2836 results about "Phosphogypsum" patented technology

The invention provides a method for cooperative activation of fly ash and decomposition of gypsum for recovery of a sulfur resource. According to the method, solid waste, i.e., fly ash, discharged by a coal-fired power plant or coal-fired boiler is used as a raw material, a certain proportion of desulfurized gypsum discharged by the coal-fired power plant or waste phosphogypsum produced in the phosphorus chemical industry is added and mixed with the fly ash, then the obtained mixture is subjected to ball milling, and activation and calcination at a temperature of 950 to 1450 DEG C are carried out for 5 to 180 min; calcium sulfate in the gypsum are almost totally decomposed after calcination, and produced gas contains sulfur dioxide or sulfur trioxide which can be used as feed gas for preparation of sulfuric acid; and calcination enables solid fly ash to be activated, leaching with a sulfuric acid or hydrochloric acid solution is carried out at a temperature of 50 to 100 DEG C, and the leaching rate of alumina is greater than 80%. The method provided by the invention has the advantages that since all the raw materials are solid waste, the purpose of treating the waste by using the waste is achieved; elemental sulphur in the gypsum can be recovered; and the fly ash can be activated and activity of the fly ash can be improved, so a high alumina recovery rate at a low temperature can be realized. With the method, high-efficiency extraction of alumina in the fly ash is realized; the sulfur resource in the gypsum is recovered; shortage in industrial sulphur in the sulfuric acid industry in China is compensated; and the method has good economic benefits and wide industrial application prospects.

The invention discloses a fertilizing and conditioning agent for improving the saline alkali soil, and the fertilizing and conditioning agent includes an organic material, an inorganic material and a regulator for the plant growth, wherein, the weight proportion between the organic material and the inorganic material is 3:2 to 1:1. The organic material is fermented and maturated by one or a plurality of such organic matters as town living sludge, excrements of livestock and poultry, and furfural slag; and the inorganic material is formed by one or a plurality of such industrial waste and materials as desulfurized gypsum, phosphogypsum, and ammonium sulphate. Moreover, appropriate growth regulator for plant which is added according to the growing requirements can not only improve the saline alkali soil and fertilize the soil, but also can improve the plant growth and promote the plant to grow well as well as providing an effective path for promoting the recycling of the waste resources and reducing the secondary pollution to the town and the country.

The invention relates to a high-strength water-proof gypsum plaster and a production method thereof. The inventive high-strength water-proof gypsum plaster is made from the following materials in weight proportions: 10-99% of gypsum-based composite binding agent, 0-90% of aggregates, 0.08-4% of additives and 0-16.1% of adsorbent. The production method comprises the following steps: weighing raw materials at the given ratio, drying the aggregates, mixing all raw materials, and packaging. The inventive high-strength water-proof gypsum plaster has high strength and good water resistance; can be made from chemical gypsum materials without needing calcination, such as desulfurized gypsum, phosphogypsum, fluorgypsum and citric acid gypsum; and has the advantages of low production cost, energy conservation, discharge reduction and environmental friendliness.

The invention discloses a new-typed salted soil modifier composition and making method, which comprises the following parts: superphosphate, calcium sulfate, poromeric material, decomposed rough organics, phosphogypsum, rough stream and macromolecular (water retention) agent for alkali soil of littoral area.

The invention discloses a method for using phosphogypsum as a polyvinyl chloride resin filler. The method is as follows: the phosphogypsum is subjected to modified treatment; a coupling agent is added in a milling process, so as to obtain the product which can be used as the polyvinyl chloride resin filler. The method comprises following concrete processes: (1) screening; (2) calcining; (3) grinding and adding the coupling agent; and (4) mixing, so as to obtain an aluminate ester modified phosphogypsum filler. The method has the advantages that (1) organic impurities and crystal water are removed by screening and calcining the phosphogypsum; the whiteness is improved; the grain sizes of the grains are controlled in a grinding manner; the method meets the requirements of the polyvinyl chloride (PVC) filler, and is low in cost; (2) the method is even to modify, and good in effect; no externally added water enters inside; the bubbling of the PVC in a machining process is avoided; (3) the method is simple in process, low in cost, good in processing rheological property and easy to mold, and the plasticization of the phosphogypsum in the PVC resin can be accelerated. The method is suitable for reinforcing and toughening of a polymer material, not only can be applied to the PVC resin, but also can be used as fillers of the materials such as polyethylene (PE), polypropylene (PP) and polystyrene (PS).

The invention discloses a stuff mining method when the ardealite adhesive is solidified and relative pulp production. The stuff mining method comprises that preparing mine house, stuffing preparation, preparing pulp, and stuffing. The pulp preparation comprises that using ardealite, coal powder/dolostone and cement as the stuff material to be added into water and mixed into stuff pulp; the stuff pulp via the stuff drill hole or the pump station is input to the upper outer flat channel of the mining field via the stuff tube, to be fed into the mining field. The inventive stuff mining method can confirm the yield and stability of mine, to improve the recycle rate of mineral and protect the environment.

The invention discloses a method for the production of phosphoric acid and the combined production of a-hemihydrate gypsum through a dehydrate-hemihydrate wet phosphoric acid technology. A dehydrate part production technology is characterized in that the reaction tank temperature is 70-80DEG C, the retention time is 1.5-3h, the free sulfate radical concentration is 1-2%, and the produced wet phosphoric acid concentration omega(P2O5) is 35-39%. A hemihydrate part production technology is characterized in that the reaction tank temperature is 86-94DEG C, the retention time is 1-2h, and the mass concentration of free sulfate radicals is 6-8%. Phosphoric acid produced through the hemihydrate technology has a concentration omega(P2O5) of 10-15% and is used as a recycle acid of the dehydrate part, the crystal water content of the combined-production hemihydrate gypsum is 5-7%, the mass percentage of free P2O5 in gypsum is less than 0.4%, and the crystal form of the produced hemihydrate gypsum is a-hemihydrate gypsum. Compared with the dehydrate technology, the method disclosed in the invention improves the phosphoric acid concentration and improves the phosphorus recovery rate to above 98%, and the combined-production a-hemihydrate gypsum can be directly used as a building gypsum product, so energy consumption saving is realized.

The invention belongs to the technical field of heavy metal pollution soil restoration, and particularly relates to a soil heavy metal passivator, a preparation method thereof, and a passivation method thereof on soil cadmium. The soil heavy metal passivator provided by the invention is prepared from the following materials in parts by weight: 30 to 50 parts of modified alkali minerals, 10 to 15 parts of rotten agriculture and forestry wastes, 1 to 10 parts of soil conditioners, 1 to 5 parts of pH sensitive gel, 1 to 5 parts of phosphogypsum, and 0.1 to 5 parts of graphene. The soil heavy metal passivator provided by the invention has stronger adsorbing and chelating functions, can effectively fix heavy metal cadmium in the soil, and prevents effective cadmium from entering into crops; regulation can be carried out according to the soil pH, so that the utilization ratio and the long-term stability of the soil heavy metal passivator are improved; meanwhile, with an added soil conditioner, the soil environment can be improved, and the soil fertility is improved. The passivator provided by the invention can better meet the urgent demand of heavy metal pollution soil restoration in China currently on strong stability, no secondary pollution, and durable and stable effect.

The invention discloses a method for reducing and decomposing phosphogypsum by sulfur, which comprises the following steps: putting the phosphogypsum into a reactor, and raising the temperature to between 500 and 900DEGC for preheating for 10 to 30 minutes at an inert atmosphere; introducing gaseous sulfur in a molar percentage of 10 to 50 percent to perform reduction reaction with the phosphogypsum for 1 to 2 hours; grinding obtained a calcium sulfide block, and uniformly mixing the ground calcium sulfide with the phosphogypsum in a molar ratio of 1-1.5:3; sintering at a temperature between 1,000 and 1,400 DEG C for 0.5 to 3 hours at a non-oxidizing atmosphere; and taking CaO in the obtained solid slag as a cement clinker for cement production, taking the generated tail gas SO2 as a raw material gas for producing sulphuric acid. The reduction rate of CaSO4 is high, the decomposition ratio of the phosphogypsum can reach over 98 weight percent, the desulfurization ratio of the phosphogypsum can reach over 95 weight percent, and the method has the advantages of low energy consumption, simple and mature process, short production period, easy control and convenient promotion.

The invention discloses a method for producing high addition-amount water-resistant ardealite building material. The method comprises the following steps that: ardealite accounting for 70 to 80 percent of the total weight, hydraulic cementing material accounting for 20 to 30 percent of the total weight and alkaline exciting agent accounting for 1 to 10 percent of the total weight are taken as raw materials and well mixed at a water-ash ratio (mass ratio) of between 0.18 and 0.22 so as to give a mixed material; a die is filled with the mixed material; the mixed material is molded under the pressure of between 10 and 20 MPa so as to prepare blank; the prepared blank is maintained for 1 to 3 days at normal temperature under normal pressure and then put into an autoclave for maintenance; and a medium of steaming-pressing maintenance is water vapor, wherein the steaming-pressing temperature is between 180 and 220 DEG C, and the heat preservation time is between 8 and 12 hours; the mixed material is discharged from the autoclave; and a high addition-amount water-resistant ardealite product can be obtained. The method has the advantages of raising the addition amount of ardealite and remarkably improving the water resistance of the gypsum product.

The invention discloses an aerated concrete building block. The aerated concrete building block comprises, by weight, 65-72 parts of fly ash, 15-20 parts of quick lime, 5-10 parts of cement, 2.83-3.83 parts of phosphogypsum, 0.1 parts of aluminum powers, 0.05 parts of a foam stabilizer and 0.02 parts of a polypropylene fibre. The modified polypropylene fiber is added to the concrete structure material, such that tensile strength and anti-impact strength of the concrete structure material are improved, a drying shrinkage value of the concrete structure material is reduced, and cracks are prevented from formation and extension during cement solidification. During a green body structural strength formation, a plurality of microcracks are generated due to a plastic shrinkage of the green body, such that during a later autoclaved process, larger cracks are easily generated from the microcracks when the aerated concrete structure extends; meanwhile, because a gradient variation of humidity of the aerated concrete material is large, cracks in the aerated concrete material are easily generated during humidity changing. Therefore, the internal structure of the aerated concrete provided by the present invention can enable improving the disadvantages of generation of aerated concrete wall cracks through an enhancement of the polypropylene fibre.

The present invention relates to a modified phosphogypsum brick and its use as cement retarder. Said modified phosphogysum brick comprises 80-95 wt% of phosphogypsum, 2-15 wt% of reinforcing agent and 3-10 wt% of modifiying agent. Said material mixture (100 wt%) is undergone the processes of forming and naturally-drying to obtain the invented product. The water content of said modified phosphogypsum brick is less than 10 wt%, SO3 is greater than 35 wt%, pH is greater than 7, P2O5 is less than 0.1 wt%. Said modified phosphogypsum brick is convenient for storage and transportation, can be used as cement retarder for production of cement instead of natural gypsum, and can reduce cement cost and raise cement property.

The invention discloses a biological pesticidal organic fertilizer and a preparation method thereof. The biological pesticidal organic fertilizer is prepared from the following raw materials in parts by weight: 40-50 parts of pig manure, 20-30 parts of tea seed pulp, 10-15 parts of coffee grounds, 8-12 parts of paulownia sawdust, 5-10 parts of phosphogypsum, 4-8 parts of corn cob, 5-10 parts of pepper seed cake, 10-15 parts of mushroom dreg, 8-12 parts of wheat bran, 15-20 parts of bentonite, 10-15 parts of opoka, 2-3 parts of ferrous sulfate, 1-2 parts of manganese sulfate, 3-5 parts of humic acid, 1-2 parts of chinese tallow tree root and bark, 2-3 parts of sophora alopecuroides, 1-2 parts of stemona, 1-3 parts of Artemisia annua, 1.5-2.5 parts of ailanthus leaf, 2-3 parts of derris and 1-2 parts of Radix Euphorbiae Ebractealatae. The organic fertilizer disclosed by the invention has multiple effects of providing nutrients, improving the soil structure, preventing and treating pests and diseases and the like, can promote the crops to quickly grow, enhances the stress tolerance of the crops, can have favorable preventing and treating effects on nematodes and soil insects, reduces or avoids use of chemical pesticides, enhances the soil fertility, regulates the ecological equilibrium of soil, improves the quality of agricultural products, has no chemical residues, and implements yield increase and income increase of agricultural products.

The invention discloses a modification and innocuous treatment method of phosphogypsum, comprising the following steps: (1) cleaning, (2) neutralizing, (3) dehydrating, (4) calcining, and (5) packaging. The modified phosphogypsum prepared by the invention is a raw material for building material, can be used for preparing a phosphogypsum high strength cement fiberboard. The modified phosphogypsum sandwich panels prepared by the phosphogypsum high strength cement fiberboard can be applied in wall material, floor and roof panel, and has the advantages of good antifreezing performance, thermal insulation performance, heat shielding performance, corrosion resisting performance, fireproof performance, high intensity, light specific gravity, easiness in installation and the like. According to the invention, the waste residue phosphogypsum of phosphorus chemical enterprises are recycled through modification treatment and can be used for producing building materials after recycling, so that the national energy saving policy and the development direction of circular economy are satisfied; even temporarily unable use occurs because of investment or other reasons, the modified phosphogypsum can be stored in long term without environmental hazard, so that the harmlessness is realized.

The invention discloses a making method of paper plaster board, which comprises the following steps: mixing the phosphogypsum and desulfuration plaster according to the weight ratio at 50-90:50-10; drying until the free water content under 5 percent; sintering the plaster at 160-220 DEG C continually to form the calcined gypsum powder with 5-9 percent crystal water; cooling in the bin; placing to obtain the architecture plaster powder; stirring the plaster powder with white corn starch latex, foaming agent, glass fiber and water evenly into material paste; compounding the roof and bottom of paper plaster board through plate-typed molder. The invention saves the natural plaster resource and cost, which improves the product property.

The invention discloses a method for producing high-water solubility nitrophosphate fertilizer by phosphorite nitrolysis and calcium nitrate freezing. The high-water solubility nitrophosphate fertilizer is prepared from the processes of phosphorite nitrolysis, fluorine removal, calcium nitrate freezing separation, further removal of calcium in ammonium sulfate, ammonia liquor neutralization and deposition removal of impurities, and evaporation concentration and crystallization. Specially, the method for producing high-water solubility nitrophosphate fertilizer by phosphorite nitrolysis and calcium nitrate freezing comprises the following steps of 1, acidolysis, 2, fluorine removal, 3, calcium nitrate freezing crystallization, 4, double decomposition removal of calcium in ammonium sulfate,5, neutralization and deposition removal of impurities, 6, evaporation concentration and crystallization, and 7, phosphogypsum transformation. The high-water solubility nitrophosphate fertilizer prepared by the method has a dissolution rate great than or equal to 99.9% in water, wherein nitrate nitrogen is easy for be absorbed by drops, satisfies requirements of a few commercial crops, has a highutilization rate, and improves a crop yield by 8 to 25% and crop quality. The method reduces waste discharge, is environmentally friendly, can be utilized for structure adjustment and product upgradeand update of the traditional phosphorus chemical industry, and has good economic and environmental benefits.

The invention provides an autoclaved aerated concrete block and a manufacturing process thereof. The autoclaved aerated concrete block comprises the following raw materials by weight parts: 60-70 parts of coal ash (sand), 15-20 parts of lime, 5-10 parts of cement, 2-4 parts of gypsum and 5-8 parts of wastes, wherein aluminum powder accounts for 0.075% of the total weight of dry materials, and the water-material ratio is 0.6-0.65. The manufacturing process comprises the following steps: storing and processing the raw materials; dosing, stirring, and pouring; standing, cutting, and grouping; autoclaving to obtain a finished product of the autoclaved aerated concrete block. According to the process, industrial solid wastes-phosphogypsum are used as the raw materials, wastewater and leftover materials discharged in a production process are recycled, the produced aerated concrete block completely meets the national standards, the influence on the aerated concrete block caused by phosphate impurities in the phosphogypsum is avoided, the problems of reasonable utilization of the leftover materials and waste slurry are solved, the industrial solid wastes are treated and turn into wealth, the ecological environment is protected, and the novel process is energy-saving and environment-friendly.

The invention relates to a roadbed filler for a road and a preparation method of the roadbed filler. The roadbed filler for the road is characterized by being prepared from lime, pulverized fuel ash, phosphogypsum and stabilizer. The weight percentage of each material in the lime, the pulverized fuel ash and the phosphogypsum is 15% of lime, 30-50% of pulverized fuel ash and 35-60% of phosphogypsum; the sum of the weight percentages of the materials is 100%; the stabilizer is water glass or NaAlO2 (sodium metaaluminate); the adding amount of the water glass is 2-6% of total mass of the lime, the pulverized fuel ash and the phosphogypsum, and the adding amount of the NaAlO2 is 0.5-2% of total mass of the lime, the pulverized fuel ash and the phosphogypsum. Due to the roadbed filler for the road prepared by the method, not only can the early strength be improved, but also the problem of water stability can be solved.

The invention discloses a method for preparing high-strength alpha hemihydrate gypsum by using phosphogypsum. The method comprises the following steps of: mixing the phosphogypsum, a pretreatment additive, water and a crystal modifier, stirring to be uniform, forming balls after aging treatment, then finishing steam curing and drying in a stilling kettle, and preparing the high-strength alpha hemihydrate gypsum. The method disclosed by the invention has the advantages that the process flow is simple, the industrialization is easy, the phosphogypsum can be greatly utilized and consumed, and the conversion rate is high; and simultaneously, the invention provides the stilling kettle capable of realizing integration of steam curing and drying, the alpha hemihydrate gypsum can be better prepared, and the high-quality building material or wall-body material can be better prepared.

A method for comprehensive utilization of red mud, phosphogypsum and coal gangue comprises the following steps: red mud, phosphogypsum and coal gangue are used as main original burning materials, a correction material is taken as a secondary original burning material, a homogeneous moisture material is prepared through two-stage batching process and is shaped or dried and crushed, and then a clinker product including main ingredients of dicalcium silicate, calcium sulphoaluminate and calcium sulphoferrite is prepared through calcination. The clinker produced by the method can be not only directly sold as a product but also further processed into a cementing material or product for sale by utilizing the prior art. The method provided by the invention is simple in process and low in investment, the production scale can be either big or small, a rapid hardening early strength clinker produced by the method is wide in use and relatively higher in value, not only are lots of clay resources and non-renewable burning coal saved, but also environmental pollution caused by waste pollutants are effectively reduced, secondary disasters is prevented, and high industrial competitiveness and favorable investment economical efficiency are realized.

The invention relates to gypsum-based door and window seam filling and sealing mortar as well as a preparation method and an application thereof. The gypsum-based door and window seam filling and sealing mortar is prepared from the following components in parts by weight: 100 parts of waste gypsum, 20-200 parts of active admixture, 0.01-10 parts of water reducing agent, 0.1-50 parts of excitant, 0-10 parts of thickening time control agent, 0-30 parts of binding agent, 0-10 parts of air entraining agent, 0.01-30 parts of plastic retaining agent, 0.01-10 parts of water repellent, 0-5 parts of starch ether, 0-150 parts of powder filler and 0-300 parts of aggregate. Compared with the prior art, the mortar has the advantages of simpleness and convenience in construction, good filling capability, high adhesion capability, good durability, low cost and the like; as the mortar takes chemical gypsum such as desulfurization gypsum and phosphogypsum as main binding materials, a novel application is provided for resource utilization of waste gypsum, not only is material property improved, but also the cost is lowered, and the purposes of sewage treatment and emission reduction are achieved.

The invention discloses a phosphogypsum light-weight partition wall board and a building block and a manufacturing method thereof, which are characterized in that the phosphogypsum light-weight partition wall board and the building block consist essentially of raw materials according to the following weight percentages: 10-50% of phosphogypsum, 10-50% of magnesium oxide, 5-20% of magnesium chloride, 10-50% of water, 10-50% of packing, 0.1-3% of foaming agent and 0-5% of short fiber reinforced material. The phosphogypsum foamed building block or foamed wall board are light in weight, and good in sound insulation and heat preservation effects, thus being ideal energy-saving and environment-protective building materials; and main raw materials of phosphogypsum concrete can be obtained locally, the phosphogypsum concrete is simple and convenient in production, low in cost and pollution-free, and phosphogypsum concrete products not only can be widely used in mined-out areas of mines or tunnel backfilling, but also can be comprehensively utilized as surface layers, base layers and under layers of roads, and the like, thus having very broad application prospect.