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2914 results about "Calcium nitrate" patented technology

Calcium nitrate, also called Norgessalpeter (Norwegian saltpeter), is an inorganic compound with the formula Ca(NO₃)₂. This colourless salt absorbs moisture from the air and is commonly found as a tetrahydrate. It is mainly used as a component in fertilizers but has other applications. Nitrocalcite is the name for a mineral which is a hydrated calcium nitrate that forms as an efflorescence where manure contacts concrete or limestone in a dry environment as in stables or caverns. A variety of related salts are known including calcium ammonium nitrate decahydrate and calcium potassium nitrate decahydrate.

Technological process for producing high concentration nitric-phosphate fertilizer

The invention discloses a technique method for producing high-concentration nitric phosphate, which comprises the following steps of: adding nitric acid into phosphorus ore for acidolysis, depositing and separating acid non-soluble substance, freezing and crystallizing calcium nitrate, filtering the calcium nitrate, neutralizing the mother liquid, vaporization, pelleting and drying. The invention is characterized in that: a step of thoroughly removing the calcium of the mother liquid is arranged between the steps of filtering the calcium nitrate, and neutralizing the mother liquid. The steps comprise the following steps of: I) thoroughly removing the calcium of the mother liquid and adding sulfuric acid or ammonium sulfate; the calcium ions and the sulfate ions in the mother liquid generate dihydrate calcium sulfate crystal; II) the grading processing of reaction slurry: employing a grading device to carry out grading processing to the reaction slurry; returning the reaction slurry provided with small grain calcium sulfate to the mother liquid for thoroughly removing the calcium, and feeding the reaction slurry provided with large grain calcium sulfate to the calcium sulfate for filtering; and III) filtering and washing the filtering reaction slurry of calcium sulfate by a filter, feeding the primary filtrate and the primary lavage fluid into the working procedure of neutralizing, and returning the secondary lavage fluid to the filter. The invention has the advantage of using middle-low quality phosphorite to prepare the high-concentration nitric phosphate.
Owner:TIANJI COAL CHEM IND GROUP +1

Preparation method and application method of grape special fertilizer

The invention relates to preparation method and application method of a grape special fertilizer, wherein the preparation method comprises the following steps: preparing an I-type fertilizer by taking the following ingredients in parts by weight: 30-40 parts of urea, 20-30 parts ammonium phosphate, 15-30 parts of potassium sulphate, 1-3 parts of humic acid, 1-3 parts of excrement, 1-5 parts of synergist, 0.1-1.0 part of ferrous sulphate, 0.1-0.8 part of zinc sulfate, 0.1-0.6 part of manganese sulphate, 0.1-0.6 part of borax, 0.1-0.4 part of copper sulfate, 3-7 parts of plaster and 3-13 parts of bentonite; preparing an II-type fertilizer by taking the following ingredients in parts by weight: 7-15 parts of urea, 25-35 parts ammonium phosphate, 35-45 parts of potassium sulphate, 1-3 parts of humic acid, 1-5 parts of excrement, 2-5 parts of synergist, 0.1-1.0 part of ferrous sulphate, 0.1-0.8 part of zinc sulfate, 0.1-0.6 part of manganese sulphate, 0.1-0.6 part of borax, 0.1-0.4 part of copper sulfate, 3-7 parts of plaster and 3-13 parts of bentonite; and blending, spraying, pelleting and drying at lower temperature to obtain the product. The application method of the fertilizer comprises the following steps: taking an organic fertilizer and the II-type fertilizer as a base fertilizer; applying the I-type fertilizer before blossom, applying the II-type fertilizer in the young fruit development period, and meanwhile, respectively spraying monopotassium phosphate and rare earth mixed liquid once on the leaf surfaces; and spraying calcium nitrate or calcium acetate to enhance the storage resistance property before picking.
Owner:新疆满疆红农资化肥科技有限公司

Calcium carbonate precipitation method

PCT No. PCT/GB96/00488 Sec. 371 Date Oct. 22, 1997 Sec. 102(e) Date Oct. 22, 1997 PCT Filed Mar. 1, 1996 PCT Pub. No. WO96/26902 PCT Pub. Date Sep. 6, 1996A method for producing precipitated calcium carbonate by reacting an aqueous solution of calcium nitrate [Ca(NO3)2] with an aqueous solution of ammonium carbonate [(NH4)2CO3] and allowing calcium carbonate to precipitate from the resultant mixture containing nitrate [NH4NO3] in the mother liquor, the process being characterized in that: (i) the calcium nitrate [Ca(NO3)2)] solution utilized in the processes is prepared by slaking lime [CaO] in water in the presence of ammonium nitrate [NH4NO3] to form calcium nitrate [Ca(NO3)2] and ammonium hydroxide [NH4OH] in solution, filtering the solution to render it solids free, and heating the filtrate to dissociate the ammonium hydroxide [NH4OH] and to drive ammonia gas [NH3] from the solution; (ii) the ammonium carbonate (NH4)2CO3 solution utilized is prepared by absorbing ammonia gas [NH3] and carbon dioxide gas [CO2] in water, the ammonia gas preferably being derived from the step in (i) above in which the Ca(NO3)2 solution is heated; and (iii) the ammonium nitrate used is derived from the precipitation phase during which calcium carbonate is precipitated from the mother liquor containing ammonium nitrate.
Owner:PRETORIA PORTLAND CEMENT COMPANY +1

Method for producing dehydrated calcium sulfate whisker

The invention provides a method for producing dehydrated calcium sulfate whisker, comprising: using copper, lead, zinc, aluminium, nickel, cobalt, stannum, non-ferrous metal secondary resource cycle utilizing, calcium nitrate solution produced in treating process of electroplating waste, calcium chloride solution, or mixed water solution of calcium nitrate and calcium chloride as raw material, using sulfuric acid as calcium ion precipitant, adding whisker shape regulating agent, controlling reaction condition, regenerating aqua fortis or hydrochloric acid lixiviant, and simultaneously producing ultralong and big length to diameter ratio calcium sulphate dihydrate whisker. After calcium sulphate dihydrate whisker is deposited from calcium nitrate solution, calcium chloride solution or the mixed solution of calcium nitrate and calcium chloride are deposited, the water solution is translated to be nitric acid solution, hydrochloric acid solution or a mixed solution of nitric acid and hydrochloric acid, returning back to leaching out or treating process for processing non-ferrous metal mineral substance, non-ferrous metal secondary resource or electroplating remove. The calcium sulphate dihydrate whisker is treated by microwave heating, forming calcium sulfate hemihydrate or anhydrous sulphate of calcium after dehydration.
Owner:BEIJING GENERAL RES INST OF MINING & METALLURGY

Recycling method for treating stainless steel pickling acid pickle and wastewater

The invention relates to a recycling method for treating stainless steel pickling acid pickle and wastewater, belonging to the field of treatment of industrial acid pickle and wastewater in iron and steel and metallurgy industries. The acid pickle and wash wastewater generated during stainless steel pickling are collected according to quality and category and the acid pickle is subjected to acid recycling. The acid pickle and wash wastewater are treated through fractional precipitation by adopting lime as a neutralizing agent. Calcium sulfate or calcium fluoride or a mixture of calcium sulfate and calcium fluoride is obtained through precipitation under the acidic condition (the pH value is equal to 3.0+/-0.5) and can serve as a cement filler or a material for brickmaking or a building material after heavy metal polluted calcium salt is removed. A metal hydroxide is obtained through precipitation under the alkaline condition (the pH value is not more than 9.0) and can serve as a stainless steel smelting raw material as the quality of the product is better than that of the imported laterite-nickel ores in China. The calcium nitrate containing wastewater obtained after the acid pickle is treated is not needed to be discharged or treated and can be recycled. After being treated, the wash wastewater can be reused as production line wash water.
Owner:上海博士高环保科技有限公司

Method for preparing nano hydroxyapatite powder

The invention relates to a method for preparing nano hydroxyapatite powder, belonging to the field of the biomedical material. The method for preparing the nano hydroxyapatite powder comprises the following steps: adding the organic polymer of polyethylene glycol to the initial reactants of calcium nitrate and diammonium phosphate solution to adjust and control the morphologies of the products of reaction; adding aqueous ammonia to adjust the pH values of the products of reaction, and making the aqueous ammonia react with the products of reaction at different water bath temperature to synthesize nano hydroxyapatite precipitate, wherein the agglomeration of the synthesized nano hydroxyapatite precipitate can be inhibited by the polyethylene glycol functioning as the dispersant; freezing and drying synthesized nano hydroxyapatite precipitate slurry to obtain dry nano hydroxyapatite powder which contains by-products of reaction and polyethylene glycol, and calcinating the dry nano hydroxyapatite powder at high temperature to remove the by-products of reaction and the polyethylene glycol which are contained in the dry nano hydroxyapatite powder to obtain the nano hydroxyapatite powder which is in the shape of the ball or the rod and in the particle size of 10-100 nm and has high yield and good dispersion. The method for preparing the nano hydroxyapatite powder is simple, needs short preparing period, causes no poison and pollution and is suitable for industrial production.
Owner:SICHUAN UNIV

Mixed molten salt as heat transfer and storage medium low in melting point

The invention relates to a formula of a mixed molten salt for medium-high temperature heat transfer and storage, and belongs to the physical heat transfer and energy storage technology in innovative and high technologies. The mixed molten salt comprises components in a ratio as follows: 10wt% of calcium nitrate, 60-70 wt% of potassium nitrate, 10-20 wt% sodium nitrate and 10wt% of sodium nitrite; the melting point of the mixed molten salt is about 130 DEG C, which is reduced by nearly 90 DEG C relative to solar salt and is reduced by about 15 DEG C relative to Hitec salt; and the thermal decomposition temperature thereof reaches above 650 DEG C. Sodium nitrate in the molten salt is changed into lithium nitrate, and the specific component ratio is as follows: 18-20wt% of calcium nitrate, 50-55 wt% of potassium nitrate, 9-10 wt% sodium nitrate and 18-20wt% of sodium lithium nitrate; after the component ratio is changed, the melting point of the mixed molten salt is about 90 DEG C, which is reduced by nearly 130 DEG C relative to the solar salt and is reduced by about 50 DEG C relative to the Hitec salt; and the thermal decomposition temperature thereof reaches above 600 DEG C. 10wt% of sodium carbonate is added continuously, then the melting point is raised to about 110 DEG C, while the decomposition temperature is raised by nearly 20 DEG C.
Owner:河北井矿新能源科技有限公司

Water culture nutrient solution prescription of lettuce and preparation method of water culture nutrient solution prescription

The invention discloses a water culture nutrient solution prescription of a lettuce and a preparation method of the water culture nutrient solution prescription, and belongs to the technical field of plant soilless culture of the agricultural science. The nutrient solution prescription of the lettuce comprises the following components: a fertilizer A composed of 584.23g/T of calcium nitrate, 421.34g/T of potassium nitrate and 47.8g/T of ammonium nitrate; a fertilizer B composed of 182.4g/T of monopotassium phosphate and, 256.23g/T of magnesium sulfate; a fertilizer C composed of 16.8g/T of FeEDTA (Ethylene Diamine Tetraacetic Acid), 3g/T of boric acid, 2g/T of manganese sulfate, 0.25g/T of zinc sulfate, 0.85g/T of copper sulfate, and 0.38g/T of ammonium molybdate; hormone composed of 0.1g/T indolebutyric acid of or 0.1g/T of naphthylacetic acid; a bactericide composed of 15g/T of carbendazim; and nutrient solution pH (Potential Of Hydrogen) adjusting acid composed of 200ml/T of phosphoric acid or 150g/T of citric acid. The prescription is nutritionally balanced, so that the demand of the lettuce to nutrition can be met, the amount of used nutrient elements is decreased at the same time, the output of the lettuce is increased, and the fertilizers are saved; and the prescription effectively decreases the contents of nitrates in the lettuce under the water culture, improves the quality of the lettuce, enables the simplification of the complicated processes in preparation based on the demand of the actual operation, and is suitable for being used for meeting the requirements of industrialization production.
Owner:NORTHWEST A & F UNIV

Calcium silicate hydrate gel solution early strength agent and preparation method thereof

The invention discloses a calcium silicate hydrate gel solution early strength agent and a preparation method thereof, and relates to the technical field of construction material production. The early strength agent and the method are used for solving problems of complicated preparation process, high cost, storage difficulty, and poor early strength effect of traditional calcium silicate hydrate powder. The calcium silicate hydrate gel solution early strength agent comprises a calcareous material, a siliceous material, a gel dispersant, and water. A weight ratio of the calcareous material to the siliceous material is 0.3-3:1. A weight ratio of water to the total of the calcareous material and the siliceous material is 5-30:1. The mass percentage of the gel dispersant is 0.1-2.0%. The preparation method of the early strength agent comprises the following steps: reaction materials are weighed; a sodium silicate water solution and a calcium nitrate water solution are respectively prepared; the two are mixed and are subjected to a reaction, such that a gel mixture solution is obtained; suction filtration is carried out; and water and the dispersant are added for re-dispersion. The early strength agent is uniform and stable, and is convenient to store. The early strength agent is highly convenient to use, and has a good early strength effect. With the early strength agent, an alkali-aggregate reaction risk can be effectively reduced.
Owner:SHANGHAI CONSTRUCTION GROUP

Calcium silicate hydrate gel solution early strength agent and preparation method thereof

InactiveCN104402288ALong term storageMaintain dispersion uniformityCalcium silicateCalcium in biology
The invention discloses a calcium silicate hydrate gel solution early strength agent and a preparation method thereof, and relates to the technical field of construction material production. The early strength agent and the method are used for solving problems of complicated preparation process, high cost, storage difficulty, weighing difficulty, and poor early strength effect of traditional calcium silicate hydrate powder. The calcium silicate hydrate gel solution early strength agent comprises a calcareous material, a siliceous material, a gel dispersant, and water. A weight ratio of the calcareous material to the siliceous material is 0.3-3:1. A weight ratio of water to the total of the calcareous material and the siliceous material is 5-30:1. The mass percentage of the gel dispersant is 0.01-0.50%. The preparation method of the early strength agent comprises the following steps: reaction materials are weighed; a sodium silicate water solution and a calcium nitrate water solution are respectively prepared; the gel dispersant is respectively added into the solutions; and the two solutions are mixed and allowed to react for a certain period of time. The early strength agent is convenient to store, transport and weigh, and have good product stability. With the early strength agent, cement-based material early strength can be effectively improved.
Owner:SHANGHAI CONSTRUCTION GROUP

Method for producing high-water solubility nitrophosphate fertilizer by phosphorite nitrolysis and calcium nitrate freezing

The invention discloses a method for producing high-water solubility nitrophosphate fertilizer by phosphorite nitrolysis and calcium nitrate freezing. The high-water solubility nitrophosphate fertilizer is prepared from the processes of phosphorite nitrolysis, fluorine removal, calcium nitrate freezing separation, further removal of calcium in ammonium sulfate, ammonia liquor neutralization and deposition removal of impurities, and evaporation concentration and crystallization. Specially, the method for producing high-water solubility nitrophosphate fertilizer by phosphorite nitrolysis and calcium nitrate freezing comprises the following steps of 1, acidolysis, 2, fluorine removal, 3, calcium nitrate freezing crystallization, 4, double decomposition removal of calcium in ammonium sulfate,5, neutralization and deposition removal of impurities, 6, evaporation concentration and crystallization, and 7, phosphogypsum transformation. The high-water solubility nitrophosphate fertilizer prepared by the method has a dissolution rate great than or equal to 99.9% in water, wherein nitrate nitrogen is easy for be absorbed by drops, satisfies requirements of a few commercial crops, has a highutilization rate, and improves a crop yield by 8 to 25% and crop quality. The method reduces waste discharge, is environmentally friendly, can be utilized for structure adjustment and product upgradeand update of the traditional phosphorus chemical industry, and has good economic and environmental benefits.
Owner:GUIZHOU RES INST OF CHEM IND

Compound microbial preparation for treating black and odorous rivers through strengthened calcium nitrate

The invention relates to a compound microbial preparation for treating black and odorous rivers through strengthened calcium nitrate and a preparation method thereof. The use amount of calcium nitrate is reduced, and the time for treating the black and odorous rivers is shortened. The compound microbial preparation is prepared from 40-80 parts of thiobacillus denitrificans and thiocapsa roseoppersicina mixed powder, 10-60 parts of composite bacillus subtilis powder and 10-60 parts of yeast and lactic acid bacterium mixed powder. By means of the preparation, sulfide in black and odorous bottom sludge, organic matter and strains suitable for growing in the black and odorous bottom sludge are screened and degraded in a targeted mode; by means of thiobacillus denitrificans with efficient hydrogen sulfide degrading and denitrification capacity, sulfur-oxidizing bacteria of thiocapsa roseoppersicina with efficient hydrogen sulfide and ammoniacal nitrogen degrading capacity, bacilli rich in protease, amylase, cellulose and other enzyme systems, yeast and lactic acid bacteria, a small amount of calcium nitrate and the compound microbial preparation are thrown into the black and odorous rivers so that water quality of the black and odorous rivers can be quickly improved, the black and odorous bottom sludge can be removed quickly, and the thickness and the organic matter content of the bottom sludge can be quickly reduced.
Owner:胡艳晖

P-Ca-V composite phosphating solution on magnesium alloy surface and chemical conversion processing method

The invention relates to a composite phosphating solution of P-Ca-V on the surface of a magnesium alloy and a method for chemical conversion treatment. The solution is characterized in that each liter of the composite phosphating solution comprises the following compositions: 4 to 20 milliliters of 85 percent phosphoric acid of, 5 to 30 grams of sodium dihydrogen phosphate, 10 to 40 grams of calcium nitrate, 0.5 to 10 grams of benzene sulfonic acid sodium salt, 0.5 to 5 grams of ammonium metavanadate, and the balance being water. The method comprises the following steps: pre-degreasing, degreasing, secondary water washing, acid washing, secondary water washing, alkaline etching, secondary water washing, chemical transformation, secondary water washing, pure water washing, and drying. Taking an AZ91D magnesium alloy as an example, 48 hours after a corrosion resistance salt spray test after the treatment by the method of the invention, the corrosion area of the AZ91D magnesium alloy is less than 1 percent; the paint film adhesive force is at 0 level by a grid method and is obviously superior to the performance of a chromate conversion coating; and the formed chemical conversion coating does not contain crystal water. The composite phosphating solution has the synergistic reaction of Ca and V, as well as the functions of a corrosion inhibitor and a wetting agent of the benzene sulfonic acid sodium salt.
Owner:嘉兴中科亚美合金技术有限责任公司
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