1611 results about "Phosphogypsum" patented technology

The invention relates to a high-performance solid-waste-based offshore wind power grouting material and a preparation method thereof, and a solid-waste-based cementing material is a hydraulic cementing material prepared by processing and grinding one or more solid wastes such as water-quenched blast furnace slag, steel slag, desulfurized gypsum, fly ash, red mud, tailings, carbide slag and phosphogypsum as raw materials according to a certain proportion. The solid waste-based cementing material is adopted to replace 525 Portland cement, the prepared grouting material product is excellent in performance, the carbon emission of the grouting material product is remarkably reduced, the cost is also reduced, resource utilization of industrial solid waste is facilitated, meanwhile, the performance of the grouting material is obviously improved, and the grouting material is suitable for popularization and application. The advantages of ultrahigh strength, elasticity modulus, high flowability, low shrinkage and high durability are realized.

The invention relates to the technical field of filling materials, and particularly discloses an ardealite-based high-strength anti-seepage filling material and a preparation process thereof, the ardealite-based high-strength anti-seepage filling material comprises 50%-65% of pretreated ardealite, 15%-25% of Portland cement, 5%-15% of superfine slag powder, 5%-10% of electrolytic manganese residues, 5%-8% of silica fume, 3%-6% of metakaolin, 2%-4% of a composite alkali activator and 0.5%-1.2% of a polycarboxylic acid water reducer, 0.3%-0.8% of an organic silicon water repellent and 0.05%-0.1% of cellulose ether; according to the invention, through chemical reaction of Mn < 2 + > in the electrolytic manganese residue and SO4 < 2-> in the phosphogypsum, micron-sized manganite crystals (MnAl2 (SO4) 4. 22H2O) are generated to actively fill internal micro-cracks of the material, so that a filling body is endowed with a self-repairing function and the impermeability is improved, and a composite alkali activator composed of NaOH and water glass is used for synergistically activating potential gelling activity of the superfine slag powder and the silica fume, so that the self-repairing filling material is prepared. And the formation of hydration products is accelerated, and 0.3-0.5 T of pulsed magnetic field is applied in the stirring process, so that the manganite crystals are guided to orderly grow along the expected stress direction of the filling body, and the compressive strength is improved.

The invention provides a slag ardealite-based solid waste cementing material as well as a preparation method and application thereof, and belongs to the technical field of building materials. The slag ardealite-based solid waste cementing material is prepared from the following raw materials in percentage by mass: 45-55% of slag, 40-50% of ardealite, 0.5-5% of carbide slag and 2-10% of silica fume, the water-cement ratio is 0.35-0.50, the slag, the ardealite, the carbide slag and the silica fume are uniformly mixed, then water is added, stirring is performed to obtain slurry, and the slurry is uniformly mixed to obtain the slag ardealite-based solid waste cementing material. Pouring into a mold, standing, demolding, and carrying out standard curing to obtain the slag ardealite-based solid waste cementing material. According to the invention, two calcium-containing solid wastes of slag and ardealite are used as main raw materials, carbide slag is used as an alkaline activator, silica fume is added to further improve the performance of the solid waste cementing material, the cement has the characteristics of low carbon, low cost, high performance and the like, and environmental and ecological problems caused by accumulation of a large amount of solid waste materials are reduced at the same time.

The invention discloses a process and system for recovering phosphorus and fluorine from ardealite leachate, which comprises the following steps: feeding the ardealite leachate into an induced crystallization reactor for induced crystallization, discharging generated large-particle fluorapatite crystals from a crystal discharge port at the bottom of the induced crystallization reactor, and collecting and recycling; aluminum hydroxide flocs and fine-particle fluorapatite crystals enter a cyclone separator along with the effluent, the fine-particle fluorapatite crystals are separated and then flow back to the induced crystallization reactor, the aluminum hydroxide flocs form precipitates in the flocculation sedimentation tank through flocculation to be removed, and the effluent of the flocculation sedimentation tank enters a multi-stage treatment system. According to the method disclosed by the invention, fluorine and phosphorus in the phosphogypsum leachate are recovered together, the recovered fluorapatite finished product is high in purity and can be recycled, and the amount of chemical sludge is also greatly reduced, so that the treatment cost of the sludge is reduced.

The present invention belongs to the field of resource utilization of building materials and solid waste, and relates to a red-mud-based cementing material based on efficient drying, component homogenization and activity improvement, and a preparation method therefor. The preparation method comprises: adding a filter aid to red mud to carry out sedimentation, then subjecting same to filter pressing until the water content is 14-16%, then drying the solid material, which has been subjected to filter pressing, until the water content is 4% or below, and finally grinding same to obtain the product. The filter aid comprises the following raw materials: 10-30 parts of polyaluminum chloride, 5-15 parts of polyaluminum sulfate, 1000-1200 parts of blast furnace slag or fly ash, 700-900 parts of steel slag, 400-600 parts of carbide slag or alkaline residues, and 300-400 parts of desulfurized gypsum or phosphogypsum or fluorgypsum. By means of the present invention, the dehydration efficiency of red mud can be improved, the red-mud-based cementing material can also be prepared in one step; the preparation process for the red-mud-based cementing material is simplified; and the prepared red-mud-based cementing material has the advantages of a high mechanical strength, high durability and erosion resistance.

The invention relates to the technical field of building materials, and particularly discloses a lightweight high-strength waterproof gypsum board and a preparation method thereof, the lightweight high-strength waterproof gypsum board comprises alpha-type high-strength gypsum, phosphogypsum, gradient lightweight aggregate, hydrophobic fiber, temperature-sensitive waterproof capsule and the like. The preparation method comprises the following steps: preparing the hydrophobic fiber, the gradient lightweight aggregate and the temperature-sensitive waterproof capsule, dry-mixing the components, mixing the dry-mixed components with water to form slurry, and pouring and curing. Lightweight and high strength are realized through cooperation of the gradient lightweight aggregate and the hydrophobic fiber, and the temperature-sensitive waterproof capsule releases components to fill pores during curing, so that the problem of insufficient early-stage waterproof performance is solved; the prepared gypsum board has the advantages of light weight, high strength, good waterproofness and durability.

The invention discloses ardealite-based concrete and a preparation method thereof, and belongs to the technical field of building materials. The ardealite-based concrete is prepared from the following raw materials in parts by weight: 40 to 60 parts of ardealite powder, 10 to 15 parts of cement, 8 to 10.5 parts of slag powder, 5 to 7 parts of fly ash, 4 to 6 parts of desulfurized fly ash, 5 to 10 parts of natural sand, 10 to 15 parts of ardealite-based artificial aggregate, 3 to 5 parts of eggshell powder, 1.5 to 3 parts of nano silicon dioxide, 0.5 to 1.5 parts of a water reducing agent, 0.05 to 0.2 part of a retarder, 0.1 to 0.5 part of an exciting agent and 0.3 to 1 part of an antifreeze agent. According to the invention, through process innovation of multi-component collaborative design and gradient aggregate doping, the technical bottlenecks of low strength, poor durability, high environmental protection risk and the like of traditional ardealite concrete are overcome while large-scale resource utilization of ardealite is realized, and a new thought is provided for high-valued utilization of industrial solid wastes.

The invention discloses a plastic hollow plate and a manufacturing method thereof, the plastic hollow plate comprises the following components by weight: 30%-60% of a polypropylene matrix and 40%-70% of phosphogypsum powder, and polypropylene provides thermoplastic formability and toughness. The preparation method specifically comprises the following steps: 1) pretreating ardealite; 2) melt blending granulation; (3) forming a hollow plate; and 4) post-processing. The ardealite hollow plate has the advantages that the ardealite filling amount is increased, meanwhile, the bending strength and impact strength of a traditional hollow plate are improved, and the performance is improved by 20% or above compared with that of a traditional hollow plate with the same filling amount; the moisture content of the pretreated phosphogypsum is less than 6%, so that bubbles in the processing process are avoided, and the interface bonding strength is improved; the comprehensive utilization rate of industrial byproduct phosphogypsum is improved, and the production cost is reduced.

The invention discloses high-performance fluid-state solidified soil for backfill based on composite ardealite of building residue soil, which is prepared by taking the building residue soil as a core raw material, taking a compound of a polycarboxylic acid water reducer and hydroxypropyl methyl cellulose as a fluidization regulator, and mixing the fluidization regulator and the building residue soil to prepare the high-performance fluid-state solidified soil for backfill. Superfine slag powder, fly ash, nano silicon dioxide, metakaolin and ardealite are used as curing agents, so that the fluid-state solidified soil with strong performance is obtained. Through the synergistic effect of all the components and innovative processes such as liquid nitrogen low-temperature grinding, nano material compounding and a segmented vacuum stirring process, the effect that the ultrahigh strength of the construction waste soil reaches 7.5 MPa within 14 days is achieved for the first time and is improved by 40% or above compared with that of conventional solidified soil, and the industrial problem that traditional waste soil is insufficient in solidification strength is solved; and collaborative optimization of strength and fluidity is realized. Meanwhile, efficient resource utilization of the construction waste is achieved, land occupation and environmental pollution caused by muck landfill are greatly reduced, and the requirement for green and sustainable development is met.

The invention discloses a road cementing material based on bulk solid wastes and a preparation method thereof, and belongs to the field of geopolymer cementing materials. The material is prepared from 35-38 parts of fly ash, 15-18 parts of acid-washed red mud, 22-25 parts of carbide slag, 20-23 parts of phosphogypsum, 5-8 parts of rice hull ash, 6-9 parts of a water reducing agent and water, and the water-binder ratio is (0.4-0.5): 1. Wherein the pickling red mud is treated by 5-6% dilute sulphuric acid (pH is 8-9, and heavy metal is reduced by 30%), and the rice hull ash (SiO2 is greater than or equal to 85%) and the nano silicon dioxide (10-30nm) synergistically optimize the microstructure. The 28-day compressive strength of the material is larger than or equal to 35 MPa, the load cycle strength loss rate is smaller than or equal to 5%, the CO2 emission amount is 62 kg / t, the heavy metal leaching concentration is lower than the national standard by 50%, and the cost is only 31.6% of that of traditional cement. According to the invention, efficient synergistic utilization of four solid wastes of fly ash, red mud, carbide slag and ardealite is realized, and the concrete has the characteristics of high strength, low pollution, salt corrosion resistance and the like, is suitable for heavy-duty road base and severe cold area engineering, and has remarkable environmental protection and economic values.

The invention discloses a method for regulating the length-diameter ratio of calcium sulfate hemihydrate whiskers prepared from ardealite, and belongs to the field of ardealite resource utilization. According to the invention, carbohydrates, alcohols and other substances containing hydroxyl groups are used as the crystal modifier, and the calcium sulfate hemihydrate whisker is prepared by regulating and controlling phosphogypsum through a normal-pressure hydrothermal method, so that the length-diameter ratio of the whisker is regulated and controlled within a certain range. The method solves the problems that the length-diameter ratio of the whisker in the calcium sulfate hemihydrate whisker product prepared from ardealite is not uniform and cannot be regulated and controlled, the preparation process is tedious, the corrosivity is strong due to excessive salt solution in the reaction system, and the waste liquid has great harm to the environment, and has a good application prospect.

The invention relates to the technical field of building materials, and particularly discloses a slag and ardealite synergetic activated gypsum batten and a preparation method thereof.The slag and ardealite synergetic activated gypsum batten comprises pretreated ardealite, superfine slag powder, a composite exciting agent, reinforced fibers, self-repairing microcapsules, a foaming agent and water, and the composite exciting agent is formed by compounding nano SiO2, CaO and metakaolin; the preparation method comprises the following steps: mixing nano silica sol and a lignin solution, performing spray drying, and performing heat treatment to obtain the self-repairing microcapsule; the preparation method comprises the following steps: carrying out dry mixing on pretreated phosphogypsum, superfine slag powder and a composite exciting agent, adding water, adding reinforced fibers, self-repairing microcapsules and a foaming agent, stirring to form slurry, carrying out injection molding on the slurry, and carrying out stepped maintenance of pre-maintenance, main maintenance and carbonization treatment to prepare the modified red mud-pretreated phosphogypsum-based self-repairing self-repairing composite phosphogypsum-based self-repairing self-repairing composite phosphogypsum-based self-repairing composite phosphogypsum-based self-repairing composite phosphogypsum-based self-repairing composite phosphogypsum. The composite excitant synergistically activates the activity of the slag, and is matched with the reinforced fibers, the self-repairing microcapsules and stepped curing, so that solid waste resource utilization is realized, the compression resistance, bending resistance and impact resistance of the batten are improved, and the environment-friendly and high-performance effects are achieved.

The invention provides an all-solid waste geopolymer grouting material and a preparation method thereof, and relates to the technical field of solid waste resource utilization and geopolymer grouting material preparation. The all-solid waste geopolymer grouting material comprises the following raw materials in parts by weight: 100-200 parts of an all-solid waste mixture, 40-50 parts of an alkaline activator, 0.1-0.5 part of an early strength agent, 0.5-1 part of a water reducing agent, 3-7 parts of a modifier and 70-90 parts of water, the all-solid waste material comprises slag powder, steel slag powder, phosphogypsum and fly ash; the modifying agent is prepared from aluminum dihydrogen phosphate, vinyl triacetoxysilane and ethylenediamine terminated polyethyleneimine. The all-solid waste geopolymer grouting material provided by the invention has the characteristics of good working performance, high early strength, micro-expansibility and the like.

The invention relates to the technical field of coating compositions, and particularly discloses an ardealite-based heat-insulation fireproof coating and a preparation method thereof.The ardealite-based heat-insulation fireproof coating is prepared from titanium dioxide modified ardealite, hollow glass beads, styrene-acrylic emulsion, modified composite flame-retardant fibers, calcium sulfate whiskers, microencapsulated red phosphorus, redispersible latex powder, deionized water, a dispersing agent and a defoaming agent; the preparation method comprises the following steps: firstly, preparing titanium dioxide modified phosphogypsum, secondly, modifying the composite flame-retardant fiber, and finally, mixing and stirring all the components. Through the synergistic effect of the titanium dioxide modified phosphogypsum and the composite flame-retardant fiber and in combination with an ultrasonic-assisted preparation process, a double heat-insulating barrier and a synergistic flame-retardant mechanism is formed; and calcium sulfate whiskers are matched for toughening, so that the fireproof heat-insulating performance and the structural stability of the coating are improved, and the problem that the coating is easy to crack is solved.

The invention provides a concrete composite expanding agent and a preparation method thereof, and belongs to the field of concrete admixtures. The concrete composite expanding agent comprises modified phosphogypsum, fly ash, bauxite, a modified oxide and an auxiliary agent, and is obtained by uniformly mixing the modified phosphogypsum, the fly ash, the bauxite, the modified oxide and the auxiliary agent which have different specific surface areas. According to the composite expanding agent, the modified ardealite and the fly ash synergistically provide an early-stage expansion source, early-stage shrinkage of concrete is compensated through calcium sulphoaluminate hydration products, meanwhile, modified magnesium oxide serves as a later-stage expansion source, magnesium hydroxide is generated through slow hydration, and long-term expansion compensation is achieved; the device has the advantages of good strength, compensation capability and the like; a large amount of industrial waste residues such as ardealite and fly ash are utilized, high-added-value utilization of the industrial waste residues is achieved, and remarkable economic benefits are achieved.

The invention belongs to the technical field of concrete preparation, and particularly relates to a preparation method of a large-mixing-amount concrete composite admixture with solid waste residues as raw materials. The large-dosage concrete composite admixture provided by the invention comprises the following raw materials: phosphogypsum subjected to activation and modification treatment, lithium slag powder subjected to calcination and fine grinding treatment, silica fume, redispersible latex powder, quartz powder and sodium silicate, and the raw materials are added into concrete to serve as cement replacement components. And the compressive strength, static elastic modulus, impermeability, freezing resistance and other properties of the concrete are not influenced.

The invention discloses a preparation process of a waste concrete recycled aggregate gypsum-based wall material, which comprises the following steps: (1) mixing a water repellent agent with an anhydrous solvent to obtain a pretreating agent, and then adding concrete recycled aggregate for standing; and separating out the recycled aggregate and drying the recycled aggregate to obtain the pretreated recycled aggregate. (2) calcining the magnesium oxide whisker, and then adding the obtained calcined whisker into an ethanol solution of polyethylene glycol to form a suspension; and spraying the suspension on the continuously stirred pretreated recycled aggregate, and then carrying out heating and stirring treatment to obtain the modified recycled aggregate. And (3) uniformly stirring ardealite powder, silica fume, potassium hydroxide powder and fine aggregate, then adding water, a retarder and a water reducing agent, uniformly stirring, then adding the modified recycled aggregate, and uniformly stirring, thereby obtaining the product. The process provided by the invention not only reduces the adverse effect of the recycled aggregate on the gypsum-based material, but also improves the water resistance of the gypsum-based material and enhances the mechanical strength.

The invention discloses a phosphogypsum mixing plant which comprises a powder batching machine, an aggregate batching machine, a curing agent metering device, a conveying device, a mixing main machine and a finished product warehouse, the powder batching machine, the aggregate batching machine and the curing agent metering device feed materials into the first conveying device according to the mixing proportion, and accurate metering and stable conveying of all the materials can be achieved; the raw materials are conveyed into the mixing main machine to be continuously vibrated and mixed, then the finished materials are transferred into the finished product bin through the second conveying device, and in the process, the segregation of the finished products can be greatly reduced through the arranged anti-segregation mechanism. And the production efficiency is greatly improved through continuous stirring of the stirring main machine.

The invention discloses a rapid curing agent for phosphorus and fluorine in phosphogypsum and a harmless method. The rapid curing agent for phosphorus and fluorine in phosphogypsum is composed of an alkaline neutralizer, a calcium-aluminum salt catalyst and a solvent. The alkaline neutralizer realizes accurate pH regulation and control of the phosphogypsum leaching solution system; the calcium-aluminum salt catalyst synchronously captures soluble phosphorus, soluble fluorine and heavy metal ions; the solvent ensures proper humidity of the curing agent reaction. According to the innocent treatment method for the ardealite, the curing rate of soluble phosphorus in the ardealite reaches 99.2% and the leaching concentration of soluble fluorine is lower than 1.5 mg / L within 3 days through the processes of crushing and homogenizing the ardealite raw slag, stirring and curing and controllable aging. According to the technology, the technical problems of long reaction period, long on-site mixing time, low synergistic fixation efficiency of soluble phosphorus and fluorine and difficulty in capturing heavy metal ions in most phosphogypsum harmless treatment technologies are solved, the treated phosphogypsum can stably reach the standard, and the treatment cost is effectively reduced by treating the phosphogypsum with the red mud and fly ash solid waste.

The invention discloses a high belite iron aluminate cement clinker, which is prepared from the following raw materials in parts by weight: 39 to 73 parts of carbide slag, 8 to 37 parts of low-grade bauxite, 10 to 16 parts of ardealite, 1 to 31 parts of fly ash and 3 to 9 parts of steel slag. According to the cement clinker, the resource utilization rate of industrial solid waste in cement preparation can be remarkably increased, and dependence on natural raw materials and high-grade raw materials is reduced; impurities in various solid wastes can be used as in-situ mineralizing agents and activating agents, and on the basis of realizing high-added-value resource utilization of various industrial solid wastes and low-grade bauxite, efficient synthesis of target minerals at a relatively low temperature is promoted; and gradient temperature control calcination and gradient cooling processes are further combined, so that sufficient crystallization and development of a target mineral phase can be effectively promoted, a clinker microstructure is optimized, excellent early strength and continuously increased later strength of the cement are ensured, and the common problems of strength shrinkage and the like of the traditional solid waste-based cement can be effectively avoided.

The invention belongs to the technical field of phosphogypsum harmless treatment equipment, and discloses a phosphogypsum harmless treatment device and method based on multi-agent cooperation. The phosphogypsum harmless treatment device based on multi-agent cooperation comprises a tank body, a feeding hopper is installed at the top of the tank body, a discharging structure is arranged at the bottom of the tank body, a first driving motor and a second driving motor are fixedly installed in the middle and the edge of one end face of the tank body correspondingly, and a material turning mechanism and a stirring mechanism are arranged in the tank body correspondingly; and the stirring mechanism is driven by the driving motor I to stir the raised materials in the tank body. According to the phosphogypsum harmless treatment device and treatment method based on multi-agent cooperation, through the design of the material turning mechanism, the stirring mechanism and the air blast mechanism, in the material mixing process, compressed air can be continuously utilized for raising materials to achieve combination of pneumatic mixing and contact mixing, high-speed airflow can hit caked materials, and the treatment effect is good. The high-efficiency mixing of the materials is realized, and the problems in the background technology are solved.

The invention provides an acid soil conditioner and a preparation method thereof, and belongs to the technical field of soil conditioners. The soil conditioner is prepared from the following raw materials in parts by weight: 30-40 parts of pH-sensitive hydrogel, 3-7 parts of slow-release nitrogen-fixing bacteria microcapsules, 5-8 parts of soil improvement bacteria, 10-20 parts of a chitosan / sodium alginate modified compound, 17-20 parts of fly ash and 18-22 parts of phosphogypsum. According to the prepared acid soil conditioner, the microorganism and chemical improvement effect is adopted, the pH value of soil can be obviously increased, the granular structure of the soil is improved, the buffering capacity of the soil is enhanced, the fertility of the soil is improved, the heavy metal content of the soil is reduced, the quality of the soil is improved, and the crop yield is increased, so that the acid soil conditioner has wide application prospects.

The invention belongs to the technical field of ardealite purification. More specifically, the invention relates to an ardealite purification method. The method comprises the following specific purification steps: carrying out ball milling on the phosphogypsum to adjust the sphericity of the phosphogypsum to 0.55-0.65, so as to obtain a ball-milled material; adjusting the water content of the ball-milled material to 20-25% to obtain a wet ball-milled material; after completely freezing the wet ball-milled material, freezing and squeezing for 10-30 minutes under the condition that the pressure is 2.0-5.0 MPa, so as to obtain a squeezed material; the squeezed material is added into a flotation tank, water is added into the squeezed material, and then the pH value is adjusted to 2.5-2.7; and then adding a trapping agent, carrying out ultrasonic stirring reaction, then adding a foaming agent, continuously carrying out ultrasonic stirring reaction, scraping bubbles, collecting residual slurry in a flotation tank, dehydrating and drying to finish the purification of the phosphogypsum. The natural pH (Potential of Hydrogen) of the phosphogypsum is 2.4 to 2.6; in addition, the whiteness of the ardealite is 30 to 35 percent.

The invention discloses an ardealite-based slow release fertilizer and a preparation method thereof, the ardealite-based slow release fertilizer comprises: a core layer, the core layer comprises ardealite and a complex microbial inoculant; in the phosphogypsum, the content of fluoride is less than or equal to 0.1 wt%, and the content of phosphorus pentoxide is more than or equal to 0.1 wt%; the complex microbial inoculants comprise phosphorophilic bacteria; and the material of the coating layer comprises a scene response material. Therefore, according to the ardealite-based slow release fertilizer, the utilization rate of ardealite can be effectively increased, and meanwhile, the slow release performance of the slow release fertilizer is further optimized.

The invention discloses a high-strength quick-setting 3D printing concrete material based on nanocrystalline nucleus synergistic excitation and a forming preparation method thereof, and belongs to the technical field of building materials. The high-strength quick-setting 3D printing concrete material based on nanocrystalline nucleus synergistic excitation is prepared from the following components in parts by weight: 40 to 50 parts of phosphogypsum, 20 to 30 parts of Portland cement, 5 to 15 parts of sulphoaluminate cement, 1 to 5 parts of nanocrystalline nucleus agent, 0.5 to 1 part of carbon nanotube, 20 to 40 parts of phosphogypsum lightweight aggregate, 1 to 3 parts of additive, 1 to 3 parts of steel fiber and 0.1 to 0.3 part of hydroxypropyl methyl cellulose. According to the invention, by introducing a nano crystal nucleus synergistic excitation technology and combining with a 3D printing process, high performance of the phosphogypsum-based concrete material is realized, and a new material solution is provided for sustainable development of the building field.

The invention discloses an iron tailing-based all-solid-waste clinker-free cementing material and a preparation method thereof, and belongs to the technical field of building materials. The cementing material comprises the following components in parts by weight: 30-50 parts of activated iron tailings, 10-20 parts of steel slag, 20-40 parts of mineral slag, 5-20 parts of phosphogypsum and 5-20 parts of an activating agent; a preparation method of the activated iron tailings comprises the following steps that the iron tailings and the red mud are mixed, then an alkaline solution is added, alkali-heat combined treatment is conducted for 2-6 h at the temperature of 150-230 DEG C after even mixing, and the activated iron tailings are obtained after drying. According to the method, the activity of the iron tailings and the red mud is improved through component complementation in the iron tailing activity excitation process, the dosage of NaOH in the alkali-heat excitation process is reduced, and the cementing material with high hydration activity is prepared through multi-source solid waste synergistic interaction in the clinker-free cementing material preparation process.

The dust treatment device comprises a spray tower, a filter box, an intercepting net and a spray pipe, one side of the spray tower is connected with the filter box through a communication port, the top end of one side of the filter box is provided with an air inlet channel, the intercepting net is arranged in the center of the interior of the filter box, and the spray pipe is connected with the filter box through a communication port. A lead screw is arranged at the position, on one side of the intercepting net, in the filtering box, the lead screw is sleeved with a driving block, a cleaning brush is arranged on one side of the driving block, a driving motor is fixed to the top of the filtering box, the output end of the driving motor is connected with the lead screw, and a spraying pipe is arranged at the top end of the interior of the spraying tower. And spray heads are uniformly distributed at the bottom of the spray pipe. By installing the filter box, the spray tower, the air inlet channel, the interception net, the lead screw, the driving motor, the driving block, the cleaning brush and the dust discharging pipe, the dust treatment device can automatically clean the interception net, and the replacement frequency is reduced, so that the dust treatment efficiency is improved.

The invention provides a solid waste-based cementing material and a preparation method thereof, and relates to the technical field of solid waste resource utilization and cementing material preparation. The cementing material is prepared by mixing and grinding 60-80 parts by weight of modified phosphogypsum and 20-40 parts by weight of an auxiliary material, and the auxiliary material comprises at least one of steel slag powder, fly ash, lithium slag and mineral slag; a preparation method of the modified ardealite comprises the following steps: carrying out microwave treatment on ardealite for 0.5-1 hour, mixing the treated ardealite with aluminum oxide, attapulgite and sodium lignosulphonate, adding a tetramethylammonium hydroxide solution, and drying to obtain the modified ardealite. According to the solid waste-based cementing material disclosed by the invention, the phosphogypsum is modified, so that the solid waste-based cementing material has the characteristics of high strength, stable cementing, strong erosion resistance and the like while the mixing amount of the phosphogypsum is increased.

The invention discloses a phosphogypsum leachate-carbonate rock dynamic corrosion reaction analysis method based on numerical simulation, and aims to research a migration-corrosion coupling mechanism of acid leachate in a carbonate rock fracture network. The method comprises the following steps: firstly, acquiring a two-dimensional image sequence of a rock core sample through CT (Computed Tomography) scanning, carrying out operations such as threshold segmentation, membrane enhancement and a light shading algorithm on an image by utilizing AVIZO software, extracting fracture structure parameters and establishing a high-precision three-dimensional model; then, multiple groups of simplified models with different fracture widths are constructed in COMSOL Multiphysics, a Darcy flow field and a solute concentration field are coupled on the basis of the Darcy law and a dilute matter transfer theory, and the dynamic corrosion effect under the multi-field coupling effect is quantitatively represented by setting hydraulic gradient boundary conditions and chemical reaction kinetic parameters; the dynamic corrosion reaction process of calcium ions, hydrofluoric acid, sulfuric acid and phosphoric acid in the ardealite leachate and carbonate rocks with different crack widths is accurately simulated.

The invention relates to the technical field of soil improvement, in particular to a solid-waste-based porous material for repairing saline-alkali soil and a preparation method and application of the solid-waste-based porous material. The solid waste-based porous material is prepared from the following raw materials: 60 to 70 percent of coal gangue powder, 24.7 to 30 percent of phosphogypsum, 5 to 9.5 percent of functional filler and 0.3 to 0.5 percent of foaming agent, and the liquid-solid ratio is 0.6 to 0.7. According to the invention, the problems of insufficient gelation activity of high-silicon-aluminum coal gangue, excessive heavy metal Cd, contradiction between pores and strength of a traditional repair material and the like are effectively improved, multi-target coordination of solid waste recycling, heavy metal stabilization and saline-alkali soil repair is realized, and an industrial feasible path is provided for large-scale saline-alkali soil treatment.