136 results about "Faujasite" patented technology

The modified octahedral zeolite is prepared through the once exchange reaction of octahedral zeolite, phosphorus compound and ammonium compound, the further reaction inside exchange slurry with introduced RE solution, filtering, washing and roasting in vapor. The catalyst contains the modified octahedral zeolite 5-45 wt%, clay 15-85 wt% and heat resistant inorganic oxide 15-85 wt%. The catalyst is prepared through mixing the zeolite component, clay and the precursor of the heat resistant inorganic oxide, spraying to form and washing. The catalyst has high activity stability, high gasoline yield, low coke yield, strong heavy oil cracking capacity and high heavy metal pollution resistance.

A molecular sieve adsorbent for the purification of gas streams containing water vapor and carbon dioxide and a process for its preparation. The adsorbent is a sodium form of a low-silica faujasite having a silica to alumina ratio of about 1.8:1 to about 2.2:1, a residual content of potassium ions less than about 8.0 percent (equiv.), a low content of crystalline and amorphous admixtures and crystal sizes generally within the range of 1-4 mum, blended with a binder.

An improved catalyst for edible oil hydrogenation produced by the incorporation of a sulphur adsorbing zeolite with a supported nickel hydrogenation catalyst. The zeolite is a cation-exchanged form of low silica faujasite with a silica to alumina ratio from about 1.8 to 2.1. The hydrogenation catalyst is a supported nickel catalyst. The zeolite is incorporated into the stabilization media with the reduced hydrogenation catalyst to form a physical blend of sulphur adsorbing zeolite and reduced nickel hydrogenation catalyst in a stabilization medium.

The present invention relates to agglomerated zeolite adsorbents based on faujasite with an Si / Al ratio such that 1<=Si / Al<=1.15, at least 70% exchanged with barium and optionally with potassium, and on a binder, preferably a zeolitizable binder.They are obtained by agglomerating zeolite powder with a binder, followed by exchange of the zeolite ions for barium ions and activation of the adsorbents thus exchanged.These adsorbents are particularly suitable for the adsorption of the para-xylene contained in aromatic C8 hydrocarbon fractions in the liquid phase, in processes of simulated fluid-bed type.

The invention relates to a sorbent for reducing sulfer content in hydrocarbon oil, which comprises 1 to 30 weight percent of rare earth faujasite, 5 to 40 weight percent of active metal oxide and 30 to 94 weight percent of carrier, wherein the carrier comprises alumina and zinc oxide. The mixture of the rare earth faujasite and the carrier is preformed into porous heat-resistant solid particles which are introduced with the metal active ingredient to prepare the sorbent; sulfer-containing light hydrocarbon oil raw material and hydrogen donors enter a reactor filled with the sorbent for separating reaction; materials and products after the separating reaction are sent to a subsequent separation system for product separation; sorbent to be regenerated after the reaction is burnt to be regenerated after steam stripping; and the regenerated sorbent is reduced by the hydrogen donors and returned to the reactor for recycling. The sorbent realizes deep removal of sulfer in the light hydrocarbon oil; meanwhile, the product gasoline has high octane number, low benzene content and high strength.

A description is given of agglomerates of faujasite X with an Si / Al ratio of 1, the inert binder of which, on the one hand, has been converted to active zeolite by conversion to zeolite in an alkaline liquor, and which have been subjected, on the other hand, to an exhaustive lithium exchange. These adsorbents develop a nitrogen adsorption capacity (1 bar / 25° C.) of at least 26 cm<3> / g, which makes them excellent adsorbents for the non-cryogenic separation of gases from air and for the purification of hydrogen.

An adsorbent-catalyst for removal of sulphur compounds from sulfur compound contaminated gas and liquid feed streams, wherein the adsorbent-catalyst is a synthetic X or Y faujasite with a silica to alumina ratio from 1.8:1 to about 5:1 and wherein 40 to 90% of the cations of the faujasite include transition metals of Groups IB, IIB and VIIB with the balance of the cations being alkali or alkaline earth metals.

A catalyst and a method for selectively reducing nitrogen oxides (“NOx”) with ammonia are provided. The catalyst includes a first component comprising a zeolite or mixture of zeolites selected from the group consisting of ZSM-5, ZSM-11, ZSM-12, ZSM-18, ZSM-23, MCM-zeolites, mordenite, faujasite, ferrierite, zeolite beta, and mixtures thereof; a second component comprising at least one member selected from the group consisting of cerium, iron, copper, gallium, manganese, chromium, cobalt, molybdenum, tin, rhenium, tantalum, osmium, barium, boron, calcium, strontium, potassium, vanadium, nickel, tungsten, an actinide, mixtures of actinides, a lanthanide, mixtures of lanthanides, and mixtures thereof; optionally an oxygen storage material and optionally an inorganic oxide. The catalyst selectively reduces nitrogen oxides to nitrogen with ammonia at high temperatures. The catalyst has high hydrothermal stability. The catalyst has high activity for conversion of low levels of nitrogen oxides in exhaust streams. The catalyst and the method may have special application to selective reduction of nitrogen oxides in exhaust gas from gas turbines and gas engines, although the catalyst and the method have broad application to a wide range of gas streams that have excess oxygen and high temperatures. The temperature of exhaust gas from gas turbines and gas engines is high. Both the high temperature and the low levels of inlet NOx are challenging for selective catalytic reduction (SCR) catalysts.

The invention provides a sorbent used for reducing the content of sulfur in light hydrocarbon oil. According to weight percentage, the sorbent comprises 1-30 percent of phosphorus-modified rare earth faujasite, 5-40 percent of active metal oxide and 30-94% of carrier; wherein, the carrier comprises alumina and zinc oxide; the rare earth faujasite is modified by phosphorus and is pre-formed into porous heat-resistance solid grains together with carrier mixture; subsequently, the active metal oxide is led into the solid grains, thus preparing the sorbent; the light hydrocarbon oil raw material containing the sulfur and hydrogen donor enter a reactor filled with the sorbent; the materials are separated after reaction; the reaction products are sent to a subsequent separation system so that the product is separated; the sorbent to be regenerated after reaction is stripped, burned and regenerated; and the regenerated sorbent is reduced by the hydrogen donor and subsequently returns to the reactor so as to be circularly used. The sorbent realizes that the sulfur of light hydrocarbon oil is deeply removed, and simultaneously, the octane number of the outcome gasoline is higher, while thebenzene content is lower and the strength is higher.

A hydrocarbon cracking catalyst containing modified octahedra zeolite is prepared from modified octahedra zeolite, one or moke kinds of other modified zeolite, clay and refractory inorganic oxide through proportional mixing, spray shaping, and washing. Its advantages are high activity and stability, high gasoline output rate, low coke output rate, and high resistance to heavy metal pollution.

A catalytic cracking catalyst and its production are disclosed. The catalyst consists of clay 20 - 80m%, silica sol 5 - 30m%, pseudodiaspore 0 - 30%, faujusite with cell parameters of (2.432 - 2.472nm) 5 - 40%, and balanced of ZSM-5 zeolite, beta zeolite and their mixture, oxide selected from Sb, rare earths, Ti, Mg, Zn, P, Sr or their mixture. It uses silica sol as substrate or silica sol and pseudodiaspore as composite substrate to increase macromolecular cracking ability and to improve wearproof performance. It can be produced by non-continuous process or multi-stream continuous process with easy mass production.

The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a cerium component which enhances the stability and sulfur reduction activity of the catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking / sulfur reduction catalyst.

A molecular sieve adsorbent for the purification of gas streams containing water vapor and carbon dioxide. The adsorbent is a combination of sodium form of a low-silica faujasite, having a residual content of potassium ions less than about 8.0 percent (equiv.), a low content of crystalline and amorphous admixtures and crystal sizes generally within the range of 1-4 mum, and a binder. A process for the adsorbent preparation which comprises specific parameters of low silica faujasite synthesis, sodium-potassium ion exchange, blending and granulation.

Hydrocracking catalyst composition comprising an optional metal hydrogenation component supported on a carrier comprising a zeolite of the faujasite structure having a unit cell size in the range of from 24.10 to 24.40 Å, a bulk silica to alumina ratio (SAR) above about 12, and a surface area of at least about 850 m2 / g as measured by the BET method and ATSM D4365-95 with nitrogen adsorption at a p / po value of 0.03.

The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a rare earth component which enhances the cracking activity of the cracking catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 4 of the Periodic Table, preferably vanadium. The rare earth component preferably includes cerium which enhances the sulfur reduction activity of the catalyst. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking / sulfur reduction catalyst.

The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a cerium component which enhances the stability and sulfur reduction activity of the catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking / sulfur reduction catalyst.

A process for removal of carbon dioxide from air using lithium-exchanged X-zeolites at low carbon dioxide partial pressures is provided. The process is particularly useful in applications where fresh air is not available and exhaled air needs to be recycled. An apparatus for carrying out the process is also provided.

A modified faujasite is obtained by exchanging the faujasite with a phosphorus compound and an ammonium compound, and then introducing a rare earth solution into the exchange slurry for further reaction, filtering, washing, and roasting with water vapor. Mix the zeolite component, clay and the precursor of the high-temperature-resistant inorganic oxide uniformly in a certain proportion, spray molding, and washing. The prepared catalyst has good activity and stability, high gasoline yield, low coke yield, and heavy oil Strong cracking ability and heavy metal pollution resistance.

A hydrocracking catalyst is provided that includes a crystalline molecular sieve material component having a faujasite structure and an alpha acidity of less than 1, preferably 0.3 or less, and a dispersed Group VIII noble metal component. The extremely low acidity allows selective hydrocracking of the aromatic and naphthenic species in a feedstock, while limiting the cracking of paraffins. The catalyst produces improved yields of products, such as diesel fuel, at high conversion rates and with high cetane values.

This invention relates to aggregates of small particles of synthetic faujasite zeolite. Small primary particles of zeolite are clustered into larger secondary particles. The observable average width of the primary particles may be 0.3 micron or less and the observable average width of the secondary particles may be 0.8 micron or more. The silica to alumina ratio of the zeolite may be less than 4:1.

The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a cerium component which enhances the stability and sulfur reduction activity of the catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking / sulfur reduction catalyst.

The invention belongs to the technical field of zeolite molecular sieve synthesis and particularly relates to a method for preparing low-silicon NaX zeolite by applying an activated silicon source. The product nano (100nm-500nm) NaX zeolite, the SiO2 / Al2O3 ratio of which is less than 2.1, is synthesized in a sodium-containing silicoaluminate system by using the method provided by the invention. The method comprises the following steps: firstly, preparing the activated silicon source, wherein the activated silicon source is obtained by adding a certain amount of alkaline aluminum source solution to a common silicon source so that the high-polymerized silicate is depolymerized to form low-polymerized silicate, and the low-polymerized silicate is combined with aluminate to generate an effective silicoaluminate precursor and a faujasite micro-crystal nucleus; and synthesizing the low-silicon NaX zeolite through controlling the crystallization conditions and crystallization temperature of the molecular sieve preparation process.

The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a cerium component which enhances the stability and sulfur reduction activity of the catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking / sulfur reduction catalyst.

A process for the production of faujasite X agglomerates containing at least 95% of faujasite LSX, that is to say with an Si / Al ratio equal to 1, constituting the active adsorbent. The agglomerate is formed from zeolite LSX and from a binder which can be converted to zeolite, the conversion of which to active zeolite is obtained by conversion to zeolite in a sodium hydroxide / potassium hydroxide or sodium hydroxide liquor.

A method is taught for capturing organoleptic odor. Where a functional additive has odors from a plurality of organolepic sources, and is blended with an odor control agent and a resin to produce a blend, where the blend exhibits at least a 5% reduction in odor based on a standardized odor test SAE-J1351. The odor control agent is selected from the group but not limited to: nepheline syenite, silica gel, hydrogels, hard and soft clays, bentonite, clinoptilolite, hectorite, cationic exchanged clinoptilolites, cerium, cesium, chabazite, faujasite, gmelinite, brewsterite, calcium silicate, hydrotalcites, zinc or magnesium aluminum hydroxy carbonates, zinc oxide, zinc hydroxide, zinc carbonate, calcium oxide, calcium hydroxide, calcium carbonate, potassium meta phosphate, silver oxide, magnesium hydroxide, magnesium oxide, copper oxide, ferric and ferrous oxides, sorbitol, glucitol, mannitol, glucose, dextrose, dextrin, allophanes, silica, sodalite, silicon oxide, aluminum oxide, natural zeolites, manganese dioxide, nano zinc oxide and nano titanium and combination thereof.

The invention discloses an adsorbent capable of simultaneously adsorbing and removing SO2, NOx and CO2 from coal-fired flue gas, and a preparation method and use thereof. In the preparation of the adsorbent, faujasite (X type and Y type), LTA (lipoteichoicacid) type zeolite, mordenite or a ZSM-5 (zeolite molecular sieve) molecular sieve is used as an adsorption carrier, and the carrier is put in solutions, such as a lithium chloride solution, a potassium chloride solution and the like for ion exchange; then, the carrier is cleaned and dried; and finally, the carrier is put in a muffle furnace for roasting so as to prepare the required adsorbent. In the use of the adsorbent, the adsorbent is applied to removing the SO2, the NOx and the CO2 from the coal-fired flue gas so as to reach the aim of purifying the flue gas. With the adoption of the adsorbent disclosed by the invention, the simultaneous removal of a plurality of pollutants from flue gases is realized, the adsorption efficiency is high, and the operation is simple; and the preparation method of the adsorbent is mature and stable, convenient and simple, and easy to realize.

The invention relates to a method for quick in situ crystallization synthesis of faujasite, which comprises the following steps: (1) dissolving alkali sodium salt, aluminum containing compounds and water glass in water or evenly mixing alkali sodium salt, aluminum containing compounds and the water glass with the water; (2) adding kaolin into the mixing solution for pulping; (3) ageing the mixing pulp while stirring the mixing pulp; (5) adding a guide agent metering a Y molecular sieve; (6) transferring the mixture to a reaction kettle for crystallization for less than 20 hours; and (7) filtering and water-washing the crystallization product to obtain the in situ crystallization product. By using the method, the in situ crystallization synthesis of the faujasite is realized in a mode of adding an aluminum source, so that the crystallizing time is greatly shortened, the product properties are improved, and the synthesized faujasite can be used as a component of hydrogenation cracking catalysts and the like.

A hydrocracking catalyst containing Si-Al oxides contains two molecular sieves, one's metal components selected from Fe, Co or Ni of VIII family, at least one of them, and another's selected from Mo or W of VIB family, at least one of them. Its K value is 0.4 - 15A.(cm2.g)-1. One molecular sieve with octahedral zeolite structure with the content of Si-Al oxides of 10 - 90wt% of the catalyst, and another's limiting exponential is 0.5 C10G 47 / 20 1 15 3 2003 / 5 / 30 1552818 2004 / 12 / 8 1261542 2006 / 6 / 28 2006 / 6 / 28 2006 / 6 / 28 SINOPEC Beijing 100029 Shi Jianwen Nie Hnog Mao Yichao xu shu pang lizhi 72001 The Company Ltd. of the Chinese Patent Agency (Hong Kong) Zi Building 22, Yingjun Centre, No.23, Gangwan Road, Hong Kong Wanzi

A catalyst and a method for selectively reducing nitrogen oxides (“NOx”) with ammonia are provided. The catalyst includes a first component comprising a zeolite or mixture of zeolites selected from the group consisting of ZSM-5, ZSM-11, ZSM-12, ZSM-18, ZSM-23, MCM-zeolites, mordenite, faujasite, ferrierite, zeolite beta, and mixtures thereof; a second component comprising at least one member selected from the group consisting of cerium, iron, copper, gallium, manganese, chromium, cobalt, molybdenum, tin, rhenium, tantalum, osmium, barium, boron, calcium, strontium, potassium, vanadium, nickel, tungsten, an actinide, mixtures of actinides, a lanthanide, mixtures of lanthanides, and mixtures thereof; optionally an oxygen storage material and optionally an inorganic oxide. The catalyst selectively reduces nitrogen oxides to nitrogen with ammonia at high temperatures. The catalyst has high hydrothermal stability. The catalyst has high activity for conversion of low levels of nitrogen oxides in exhaust streams. The catalyst and the method may have special application to selective reduction of nitrogen oxides in exhaust gas from gas turbines and gas engines, although the catalyst and the method have broad application to a wide range of gas streams that have excess oxygen and high temperatures. The temperature of exhaust gas from gas turbines and gas engines is high. Both the high temperature and the low levels of inlet NOx are challenging for selective catalytic reduction (SCR) catalysts.