parts of graphene nanosheets, 5-7 parts of hydroxypropyl methyl cellulose, 6-9 parts of lanthanum oxide, 4-6 parts of scandium oxide, 1-3 parts of nano titanium dioxide, 4-6 parts of bismuth magnesium boron, 9-13 parts of ferric sulfate, 3-5 parts of manganese sulfate, 4-6 parts of zinc sulfate, 2-4 parts of copper sulfate and 2-3 parts of samarium sulfate. By utilizing a physical vapor deposition gradient doping process, the problems that an existing ferrite magnetic material is single in electromagnetic performance, cannot stably and efficiently work in a multi-frequency-band complex electromagnetic environment and cannot meet the requirements of the fields of communication, radar, electronic countermeasure and the like for wide-frequency-band and high-performance magnetic materials can be solved.

The invention discloses a method for recovering scandium from a byproduct ferrous sulfate monohydrate in a sulfuric acid process titanium white waste acid concentration process, which comprises the following steps: adding water to dissolve the byproduct ferrous sulfate monohydrate, filtering to obtain a first ferrous sulfate solution, and enabling the pH value of the first ferrous sulfate solution to be less than or equal to 2.5; the first ferrous sulfate solution reacts with metallic iron, iron ions in the solution exist in the form of ferrous ions, then filtering is conducted, and a second ferrous sulfate solution is obtained; adjusting the pH value of the second ferrous sulfate solution to 3.5-5 by adopting an alkaline substance, and filtering to obtain a third ferrous sulfate solution and scandium-containing filter residues; and adding acid into the scandium-containing filter residue, stirring, and then filtering to obtain a scandium-containing solution and a mixed solid of an insoluble titanium compound and calcium sulfate. According to the method, scandium in the scandium can be efficiently recycled, high-purity scandium oxide can be obtained, and the method is convenient to operate, simple in technological process, high in efficiency, low in production cost, good in environmental protection benefit and easy to industrialize.

The application discloses a preparation method of a homogenized aluminum-scandium intermediate alloy, and comprises the following steps: smelting: the scandium oxide, the molten salt and the aluminum ingot are heated to 1000-1200 DEG C, and then the temperature is kept at 900-1000 DEG C and stirred, the mass ratio of the scandium oxide, the molten salt and the aluminum ingot is 3.5-4.5:50-65:100; the aluminum-scandium intermediate alloy liquid is obtained through impurity removal and temperature keeping; the aluminum-scandium intermediate alloy is obtained through slagging, casting and cooling. Through process optimization, the aluminum-scandium intermediate alloy prepared by the preparation method has low segregation rate, uniform composition and low impurity content.

This application provides a method and system for extracting scandium from a scandium-containing cobalt-nickel hydroxide solution, belonging to the field of heavy metal recovery technology. The method includes the following steps: extracting the scandium-containing cobalt-nickel hydroxide solution with an organic extractant to obtain a scandium-containing organic phase; washing the scandium-containing organic phase to obtain a purified organic phase; back-extracting the purified organic phase with hydrochloric acid to obtain a scandium-containing back-extract and a back-extracted organic phase; performing scandium extraction treatment on the scandium-containing back-extract to obtain scandium oxide; and regenerating the back-extracted organic phase sequentially with sodium carbonate and dilute sulfuric acid to obtain a regenerated organic extractant, which is then reused. This application first sequentially washes the chlorine with sodium carbonate and sulfuric acid solutions, solving the emulsification problem in the extraction, washing, and back-extraction stages caused by washing with sodium carbonate solution. Furthermore, compared to directly using sulfuric acid solution for washing, this application uses less sulfuric acid in the regeneration stage, preventing phase miscibility during the washing process.

This invention provides a composite battery separator, its preparation method, and its application, relating to the field of lithium-ion battery technology. Specifically, the composite battery separator includes a base film and a coating loaded on at least one side of the base film; the coating includes organic components, inorganic components, and functional components; wherein the organic component includes polyethylene oxide (PEO), and the inorganic component includes scandium oxide and titanium dioxide. This invention improves the thermal stability, electrolyte affinity, and ionic conductivity of the separator by coating a mixture of inorganic metal materials and the organic component PEO onto the base film. Simultaneously, the nanoparticles formed by the mixed doping of scandium oxide and titanium dioxide effectively improve the uneven pore distribution on the surface of the polyolefin separator, reducing the formation of lithium dendrites.

The invention belongs to the field of inorganic ceramic materials, particularly relates to a scandium oxide modified continuous aluminum oxide-zirconium oxide high-temperature-resistant composite ceramic fiber and a preparation method thereof, and particularly relates to a technology for regulating and controlling the microstructure of the composite fiber through the synergistic effect of rare earth oxide and a preparation process so as to improve the high thermal stability. The fiber composite ceramic fiber comprises the following components in percentage by mass: 0.1 to 3 percent of scandium oxide, preferably 0.5 to 2.5 percent, further preferably 0.8 to 1.2 percent, 8 to 9.5 percent of zirconium oxide, preferably 8.8 to 9.2 percent, and the balance of aluminum oxide, the grain size of the aluminum oxide is 150 to 200nm, the grain size of the zirconium oxide at the grain boundary is 40 to 80nm, and the grain size of the zirconium oxide at the intragranular position is 5 to 20nm. The obtained product is subjected to heat preservation service for 100 hours at the temperature of 1200 DEG C in the air atmosphere and then cooled to the room temperature, and the grain size of aluminum oxide in the product is only 0.21-0.33 micron. The composition is reasonable in design, the preparation process is simple and controllable, and the obtained product is extremely excellent in heat resistance and mechanical property and convenient for industrial application.

The invention discloses a titanium white waste acid treatment process, and relates to the technical field of industrial waste regeneration. The titanium white waste acid is subjected to microfiltration and membrane electrolysis treatment, sulfuric acid is separated and recycled under the control of constant pressure and constant current, and residual liquid is subjected to electrodialysis treatment to oxidize ferrous ions into ferric hydroxide precipitates and calcined into ferric oxide; carrying out reduction leaching on the titanium-containing material, hydrolyzing to generate metatitanic acid, and calcining to obtain titanium dioxide; oxidizing the hydrolysate to precipitate vanadate, and calcining to obtain vanadium pentoxide; adjusting the pH value of the filtrate, selectively adsorbing scandium through a biological adsorption column, precipitating and calcining the eluent to obtain scandium oxide, and regenerating and recycling the adsorbent through acid pickling. According to the process, through multi-stage treatment and biological adsorption, resource recycling of sulfuric acid, iron, titanium, vanadium and scandium components in the waste acid is achieved, the process is clean and efficient, secondary pollution of a traditional process is avoided, and a green low-carbon solution is provided for waste acid treatment in the titanium dioxide industry.

The invention belongs to the field of photocatalytic functional materials, and discloses a preparation method and application of a scandium monatomic anchored polytriazine imide photocatalytic material. In a high-temperature molten salt medium, scandium oxide and a melamine precursor are subjected to a synchronous reaction, so that scandium is anchored in a polytriazine imide carrier lattice in a monatomic form. Scandium is stably anchored on the surface of the polytriazine imide carrier in an atomic-scale dispersion form. The structure can synergistically increase active sites and effectively promote separation and migration of photo-induced electron-hole pairs, so that the activity of the material in photocatalytic synthesis of hydrogen peroxide is remarkably improved.

The embodiment of the present application relates to a kind of scandium negative electrode material and its preparation method and application.The preparation method includes: the homogeneous solution obtained by dissolving the ion-free aqueous solution of scandium-containing compound, first solution is obtained by adding coagulation agent and stirring mixing;First solution is placed in heating device, the molecular chain of coagulation agent is broken and dissolved, and the sol of cross-linked scandium ion-containing solution is formed;The solid gel is obtained by the sol at room temperature;Solid gel is heat-pressed and cured to obtain the solidified sample of scandium ion uniform dispersion;The carbon matrix containing scandium nitride is obtained by heat treatment of solidified sample in tube furnace, and the carbon matrix containing scandium nitride is modified by soaking in surface oxidizing agent solution, the modified sample is washed with water and suction filtered, and the modified scandium-based carbon matrix is obtained after drying;Or the carbon matrix containing scandium nitride is directly washed with water and suction filtered, and the unmodified scandium-based carbon matrix is obtained after drying;Finally, under oxidizing atmosphere, the residual carbon is removed to obtain scandium oxide nanoparticles.

The invention relates to a polycrystalline fused product of formula (Sc2O3)yAx(ZrO2 + HfO2)1-x-y, with 0.030 ≤ y ≤ 0.150, and 0.000 ≤ x ≤ 0.070, and x ≤ y, A denoting an additive selected from Y2O3, Al2O3, CeO2, Yb2O3, Gd2O3, MnO, Bi2O3, La2O3, Pr2O3, Nd2O5, Sm2O3, Eu2O3, Tb4O7, Ta2O5, Nb2O5 and mixtures thereof, ZrO2 + HfO2 + Sc2O3 + A representing more than 98% of the mass of the fused product, MnO expressing the total content of manganese oxides expressed in the form MnO, Pr2O3 expressing the total content of praseodymium oxides expressed in the form Pr2O3, Nd2O5 expressing the total content of neodymium oxides expressed in the form Nd2O5, Tb4O7 expressing the total content of terbium oxides expressed as Tb4O7, Ta2O5 expressing the total content of tantalum oxides expressed as Ta2O5, and Nb2O5 expressing the total content of niobium oxides expressed as Nb2O5.

The invention belongs to the technical field of ceramic metal composite materials, and particularly relates to a multiphase ceramic composite plate and a preparation method thereof, and a metal-based ceramic composite lining plate for a ball mill and a preparation method thereof. The composite material comprises the following components in parts by weight: 70-90 parts of zirconium oxide, 5-10 parts of silicon carbide, 5-10 parts of aluminum oxide, 2-6 parts of titanium dioxide, 2-5 parts of tungsten carbide, 2-4 parts of scandium oxide, 2-4 parts of cobalt oxide, 1-3 parts of potassium tantalate, 1-3 parts of potassium titanate, 1-2 parts of bismuth trioxide and 1-2 parts of erbium oxide. A compact ceramic plate is obtained through mixing, wet grinding, drying, pressing and high-temperature sintering, and the special-shaped ceramic sheet is formed through further crushing and screening. The special-shaped sheet is laid in a mold and filled with high-chromium cast iron powder, and the integrated metal-based ceramic composite lining plate with a stable structure is formed through compaction and high-temperature sintering. The prepared lining plate has the high hardness of ceramic and the toughness of metal, and is suitable for high-abrasion equipment such as a ball mill.

The application discloses a beneficiation-metallurgy combined method for comprehensively recovering niobium, silicon and scandium from niobium-containing tailings, and belongs to the technical field of mineral processing and metallurgical engineering. The application first adopts one roughing and two cleaning flotation to obtain a niobium rough concentrate, and then adopts hydrogen-based mineral phase conversion roasting to activate the niobium rough concentrate, and the roasting product is subjected to acid leaching, so that niobium and scandium enter into a leaching solution, and silicon is enriched in a leaching residue; the leaching solution is subjected to solvent extraction, precipitation and calcination to obtain a niobium oxide product; the leaching residue is subjected to alkali leaching and pH adjustment to obtain white carbon black; and the raffinate is subjected to selective extraction to obtain a scandium oxide concentrate. The preparation method has the advantages of low-temperature hydrogen-based roasting, low carbon and low energy consumption, and can realize the step-by-step recovery of three valuable products, realizes the high-value utilization of all components of the niobium tailings, and has the advantages of mild process conditions, a niobium recovery rate of greater than or equal to 70% in the whole process, a scandium recovery rate of greater than or equal to 60% in the whole process, a white carbon black SiO2 content of greater than or equal to 95%, and good industrial application prospect.

The invention relates to a preparation method of a composite material, which comprises the following steps: providing a preform consisting of continuous carbon fibers, arranging the carbon fibers in the preform in a single layer, and aligning the fibers through a polyester net and an adhesive; zirconium boride powder is mixed with silicon carbide and scandium oxide, the mixed powder is mixed with the dispersion liquid, and slurry is prepared through ball milling homogenization; the prefabricated bodies are laid in a mold layer by layer, the space between every two layers is soaked with the slurry so that the fiber surface can be evenly covered, the prefabricated bodies are stacked at the 0-degree configuration, and at least 30 layers are stacked to prepare a plate with the thickness being 3-3.5 mm; in a vacuumizing state, curing the plate at 80 DEG C for 2 hours to form a stable composite structure; controlling the sintering time and temperature gradient promotes densification of the composite structure but prevents formation of an interface layer.

This invention relates to a method for preparing a composite material, comprising: providing a preform composed of continuous carbon fibers, wherein the carbon fibers in the preform are arranged in a single layer and the fibers are aligned by a polyester mesh and an adhesive; mixing zirconium boride powder with silicon carbide and scandium oxide, mixing the mixed powder with a dispersion, and homogenizing by ball milling to prepare a slurry; laying the preform layer by layer in a mold, and impregnating each layer with the slurry to uniformly cover the fiber surface, the preforms being stacked at 0° configuration, and at least 30 layers are stacked to prepare a plate with a thickness of 3–3.5 mm; curing the plate at 80°C for 2 hours under vacuum to form a stable composite structure; and controlling the sintering time and temperature gradient to promote densification of the composite structure but prevent the formation of an interface layer.

The present invention provides a semiconductor structure comprising: a silicon substrate in [100] orientation; a scandium oxide layer over the substrate, in [111] orientation; and a scandium-rare earth-oxide layer over the scandium oxide layer. The scandium-rare earth-oxide layer can have a graded composition to transition lattice constant to match to a subsequent layer, such as an indium nitride layer having very high electron drift velocity. InN over Si (100) offers transistors, photonics and passive electronics that operate in the terahertz frequency range.

This application provides a method for deep removal of calcium impurities from scandium oxide, belonging to the field of rare earth metal oxide purification. The method includes: dissolving scandium oxide raw material containing calcium impurities to obtain a calcium-containing scandium solution; adding a pH adjuster to the calcium-containing scandium solution to obtain a first scandium solution; reacting the first scandium solution with phosphoric acid and / or phosphate to obtain a second scandium solution and solid calcium phosphate; reacting the second scandium solution with a complexing agent to obtain a third scandium solution; reacting the third scandium solution with oxalic acid and / or sodium oxalate to obtain scandium oxalate crystals and a calcium complex solution; adding a strong acid solution to the calcium complex solution; and calcining the scandium oxalate crystals to obtain scandium oxide. Through calcium phosphate precipitation-complexation-crystallization, not only can calcium impurities be deeply removed from scandium oxide products, but impurities such as iron, titanium, and zirconium can also be removed, resulting in scandium oxide products with a purity of over 99.99%.

The invention relates to yttrium-scandium oxide transparent ceramic nano-powder, transparent ceramic and a preparation method thereof, and the preparation method of the yttrium-scandium oxide transparent ceramic nano-powder comprises the following steps: synthesizing a yttrium-scandium composite precursor through a wet chemical coprecipitation method, and calcining to obtain high-activity nano-powder; carrying out ball milling on the nano powder and a dispersion medium to prepare slurry, and forming a uniform green body through a pressure-assisted slip casting technology; and carrying out vacuum sintering on the green body after glue discharging treatment, and finally annealing in an oxygen atmosphere to obtain the transparent ceramic. Compared with the prior art, a wet chemical process chain cooperation strategy without a sintering aid is adopted, a co-precipitation method is combined with pressure-assisted slip casting, the agglomeration defect and the dry pressing forming stress problem of traditional mechanical powder preparation are broken through, and intrinsic regulation and control of yttrium scandium oxide solid solution crystal lattices are achieved; the obtained transparent ceramic crystal boundary is clean and free of a second phase, the oxygen vacancy concentration is obviously reduced, and the transparent ceramic has high transmittance in a wide spectrum range.

The invention provides a method for extracting scandium oxide based on P507 extraction resin, and particularly relates to a novel method for extracting scandium oxide from titanium white waste acid and a red mud solution. Figure 1 is a product process flow diagram. The method specifically comprises the following steps: adsorbing raw materials, washing with ultrapure water, treating with a potassium hydroxide solution, washing with an acid solution, desorbing and electrolyzing. The concentration of the potassium hydroxide solution is 1N-8N; the P507 extraction-elution enrichment resin comprises P507 extraction-elution resin and silicon-based amidoxime resin; the concentration of the hydrochloric acid solution is 1-3 mol / L; and the resin desorption agent is any one of ultrapure water or a dilute acid solution with the pH value of 1-5. The method is easy to operate and low in cost, and scandium oxide with the purity of 99.99% or above can be obtained through purification.

The application belongs to the technical field of scandium separation and purification, and particularly relates to a method for separating and purifying scandium from crude nickel-cobalt hydroxide, which comprises the following steps: using 0.1-0.5 mol / L dilute sulfuric acid to leach the crude nickel-cobalt hydroxide, and filtering to obtain a scandium-containing leaching solution, wherein the ratio of the dilute sulfuric acid to the crude nickel-cobalt hydroxide is (3-5) mL:1 g, and the molar ratio of sulfuric acid to scandium is (3-5):1; using an extractant comprising Cyanex572 and Aliquat336 to treat the scandium-containing leaching solution to obtain a scandium-containing organic phase; using an oxalic acid solution to back-extract the scandium-containing organic phase to obtain scandium oxalate precipitation; and calcining the scandium oxalate precipitation to obtain scandium oxide. The technical scheme adopts a selective leaching process to realize efficient separation of scandium from main metals nickel and cobalt at the front end, has low reagent consumption, a short process, and great cost advantages; a new type of synergistic extraction technology is adopted, which has super-high selectivity and extraction capacity for scandium, the prepared scandium oxide has a purity of greater than or equal to 96%, and the scandium recovery rate is greater than or equal to 89%.

This invention discloses a multi-cavity thin-walled battery tray-type aluminum alloy profile for new energy vehicles and its preparation method, relating to the field of battery tray technology. The internal chemical composition of the aluminum alloy profile, by mass percentage, includes: Si: 0.65%–0.75%, Mg: 0.70%–0.85%, Cu: 0.10%–0.20%, Mn: 0.10%–0.18%, Cr: 0.06%–0.12%, Ti: 0.05%–0.10%, Sc: 0.02%–0.08%, Zr: 0.05%–0.12%, Fe≤0.20%, B≦0.10%, with the balance being Al. This invention successfully constructs a nanoscale dispersed reinforcing phase in the matrix through stepwise pretreatment of Sc / Ti elements and a two-stage aging process. Combined with an upward dual-medium quenching technology, the high-temperature zone utilizes a scandium oxide-containing water-based medium for rapid cooling, effectively freezing the supersaturated solid solution. The low-temperature zone utilizes an oil-based medium for slow cooling, eliminating harmful residual stress and significantly improving the load-bearing capacity and collision energy absorption safety of the battery tray.

The invention provides a method and a system for extracting scandium from a scandium-containing cobalt-nickel hydroxide solution, and belongs to the technical field of heavy metal recovery, and the method comprises the following steps: extracting the scandium-containing cobalt-nickel hydroxide solution by adopting an organic extraction agent to obtain a scandium-containing organic phase; washing the scandium-containing organic phase to obtain a purified organic phase; hydrochloric acid is adopted for back extraction of the purified organic phase, and scandium-containing back extraction liquid and a back extraction organic phase are obtained; the scandium-containing strip liquor is subjected to scandium extraction treatment, and scandium oxide is obtained; the reverse extraction organic phase is regenerated through sodium carbonate and dilute sulphuric acid in sequence, a regenerated organic extraction agent is obtained, and the regenerated organic extraction agent is recycled. Sodium carbonate and a sulfuric acid solution are sequentially adopted for chlorine washing, and the problem of emulsification of an extraction section, a washing section and a reverse extraction section caused by chlorine washing with a sodium carbonate solution is solved; meanwhile, compared with a mode that a sulfuric acid solution is directly adopted for chlorine washing, little sulfuric acid is adopted in the regeneration section, and phase mixing in the chlorine washing process cannot be caused.

The application provides a titanium dioxide type low-temperature hydrogenolysis catalyst and a preparation method and application thereof. The catalyst comprises a titanium dioxide carrier and an active component loaded on the titanium dioxide carrier, and the active component comprises scandium oxide and tungsten oxide. The preparation method of the catalyst comprises the following steps: dipping the titanium dioxide carrier in a mixed solution of scandium salt and tungsten salt for a period of time, so that the scandium salt and the tungsten salt are loaded on the titanium dioxide carrier; and then drying and calcining the titanium dioxide carrier loaded with the scandium salt and the tungsten salt, to obtain the titanium dioxide type low-temperature hydrogenolysis catalyst. The catalyst has good sulfur dioxide hydrogenation activity and organic sulfur hydrolysis activity, and can be applied to a process for treating sulfur recovery tail gas at a low temperature of 210-220 DEG C.

The invention relates to the technical field of metal materials, and discloses an aluminum alloy cooperatively added with scandium and scandium oxide and a preparation method of the aluminum alloy. The method comprises a casting method of an Al-4. 5Cu-0. 3Mg aluminum alloy, and Sc and Sc2O3 are added into an Al-4. 5Cu-0. 3Mg aluminum alloy matrix; comprising the following steps that under high-purity argon protection and high vacuum, an aluminum alloy matrix is mixed with Sc and Sc2O3, and homogenization treatment is conducted after smelting; carrying out primary and secondary aging treatment on the alloy subjected to solid solution treatment; and low-temperature aging treatment and short-time high-temperature aging precipitation are conducted, and the alloy is prepared. By synergistically adding scandium and scandium oxide, the high-temperature performance and stability of the cast aluminum alloy are remarkably improved, and compared with single addition, grains are refined, and the structure is optimized; the tensile strength, yield strength and plasticity of the alloy are good after thermal exposure, an Al3Sc precipitated phase is formed, scandium distribution is more uniform, and the high-temperature performance and stability of the alloy are improved.

The invention discloses a method for extracting scandium impurities in an MHP wet process and producing scandium oxide, which comprises the following steps: by taking pickle liquor in the MHP wet process as a raw material, a composite solvent containing phosphorus and carboxylic acid substances as an extracting agent, dilute sulphuric acid as a washing solution and an oxalic acid solution as a strip liquor, removing iron, extracting, washing and stripping to obtain scandium oxalate, and drying and calcining to obtain scandium oxide. According to the method, the phenomena of three-phase emulsification and interface flocculation caused by abnormal interfacial tension in the scandium extraction process are improved by adding the non-silicon defoaming agent, the extraction stage efficiency is improved, the production efficiency is guaranteed, the occupied area of equipment is reduced, meanwhile, the necessary multi-stage separation and deep purification steps in traditional coarse scandium preparation are omitted, and the economic value is high.

A power storage device 1 comprises: a first electrode 10 that functions as a p-type semiconductor; a second electrode 20 that functions as an n-type semiconductor; and an oxygen vacancy region 30 that is disposed between the first electrode 10 and the second electrode 20. The first electrode 10 preferably contains manganese oxide. In addition, the second electrode 20 preferably contains tin oxide. The oxygen vacancy region 30 also preferably contains zirconium oxide stabilized by yttrium oxide, cerium oxide, calcium oxide, magnesium oxide, or scandium oxide.

The utility model discloses a glass cover plate, a display module and electronic equipment, and the glass cover plate comprises a base material layer; the titanium diboride layer is arranged on the upper surface of the base material layer; and the scandium oxide layer is arranged on one side, back to the base material layer, of the titanium diboride layer. The mechanical property and the wear resistance of the product are improved, and the optical property is also considered.

The invention discloses high-light-yield boron gadolinium silicate scintillation glass with a wide aluminum content range and a preparation method and application of the high-light-yield boron gadolinium silicate scintillation glass. The scintillation glass comprises a matrix and light-emitting central ions dispersed in the matrix, the boron-gadolinium silicate scintillation glass with the wide aluminum content range and the high light yield comprises a matrix and light-emitting central ions dispersed in the matrix, wherein the matrix comprises the following components in percentage by mass: 3-15% of silicon dioxide, 5-15% of silicon dioxide, 5-15% of silicon dioxide, and the balance of water. 4 to 11% of diboron trioxide; 50 to 70% of gadolinium oxide; 6-20% of gadolinium fluoride; 4-20% of aluminum oxide; 1-3% of gallium oxide; 2-5 parts of barium oxide; 0.5 to 1.5 percent of calcium oxide; the content of the luminescent central ions is 2-9%, and the sum of the proportions of the components is 100%. The gadolinium borosilicate scintillation glass is characterized in that gadolinium trioxide, silicon dioxide and diboron trioxide are used as main components, a large amount of aluminum oxide is added, so that the gadolinium borosilicate scintillation glass has high density, high light yield and high transmittance, and the preparation cost of the high-performance scintillation glass is remarkably reduced.