1337 results about "Ammonium carbonate" patented technology

The invention provides a method for preparing lithium cobaltate by directly using an invalid lithium ion battery. The method comprises the following steps: crushing the invalid lithium ion battery or scraps generated when a lithium cobaltate battery is produced by a mechanical crusher at normal temperature; adding water and one or more of acetic acid, sulfuric acid, hydrochloric acid or nitric acid to produce mixed aqueous solution of the battery scraps and acid; filling the mixed aqueous solution into a hermetic pressure reactor, and controlling the temperature in the reactor to be between 50 and 150 DEG C; introducing or adding one leaching additive of sulfur dioxide or hydrogen, or adding hydrazine hydrate; stirring and leaching, cooling, and filtering; adding one precipitator of sodium carbonate, potassium carbonate and ammonium carbonate, or adding composite precipitator consisting of one of the sodium carbonate, the potassium carbonate and the ammonium carbonate and one of sodium hydroxide and potassium hydroxide to obtain mixture of lithium carbonate, cobalt carbonate and cobalt hydroxide; drying and calcining at high temperature to produce a lithium cobaltate product. The method is particularly suitable for the treatment scale of medium-sized and small enterprises, and is an effective method for directly materializing cobalt secondary resources.

The present invention relates to a variety of conductive ink compositions comprising a metal complex compound having a special structure and an additive and a method for preparing the same, more particularly to conductive ink compositions comprising a metal complex compound obtained by reacting a metal or metal compound with an ammonium carbamate- or ammonium carbonate-based compound and an additive and a method for preparing the same.

The invention discloses a method for preparing lithium nickel cobalt manganese oxide by taking a waste lithium ion battery as a raw material. The method is mainly characterized in that a waste lithium ion battery taking the lithium nickel cobalt manganese oxide, lithium nickel cobalt oxide and so on as a battery positive material is selected as the raw material and is pretreated through disassembly, separation, crushing, screening and so on, and then processes such as adhesive removal at high temperature and aluminum removal by sodium hydroxide are adopted to obtain an inactivated positive material containing nickel, cobalt and manganese; then a sulfuric acid and hydrogen peroxide system is adopted to leach, and P204 is adopted to remove impurities by extraction to obtain pure nickel, cobalt and manganese solution, and proper manganese sulfate, nickel sulfate or cobalt sulfate is blended to ensure that the mol ratio of nickel, cobalt and manganese elements in the solution is 1: 1: 1; and then ammonium carbonate is adopted to adjust the pH value to form a nickel cobalt manganese carbonate precursor, and then a proper amount of lithium carbonate is blended for high temperature sintering to synthesize a lithium nickel cobalt manganese oxide battery material. The first discharge capacity of the material is 150 mAh/g, the discharge capacity is still kept more than 130mAh/g after the circulation for 30 times, and the material has good electrochemical performance.

The invention provides a full-component resource reclamation method for waste positive electrode materials of lithium ion batteries. The method comprises the following steps: 1) separating active substances and aluminum foils in waste positive electrode materials of lithium ion batteries by using an aqueous solution of fluorine-containing organic acid and carrying out liquid-solid-solid separation so as to obtain leachate, the lithium-containing active substances and the aluminum foils; 2) respectively carrying out high temperature roasting and impurity removal with alkali liquor on the lithium-containing active substances; 3) respectively carrying out recovery of the fluorine-containing organic acid through addition of acid and distillation, deposition of impurity ions through addition of alkali and ammonium carbonate coprecipitation on the leachate so as to prepare nickel-cobalt-manganese carbonate ternary precursor; and 4) carrying out component regulation on a mixture of the treated active substances and the nickel-cobalt-manganese carbonate ternary precursor, adding lithium carbonate in a certain proportion and carrying out high temperature solid phase sintering so as to prepare a lithium nickel cobalt manganese oxide ternary positive electrode material. The method provided in the invention has the following advantages: the application scope of the method is wide; separation efficiency of the lithium-containing active substances and the aluminum foils is high; short-flow direct re-preparation of positive electrode materials in waste lithium ion batteries is realized; and the method is applicable to large-scale resource reclamation of waste lithium ion batteries.

The present invention relates to a variety of conductive ink compositions comprising a metal complex compound having a special structure and an additive and a method for preparing the same, more particularly to conductive ink compositions comprising a metal complex compound obtained by reacting a metal or metal compound with an ammonium carbamate- or ammonium carbonate-based compound and an additive and a method for preparing the same.

The invention relates to a method for preparing carbon nanofibers. The method comprises the following steps: taking a polyacrylonitrile solution or an acrylonitrile copolymer solution or melt as materials, preparing nanofibers by the electrostatic spinning or the airflow spray method, and then preparing the nanofibers into carbon nanofibers. The method is characterized in that the carbon nanofibers are acidified or electrochemically treated into carbon nanofibers containing oxygen or nitrogen functional groups. The acidifying process comprises the following steps of: placing the carbon nanofibers in a nitric acid solution with the mass concentration of 30-68% and treating for 1-10 hours at 10-50 DEG C; rinsing with deionized water and drying; thus, obtaining the carbon nanofibers containing carboxyl functional groups. The electrochemical treating process comprises the steps of: placing the carbon nanofibers in a nitric acid or phosphoric acid solution with the mass percentage concentration of 1-20% at 10-50 DEG C, or in ammonium carbonate or ammonium hydrogen carbonate, and treating with the apparent current density of 10-100A/m2 for 1-120 minutes to obtain the carbon nanofibers containing carboxyl or amino functional groups.

The invention discloses a method for extracting vanadium from vanadium slag clinker leached by ammonium carbonate. The method comprises the following steps of: calcifying and roasting vanadium slag of which the molar ratio of CaO to V2O5 is (2-3):1 at the temperature of between 700 and 900 DEG C, grinding the vanadium slag clinker, sieving, and leaching by an ammonium carbonate solution at the leaching temperature of between 60 and 98 DEG C for 30 to 120 minutes, filtering to obtain vanadium-containing leachate, performing vanadium deposition on the vanadium-containing leachate to obtain a vanadium finished product, wherein when the ammonium carbonate solution is leached, the concentration of the ammonium carbonate solution is between 200 and 800 g/L, and a liquid/solid ratio of the ammonium carbonate solution to the vanadium slag clinker is (5-30):1. According to the method, a leaching process is easy to operate and low in cost, and has low requirement on the equipment; and a leaching agent is low in cost and can be recycled, so that the production cost is reduced. By the method, the leaching rate of the vanadium is high, namely is over 90 percent, impurity elements and particularly a phosphorus element in the leachate are reduced, and the leaching rate of phosphorus is less than 10 percent.

PCT No. PCT/GB96/00488 Sec. 371 Date Oct. 22, 1997 Sec. 102(e) Date Oct. 22, 1997 PCT Filed Mar. 1, 1996 PCT Pub. No. WO96/26902 PCT Pub. Date Sep. 6, 1996A method for producing precipitated calcium carbonate by reacting an aqueous solution of calcium nitrate [Ca(NO3)2] with an aqueous solution of ammonium carbonate [(NH4)2CO3] and allowing calcium carbonate to precipitate from the resultant mixture containing nitrate [NH4NO3] in the mother liquor, the process being characterized in that: (i) the calcium nitrate [Ca(NO3)2)] solution utilized in the processes is prepared by slaking lime [CaO] in water in the presence of ammonium nitrate [NH4NO3] to form calcium nitrate [Ca(NO3)2] and ammonium hydroxide [NH4OH] in solution, filtering the solution to render it solids free, and heating the filtrate to dissociate the ammonium hydroxide [NH4OH] and to drive ammonia gas [NH3] from the solution; (ii) the ammonium carbonate (NH4)2CO3 solution utilized is prepared by absorbing ammonia gas [NH3] and carbon dioxide gas [CO2] in water, the ammonia gas preferably being derived from the step in (i) above in which the Ca(NO3)2 solution is heated; and (iii) the ammonium nitrate used is derived from the precipitation phase during which calcium carbonate is precipitated from the mother liquor containing ammonium nitrate.

Applicant has discovered an in situ method of preparing quaternary ammonium methocarbonate salts and quaternary ammonium alkylcarbonate salts in high yield from tertiary amines, methanol, and at least one of a cyclic carbonate, an aliphatic polyester (such as a polycarbonate), or an ester (such as a carbonate ester), and their subsequent conversion to quaternary ammonium bicarbonates, quaternary ammonium carbonates or both in a one-pot reaction. According to one embodiment of the invention, the method includes reacting an amine and methanol with at least one of a cyclic carbonate and an aliphatic polyester to yield a quaternary ammonium methocarbonate. This method does not produce or require the handling of corrosive quaternary ammonium hydroxides. Another embodiment is a method of preparing quaternary ammonium alkylcarbonate salts by reacting tertiary amines, methanol, and an ester. The quaternary ammonium methocarbonate or alkylcarbonate can be converted to the corresponding bicarbonate, carbonate, or mixture thereof by methods known in the art.

The invention relates to a method for preparing aluminum oxide and other products by aluminum-containing materials of bauxite, alunite, nepheline, fly ash, kaolin, coal gangue and clay. The method comprises the following steps: (1) crushing and grinding an aluminum-containing material, carrying out mixing and baking for the treated aluminum-containing material and ammonium bisulfate; (2) carryingout dissolution and filtering for the baked clinker to obtain a crude ammonium aluminum sulfate solution and aluminum extracting residue; (3) carrying out an iron precipitating treatment for the ammonium aluminum sulfate solution with the concentration more than 1 g/L by adopting a jarosite method, then carrying out an iron precipitating treatment by a goethite method, carrying out an aluminum precipitating treatment for the resulting solution, carrying out calcination for the resulting aluminium hydroxide to prepare aluminum oxide; (4) carrying out an iron precipitating treatment for the ammonium aluminum sulfate solution with the concentration less than 1 g/L by adopting the goethite method, and carrying out an aluminum precipitating treatment to prepare aluminum oxide, or adopting a recrystallization method to carry out purification, adopting a reaction of the ammonium aluminum sulfate crystal and a ammonium carbonate solution to precipitate the aluminum to obtain ammonium aluminumcarbonate, carrying out calcination for the ammonium aluminum carbonate, and adopting a Bayer method to treat the calcined ammonium aluminum carbonate to prepare sandy aluminum oxide; (5) washing anddrying the aluminum extracting residue, wherein the dried aluminum extracting residue is adopted as the silicon dioxide product.

The invention provides a simple, efficient and environment-friendly method for recovering valuable metals from a positive electrode material of a waste lithium ion battery; the method comprises the following steps of performing discharging of a salt solution; performing disassembling to separate a positive plate; performing smashing on the positive plate to separate a positive electrode material and an aluminum foil; performing mixed low-temperature roasting on the positive electrode material and a roasting agent ammonium sulfate and/or ammonium bisulfate; performing leaching on the roasted material and separating to obtain carbon and a lixivium; adding a precipitant into the lixivium, and regulating the pH value by using NH<3>-containing flue gas, performing deposition on other metals except Li, and carrying out solid-liquid separation; regulating the pH value of a filtrate by using the NH3-containing flue gas, adding ammonium carbonate or ammonium bicarbonate or pumping CO<2> gas, and carrying out lithium precipitation to obtain a lithium carbonate product. The preparation process is simple, the process conditions are mild, the time required by the process is short, a large amount of acid and alkali do not need to be consumed, and the cost is low; and in addition, recovery of the valuable metals and carbon from the positive electrode material can be effectively realized, themethod is green and environment-friendly, and a large amount of solid waste and wastewater cannot be generated.

The invention provides a silicon-based electrode with an adjustable pore structure; the porosity of the silicon-based electrode is 30%-60%; the pore structure of the silicon-based electrode is adjusted by controlling the compaction density of the electrode and adding a pore-forming additive, wherein the pore-forming additive is one or more of ammonium carbonate, ammonium hydrogen carbonate, ammonium acetate, ammonium nitrate and ammonium chloride. The invention further provides a preparation method of the silicon-based electrode. The porosity of the electrode is controlled by changing the compaction density, and the appropriate porosity can be consistent with the volume expansion rate of a high specific capacity silicon carbon negative electrode material in a lithium intercalation state, so that the integrity of the structure is kept in the circulation process of the electrode; and the volume change of silicon can be effectively buffered through the high-capacity silicon-based negativeelectrode with the variable pore structure, so that the diffusion speed of lithium ions and electrons is increased, the cycling stability of the electrode is obviously improved, and the large-currentdischarge performance of the electrode is improved.

An o-chloroaniline production method takes o-nitrochlorobenzene as raw material and is characterized in that the o-nitrochlorobenzene is dissolved in alcohol solvent in the presence of catalyst and additive and reacted with hydrogen at 10-120 DEG C and under 0.3-4.0 MPa; the reaction process is continuous reaction; after the completion of the reaction, the o-chloroaniline is obtained through treatment, wherein, the catalyst can be selected from one of the following: Ni/Al2O3, Raney Ni, Pt/C and Pd/C; while the additive can be selected from one, or two, or three of the following compounds: cyclohexylamine, ethylenediamine, ethanolamine, diethanolamine, triethanolamine, pyridine, liquid ammonia, ammonium bicarbonate, ammonium carbonate, sodium carbonate, sodium bicarbonate, potassium bicarbonate, potassium carbonate, potassium hydrogen phosphate, potassium dihydrogen phosphate, sodium hydrogen phosphate and sodium dihydrogen phosphate; the dosage of the catalyst takes up 0.05% to 20% of the mass of the o-nitrochlorobenzene; the dosage of the additive takes up 0. 5% to 20% of the mass of the o-nitrochlorobenzene; the alcohol can be methanol or ethanol; the dosage of alcohol takes up 30% to 150% of the dosage of the o-nitrochlorobenzene; the continuous reaction is realized through 1 to 6 tank reactors which are connected in series.

The invention relates to an alumina carrier and a preparation method thereof. The pore distribution of the alumina carrier is as follows: the pore volume of holes with the pore diameter of less than 10 nanometers accounts for less than 10 percent of the total pore volume; the pore volume of holes with the pore diameter between 10 and 50 nanometers accounts for 40 to 80 percent of the total pore volume; the pore volume of holes with the pore diameter between 100 and 1,000 nanometers accounts for 1 to 40 percent of the total pore volume; and the pore volume of holes with the pore diameter between 5,000 and 10,000 nanometers accounts for 1 to 20 percent of the total pore volume. The preparation method for the alumina carrier comprises: adopting a small quantity of starch and/or carbon black as crystal seeds, adopting a method of co-current flow first and swing then to prepare a serum containing aluminum hydroxide, using ammonium carbonate and/or ammonium bicarbonate to adjust the pH value, and finally preparing the alumina carrier. Alumina obtained by the method still maintains high strength under the condition of enlarged pore volume and pore diameter. The alumina carrier is particularly suitable to be a carrier of a residual oil hydrotreating catalyst.

The invention relates to a method for preparing high-sphericity-degree and large-particle cobaltosic oxide. The method includes the steps that at least one of cobalt chloride, cobaltous sulfate and cobalt nitrate serves as a raw cobalt salt material, and is purified and prepared to obtain a cobalt salt solution; at least one of ammonium carbonate, ammonium bicarbonate, sodium carbonate and sodium bicarbonate serves as a precipitant; a precursor is prepared with the solution direct precipitation method, and added into a reaction vessel with the concurrent adding method, the parameters of the injecting speed, the reaction temperature, the stirring speed, the PH value and the like of the solution are controlled, the batch-type crystallization technology and the kettle dividing technology are adopted, the chemical impurities of the precursor and the crystallinity degree, the granularity, the density and the like of crystals are effectively controlled, a precipitate precursor is synthesized, washing and centrifuging are carried out, then sintering is carried out twice, and the high-sphericity-degree and large-particle cobaltosic oxide is finally obtained. The method is simple in technology and low in cost, and the prepared cobaltosic oxide is high in cut-off voltage, tap density and stability.

The invention discloses melt-blown polypropylene as well as a preparation method and application thereof. The melt-blown polypropylene comprises following raw polypropylene resin, a degradation agent,an antioxidant and a lubricant, wherein the degradation agent is selected from one or more of hydrogen peroxide, sodium percarbonate, ammonium percarbonate and urea peroxide. The melt-blown polypropylene also comprises a nucleating agent selected from one or more of dibenzylidene sorbitol, aryl phosphate and nano scale amorphous silicon dioxide, wherein the degradation agent and the nucleating agent respectively account for 0.05-0.5% of the mass percentage of the raw materials. The preparation method comprises the following steps: premixing raw materials, stirring, then selectively adding a deodorant; and melting and granulating by an extruder to obtain the product. The invention also discloses an application of the melt-blown polypropylene in manufacturing melt-blown non-woven fabrics, melt-blown filter elements and sound-absorbing cotton. The melt-blown polypropylene has the advantages of low odor, high electret charge stability and the like.

The invention discloses a method for preparing alumina by using power plant fly ash, characterized by: grinding the fly ash, leaching with concentrated sulfuric acid to obtain an aluminum sulfate solution, precipitating aluminum sulfate crystals by concentrating and cooling, dissolving the aluminum sulfate crystals with hydrochloric acid, then letting an HCl gas in the solution to saturate the solution to precipitate AlCl3-6H2O crystals, reacting the AlCl3-6H2O crystals with an ammonium hydroxide solution or liquid ammonia or an ammonium bicarbonate solution or an ammonium carbonate solution to obtain an aluminium hydroxide and ammonium chloride solution, calcining aluminium hydroxide to obtain alumina, displacing ammonium chloride by using magnesium oxide to obtain ammonia gas and magnesium chloride, and hydrolyzing magnesium chloride to obtain magnesium oxide and hydrochloric acid for recycling.

The invention discloses a latent epoxy resin curing-foaming agent and a method for preparing the same and belongs to the technical field of plastic additives. A commercialized amine curing agent for epoxy resin is utilized to absorb and fix carbon dioxide, so as to synthesize a series of novel alkyl ammonium carbamate compounds or alkyl ammonium carbonate compounds. The alkyl ammonium carbamate compounds or the alkyl ammonium carbonate compounds are stable at normal temperature and can release carbon dioxide gas and the amine curing agent again when heated, so as to effectively foam and cure the epoxy resin, and the latent epoxy resin curing-foaming agent is environmentally friendly.

The invention relates to a preparation method of a supported nano TiO2 photocatalysis material with a diatomite filter aid as a carrier. The preparation method comprises the steps of adding water into the diatomite filter aid, stirring the mixture to prepare slurry and adding acid to regulate pH value; then cooling the slurry, then sequentially adding TiCl4 solution and ammonium sulphate for reaction, heating reaction liquid to a certain temperature, then adding ammonium carbonate solution to regulate the pH value of solution and ageing the reaction liquid for a period of time; and finally filtering, washing, drying and calcining the reaction product, thus obtaining the diatomite filter aid supported nano TiO2 photocatalytic material. The supported nano TiO2 photocatalytic material has excellent photocatalytic performance under ultraviolet light and visible light and has more than 80% of degradation removal rate on formaldehyde in 24 hours under a fluorescent lamp.

This invention relates to a method for treating diluted ammonium sulfate wastewater. The method solves the problems of high solid waste and organic nitrile impurity contents, low ammonium sulfate concentration, and difficult ammonium sulfate recovery. The method comprises: (1) removing solid impurities from diluted ammonium sulfate wastewater, adjusting the pH value to 6.5-7.5, performing flash evaporation, stripping or rectification, removing lightweight organic fractions at the overhead, collecting heavy fractions at the bottom, and extracting the rest ammonium sulfate wastewater at 1st-5th theoretical plates from the overhead; (2) sending the rest ammonium sulfate wastewater to ion exchange reaction, and removing NH4+; (3) treating regenerated liquid of the ion exchange resin with Ca(OH)2 aqueous solution to produce CaSO4 and diluted ammonia solution, performing solid-liquid separation, reacting CaSO4 and diluted ammonia solution with CO2 to obtain ammonium carbonate or ammonium hydrogen carbonate.

The invention discloses a method for preparing alumina from low-grade bauxite by acid leaching, characterized by: grinding the low-grade bauxite, leaching with concentrated sulfuric acid to obtain an aluminum sulfate solution, precipitating aluminum sulfate crystals by concentrating and cooling, dissolving the aluminum sulfate crystals with hydrochloric acid, then introducing an HCl gas in the solution to saturate the solution to precipitate AlCl3.6H2O crystals, reacting the AlCl3.6H2O crystals with an ammonium hydroxide solution or liquid ammonia or an ammonium bicarbonate solution or an ammonium carbonate solution to obtain aluminium hydroxide and an ammonium chloride solution, calcining aluminium hydroxide to obtain alumina, carrying out displacement reaction on ammonium chloride and magnesium oxide to obtain ammonia gas and magnesium chloride, and hydrolyzing magnesium chloride to obtain magnesium oxide and hydrochloric acid for recycling.

The invention relates to methods for coproducing sodium carbonate and ammonium sulfate from melamine tail gas and mirabilite. The method for producing the sodium carbonate comprises the following steps of: a, providing a sodium sulfate water solution; b, introducing melamine tail gas into the sodium sulfate water solution to form an ammonium carbonate-sodium sulfate water solution; c, introducing carbon dioxide into the ammonium carbonate-sodium sulfate water solution to obtain a suspension serous fluid of sodium bicarbonate crystals; and d, carrying out solid and liquid separation on the suspension serous fluid to obtain sodium bicarbonate and a mother solution I, calcining sodium bicarbonate solid to obtain the sodium carbonate. The method further comprises the following steps of: e, adding the mother solution I into an ammonia stilling tower, heating, forming tower top mixed gas containing ammonia and carbon dioxide, generating a deamination solution in the tower; f, evaporating the deamination solution for dewatering to obtain sodium sulfate crystals and a mother solution II; g, cooling the mother solution II for crystallizing to obtain Na2SO4.(NH4)2SO4.4H2O salt crystals and a mother solution III; and h, evaporating the mother solution III for dewatering, and separating out ammonium sulfate crystals. The methods have the advantages of high utilization rate of raw materials and low energy consumption.