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323 results about "Nickel catalyst" patented technology

Nickel(II) precatalysts are a type of catalyst used in organic reactions. Many transformations are catalyzed by nickel in organometallic chemistry and in organic synthesis. Many of these transformations invoke a low valent (generally Ni(0)) species as the active catalyst.

Supported nickel catalyst for preparing 1, 3-propylene glycol through hydrogenation of 3-hydroxypropionaldehyde as well as preparation method and application of supported nickel catalyst

The invention discloses a supported nickel catalyst for preparing 1, 3-propylene glycol through hydrogenation of 3-hydroxypropionaldehyde as well as a preparation method and application of the supported nickel catalyst, and relates to the technical field of catalysts. The modified long-chain multi-carbon inducer is used, and a special long-chain molecular structure and a branched chain group of the inducer can effectively and selectively adsorb and occupy a micropore impregnation site; the preparation method has the beneficial effects that more active component nickel species are obviously promoted to be dispersed in main reaction confinement spaces such as mesopores and macropores and interact with the carrier to form effective active sites, and active component steeping liquor is inhibited from entering micropore channels due to capillary action; the active site failure caused by agglomeration of nickel species in micropores in the subsequent drying and roasting process of the catalyst precursor is avoided, the efficient and directional reaction is ensured, the generation of by-products is greatly reduced, the pressure is relieved for the subsequent product rectification separation, and the final product purity is improved. The catalyst provided by the invention can still keep an excellent catalytic effect when the air speed of a 3-hydroxypropionaldehyde solution is increased to 6.5 h <-1 >.
Owner:FUHAI (DONGYING) TECHNICAL SERVICES CO LTD

Rare earth microalloyed ultrahigh-strength high-toughness hot work die steel and preparation method thereof

The invention relates to the technical field of powder metallurgy materials, and discloses rare earth microalloyed ultrahigh-strength high-toughness hot work die steel and a preparation method thereof.The die steel is prepared from 4Cr5MoSiV1 pre-alloyed powder, rare earth hydride, boron carbide and porous amorphous carbon powder loaded with a nickel catalyst. The preparation method comprises the steps of material mixing, sheath packaging, graded dynamic reaction thermal devolatilization, hot isostatic pressing densification and heat treatment, in the graded dynamic reaction thermal devolatilization, active hydrogen generated by decomposition of rare earth hydride is used for reducing oxide on the surface of powder, and nickel catalyzed carbon powder is used for capturing water vapor at low temperature to generate CO to be discharged. An oxide film on the surface of the powder is thoroughly removed through in-situ chemical reaction, original particle boundaries are eliminated, meanwhile, a nano strengthening phase with high thermal stability is generated in situ, and the high-temperature strength, impact toughness and tissue compactness of the die steel are remarkably improved.
Owner:XINYU UNIV

Electrocatalytic oxidation method for highly selectively converting 5-hydroxymethylfurfural into 2, 5-furandicarboxylic acid by using cobalt-nickel bimetallic catalyst

The invention discloses an electrocatalytic oxidation method for highly selectively converting 5-hydroxymethylfurfural into 2, 5-furandicarboxylic acid by using a cobalt-nickel bimetallic catalyst, and belongs to the technical field of electrochemistry. Firstly, foamed nickel is pretreated; secondly, preparing a cobalt-nickel mixed solution, synthesizing the catalyst by adopting a solvothermal method, and characterizing the catalyst; and thirdly, preparing a three-electrode system by taking the cobalt-nickel catalyst as a working electrode, a spiral platinum wire electrode as a counter electrode, a Hg / HgO electrode as a reference electrode, an alkaline solution as an electrolyte and a Nafion 117 proton membrane as a diaphragm to realize conversion. And finally, testing the stability and cyclicity of the cobalt-nickel catalyst. Under the same potential, the material has the highest current density, the maximum electrochemical active area and the optimal charge transfer rate; the self-degradation of HMF can be effectively inhibited, the electrocatalytic oxidation has lower initial potential than the oxygen evolution reaction, and the electrode cycle stability is good; the method is simple in process, mild in condition and beneficial to industrial production.
Owner:DALIAN UNIV OF TECH

A green deolefination method that completely replaces white clay

The present application relates to a kind of green olefin removal method completely replacing clay, which comprises under liquid phase continuous hydrotreating conditions, first, reforming generated oil is mixed with hydrogen through high-efficiency mixer, hydrogen is mixed with reforming generated oil intensively and quickly, and saturated hydrogen-dissolved reforming generated oil is obtained, the saturated hydrogen-dissolved reforming generated oil is sent into first hydrogenation reactor, first contact with nickel-containing catalyst, and the reaction product is then introduced into second hydrogenation reactor, and contact with noble metal-containing catalyst.Reformate is treated by olefin removal, and the product obtained mainly contains benzene, toluene, xylene and other aromatic hydrocarbons, the bromine index of which is less than 20 mgBr / 100g oil, and the loss of aromatic hydrocarbons is less than 0.1wt%.
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

Titanium dioxide modified mesoporous nickel catalyst as well as preparation process and application thereof

The invention relates to the technical field of preparation of catalysts, in particular to a titanium dioxide modified mesoporous nickel catalyst, a preparation process and application thereof, and the preparation method comprises the following steps: S1, preparing a titanium dioxide modified mesoporous silicon dioxide material; s2, nickel-based acid liquid is added into the titanium dioxide modified mesoporous silicon dioxide material, ultrasonic treatment is performed for 1 h after sufficient mixing, standing is performed for 24 h at the room temperature so as to perform the dipping process, and then the mixture is transferred into a drying oven and dried at the temperature of 110 DEG C; and S3, uniformly grinding the dried solid, putting a sample into a crucible, transferring the sample into a tubular furnace, introducing argon as a protective atmosphere, heating to 550 DEG C at a heating rate of 1 DEG C / min, and roasting for 6 hours to obtain the titanium dioxide modified mesoporous nickel catalyst. The method has relatively high industrial potential, can replace an expensive noble metal catalyst to be used for industrial production, and lays a certain technical foundation for realizing final industrial production of a carbon dioxide methane reforming reaction and integrating the reaction into a green energy storage system.
Owner:BENGBU COLLEGE

Preparation method of bicyclobutane

The invention provides a preparation method of bicyclobutane, and belongs to the technical field of aerospace fuels. According to the method, the bicyclobutane fuel is efficiently synthesized through nickel-catalyzed bromocyclobutane coupling reaction, and according to the method, nickel chloride serves as a catalyst, a reducing agent manganese powder is added, and the debromination self-coupling reaction of halogenated cyclobutane is promoted. The reduction coupling fuel synthesis strategy shows high efficiency, and the conversion number (TON) of the nickel catalyst can reach 44. The reaction can be carried out in an open system at the temperature of 40 DEG C, a water-free and oxygen-free environment is not needed, the yield of the bicyclobutane fuel is 88%, and the purity of the bicyclobutane fuel is 99% or above. Fuel performance tests show that bicyclobutane has excellent physical and chemical properties, the density is 0.82 g.mL <-1 >, the combustion net heat value is 44.39 MJ.kg <-1 >, and bicyclobutane is a high-energy aerospace fuel with great potential.
Owner:龙子湖新能源实验室

Synthesis and photocatalytic application of carbazole terpyridyl nickel catalyst

The invention belongs to the technical field of preparation of transition metal organic photocatalysts, and particularly relates to design and a preparation method of a carbazole terpyridyl nickel catalyst. The invention aims to design and synthesize a carbazole terpyridyl nickel catalyst with light / nickel synergistic catalytic activity. The preparation method comprises the following specific synthesis steps: reacting different types of alpha-pyridone pyridinium and alpha, beta-unsaturated ketone in methanol, and carrying out suction filtration, washing, drying and other operations to obtain the corresponding carbazole terpyridyl ligand. The carbazole terpyridyl ligand and anhydrous nickel bromide are subjected to a heating reflux reaction in a tetrahydrofuran solution, and the corresponding carbazole terpyridyl nickel catalyst is obtained through methanol washing, suction filtration, drying and other operations. The terpyridyl nickel catalyst has high catalytic activity in a C-N, C-O and C-S coupling reaction promoted by visible light.
Owner:NANJING FORESTRY UNIV

Monolithic foamed nickel catalyst, preparation method thereof and efficient application of monolithic foamed nickel catalyst in methane dry reforming

The invention discloses a monolithic foamed nickel catalyst, a preparation method of the monolithic foamed nickel catalyst and efficient application of the monolithic foamed nickel catalyst in methane dry reforming, and relates to a strategy of in-situ construction of a Ni interface active site monolithic catalyst by taking porous foamed metal as a substrate. The reaction rate of methane dry reforming is improved by utilizing excellent thermal conductivity and abundant three-dimensional channels of a foamed nickel structured metal material, and adverse effects of sintering, carbon deposition and the like on active sites caused by methane cracking and carbon monoxide cracking are balanced; the monolithic catalyst prepared by the invention is applied to a methane dry reforming reaction with a certain concentration, under the conditions that the pressure is 0.1-1 MPa, the mass space velocity is 10000-50000 mL.gcat <-1 >. H <-1 >, CH4: CO2: N2 is 1: 1: 3 and the temperature is 650-700 DEG C, the CO2 conversion rate exceeds 85%, the CH4 conversion rate exceeds 75%, and the monolithic catalyst is expected to be applied to an industrial methane dry reforming process.
Owner:ZHEJIANG UNIV OF TECH

Methods for preparing copolymers and for the oxidative degradation thereof

PendingUS20250361333A1Nickel catalystAlkali ions
This invention relates to nickel catalysts with alkali ions for homopolymerization and copolymerization. This invention also relates to methods of preparing copolymers and to methods of degrading copolymers.
Owner:UNIV HOUSTON SYST

Ceramic matrix composite (CMC) and preparation method thereof

The invention relates to the field of advanced ceramic materials, in particular to a ceramic matrix composite (CMC) and a preparation method thereof. The technical problems that a traditional CMC preparation technology is long in period, poor in structural uniformity and insufficient in toughness are solved. According to the method, surface-modified aluminum oxide ceramic microspheres are used as reinforcements, the surfaces of the microspheres are sequentially modified with hexagonal boron nitride nanosheets and a metal nickel catalyst, the microspheres, silicon carbide nanoparticles and a polycarbosilane precursor are mixed to form slurry, and a complex component is formed through multi-material additive manufacturing. A green body is prepared by using a 3D printing technology combining photocuring and material extrusion; carrying out ultraviolet curing on the green body, and carrying out staged heat treatment in an inert atmosphere, so that the precursor polymer is subjected to cross-linking curing, and meanwhile, carbon nanowires grow through in-situ catalysis; and finally, sintering under a pressurizing condition to realize matrix densification. The preparation period is greatly shortened, and the obtained composite material is uniform in structure, compact in matrix and excellent in mechanical property.
Owner:SICHUAN DONGZE TECH CO LTD

Carbon nano-reinforced thermoplastic polyurethane composite material as well as preparation method and application thereof

The invention relates to a carbon nano reinforced thermoplastic polyurethane composite material as well as a preparation method and application thereof. The composite material is prepared from the following components in parts by mass: 5 to 20 parts of diisocyanate, 10 to 30 parts of oligomer dihydric alcohol, 1 to 10 parts of bifunctional chain extender and 1 to 20 parts of filler, the filler is prepared from the following components in parts by mass: 0.95 to 18 parts of inorganic filler and 0.05 to 2 parts of carbon-based nano filler; preparing a carbon-based nanofiller of flaky carbon nanofibers, tubular carbon nanofibers or fishbone-shaped carbon nanofibers from reaction gas by using a metal catalyst through a chemical vapor deposition method; the metal catalyst is selected from an iron-nickel catalyst or a nickel-copper catalyst, the reaction gas comprises a carbon source gas and a reducing gas, the carbon source gas is selected from carbon monoxide or ethylene, and the reducing gas adopts hydrogen. Compared with the prior art, the material has good mechanical properties and damping performance, especially has excellent normal-temperature damping performance and damping temperature range, and is suitable for 3D printing.
Owner:SHANGHAI JIAOTONG UNIV

Cerium oxide supported nickel catalyst and preparation method and application thereof

The invention belongs to the technical field of catalysts, and relates to a cerium oxide supported nickel catalyst and a preparation method and application thereof, and the catalyst is composed of a metal nickel active component and a cerium oxide carrier. The cerium oxide prepared by adopting a reversed-phase microemulsion method is dispersed in a nano-scale manner, has a large specific surface area and abundant oxygen vacancies on the surface, can realize high dispersion of metal nickel after loading nickel on the cerium oxide, has relatively high stability, and is beneficial to realizing efficient methanation of carbon dioxide hydrogenation. By changing the preparation conditions of the reversed-phase microemulsion, the number of oxygen vacancies on the surface of the catalyst can be effectively adjusted, and the CO2 hydrogenation reaction performance of the catalyst is regulated and controlled. The cerium oxide supported nickel catalyst prepared by the invention has the CO2 conversion rate of 83% and the CH4 selectivity of 97%, and shows excellent CO2 conversion rate and methane selectivity, which indicates that the cerium oxide-containing catalyst provided by the invention has excellent CO2 hydrogenation performance, shows excellent catalytic activity, product selectivity and stability, and can be used for preparing a catalyst for hydrogenation of CO2. And large-scale industrial application can be realized.
Owner:YANSHAN UNIV

Fibrous silica lanthanum oxide-based catalyst for dry reforming of methane and methods of preparation thereof

A method for dry reforming of methane (DRM) includes introducing and passing a hydrogen (H2)-containing feed gas stream through a reactor to contact the H2-containing feed gas stream with particles of a catalyst at a temperature of from 500° C. to 900° C. to form a reduced catalyst; introducing and passing a mixed feed gas stream comprising methane (CH4) and carbon dioxide (CO2) through the reactor to contact the mixed feed gas stream with the reduced catalyst at a temperature of from 500° C. to 1000° C. thereby converting at least a portion of the CH4 and CO2 to H2 / CO and regenerating the catalyst particles to form a regenerated catalyst and producing a residue gas stream leaving the reactor. The catalyst may be a fibrous silica lanthanum oxide (FSL) catalyst, and / or a nickel-containing FSL (Ni / FSL) catalyst.
Owner:KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

Method for constructing aryl C-P bond through reaction of Ar-F compound of electron donating group catalyzed by nickel

The invention provides a method for constructing an aryl C-P bond through a reaction of an Ar-F compound of a nickel catalysis electron donating group, which comprises the following steps: in the presence of a nickel catalyst, an additive and alkali, carrying out a coupling reaction on a substituted aryl compound in a formula B and a compound in a formula C diphenylphosphine oxide in an organic solvent to generate an aryl phosphine oxide compound in a formula A, the reaction formula is shown in the specification, Ar is or, and R is an electron-donating group. The method disclosed by the invention has the effects that the substrate has universality, the operation is simple, the condition is mild, a noble metal catalyst and a phosphine ligand are not needed, the cost is low, and the yield is high.
Owner:JIUZHOU PHARMACEUTICAL (HANGZHOU) CO LTD

Oxidant for humic acid modification and method for preparing humic acid rich in carboxyl groups

An oxidant for humic acid modification and a method for preparing humic acid rich in carboxyl groups are provided. The oxidant used for humic acid modification includes cobalt-nickel catalyst loaded on biochars and hydrogen peroxide solutions. When preparing humic acid rich in carboxyl groups, first dissolving the humic acid in a 2 wt % sodium hydroxide solution to prepare a sodium humate solution; then, under stirring conditions, adding the oxidant used for humic acid modification to the sodium humate solution and react at 45-55° C. for 90-150 minutes; then freeze-drying to obtain the final product. The present disclosure selectively breaks and destroys the aromatic carbon structure of humic acid by using cobalt-nickel catalyst loaded on biochar in combination with hydrogen peroxide solution, and avoids the release of carbon dioxide generated by excessive oxidation of humic acid carbon structure, thereby directionally increasing the carboxyl content of humic acid.
Owner:INST OF AGRI RESOURCES & REGIONAL PLANNING CHINESE ACADEMY OF AGRI SCI

A coal tar pitch-based nickel catalyst, its preparation method and application

This invention provides a coal tar pitch-based nickel catalyst, its preparation method, and its application, belonging to the field of solid waste resource recycling and synthetic carbon materials technology. This invention uses a mixed roasting method to prepare a coal tar pitch-based nickel catalyst with micropores and mesopores from the residual coal tar pitch after coal tar extraction. The synergistic effect of active nickel as an active site and the functional groups on the support surface significantly improves its catalytic liquefaction performance, exhibiting the advantages of "low cost, high temperature resistance, and strong adaptability." The preparation method provided by this invention not only offers an effective way for the high-value recycling of coal tar pitch but also provides a low-cost material for green conversion, environmental governance, catalysis, and other fields. It represents a green resource utilization strategy with significant economic and environmental benefits and broad commercial prospects.
Owner:XINJIANG UNIVERSITY

Application of supported foamed nickel catalyst in catalytic oxidation of low-carbon alkane and aromatic hydrocarbon

The invention belongs to the field of catalysts, and particularly relates to a supported foam nickel catalyst for catalytic combustion of low-carbon alkane and aromatic hydrocarbon and a preparation method of the supported foam nickel catalyst. According to the invention, the strong oxidizing property of the acidic potassium permanganate is utilized to etch the foamed nickel, the capacity of the carrier for supporting the active component is improved, the non-noble metal active component is introduced through a simple impregnation method, the method has the advantages of simple operation, low preparation cost, high universality and the like, and the problems of low introduction amount of the active component, poor catalytic activity and the like of the foamed nickel catalyst are solved. The catalyst disclosed by the invention not only can be used for catalytic combustion of low-carbon alkane such as ethane and propane, but also can be used for catalytic combustion of other non-low-carbon alkane VOCs (Volatile Organic Compounds), and has a good application prospect.
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

Neutral phosphine phenol nickel catalyst with tert-butyl structure and preparation method of neutral phosphine phenol nickel catalyst

The invention discloses a neutral phosphine phenol nickel catalyst based on a tert-butyl structure. The catalyst has a structure shown as a formula (I), wherein R1 and R2 are respectively and independently selected from hydrogen, C1-C20 alkyl, fluorine, chlorine, bromine, iodine, nitryl, hydroxyl, substituted silicon group and C1-C20 substituted alkyl; r3 is independently selected from C1-C20 alkyl, C1-C20 substituted alkyl, phenyl or substituted phenyl, R4 and R5 are independently selected from hydrogen, fluorine, chlorine, bromine, iodine, C1-C20 alkyl, aryl, an oxygen-containing group, a nitrogen-containing group, a sulfur-containing group, a boron-containing group, an aluminum-containing group, a phosphorus-containing group, a silicon-containing group or a tin-containing group; tert-butyl is introduced into para-position and meta-position of a ligand phenol oxygen ring, and a protection barrier is formed by utilizing the steric hindrance effect of the t-butyl, so that decomposition and deactivation of the catalyst under a high-temperature condition are inhibited, the catalyst can stably play a catalytic role in an industrial common medium-high-temperature polymerization environment, and the process adaptation range of the catalyst is widened.
Owner:ANHUI UNIV

Nitrogen-doped carbon-wrapped nickel catalyst for synthesis of higher alcohols by assembly of bioethanol and preparation method therefor

The present invention relates to a nitrogen-doped carbon-wrapped nickel catalyst for synthesis of higher alcohols by assembly of bioethanol and a preparation method therefor. The preparation method includes the following steps: S1, subjecting a soluble nickel salt and polyacrylamide to stirring with water, completely dissolving and then drying to obtain a precursor, where a molar ratio of the soluble nickel salt to polyacrylamide is 1:(0.5-8); and S2, subjecting the precursor to pyrolysis in an inert atmosphere at 300° C.-800° C. for 1-6 hours to obtain the nitrogen-doped carbon-wrapped nickel catalyst. The catalyst prepared by the method of the present invention has an active phase with high dispersity which enables synthesis of higher alcohols by efficient assembly of small molecules, and has relatively high stability which can still maintain high conversion rate and high yield for organic phase after 10 times of repeated use.
Owner:GUANGDONG UNIV OF TECH

A transition metal phosphide catalyst, its preparation method and application

PendingCN122079091Atunable electronic structureIncrease transfer ratePhosphidesElectrodesNickel saltPtru catalyst
This invention discloses a transition metal phosphide catalyst, its preparation method, and its application, belonging to the field of electrocatalysis technology. The process includes: firstly, dissolving nickel salt, lanthanum salt, urea, and ammonium fluoride in deionized water to synthesize a nickel-lanthanum layered hydroxide nanosheet precursor via a hydrothermal method; secondly, preparing a lanthanum-doped nickel phosphide catalyst using a phosphating reaction; and thirdly, utilizing a lanthanum doping strategy to modulate the electronic structure of nickel phosphide and improve its electrocatalytic reaction performance. This lanthanum-doped nickel phosphide material exhibits good catalytic activity when used to catalyze hydrogen evolution and sulfide ion oxidation reactions. In an integrated two-electrode electrolyzer for sulfide ion oxidation-assisted hydrogen production, it outputs 10 mA cm⁻¹. ‑2 This invention achieves the goal of producing hydrogen and high-value-added sulfur products with low energy consumption by requiring a relatively low voltage of 0.525 V at a current density. It has advantages such as simple preparation process, controllable operating conditions, and low raw material costs, possessing the potential for large-scale production and serving as a high-performance catalyst for electrocatalytic hydrogen production and sulfur ion oxidation reactions.
Owner:NANTONG UNIV

Alpha-diimine ligand compound, alpha-diimine nickel catalyst and preparation method and application of alpha-diimine ligand compound and alpha-diimine nickel catalyst

The invention provides an alpha-diimine ligand compound, an alpha-diimine nickel catalyst and a preparation method and application of the alpha-diimine ligand compound and the alpha-diimine nickel catalyst, and belongs to the technical field of organic synthesis. Wherein R1 is selected from hydrogen, methoxyl or tertiary butyl; r2 is selected from methyl, ethyl or isopropyl; and R3 is selected from hydrogen or methyl. The alpha-diimine nickel catalyst prepared by adopting the alpha-diimine ligand compound can catalyze olefin to carry out homopolymerization reaction or copolymerization reaction, so that not only is excellent catalytic performance shown, but also a polyolefin material obtained by catalyzing olefin monomer homopolymerization reaction has excellent elastic recovery performance; and the catalyst has certain application potential in olefin polymerization industry.
Owner:UNIV OF SCI & TECH OF CHINA

Electrochemical method for preparing deuterated silane

PendingCN121519072AIsotope introduction to sugar derivativesSilicon organic compoundsPtru catalystSilanes
The invention discloses an electrochemical method of deuterated silane. The method comprises the following steps: in a protective atmosphere, mixing substituted silane, an electrolyte, a nickel catalyst, a ligand and deuterium water in a solvent, carrying out an electrochemical deuterization reaction under a constant current condition, and carrying out post-treatment to prepare the deuterated silane compound. The method takes deuterium water as a deuterium source, and is green, economical, cheap and easy to obtain; a catalytic amount of nickel and silane form a silicon-nickel intermediate, so that the polarity of silicon is reversed, and the generation of a silane self-coupling product and a silanol byproduct is effectively avoided; the electrochemical synthesis method has the characteristics of mild reaction conditions, cleanness, greenness and simplicity in reaction operation. The electrochemical synthesis method provided by the invention realizes successful preparation of the natural product post-modified deuterated silane, and has important significance in the aspects of drug development and deuterated compound research; the electrochemical synthesis method disclosed by the invention can resist high current to prepare the ten-gram-grade deuterated silane, and has a wide industrial application prospect. In addition, the deuterated silane synthetic product can be used as a silicon deuteration reagent, the practicability of the deuterated silane synthetic product in unsaturated bond reduction reaction is proved, and the deuterated silane synthetic product has a wide development prospect.
Owner:NANKAI UNIV

Method for producing 2-aminopropane-1-ol from hydroxyacetone by reductive amination

The invention relates to a method for producing 2-aminopropane-1-ol from hydroxyacetone by reductive amination using ammonia water and a co-solvent. The method comprises the following steps: mixing hydroxyacetone and ammonia water at a temperature of not more than 20 DEG C to obtain an oxazoline intermediate product; and adding either a solvent alone or a solvent and a second ammonia water to the oxazoline product in the presence of a nickel catalyst and hydrogen, and hydrogenating at a temperature of not more than 90 DEG C and a pressure of not more than 12 barggage to obtain 2-aminopropan-1-ol.
Owner:ADITYA BIRLA CHEM (THAILAND) LTD

A platinum-nickel catalyst gas diffusion electrode and its preparation method and application

The present invention provides a platinum-nickel catalyst gas diffusion electrode, its preparation method and application, belonging to the technical field of electrode materials. First, a conductive material and a polymer are dispersed in ethanol to obtain a dispersion liquid, and then the dispersion liquid is coated on a Ni mesh and subjected to calcination treatment to obtain a gas diffusion layer electrode. Then, the gas diffusion layer electrode is placed in an electrolyte for electrodeposition, and then calcination treatment is carried out to obtain the platinum-nickel catalyst gas diffusion electrode. The platinum-nickel catalyst gas diffusion electrode prepared by the present invention effectively solves the problem of slow kinetics of the 2e- electrochemical oxygen reduction reaction under neutral conditions, reduces the usage amount of noble metals, increases the production of hydrogen peroxide, shows high catalytic activity and stability, and can also remove harmful substances such as malachite green in water bodies.
Owner:浙江净界智能科技有限公司

Method for synthesizing propargyl silane derivative through nickel catalytic reduction coupling

The invention belongs to the technical field of organic synthesis, and discloses a method for synthesizing propargyl silane derivatives through nickel catalytic reduction coupling. The method comprises the following steps: in a protective atmosphere, taking an organic solvent as a reaction medium, and reacting a halogen-containing butyne compound with chlorosilane under the action of a catalyst, a ligand and a reducing agent to obtain the propargyl silane derivative. The structural formula of the propargyl silane derivative is I, the catalyst is a nickel catalyst, and the ligand is a nitrogen or phosphine ligand. The method disclosed by the invention is simple, low in cost, efficient in reaction, few in byproducts, easy to separate and purify and high in yield.
Owner:SOUTH CHINA UNIV OF TECH

Ruthenium-doped alumina-supported cobalt / nickel catalyst for ammonia decomposition to hydrogen and nitrogen

A method for ammonia (NH3) decomposition to hydrogen (H2) and nitrogen (N2) using a ruthenium-doped alumina-supported cobalt / nickel (Ru—CoNi / Al2O3) catalyst. The method includes introducing and passing an NH3-containing feed gas stream into a reactor to contact the NH3-containing feed gas stream with a reduced Ru—CoNi / Al2O3 catalyst at a temperature of 100 to 1000° C. thereby converting at least a portion of the NH3 to H2 and regenerating the Ru—CoNi / Al2O3 catalyst particles to form a regenerated Ru—CoNi / Al2O3 catalyst, and producing a residue gas stream leaving the reactor.
Owner:KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

A method for preparing a high carbon number diiodoperfluoroalkane

ActiveCN117843440BAlkaneCarbon number
The application relates to the technical field of fluorine-containing iodoalkane preparation, in particular to a preparation method of high-carbon-number diiodoperfluoroalkane, which comprises the following steps: reacting tetrafluoroethylene and elemental iodine to generate diiodotetrafluoroethane; and under the action of a catalyst, the diiodotetrafluoroethane is subjected to telomerization reaction with tetrafluoroethylene to generate high-carbon-number diiodoperfluorobutane and diiodoperfluorohexane; and the catalyst is a metal nickel catalyst supported on silicon dioxide. The metal nickel catalyst supported on silicon dioxide is used to make the diiodotetrafluoroethane and the tetrafluoroethylene subjected to telomerization reaction to obtain diiodoperfluoroalkane with higher carbon number. The application has the advantages of simple process, low reaction temperature and the like, and can significantly improve the yield of diiodoperfluorobutane and diiodoperfluorohexane.
Owner:ZHONGHAO CHENGUANG RES INST OF CHEMICALINDUSTRY CO LTD

Process for the hydrogenation of anhydromevalonolactone

The invention relates to a process for the manufacturing of biobased 3-methyl-delta-valerolactone (3MdVL) and 3-methyl-1,5-pentanediol (3MPD) via one- pot hydrogenation of anhydromevalonolactone (aMVL) in the presence of a Raney- Nickel catalyst. The hydrogenation occurs without solvent at a temperature from 120ºC-180ºC, preferably at 130ºC-170ºC and a pressure between 15-30 bar, preferably at a pressure between 18 and 22 bar. The hydrogenation time may vary between 3 and 25 hours, preferably between 6 and 24 hours.
Owner:MEVALDI BV

Preparation method and application of bimetallic catalyst for organic liquid hydrogen storage process

The present invention discloses a method for preparing a bimetallic catalyst for an organic liquid hydrogen storage process. The method comprises the following steps: mixing a nickel salt, a cobalt salt, ethylenediaminetetramethylenephosphonic acid, alanine, and a certain amount of deionized water to obtain a uniform composite active metal precursor impregnation solution; mixing the solution with pseudo-boehmite powder, ethylene glycol, hydrazine hydrate, and a dispersant and ultrasonically dispersing the solution to obtain a suspended fluid; then reducing the active metal component, adding a binder to the obtained semi-dry and semi-wet material, kneading the mixture, and extruding it into strips. Finally, drying the mixture to remove moisture and impurities, thereby obtaining a supported non-precious bimetallic cobalt-nickel hydrogenation catalyst for use in an organic liquid hydrogen storage process. The present invention obtains a supported non-precious bimetallic cobalt-nickel catalyst by adopting a suitable preparation method, which not only improves the activity of non-precious monometallic catalysts in the organic liquid hydrogenation process, but also avoids the high cost problem faced by using precious metal catalysts.
Owner:CHINA HYDROGEN YUANAN (BEIJING) TECH CO LTD