55results about How to "Less acid consumption" patented technology

The invention discloses a technology for recovering production of electrolytic copper and zinc from smelting ash. The technology comprises a step of smelting ash leaching, a step of copper extraction and purification through copper electrodeposition, a step of iron removal through neutralization, a step of cadmium removal, and a step of zinc extraction and purification through zinc electrodeposition. The method is characterized in that chemical components in the smelting ash are analyzed, and the smelting ash is leached by a sulfuric acid solution leaching agent; the leachate obtained after the above leaching reaction undergoes a separation operation of copper extraction and purification through the copper electrodeposition; the resultant copper extraction liquor is neutralized by high-zinc dust which is a neutralizer to remove iron; cadmium is displaced and deposited by zinc powder having a mass same with cadmium after the iron removal through the neutralization; and the zinc extraction is carried out through the zinc electrodeposition by casting zinc ingot products. The technology has a wide adaptability, adopts two steps to complete the exchange reaction of zinc oxide and copper oxide in the raw material with an acid, and adopts the high-zinc dust as the neutralizer, so the massive zinc loss caused by entrainment of routine neutralizers comprising calcium oxide and sodium hydroxide is avoided. A zinc extraction liquor obtained in the above step is purified by N235, so economy and effectiveness are realized.

The invention discloses an extraction seperation method of a rare-earth element. According to extraction seperation method, positive ions and negative ions in a quaternary ammonium salt ionic liquid extracting agent, i.e. 2-ethylhexyl phosphonic acid mono 2-ethylhexyl ester trialkyl methyl ammonium and phosphonic acid binary (2-ethylhexyl) ester trialkyl methyl ammonium react with rare earth ions to form neutral complex molecules, and the positive ions and negative ions in the quaternary ammonium salt ionic liquid extracting agent have inner synergistic effect and competitive effect in the process of extracting the rare-earth element, thereby the seperation factor of the rare-earth element is increased. Therefore, the extraction seperation method provided by the invention has the advantages that an interfacial phenomenon is good in the extraction process, no emulsification is generated, and an extracting solvent does not need to be saponified, the extraction seperation method has higher seperation factor of the rare-earth element and particularly high extraction seperation effect on heavy rare earth. In addition, the extraction seperation method of the rare-earth element, which is provided by the invention, has low extraction acidity and back extraction acidity and consumes little acid.

The invention relates to a method for extracting scandium from modified red mud by using a composite extractant, belonging to the technical field of extraction and preparation methods of rare-earth metal scandium. The method for extracting the scandium from the modified red mud ensures good extracting effect, high recovery rate and product purity and is suitable for industrialized production. The method comprises the following steps of: a first step: preparing the modified red mud; a second step: leaching the modified red mud by using hydrochloric acids so as to obtain an acid leaching solution; a third step: preparing the composite extractant; a fourth step: mixing the acid leaching solution obtained from the second step with the composite extractant for extraction and separation; a fifth step: washing extracted upper organic phases by using the hydrochloric acids, then washing by using water, and then carrying out back extraction by using a NaOH solution to obtain an Sc(OH)3 solution; a sixth step: precipitating the Sc(OH)3 solution by using oxalic acids, and filtering, and drying; and a seventh step: roasting a solid obtained from the sixth step at high temperature to obtain white scandium oxide powder. The invention can be widely used for the technical field of extraction and preparation of the rare-earth metal scandium.

The invention provides a method for extracting and separating rare earth elements in a hydrochloric acid system. The method includes the steps: taking mono (2-ethylhexyl) phosphonate 2-ethylhexyl methoxy cinnamate trialkyl methyl ammonium or phosphonate (2-ethylhexyl) diester trialkyl methyl ammonium as an extracting agent; taking normal heptane as diluent; and extracting the rare earth elements in rare earth chloride water solution into the normal heptane. The extracting agent used in the method does not need to be saponified, extraction and reverse extraction acidity is low, and separation coefficient for the rare earth elements is high.

The invention relates to a chromium slag treatment when coupling and reducing hexavalent chromium from chromium slag, wherein said method comprises using wet method to break, and adding the solution with acid and reducer, controlling the pH value, reducing the density of hexavalent chromium; transferring the liquid-solid mixture to another reactor, adding acid and reducer, mixing to reduce the hexavalent chromium; adding anaerobe, emerging. The acid can be sulfuric acid, etc; the reducer can be sulfite, etc; the anaerobe can be the mixture of SRB, Pseudomonas putida and Escherichia coli.

The invention discloses a comprehensive utilization method of high titanium slag in the slag treatment technology. The method comprises the following steps: firstly, carrying out acid leaching by using diluted hydrochloric acid; then, carrying out acidolysis by using dilute sulphuric acid, wherein the leaching rate is improved; using a black titaniferous liquid after acidolysis to prepare titanium dioxide; settling Fe(OH)3, Al(OH)3, Mg(OH)2 and Ca(OH)2 from a primary filtrate obtained by acid leaching and recovering sodium chloride; and using Si, Mg and Ca in slag to prepare an Si-Ca-P-Mg composite fertilizer. The method disclosed by the invention is extremely low in acid consumption of acid which is recycled, various effective components of high titanium slag can be comprehensively utilized, and factors in many aspects such as environment friendliness, technology and economical benefit are taken into consideration. The slag is low in cost, and titanium, ferrum, aluminum, magnesium, calcium, silicon, sodium chloride and the like can be comprehensively recovered, so that the economic benefit is remarkable, the long-term pendent problem on utilization of high titanium slag is solved, the land for slag is saved, the environmental pollution is reduced, wastes are turned into wealth, and the high titanium slag has a good social benefit.

The present invention is biological leaching process for separating out metal ions from waste battery directly, and the green process may be used in supplementing or replacing high temperature chemical leaching with strong acid. The present invention has direct waste battery leaching process with simultaneous acid generating and leaching, and is suitable for all kinds of waste battery. The process of the present invention has lower acid consumption, low cost, high metal leaching rate, mild operation and other advantages, and possesses excellent application foreground.

The invention provides a method for extracting and separating rare earth elements in a sulfuric acid system. The method includes the steps: taking mono (2-ethylhexyl) phosphonate 2-ethylhexyl methoxy cinnamate trialkyl methyl ammonium as an extracting agent; taking normal heptane as diluent; and extracting the rare earth elements in rare earth sulfate water solution into the normal heptane. The extracting agent used in the method does not need to be saponified, extraction and reverse extraction acidity is low, and separation coefficient for the rare earth elements is high.

A preparation method of expandable graphite comprises the following steps: oxidizing natural flake graphite for 5-120 min at 0-90 DEG C in the presence of an oxidant by using a mixed solution of perchloric acid and phosphoric acid in a mass ratio of 1:(0.05-3); deacidifying by centrifuging; further impregnating and intercalating the oxidized natural flake graphite by using organic acid; after water washing, drying at low temperature till the moisture content is less than 1% to prepare the expandable graphite. The expandable graphite is high in cryogenic expansion volume, low in energy consumption and acid consumption, sulfur-free or low in sulfur and stable in quality; the environmental pollution is reduced; the preparation method is easy to master.

The invention relates to a preparation method for noble metal modified titanium anode materials, belonging to the technical field of high-performance electrode materials. The preparation method for noble metal modified titanium anode materials comprises the following steps of: taking noble metal organic complex as a precursor; atomizing the precursor into atomizing flow after being dissolved in organic solvent; depositing the precursor on the surface of a titanium sheet; thermally decomposing and cooling under the existence of inertia gas; repeating three continuous steps of depositing, thermally decomposing and cooling for at least once; and carrying out aftertreatment, so as to obtain the noble metal modified titanium anode materials. The titanium anode prepared by the method has high yield and less surface exposed point; the noble metal and pure titanium base material have high binding force; and the whole coating has better homogeneity and uniformity. Experiments show that the titanium anode prepared by the method has better electrochemical performance and long service life.

The invention discloses a method for enriching germanium from lignite flue dust. The method comprises the following steps: 1, mixing lignite flue dust with coal powder and lime, and granulating the obtained mixture to obtain material particles; and 2, putting the material particles in a heating furnace, carrying out reducing volatilization at 1200-1500DEG C in reducing atmosphere in the heating furnace for 2-18h, and collecting dusts to obtain a germanium-rich material. The method greatly reduces the acid consumption in the subsequent wet treatment process of germanium concentrate, avoids discharge and treatment of a large amount of wastewater and waste residues, reduces the device size, and reduces the investment cost.

The invention discloses a strip steel pickling circulating system. The strip steel pickling circulating system is mainly characterized in that a strip steel inlet is formed in a first pickling tank, and the first pickling tank is connected with a second pickling tank; the second pickling tank is connected with a third pickling tank, and the first pickling tank, the second pickling tank and the third pickling tank are all connected with an acid mist pretreatment device; the acid mist pretreatment device is connected with an acid mist purification tower and a rinsing tank, and the right end of the acid mist purification tower is directly connected with atmosphere through a pipeline; the lower end of the acid mist pretreatment device and the left end of the rinsing tank are connected with the upper end of a third acid storage tank through pipelines; a water supplementing pipe is connected with the upper end of a condensate water tank, and the condensate water tank is connected with a first heater, a second heater and a third heater through pipelines; a strip steel outlet is formed in the right end of the rinsing tank, and a rinse water draining opening is formed in the bottom end of the rinsing tank; and the bottom end of the rinsing tank is connected with the right end of the condensate water tank through a water pump.

The invention discloses a method for measuring sodium in sodium humate. By carrying out pretreatment with H2SO4-H2O2 in a temperature control type infrared digestion furnace and optimizing ICP-AES measurement parameters, the method for measuring the content of sodium in sodium humate by ICP-AES is established. The method has the advantages of being small in acid consumption, high in analysis speed, simple to operate and being relatively high in precision and accuracy and being suitable for analytic detection on the content of sodium in daily sodium humate.

The invention belongs to the technical field of waste battery metal recovery treatment, and relates to a method for recycling metal in a lithium ion battery through inorganic acid leaching-bioleachingcollaboration. The method includes the steps that (1) domestication of thiobacillus ferrooxidans is conducted; (2) battery disassembling is performed; (3) acid leaching is carried out, inorganic acidis thrown into mixed electrode material powder, a solution containing heavy metal and electrode powder is obtained, and the final pH of a reaction system is 1.8-2.5; and (4) bioleaching is performed,a culture solution is added into the solution, the domesticated thiobacillus ferrooxidans are further added, the mixed solution is precipitated and separated after reacting is completed, the mixed solution obtained through separation is centrifuged, and the centrifuged solution containing the heavy metal is subjected to heavy metal recovery. According to the method for recycling the metal in thelithium ion battery through inorganic acid leaching-bioleaching collaboration, inorganic acid leaching and bioleaching are combined, the using amount of acid is small, the metal leaching rate is high,the advantage of being moderate in bioleaching reaction condition is given into play, and environmental protection and safety are achieved.

The invention provides a method for separating and recycling metal silver and gallium. The method comprises the steps that S1, waste containing silver and gallium and an alkali material are evenly mixed and then smelted; S2, dross obtained after smelting in S1 is soaked with alkali liquor and filtered, and then leach liquor is subjected to electro-deposition to obtain metal gallium; and S3, a silver ingot obtained after smelting in S1 serves as an anode, silver nitrate serves as electrolyte, and metal silver is purified through electrolysis. According to the method for separating and recycling metal silver and gallium, the pyrogenic process and the wet process are combined, then silver and gallium can be rapidly separated and recycled, the whole technological process is low in acid consumption and high in speed, accumulation of silver powder can be reduced, and the purity of the recycled product is good.

The invention discloses a method for leaching valuable metals from a waste lithium ion ternary positive electrode material. The method comprises the following steps: carrying out ball milling on an active substance separated from the waste lithium ion battery positive electrode material to obtain powder; wetting the powder with water to obtain a wet material; mixing the wet material with concentrated sulfuric acid; roasting at low temperature to obtain a roasted material; and carrying out water leaching on the roasted material, and carrying out solid-liquid separation to obtain carbon and a metal leachate. According to the method for leaching the valuable metal, efficient leaching of the metal is achieved under the condition that no reducing agent or additive exists, and energy consumptionis reduced. The invention further discloses a method for adjusting the molar ratio of nickel to cobalt to manganese in the leachate, then adding the urea, mixing with the ethylene glycol and carryingout a hydrothermal reaction to prepare a ternary positive electrode material precursor, so that separation of different metals is avoided, valuable metals are effectively recycled, the process flow is shortened, the operation is simple, industrial production is facilitated, and the prepared ternary positive electrode material precursor has excellent electrochemical performance.

The invention discloses a method for removing alkali of an alkaline uranium ore. The method is characterized by comprising the following step: removing alkali by adopting hydrochloric acid, wherein the step of removing alkali by adopting hydrochloric acid mainly performs calcium carbonate removal substantially; a measurement index of the process of removing calcium carbonate by hydrochloric acid is a boundary value of the calcium content of a leaching liquid without calcium sulfate precipitation; the process conditions of removing alkali by using hydrochloric acid are that in an initial stage, operating conditions that a pH value control value of a 10g/L hydrochloric acid leaching solution and leaching liquid exchange liquid is 4 are adopted. The calcium removal process condition is relatively high in working efficiency, and is relatively acid-saving; the average liquid calcium removal rate is 36.6%; the calcium carbonate removal rate can reach 65-90%; the calcium content in the leaching liquid is smaller than 50-550mg/L; the average acid consumption rate is 13.39%; the average calcium removal cycle is 51 days; and moreover, the threats of calcium sulfate precipitation can be eliminated.

The invention relates to a cleaning method for removing an oxide layer on the surface of a silicon material, and belongs to a silicon material cleaning technology. A cleaning solution is prepared and evenly stirred, and the silicon material is completely placed in the cleaning solution to be soaked, taken out, rinsed and dried. By optimizing the formula and proportion of the cleaning solution, the oxide layer on the surface of the silicon material can be removed only by soaking the silicon material, operation is convenient and fast, and cleaning efficiency is high. And the acid consumption is low, the skill requirement on operators is low, acid marks are avoided, and the cleaning effect is remarkable.