3299 results about "Coke" patented technology

The present invention provides carbonaceous fuels and processes for making them. Moreover, the invention also relates to processes using the carbonaceous fuels in the production of cement products. One embodiment of the invention is a carbonaceous fuel comprising (a) unconverted fines of a carbonaceous feedstock, the carbonaceous feedstock having an ash content of greater than 1%, the fines having an average particle size less than about 45 μm; and (b) a char residue formed by catalytic gasification of the carbonaceous feedstock, the char residue having an ash content of greater than about 30%, wherein the ash includes at least one aluminum-containing compound or silicon-containing compound; and having a weight ratio of fines to char residue in the range of about 4:1 to about 1:4, and a total dry basis wt % of carbon of least about 40%. Another embodiment of the invention is a process of making a cement product comprising: (a) providing a carbonaceous fuel as described above; (b) passing the carbonaceous fuel into a cement-making zone; and (c) at least partially combusting the carbonaceous fuel to provide heat for a cement producing reaction within the cement-making zone.

Disclosed are a method and a corresponding apparatus for converting a biomass reactant into synthesis gas. The method includes the steps of (1) heating biomass in a first molten liquid bath at a first temperature, wherein the first temperature is at least about 100° C., but less than the decomposition temperature of the biomass, wherein gas comprising water is evaporated and air is pressed from the biomass, thereby yielding dried biomass with minimal air content. (2) Recapturing the moisture evaporated from the biomass in step 1 for use in the process gas. (3) Heating the dried biomass in a second molten liquid bath at a second temperature, wherein the second temperature is sufficiently high to cause flash pyrolysis of the dried biomass, thereby yielding product gases, tar, and char. (4) Inserting recaptured steam into the process gas, which may optionally include external natural gas or hydrogen gas or recycled syngas for mixing and reforming with tar and non-condensable gases. (5) Further reacting the product gases, tar, and char with the process gas within a third molten liquid bath at a third temperature which is equal to or greater than the second temperature within the second molten liquid bath, thereby yielding high quality and relatively clean synthesis gas after a relatively long residence time needed for char gasification. A portion of the synthesis gas so formed is combusted to heat the first, second, and third molten liquid baths, unless external natural or hydrogen gas is available for this use.

A method for producing propylene and gasoline diesel-oil by two-section catalyzed cracking style is carried out by adopting two-section lift pipe catalyzing process and catalyst with molecular sieve, taking heavy petroleum hydrocarbon or various animal and vegetable oils containing hydrocarbon as raw materials, optimization combining by charging style for various reactants, and controlling proper reactive conditions. It can improve propene and light-oil recovery rate and quality, and inhibit to generate dry gas and coke.

An improved corbel includes a first tier having first blocks and a second tier having second blocks. Each of the first blocks includes a first aperture extending through the block from a first surface to a back surface and a second aperture formed through a top surface of the block, extending into the first aperture. The first blocks are arranged on a substantially planar surface to align the respective first apertures to define a first passageway. Each of the second blocks includes a third aperture extending through the second block from a top surface to a bottom surface. The second blocks are disposed above the first tier to align the third aperture of each of the second blocks with the second aperture of the first blocks to form a second passageway.

The invention relates to a method for producing formed coke, in particular to a method for preparing coal powder into the formed coke by microwave. The method adopts coal powder as raw material and comprises the following steps: sieving the coal powder for preparing fine coal powder, sending the fine coal powder into a first microwave heating device for dehydration until the water content of the heated fine coal powder is below 1 percent, and sending the heated fine coal powder into a second microwave heating device by a conveying device for dry distillation; performing the dry distillation to the fine coal powder by the second microwave heating device to analyze other materials in the coal powder, preparing carbocoal after the dry distillation, sending the carbocoal into a mixer by the conveying device to prepare the mixture after adding bonding material; sending the mixture to a forming machine by a conveyer for forming so as to prepare a formed coke semi-finished product; sending the reformed coke semi-finished product into a third microwave heating device for being heated and carbonized to prepare red coke, and sending the carbonized red coke into a coke car to prepare a formed coke product. The invention has low production cost, high production efficiency, cleanness and environment protection because coke powder and waste are not produced during the production.

The invention discloses a three-fluidized-bed solid heat carrier coal pyrolysis, gasification and combustion cascade utilization method. The method comprises the following steps of: mixing coal and high temperature circulating ash serving as a solid heat carrier in a fluidized bed pyrolysis furnace, pyrolyzing to separate out volatile, cooling and separating the volatile to obtain tar and pyrolysis gas, conveying pyrolysis semi-coke generated by pyrolyzing the coal to a fluidized bed gasification furnace, performing gasification reaction by using water vapor and O2 as gasification agents to prepare synthesis gas, conveying the semi-coke which is incompletely gasified in the gasification furnace to a circulating fluidized bed combustion furnace, blowing air for the conventional combustion or blowing O2/CO2 for oxygen-enriched combustion, heating the circulating ash serving as the solid heat carrier, and producing gasification agent vapor required by the gasification furnace by using high temperature flue gas generated by combustion. The method has the advantages that: the tar, the pyrolysis gas and the synthesis gas are co-produced through coal pyrolysis, gasification and combustion cascade utilization, the gasification condition of the semi-coke is reduced, and good economic benefits and social benefits are achieved.

The invention relates to a combustible material plasma high-temperature gasification technique and equipment thereof. The technique comprises the following steps: firstly, laying a coke bed layer at the bottom part of a gasification furnace; secondly, putting the combustible material, a fluxing agent and an extra coke on the coke bed layer continuously to form a fuel bed layer; then injecting a primary oxidizing agent, starting a first-stage plasma torch to generate high temperature and high heat, forming a fusing zone at the joint of the coke bed layer and the fuel bed layer, forming a gasifying zone above the fusion zone, gasifying the combustible material to generate crude synthesis gas, and discharging the generated fused slag from the bottom part of the gasification furnace; then introducing the crude synthesis gas into a gas-solid separator for removing impurities to obtain purified synthesis gas; and finally introducing the purified synthesis gas into a detarrer, injecting a secondary oxidizing agent, starting a second-stage plasma torch to generate high temperature and high heat, cracking residual tar therein to obtain fined synthesis gas. The equipment mainly comprises three parts, namely the gasification furnace, the gas-solid separator and the detarrer. The fuel has good adaptability, high gasification efficiency, few tar content in the synthesis gas and high activeingredient.

The present invention relates to an improved delayed coking process. A coker feed, such as a vacuum resid, is treated with (i) a metal-containing agent and (ii) an oxidizing agent. The feed is treated with the oxidizing agent at an oxidizing temperature. The oxidized feed is then pre-heated to coking temperatures and conducted to a coking vessel for a coking time to allow volatiles to evolve and to produce a substantially free-flowing coke. A metals-containing composition is added to the feed at at least one of the following points in the process: prior to the heating of the feed to coking temperatures, during such heating, and/or after such heating.

The invention provides a technology for preparing a needle coke raw material from coal-tar pitch. The technology comprises the following steps of 1, fully mixing asphalt and a solvent, and removing insoluble substances in the mixture by a physical separation method, wherein the solvent is a mixture of coal light oil and coal aromatic oil or is a mixture of BTX and coal aromatic oil; a mass ratio of the coal light oil or the BTX to the coal aromatic oil is in a range of (20: 80) to (95: 5); and a mass ratio of the solvent to the asphalt is in a range of 0.5 to 10, 2, feeding a clear liquor without the insoluble substances into a separator, and separating the light solvent from the clear liquor to obtain a heavy fraction having low QI, and 3, carrying out hydrotreatment on the heavy fraction in the presence of a hydrogenation catalyst at a temperature of 300 to 450 DEG C under the pressure of 5 to 20MPa. The needle coke raw material obtained by the technology has low sulfur content and a small expansion coefficient.

A combined cycle process that includes gas turbines, a steam turbine train, a heat recovery unit, and a gasification unit that produces low or mid BTU fuel gas from coal, lignite, coke, biomass, or other suitable hydrocarbon containing material wherein the fuel gas is burned in the heat recovery unit at one or more points to increase steam rate to the steam turbine train.

The fuel gas injection flow rates into the heat recovery unit are controlled to avoid exceeding peak temperatures in the heat recovery unit of about 2500 F.

Optionally, the fuel gas from the gasification unit is cooled by transferring sensible heat to condensate from the steam turbine train to convert the condensate to high pressure steam for driving the steam turbine train.

Optionally, a steam boiler unit is integrated into the combined cycle process to raise additional high pressure steam for the steam turbine train. The steam boiler feed water is condensate from the steam turbine train. The steam boiler produces saturated high pressure steam that is superheated in the heat recovery unit.

A desulfurizing process with circulating fluidized bed for the flue gas at 70-200 deg.C containing SO2 and NOx is characterized by that said flue gas and the active coke as desulfurizing agent are continuously fed in the reactor of desulfurizing tower for removing dust, SO2 and NOx, the clean flue gas flows in chimney for exhausting it, the active coke is regenerated then in regenerating tower for further using it in desulfurizing tower, and SO2 is reduced to become sulfur to be recovered. Its advantages are high desulfurizing efficiency, low cost and water consumption, and no secondary pollution.

The present invention provides an ultra high power graphite resistor rod with 600mm diameter and a method for producing the same. The method utilizes domestic coal series acicular coke with low true density in main physicochemical standard, high heat expansion coefficient and sulphur content for producing the large-size ultra high power graphite resistor rod with 600mm diameter. Volumetric density, bending strength, elastic modulus, electric resistivity and heat expansion coefficient of the product reaches the international standard after detecting which can solve difficult problem that the domestic coal series acicular coke can not produce the large-size ultra high power graphite resistor rod with 600mm diameter because of low true density in main physicochemical standard, high heat expansion coefficient and sulphur content, and can realize localization for raw material acicular coke of the large-size ultra high power graphite resistor rod, simultaneity, also can solve problem that the acicular coke depends on importation in a long time and has high cost for restricting expanding yield and scale of the ultra high power graphite resistor rod in carbon industry. The product can reduce cost and improve economic performance.

The invention relates to a water heat-transfer shift process for by-product high-grade steam energy-saving deep conversion. According to the process, a primary water heat-transfer shift converter and a secondary shift converter are adopted, CO in feed gas reacts with H2O to generate H2 and CO2 under the catalysis of a Co-Mo (copper-zinc) catalyst, and CO in shift gas coming out of a shift system is less than or equal to 0.1% (dry basis). In the process, CO is subject to deep conversion, the feed gas (containing water gas, semi-water gas, natural gas conversion gas or coke-oven gas conversion gas) utilization rate is high, the shift catalyst is not overheated, and the catalyst has a long service life; meanwhile, by-product saturated steam with the pressure of 0.5 to 9.0 MPa is generated, sensible heat and latent heat in the shift gas are further recovered by deoxygenated water and desalted water, low-grade heat energy is converted into high-grade heat energy, cooling water consumption is reduced, the temperature of` the shift gas coming out of a process system is lower than or equal to 40 DEG C, equipment is few, the flow is short, the investment is small, and the resistance is low (less than or equal to 0.05MPa).

The present invention relates to amorphous refractory material, and is especially one kind of no-water stemming material for blast furnace taphole and its preparation process. The no-water stemming material is prepared with coke powder 15-25 wt%, clay 10-20 wt%, bauxite corundum 20-36 wt%, silicon carbide 10-20 wt%, asphalt 8-16 wt%, sericite 5-9 wt%, additive 1-5 wt% and binding agent 12-22 wt%, and through crushing, sieving, pre-mixing, rolling, kneading and extruding. The no-water stemming material has excellent plasticity and sintering performance, high strength at high and middle temperature and high slag and molten iron flush resistance, and can meet the requirement of high strength smelting in blast furnace.

The present invention relates to a production method of foundry shaped coke and its equipment system for producing said foundry shaped coke. Said method includes the procedures of preparing material,pulverizing, cold stirring, hot stirring, forming and carbonization and coking, and its equipment system includes material-preparing chamber, pulverizing machine, cold stirring machine, hot stirring machine, forming machine and carbonizing furnace, etc.

The invention discloses a gas heat carrier low-temperature pyrolyzing furnace and a gas heat carrier low-temperature pyrolyzing method. High-moisture materials are subjected to drying preprocessing in the pyrolyzing furnace by means of a gas heat carrier convection drying method, and hot gas is uniformly distributed in a drying section under the action of a gas distribution umbrella. Dried materials enter a dry distillation area where gas heat carriers transversely penetrate through materials, and exchange heat with the gas heat carriers prior to heating to enable low-temperature pyrolytic reaction. Gas in the furnace is formed by mixing lower coke quenching coal gas with hot flue gas in a combustion area, enters a flame path, then flows across a material layer from a flame path lattice wall to a gas collection lattice wall to enter a gas collection chamber, and is finally led out of the furnace through a gas collection passage formed by double-faced gas collection lattice walls and gas collection chamber gas distribution bricks. Pyrolyzed product hot semi-cokes enter a combined dry quenching device to be cooled and pass through a coal gas quenching area and a water-cooling heat exchange area sequentially. A guide chute on the lower portion of the furnace is connected with a discharger and a conveyor, and semi-cokes are uniformly led out and conveyed to a semi-coke storage yard under the action of the discharger and the conveyor.

A stemming for the tap hole of blast furnace is proportionally prepared from industrial corundum particles, silicon carbide particles, medium-temp asphalt particles, Suzhou clay powder, coke powder, high-Al powdered coal ash and tar oil through proportional mixing, stirring and vacuum extruding. It features low cost and high stability.

The invention relates to a process and a device for quickly preparing powdered active coke for desulfurization by utilizing pulverized coal. The process and the device are used for producing a powdered active coke product with certain desulfurization performance and reducing combustible gas. According to the process, the powdered active coke for desulfurization and a byproduct reducing gas are prepared from the pulverized coal of 20 to 500 microns by remaining in an entrained-flow bed fast reaction furnace for 1 to 60 seconds. The process and the device has three characteristics that 1, the desulfurization active coke can be prepared by directly utilizing the pulverized coal for combustion of a boiler, so in-situ preparation of a desulfurizing agent of a coal-fired power plant can be realized, and the production cost and the transportation cost of the active coke are reduced; 2, the reducing combustible gas generated in the production process of the active coke can serve as a reburning fuel and is fed into the boiler, so the production quantity of nitric oxide during combustion of the pulverized coal is reduced and the energy efficiency of the whole process is improved; and 3, sulfur dioxide can be recovered and high-concentration sulfur dioxide can be reduced into elemental sulfur, so resource utilization of the sulfur dioxide can be realized.

The invention relates to a method for producing active pulverized lime by utilizing coal gas to calcine limestone through a suspended state pre-heating decomposing furnace, which belongs to the field of environment protection production of building materials. The method comprises the voltage stabilizing and conveying process of coal gas, the combustion heating process of the coal gas in a decomposing furnace for sufficiently combusting the coal gas in the suspended state pre-heating decomposing furnace to obtain the active quicklime powder as staflux in the lime calcining production, and the process for cooling the lime by a grate type cooler. Coke-oven coal gas, blast furnace coal gas, converter coal gas and mixed coal gas in the metallurgy production process are respectively adopted as fuel for replacing the coal powder in the traditional process for calcining and decomposing the lime powder. The method solves the problem of environment pollution caused by coal firing, improves the utilization rate of the excessive coal gas generated during steel making, reduces the outwards discharge of the coal gas, simultaneously improves the production efficiency and the heat efficiency of the lime calcination, and improves the activity of the lime.