1224 results about "Pregnant leach solution" patented technology

This invention discloses a method for leaching lithium iron phosphate mixed powder with iron salts and recovering all components, belonging to the field of battery recycling. The invention uses an iron salt solution to leach the mixed powder, obtaining a lithium-containing leachate and leaching residue. Ferrous ions in the leachate are regenerated into ferric iron through acidification and oxidation, and recycled for leaching the next batch of mixed powder. After reaching a preset number of cycles, the leachate is used for re-leaching multiple batches of leaching residue to improve the lithium leaching rate. Ultimately, a enriched solution containing Li, Fe, Cu, and Al and graphite-containing iron phosphate residue are obtained. Copper is recovered from the enriched solution through iron powder replacement, and a high-purity lithium chloride solution is obtained through extraction and separation, while ferric chloride (recycled) and aluminum chloride crystals are also recovered. The leaching residue is treated with hydrochloric acid to obtain regenerated graphite, and the pH is adjusted with alkali to obtain high-purity iron phosphate. This method achieves full component recovery under mild conditions, reducing separation steps and chemical consumption through a "leaching-regeneration-leaching" cycle mechanism, thus achieving both environmental and economic benefits.

The invention provides a metal material recycling device and a method for leaching fluorine beryllium thallium and lithium rubidium cesium in lithium slag. Relates to the field of metal material recycling, and comprises a leaching tank placed on the ground through four supporting frames, the top of the leaching tank is fixedly provided with a top cover, and the bottom of the leaching tank is fixedly provided with a bottom cover. According to the metal material recycling device and the leaching method for fluorine beryllium thallium and lithium rubidium cesium in the lithium slag, the ultrasonic generator is arranged to supply energy to the first ultrasonic transducer and the second ultrasonic transducer to generate ultrasonic waves, the ultrasonic waves generate microjet flow to impact the surface of minerals, acid liquor permeation and ion diffusion are accelerated, the leaching time is shortened, and the efficiency is improved; the surface of the lithium slag is not prone to passivation, the leaching rate of target metal ions is increased, the leaching liquid is pumped out through the water suction pump, manual contact with the leaching liquid in the next solid-liquid separation procedure is facilitated, dilute sulfuric acid is supplemented through the acid supplementing pipe, then the lithium slag is placed through the funnel, and the consistency and controllability of starting of the leaching reaction are guaranteed.

The invention belongs to the technical field of hydrometallurgy, and particularly relates to a pretreatment method for improving the leaching rate and the carbon adsorption rate of high-sulfur-arsenic gold ore. Comprising the following steps that the high-sulfur-arsenic gold ore is ground and then prepared into ore pulp; a green oxygen activating agent and hydrogen peroxide are sequentially added into the ore pulp, oxidation pretreatment is conducted on the high-sulfur-arsenic gold ore, ore pulp activating liquid is formed, and the green oxygen activating agent is a mixture of calcium oxide, sodium persulfate and soluble bivalent iron salt; and adding a gold leaching agent into the ore pulp activation solution, adjusting the pH value of the ore pulp to 9-12, carrying out stirring gold leaching treatment, filtering to obtain a leaching solution, and then adding activated carbon to adsorb and extract gold. According to the method, a stronger oxidation environment is provided, meanwhile, the residual concentration of arsenate radicals in the solution is effectively reduced, the leaching rate of gold and the adsorption rate of activated carbon are greatly increased, excellent oxidation performance and environment friendliness are shown, and a more sustainable high-sulfur-arsenic gold ore pretreatment process is provided.

The application provides a coal-based solid waste flotation-metallurgy-material resource comprehensive utilization process method and application, and belongs to the technical field of coal-based solid waste comprehensive utilization.The coal-based solid waste is first separated by flotation to obtain residual carbon and tail ash; then the tail ash is dried and alkali melted to become active material; then the active material is leached and filtered to obtain leaching liquid and leaching residue, and Li and Ga in the leaching liquid are adsorbed and enriched; the adsorbed leaching liquid is adjusted in silicon-aluminum ratio, hydrothermally crystallized, filtered and high-temperature calcined to obtain mesoporous molecular sieve; the filtered silicon-containing alkali liquor is carbonized and calcined to obtain white carbon black; the tail ash and the leaching residue are mixed, and through moisture adjustment and curing process, a geopolymer product is obtained.The method in the application does not produce waste residue and waste water in the implementation process, finally obtains four products of Li and Ga enrichment product, geopolymer product, mesoporous molecular sieve and white carbon black, realizes full and comprehensive utilization of the coal-based solid waste, and has good environmental benefits and great significance.

The invention provides a method for recovering platinum group metal from a waste automobile exhaust purification catalyst, and belongs to the field of precious metal recovery. The method comprises the following steps: carrying out crushing and impurity removal pretreatment on the waste catalyst to obtain solid residues; mixing the obtained solid slag with alkali liquor, and performing hot-pressing activation to obtain active slag; leaching the active slag by using an acid leaching system of hydrochloric acid-hydrogen peroxide-sodium chloride to obtain a leaching solution enriched with platinum group metals; adjusting the acidity of the leachate, adding a first adsorption material, selectively adsorbing platinum and palladium, and separating supernate and a platinum / palladium enrichment material; adjusting the acidity of the supernate, adding a second adsorption material, selectively adsorbing rhodium, carrying out solid-liquid separation, and collecting a rhodium enrichment material; respectively eluting and refining the platinum / palladium enrichment material and the rhodium enrichment material, and recovering platinum, palladium and rhodium; through the optimally designed recovery method of alkaline hot-pressing activation-mild acidic directional leaching-two-stage magnetic adsorption separation, efficient recovery of platinum, palladium and rhodium in the waste automobile exhaust catalyst is realized.

The present disclosure provides a method for recovering metal from metal-containing waste material by leaching, the method comprising providing aqueous solution (14), providing leaching agent precursor, providing a source of external energy (10), treating the aqueous solution (14) with the external energy (10) to form reactive species, reacting the leaching agent precursor with the reactive species to form a leaching agent and to obtain a leaching solution, providing metal-containing material, reacting the metal-containing material with the leaching solution to obtain soluble metal complexes, and recovering the metal complexes. The present disclosure also provides a device for recovering metal by leaching.

An efficient multiphase-flow graded-separation, concentration, and purification system for argillaceous sandstone uranium ore includes a hydraulic tossing washing and scattering pretreatment device, a high-frequency linear vibration grading device, a first-stage multiphase-flow swirling grading device, an energy-gathering ultrasonic scrubbing device, a second-stage multiphase-flow swirling grading device, a high-frequency linear vibration dewatering device, an efficient uniform-mixing and activating system and a conditioning and pressing dewatering system. The present disclosure implements intensive mud-sand stripping of crushed argillaceous sandstone uranium ore, fine graded-separation of material, and efficient uniform-mixing and activating and deep efficient dewatering of fine-particle argillaceous material. Finally, four types of core material of coarse sand material, fine sand material, dry tailings residue and a high-concentration uranium ore leaching solution are formed through continuous work. Efficient multiphase-flow graded-separation, concentration and purification of the argillaceous sandstone uranium ore are implemented, and an intensive extraction rate of uranium ore resources is improved.

The invention relates to a method for recovering lithium and fluorine from aluminum electrolysis hazardous waste, which comprises the following steps: firstly, mixing organic polyol and alkaline hydroxide according to a molar ratio of 1: (0.5-2) to obtain a eutectic solvent; heating the eutectic solvent to 80-150 DEG C, and adding a proper amount of raw material fine powder and calcium oxide for reaction leaching; carbonating and filtering the leachate to obtain lithium carbonate; washing the leaching residues with an acetic acid solution to obtain a calcium fluoride product; the concentration of fluorine ions in the leachate is smaller than or equal to 200 ppm, and the purity of calcium fluoride is larger than or equal to 90%; the leaching rate of lithium in the method is greater than 85%; the slag feeding rate of fluorine is greater than 95%; and no hydrogen fluoride gas is generated in the method. According to the method, a non-toxic and biodegradable eutectic solvent is adopted as a leaching agent, and efficient leaching of lithium and fluorine in the aluminum electrolysis dangerous waste materials is achieved; calcium oxide is used as a precipitating agent, free fluorine is promoted to be precipitated and recycled as calcium fluoride, the whole process meets the requirement of green metallurgy, and the win-win situation of resources and the environment is achieved.

The invention provides a separation and recovery method of a nickel-iron alloy. The separation and recovery method comprises the following steps that S1, the ferro-nickel alloy material is subjected to atmospheric pressure leaching, and leaching residues and leaching liquid are obtained; s2, mixing the leachate in the S1, phosphoric acid and a first pH regulator, regulating the pH value to 1.6-1.8, and carrying out first impurity removal treatment to obtain iron phosphate and an impurity-removed solution; and S3, adjusting the pH value of the liquid subjected to impurity removal by adopting a second pH regulator until the pH value is 2.1-2.3, and carrying out second impurity removal treatment to obtain precipitation slag and a nickel-containing solution. According to the method, under the condition that impurities in the leachate are removed through phosphoric acid, the pH value of the leachate is adjusted and controlled in two stages, so that few main metal is included in impurity precipitates, the filtering performance is good, meanwhile, the loss of the main metal in the impurity removal process is reduced, and the recovery rate of nickel in the nickel-iron alloy material is increased.

The invention provides a method for short-process all-component echelon recovery of a waste hydrogenation catalyst, and relates to the field of solid waste treatment. The recovery method of the waste hydrogenation catalyst comprises the following steps: roasting the waste hydrogenation catalyst and sodium carbonate to obtain a roasted product; the roasted product is leached with water, and leaching liquid and leaching residues are obtained; extracting the leaching solution by using an extracting agent to obtain a vanadium-molybdenum-containing organic phase, sequentially carrying out reverse extraction treatment on the vanadium-molybdenum-containing organic phase by using a strong alkaline reverse extraction agent and a weak alkaline reverse extraction agent to obtain a vanadium reverse extraction solution and a molybdenum reverse extraction solution, and carrying out vanadium precipitation treatment on the vanadium reverse extraction solution to obtain ammonium metavanadate; acidizing the molybdenum strip liquor to precipitate molybdenum to obtain ammonium molybdate; carrying out sintering treatment on the leaching residues and alkaline substances, leaching obtained calcine with water to obtain water leaching residues and filtrate, and carrying out aluminum precipitation treatment on the filtrate to obtain aluminum hydroxide, aluminum oxide or pseudo-boehmite; and reducing and smelting the water leaching residues to obtain the ferro-nickel alloy. According to the invention, multi-element comprehensive recovery of all components of vanadium, molybdenum, nickel, aluminum and sulfur can be realized, and high-value utilization of all components of the waste hydrogenation catalyst is realized.

The invention relates to a method for recovering tellurium from copper anode slime through cooperation of ultrasound and hydrogen peroxide, and belongs to the field of wet metallurgy of scattered metal. The method comprises the following steps: drying and grinding copper anode slime to obtain copper anode slime powder; the method comprises the following steps: adding copper anode slime powder into a sulfuric acid solution, mixing to obtain copper anode slime slurry, adding hydrogen peroxide into the copper anode slime slurry, carrying out ultrasonic enhanced leaching for 20-160min, and carrying out solid-liquid separation to obtain a leaching solution containing copper and tellurium and high-grade valuable metal leaching residues. According to the method, hydrogen peroxide is effectively promoted to be decomposed by ultrasound to generate hydroxyl radicals, the oxidation potential of a system is regulated and controlled, copper and tellurium are selectively converted into copper ions, tellurate radicals enter a solution, and valuable elements such as gold, silver and selenium are enriched in slag; necessary heat is provided for the reaction by utilizing the heat effect of ultrasonic and heat released by chemical reaction, and extra heating is not needed; strong jet flow generated by ultrasound effectively destroys raw material inclusion and secondary wrapping, reaction mass transfer is enhanced, and the leaching rate of tellurium is increased. The method disclosed by the invention is simple in leaching process operation, low in cost and high in reaction speed.

The invention provides a laterite-nickel ore leaching solution catalytic oxidation-fractional precipitation method, and relates to the field of hydrometallurgy, the method comprises the following steps: adding a catalytic oxidant and a first neutralizer into a laterite-nickel ore leaching solution to obtain a first filtrate and iron slag; adding a catalytic oxidant, a second neutralizer and a first coalescing agent into the first filtrate to obtain a second filtrate and a second precipitate; adding a third neutralizer and a first reducing agent into the second filtrate to obtain a nickel-cobalt precipitate and a third filtrate; adding a fourth neutralizer and a second reducing agent into the third filtrate to obtain a fourth precipitate and a fourth filtrate; mixing the second precipitate with a third reducing agent, performing reduction leaching, and adding a second coalescing agent and a fifth neutralizing agent to obtain a silicon-aluminum precipitate and manganese-scandium filtrate; the manganese-scandium filtrate is extracted, and manganese enters raffinate; and adding a catalytic oxidant and a sixth neutralizer into the raffinate to obtain the manganese oxide. Elements are recycled step by step, and the method has the advantages of multiple types of recycled elements, less resource waste and the like.

The invention provides a method for preferentially extracting gold and silver from lead anode slime, and relates to the technical field of precious metal recovery, firstly, silver, antimony and other valuable metals in the lead anode slime are leached into a solution through catalytic oxidation leaching in the presence of a protective agent, and gold is enriched in residues; then, silver is selectively precipitated from the leachate, and silver precipitation residues and a valuable metal solution are obtained; and finally, valuable metals in the solution are recovered by adding a neutralizer and a precipitator, the obtained leaching mother liquor can be returned for leaching after being supplemented with hydrochloric acid, and the valuable metal precipitates are used for recovering antimony and bismuth. The method changes the traditional lead anode slime treatment thinking of first impurity removal and second refining, has the characteristics of high gold and silver direct recovery rate (greater than 99.5%), high reaction speed (total consumed time is less than 1 h), low cost and no generation of waste residue and wastewater, and is expected to solve the problems of long gold and silver recovery process, low direct recovery rate, capital overstock and difficult treatment of arsenic and antimony-containing smoke in the existing lead anode slime treatment method. The method has remarkable economic and environmental benefits and a good application prospect.

The present application relates to the field of nonferrous metallurgy, and particularly relates to a method for extracting molybdenum from refractory molybdenum ore by mechanical activation. The method comprises the following steps: step S1: mechanically crushing colloidal sulfur molybdenum ore to below 2 mm; step S2: adding an activation agent and water in a predetermined ratio to the molybdenum ore particles with a particle size of 2 mm or less after crushing, and ball-milling and activating to obtain activated ore; step S3: adding a leaching solution to the activated ore according to a solid-liquid ratio, controlling the leaching temperature at 20-100 DEG C, and leaching for 1-12 hours; and step S4: after leaching, separating the solid and liquid to recover molybdenum in the leaching solution. The present application can efficiently leach molybdenum in colloidal sulfur molybdenum ore into a solution, and the process is simple, environmentally friendly, and can realize efficient utilization of refractory colloidal sulfur molybdenum ore and associated minerals.

The invention discloses a uranium ore in-situ leaching mining multi-field coupling simulation method, device, equipment and medium, and relates to the field of in-situ leaching uranium mining. According to the uranium mine in-situ leaching mining multi-field coupling simulation method, the device, the equipment and the medium, in-situ leaching uranium mining reactive solute transport control of sandstone type uranium mine reservoir stress-seepage-chemical action is considered, and the influence of fluid temperature in the uranium mine reservoir and reservoir damage in the in-situ leaching process on in-situ leaching mining is emphatically considered; a distribution function is adopted to represent heterogeneity of mechanical parameters, so that a seepage-chemical-temperature-damage full-coupling numerical model suitable for sandstone type uranium mine CO2 and O2 in-situ leaching is established, and leachate uranium concentration data obtained through simulation calculation is compared with uranium concentration data of an on-site leaching test; the full-coupling numerical model is optimized to obtain a reasonable mathematical model to predict the parameter change trend in the CO2 and O2 in-situ leaching uranium mining process, and important guiding significance is provided for optimization of site scale CO2 and O2 in-situ leaching mining.

The invention relates to the technical field of in-situ leaching uranium mining, and provides an in-situ leaching uranium mine unit pre-oxidation circulating system and method. The in-situ leaching uranium mine unit pre-oxidation circulation system comprises a liquid extraction drilling hole; a plurality of liquid injection drill holes; the drainage hole is connected with the drainage hole through an ore bed seepage channel; the deep well submersible pump is arranged in the liquid extraction drill hole; the buffer device comprises a tank body, a plurality of communicating pipes arranged at the lower part of the tank body and a sampling nozzle arranged on the tank body; two ends of the lifting pipe are respectively connected with an outlet of the deep well submersible pump and the top of the buffer device; the plurality of liquid injection well inner pipes are respectively connected with the corresponding communicating pipes of the buffer device and the liquid injection drill holes; wherein the deep well submersible pump is used for conveying leaching liquid in the liquid pumping drill holes to the buffer device through the lifting pipe, the leaching liquid is distributed through the buffer device, then is injected into the corresponding liquid injection drill holes through the liquid injection well inner pipes and flows back to the liquid pumping drill holes through the ore bed seepage channel, and a pre-oxidation circulation loop is formed. Pre-oxidation circulation is completed in advance, and the leaching time of a mining area is shortened.

The invention provides a method for synchronously recovering iron and rare earth from iron separation tailings, which comprises the following steps of: roasting the pretreated iron separation tailings in a graphite crucible to obtain a roasted product; the roasted product is crushed and screened, oversize products and undersize products are obtained, and the oversize products are reduced iron products; the screen underflow and an acid solution are mixed for leaching, and leaching liquid containing rare earth elements and acid leaching residues are obtained; and adding a precipitant into the leachate to obtain a precipitate containing rare earth elements, and recovering fluorite concentrate from the acid leaching residues. According to the method, the traditional disjunction mode of pre-enrichment and then smelting is broken through, a roasting-acid leaching integrated process with deep beneficiation and smelting coupling is provided, the complex pre-enrichment link is abandoned, efficient and synchronous recovery of iron and rare earth is achieved, and the method has the advantages of being short in process, low in energy consumption, few in flotation reagent, high in rare earth recovery rate, high in resource comprehensive utilization rate and the like.

The invention relates to the technical field of waste hydrogenation catalyst treatment, and discloses a recovery method of active metal in a waste hydrogenation catalyst, a preparation method of a residual oil hydrogenation catalyst and application of the residual oil hydrogenation catalyst, and the method comprises the following steps: (1) leaching the waste hydrogenation catalyst by using an acid solution to obtain a leachate; (2) the concentration of hydrogen ions in the leachate is adjusted to be 0.05-2 mol / L, then the leachate is in contact with a first extraction agent, washing and reverse extraction are conducted, and a Mo solution is obtained; (3) adjusting the pH value of the first raffinate to 1-2.1, then contacting the first raffinate with a second extraction agent, and then carrying out washing and reverse extraction to obtain an Al solution; and (4) adjusting the pH value of the second raffinate to 2.2-3.5, then contacting the second raffinate with a third extraction agent, and then carrying out washing and reverse extraction to obtain a Ni and / or Co solution. The method can realize hazardous waste resource utilization, and can significantly reduce the production cost of the hydrogenation catalyst.

The application belongs to the technical field of waste lithium battery positive electrode material recycling, and specifically discloses a method for preparing basic lithium iron phosphate from waste lithium iron phosphate positive electrode powder, which comprises the following steps: subjecting the waste lithium iron phosphate positive electrode powder to acid leaching treatment, and performing solid-liquid separation to obtain a leaching solution; subjecting the leaching solution to oxidation treatment, and then performing precipitation treatment with sodium hydroxide, and performing solid-liquid separation to obtain a lithium solution and iron-phosphorus slag; subjecting the slurry formed by slurrying the iron-phosphorus slag and a lithium source to hydrothermal treatment at a temperature of 200 DEG C or above to obtain the basic lithium iron phosphate. The application also comprises a scheme for preparing lithium iron phosphate by mixing and reacting the basic lithium iron phosphate and a carbon source. The scheme can obtain basic lithium iron phosphate with high phase purity, and further can prepare regenerated lithium iron phosphate material with better performance.

The invention provides a method for preparing a poly-aluminum and functional silicon material by activating coal gasification slag and waste hydrochloric acid through microwave synergistic mechanical force, and belongs to the technical field of industrial solid waste recycling. The method comprises the following steps that the coal gasification slag is sequentially subjected to microwave radiation treatment and ball milling, activated slag and waste hydrochloric acid are subjected to an acid leaching reaction, and aluminum-iron-containing leachate and silicon-rich slag are obtained; extracting the aluminum-iron-containing leaching solution to obtain an iron-rich organic phase and a purified aluminum chloride solution; performing thermal polymerization reaction on the purified aluminum chloride solution to obtain polyaluminum chloride; the method comprises the following steps: carrying out alkaline leaching reaction on silicon-rich slag and waste alkali liquor, adding a structure-directing agent into a sodium silicate solution, and sequentially carrying out aging, solution pH value adjustment and crystallization precipitation to obtain mesoporous silica. According to the method, the aluminum-silicon leaching rate is remarkably increased through microwave-mechanical force synergistic activation, synergistic and efficient treatment of the three kinds of waste including the coal gasification slag, the waste hydrochloric acid and the waste alkali liquid is achieved, the technological process is closed, the product additional value is high, and the environmental and economic benefits are remarkable.

The invention provides a method for recovering fluorine in tailings containing fluorine, tantalum and niobium. The recovery method comprises the following steps: mixing and leaching the fluorine-containing tantalum-niobium ore tailings and a sulfuric acid solution, and carrying out solid-liquid separation to obtain a leachate; mixing and reacting a reducing agent with the leaching solution to reduce iron ions in the leaching solution into ferrous ions, so as to obtain an extraction material solution; mixing the extraction feed liquid with an organic phase, carrying out extraction treatment, and carrying out phase splitting to obtain a fluorine-containing extraction liquid; the organic phase comprises trioctylamine, an additive and a diluent; and mixing the fluorine-containing extraction liquid with an alkali solution, carrying out reverse extraction treatment, and carrying out phase splitting to obtain a fluorine-containing reverse extraction liquid and a no-load organic phase.

The invention discloses a metallurgical solid waste all-component collaborative recovery and high-value utilization method, and belongs to the technical field of metallurgical resource recycling and green metallurgy. According to the method, blast furnace gas sludge, iron-manganese slag and vanadium extraction converter sludge are synergistically blended, and after briquetting and drying, reduction smelting is carried out in an inert atmosphere. Reducing the iron into molten iron; volatile metals such as zinc, indium and gallium are evaporated and enter flue gas, and gallium-indium alloy, crude zinc and residual ash are recovered in a graded manner through a multi-stage condensation system; the slag is subjected to acid leaching to enrich scandium, the leaching liquid is separated to extract vanadium, manganese and scandium, and the leaching slag is used for preparing low-carbon cement. According to the method, all-component collaborative recovery of valuable metals in various metallurgical solid wastes and building material utilization of residual solid wastes are realized, and the method has the advantages of high resource efficiency and environmental friendliness.

The invention relates to the technical field of efficient lithium extraction of clay-type lithium ore and waste lithium iron phosphate, in particular to a method for collaborative roasting-selective lithium extraction of clay-type lithium ore and waste lithium iron phosphate, which comprises the following steps: respectively crushing and finely grinding clay-type lithium ore and waste lithium iron phosphate until-200 meshes account for 50-90%, dynamically proportioning and mixing to obtain a mixture with Li2O grade of 0.9-1.2%; and then carrying out mixed roasting, adding into a dilute sulphuric acid solution, and carrying out agitation leaching and filtering to obtain a lithium-containing leaching solution. According to the method, the thermodynamic complementation mechanism of the two materials is utilized, the roasting energy consumption is reduced, the double synergistic leaching mechanism is utilized, the leaching of lithium is enhanced, the content of impurities in the leaching solution is reduced, and the efficient selective leaching of the clay type lithium ore and the lithium in the waste lithium iron phosphate is realized.

The invention discloses a method for recovering valuable metals from copper anode slime step by step, and belongs to the technical field of metallurgy and chemical industry. According to the method, through control over the oxidation-reduction potential, the oxidation-reduction potential is high in the leaching stage, and it is guaranteed that gold, selenium, tellurium and the like can be oxidized to enter a leaching solution; in the reduction stage, gold, selenium and tellurium products are reduced step by step according to the difference of gold, selenium and tellurium in reduction potentials; in the leaching stage, soluble chlorine salt is added while enough oxidation potential is guaranteed, enough chloride ions are provided for the solution, and therefore gold can enter the solution in the form of AuCl4-(tetrachloroauric acid); meanwhile, in the oxidation leaching stage, a small amount of silver enters the solution in the form of silver sulfate or silver complex, and under the condition that enough chloride ions are provided, silver is precipitated and retained in residues in the form of silver chloride, so that separation of gold and silver is achieved, and meanwhile dispersion of gold and silver in the leaching process is reduced. According to the method, valuable metal is efficiently separated and recycled.

The invention provides application of sodium citrate as a retardant in ion adsorption type rare earth ore seepage leaching, and relates to the technical field of nonferrous metal mining. The application provided by the invention comprises the following steps: in the in-situ ore leaching process of the ion adsorption type rare earth ore, injecting a sodium citrate solution as a retardant in the downward direction of a diversion hole excavated in the rare earth ore and in other areas needing closure and speed control in advance, so as to reduce the seepage rate of the ore leaching agent in the areas and realize regulation and control of the seepage direction. According to the invention, the leaching liquid can be prevented from seeping downwards through the flow guide holes so as to improve the liquid yield, the seepage extraction of a mineral leaching agent on wider areas such as a semi-weathered layer is enhanced, the mineral leaching blind area is effectively reduced, and the leaching efficiency is improved.

The invention relates to the technical field of solid waste recycling treatment, and provides a red mud resource recycling treatment method which comprises the following steps: crushing red mud; washing red mud particles, and removing soluble salt; acid leaching treatment; putting the washed red mud particles into an acid solution, and stirring to react for 2-4 hours; then carrying out filtering treatment to obtain a leaching solution containing Fe < 3 + > and Al < 3 + > and silicon slag; separating iron and aluminum; naOH or sodium carbonate is added into the filtered leachate, the PH value of the leachate is adjusted to 2.5-6, and Fe (OH) 3 and Al (OH) 3 precipitates are obtained; and concentrating the mother liquor, introducing CO2, crystallizing, and filtering to obtain Na2CO3. 10H2O. According to the invention, crushing, washing and acid leaching are carried out; and then, the leachate is subjected to precipitation treatment, and iron and aluminum elements in the red mud are recycled. In the acid leaching process, a large amount of heavy metal is dissolved and leached in liquid, and leached sediment after detoxification is decomposed through a microbial agent and then serves as organic soil.

A method for recovering platinum group precious metal in a silicon carbide DPF catalyst comprises the steps that S1, smelting treatment is conducted, specifically, the silicon carbide DPF catalyst is crushed and then mixed with a smelting agent in a layered mode, a smelting reaction is conducted at the high temperature, and the smelting agent is composed of sodium carbonate and sodium peroxide; s2, leaching and separation are conducted, specifically, after the smelting product obtained in the step S1 is cooled, acid leaching treatment is conducted through hydrochloric acid, leaching liquid containing platinum group precious metal and residues are obtained through filtering separation, the residues are washed, and washing liquid is added into main leaching liquid; and S3, precious metal enrichment is conducted, specifically, the leachate obtained in the step S2 is enriched through a chemical precipitation method, the obtained precipitate is dissolved with aqua regia, and a platinum-palladium chloride mixed solution is obtained. The method is high in recovery rate, and under the optimal condition, the recovery rate of platinum can reach 91% or above, and the recovery rate of palladium can reach 96% or above; the process is simple, the cost is controllable, the used smelting agent is a common chemical raw material, and the cost is low.

The invention discloses a method for recovering valuable elements in phosphorite step by step through gradient acid leaching, which comprises the following steps: firstly, mixing high-magnesium phosphorite and high-silicon phosphorite in proportion for ore blending, and carrying out crushing, grading and ball milling until the particle size is less than or equal to 200 meshes; then, adopting a gradient acid leaching process: (1) leaching with low-concentration inorganic acid (1-3wt%), and preferentially and selectively removing dolomite and calcite to obtain phosphate concentrate and leachate rich in calcium and magnesium; (2) leaching the phosphate concentrate by using medium-concentration inorganic acid (5-8wt%), and dissolving the phosphate concentrate to obtain a phosphate concentrate leachate and residues mainly containing iron, aluminum and silicon; and (3) leaching the residues by using high-concentration inorganic acid (30-40wt%) to obtain silicon-rich residues and a leaching solution rich in iron and aluminum. (4) neutralizing and carbonizing the calcium-magnesium leaching solution, and respectively precipitating and recovering magnesium hydroxide and calcium carbonate; (5) carrying out fractional precipitation on the phosphate concentrate leachate to obtain rare earth enrichment and calcium hydrogen phosphate; (6) carrying out alkali dissolution and carbonization reaction on the silicon-rich slag to prepare high-purity white carbon black; and (7) carrying out iron powder reduction, neutralization aluminum removal and oxidation iron precipitation on the iron and aluminum lixivium to prepare the battery-grade iron phosphate. The method is simple and convenient to operate, energy-saving and environment-friendly, various valuable elements in the phosphorite are efficiently recycled, and the economic added value of phosphorite resources is increased.

The invention discloses a method for preparing iron phosphate through hydrogen-based micro-reduction roasting reinforced iron ore acid dissolution. The method comprises the following steps that (1) iron ore is pretreated into iron ore powder with D90 smaller than 74 micrometers; (2) hydrogen is introduced into the iron ore powder within the temperature range of 700-900 DEG C for micro-reduction roasting, the hydrogen flux of each kilogram of iron ore is 10-60 L / min, the roasting time is 5-30 min, and micro-reduction iron ore powder is obtained after cooling; (3) adding the micro-reduced iron ore powder into a mixed acid solution, adding a proper amount of a hydrogen peroxide solution, stirring and leaching at a set temperature to obtain a leaching mixed solution, and carrying out solid-liquid separation on the leaching mixed solution to obtain leaching residues and a leaching solution; (4) adjusting the pH value of the leachate, heating to a preset temperature, carrying out auxiliary stirring reaction, aging and filtering to obtain crude iron phosphate; and (5) calcining the crude iron phosphate, and cooling to obtain the battery-grade iron phosphate. By means of the method, the acid dissolution efficiency of the iron ore can be effectively improved, acid consumption and energy consumption are reduced, meanwhile, green production can be achieved, and the requirement for sustainable development is met.

The invention discloses a non-aqua regia gold extraction agent and method for recovering precious metal from waste containing precious metal. The non-aqua regia gold extraction agent is composed of nitrate, metal chloride and weak acid, by precisely regulating and controlling the concentrations of nitrate, chloride ions and hydrogen ions in the non-aqua regia gold extraction agent, the precious metal in the waste containing the precious metal can be subjected to green, efficient and selective oxidation leaching under the normal temperature condition, the precious metal ions in the leaching solution are subjected to reduction operation, and therefore the recovery rate of the precious metal in the waste containing the precious metal is improved. And a pure noble metal product can be obtained. Compared with a traditional aqua regia method, the method has the advantages that strong acid reagents such as concentrated nitric acid and concentrated hydrochloric acid are not used, corrosion to equipment and operation risks are remarkably reduced, and secondary emission of harmful gas is avoided. The method has the remarkable advantages of being environmentally friendly, easy and convenient to operate, mild in reaction condition, low in equipment requirement, high in leaching rate and the like, is suitable for large-scale and industrial production, and has wide application prospects and commercial value in the field of precious metal recovery.