1089 results about "Hydrogen atom" patented technology

The invention provides a device for simulating the influence of deep fracture on natural hydrogen migration and an evaluation method, and belongs to the technical field of natural gas exploitation, the device comprises a core holder, an overburden pressure tracking pump, a temperature control device, a hydrogen storage tank and a nuclear magnetic device; the core holder is provided with two connecting ends; each connecting end is provided with a pressure gauge; the overburden pressure tracking pump is respectively connected with the two connecting ends; the temperature control device is connected with the core holder; the hydrogen storage tank is respectively communicated with the two connecting ends; a flow density meter is arranged on a communicating pipeline between the hydrogen storage tank and each connecting end; the nuclear magnetic device is used for forming a uniform magnetic field area at the core holder and acquiring nuclear magnetic signals of hydrogen atoms in the loaded sample in the uniform magnetic field; the evaluation method is carried out by adopting the device. According to the device for simulating the influence of the deep fracture on the migration of the natural hydrogen and the evaluation method, the migration mode of the hydrogen in the fractured reservoir can be accurately tracked and determined, and obtained experimental data are more comprehensive and accurate.

A photosensitive surface treating agent containing a compound represented by the following Formula (M1). In Formula (M1), R1 is a linear, branched or cyclic alkyl group having 1 to 6 carbon atoms, Y1 is a linear or branched alkylene group having 1 to 4 carbon atoms or a single bond, and the terminal carbon atom of the alkyl group for R1 may be bonded to a carbon atom constituting the alkylene group for Y1, and R1 and Y1 may form a ring. R2 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, R3 and R4 are each independently an alkyl group having 1 to 3 carbon atoms, n0 is an integer of 0 or more, and X is a halogen atom or an alkoxy group.

Systems and methods for measuring the content of an element in a soil comprises: a neutron source for irradiating the soil with neutrons; a detector assembly configured to detect an INS gamma spectrum of the soil; an instrument for measuring a moisture content of the soil; and a processor in communication with the detector assembly, the processor configured to: apply a moisture calibration coefficient to calculate a net peak area of a characteristic peak of the element in the INS gamma spectrum, the moisture calibration coefficient calculated to account for the moderation of fast neutrons by hydrogen atoms of water present in the irradiated soil at the location under analysis; and generate a concentration of the element in the soil. The instrument for measuring a moisture content of the soil may comprise the detector assembly. Systems and methods incorporating a temperature-controlled housing for the gamma detector assembly are also provided.

The invention discloses a hydrogen embrittlement-resistant welding wire for tailor welding of ultrahigh-strength aluminum-silicon coating hot-formed steel and a welding method, and belongs to the technical field of metal materials. 5.0%-7.0% of Ni; 0.3%-0.6% of Mo; 0.08% to 0.12% of Nb; mo, Nb and C react to form Mo2C / NbC nanophase fixed free hydrogen; 0.05%-0.1% of V: carrying out a reaction to form VC nanophase fixed free hydrogen; 0.5% to 0.8% of La; 0.3%-0.5% of Ce; 0.1%-0.5% of Ti; according to the invention, hydrogen atoms diffused in the welding process can be captured, the hydrogen content in a welding seam is obviously reduced, and the diffusible hydrogen amount is reduced by more than 40% under the hydrogen capturing effect of retained austenite, so that the hydrogen-induced crack sensitivity is reduced by 70%.

A high thermal conductive silicone composition including: (A) an organopolysiloxane having at least two aliphatic unsaturated hydrocarbon groups in one molecule and a kinematic viscosity at 25 C of 100 to 100,000 mm2 / s; (B) an aluminum powder having an average particle size of 50 μm or more; (C) a thermal conductive filler having an average particle size of 0.1 to less than 50 μm; (D) an organohydrogenpolysiloxane having two or more hydrogen atoms bonded to a silicon atom (Si—H groups) in one molecule; (E) a hydrolyzable organopolysiloxane represented by the following general formula (1); and (F) a platinum group metal catalyst having an effective amount. The high thermal conductive silicone composition can conform to the warpage of a substrate due to an increased material thickness and can maintain heat dissipation performance due to a high thermal conductivity.

The invention discloses a polyolefin catalyst, a preparation method thereof and an olefin polymerization method. R1 and R8 are selected from hydrogen atoms and respectively meet the following conditions: 6.0 ppm < = delta1 < = 6.8 ppm, 6.0 ppm < = delta8 < = 6.8 ppm, and delta1 and delta8 are respectively chemical shifts of R1 and R8 in hydrogen spectrum nuclear magnetism of the catalyst. The catalyst can catalyze copolymerization of ethylene / alpha-olefin with high activity.

This reactive silicon group-containing organopolysiloxane has, in each molecule, at least one group represented by structural formula (1) bonded to a silicon atom. The reactive silicon group-containing organopolysiloxane has good curability even if an amine-based compound is used as a curing catalyst, and gives a cured product having excellent yellowing resistance and heat resistance. (In the formula, R1 and R2 each independently represent a hydrogen atom, a C1-10 aliphatic saturated hydrocarbon group or a C6-10 aryl group, each R3 independently represents a C1-10 aliphatic saturated hydrocarbon group or a C6-10 aryl group, and n is an integer of 2-12. The wavy line represents a bond.)

The present disclosure belongs to technical field of OLEDs, and provides a compound suitable as a hole transport material and an electron blocking material of OLEDs. The compound has a general structure according to [Chemical Formula 1], in which Ar1 and Ar2 are each independently selected from a hydrogen atom, a substituted or unsubstituted C5-C40 aryl, or a substituted or unsubstituted C5-C40 heteroaryl; m and n are each an integer independently selected from 0, 1, or 2; X is selected from O, S, or —NR—; R is selected from hydrogen, or a substituted or unsubstituted C5-C40 aryl; Ar3 has a structure according to [Chemical Formula 2], in which R1-R8 are each independently selected from a hydrogen atom, or a substituted or unsubstituted C5-C40 aryl; Y is selected from O, S, or —NR′—; and R′ is selected from a hydrogen atom, or a substituted or unsubstituted C5-C40 aryl.

The present invention provides a hydrogenation catalyst for petroleum resin, the hydrogenation catalyst comprises a catalyst, the catalyst contains an active component main body expressed as a general formula of M1-M2 / SiO2-Al2O3, M1 is an alloy of Ni and Co, and the atomic ratio of Ni to Co is 2: 1-4: 1; m2 is a composite oxide of Mo and W, and the molar ratio of Mo to W is 1: 1-3: 1; and SiO2-Al2O3 is used as an aluminum silicate precursor and is subjected to hydrolytic condensation to form a composite carrier with a three-dimensional silicon-aluminum bond network structure. The invention relates to the technical field of petroleum resin catalysts. The surface of the carrier is anchored with double active components, namely nickel-cobalt alloy capable of efficiently cracking hydrogen and generating active hydrogen atoms and molybdenum-tungsten composite oxide capable of selectively adsorbing aromatic rings and sulfide molecules; and cracked hydrogen atoms can be quickly migrated to adsorption sites through the surface of the carrier, and aromatic ring hydrogenation saturation and deep removal of sulfur impurities can be synchronously realized, so that the working efficiency of the hydrogenation catalyst is effectively improved.

A paste that includes particles of a layered material in an ammonia aqueous solution. The particles include one or plural layers, the layers having a layer body represented by MmXn, wherein M is at least one metal of Group 3, 4, 5, 6, or 7, X is a carbon atom, a nitrogen atom, or a combination thereof, n is not less than 1 and not more than 4, and m is more than n but not more than 5, and a modifier or terminal T exists on a surface of the layer body, wherein T is at least one selected from the group consisting of a hydroxyl group, a fluorine atom, a chlorine atom, an oxygen atom, and a hydrogen atom, wherein the paste has a viscosity of 1 Pa·s or more at a shear velocity of 1 / s when the paste has a solid content concentration of 1.0% by mass.

The present invention is an addition-curable silicone composition containing components (A) to (C): (A) An addition reaction product of an organopolysiloxane represented by formula (1) and a compound represented by formula (2), the addition reaction product having two addition-reactive carbon-carbon double bonds per molecule. (1) (R1 is a C1-12 monovalent hydrocarbon group, R2 is a methyl group or a phenyl group, a is an integer of 0-50, and b is an integer of 0-300. ), (2) (R3 represents a C1-12 divalent hydrocarbon group.), (B) an organosilicon compound having a hydrogen atom bonded to at least two silicon atoms per molecule, and (C) a hydrosilylation reaction catalyst. Thus, provided are an addition-curable silicone composition that has high transparency and a high refractive index and yields a cured product having high strength and high elongation and a highly reliable optical semiconductor device sealed by a cured product thereof.

The present application provides a compound containing hydroxyl triarylamine, which can be used as a light extraction material, and its structure is shown in formula (I). In formula (I), hydroxyl groups and benzoxazole or benzothiazole are introduced into the triarylamine main structure of the traditional light extraction layer material. The hydrogen atoms in the hydroxyl group can form intramolecular hydrogen bonds with the heteroatoms on benzoxazole or benzothiazole, thereby improving the planarity of the molecule and increasing the packing density between molecules. At the same time, this intramolecular hydrogen bond undergoes intramolecular proton transfer under light conditions to form a resonance structure. This process converts ultraviolet light energy into heat energy release instead of material deterioration caused by photochemical reactions, thereby reducing the damage caused by ultraviolet light to the device. In addition, the raw materials of the compound are easy to obtain, and it has higher economic value while ensuring good device protection function. The present application also provides an organic electroluminescent device and a display device. #imgabs0#

Provided is an yttrium-based protective film which is excellent in plasma resistance and appearance. An yttrium-based protective film containing yttrium oxide is provided, wherein the yttrium-based protective film has a porosity of less than 0.5 vol % and a Vickers hardness of at least 800 HV. This yttrium-based protective film preferably has a thickness of at least 0.3 μm, a crystallite size of at most 40 nm, a Y2O3 (222) plane orientation of at least 50%, a hydrogen atom number of at most 5.0×1021 atoms / cm3 and a compressive stress of 100 to 1700 MPa.

A compound has a molecular weight of 500 to 5,000 and is composed of a hydrogen atom, a carbon atom, and a hetero atom. The hetero atom is at least one selected from an oxygen atom, a sulfur atom, a fluorine atom, and a silicon atom, and has one or more alicyclic structures, one or more aromatic ring structures directly bonded to the alicyclic structures, and one or more monovalent substituents Ms directly bonded to the aromatic ring structures. The monovalent substituent Ms is at least one substituent selected from a group containing a monovalent fluorine-containing aliphatic group, a group containing a monovalent sulfur fluoride-containing group, a group containing a monovalent siloxanyl group, and a group containing a monovalent saturated hydrocarbon group.

The invention discloses a rare earth doped zirconium titanium cobalt hydrogen storage material and a preparation method thereof, the chemical general formula of the zirconium titanium cobalt hydrogen storage material is Zr < 0.8 > Ti < 0.2-x > M < x > Co, x is 0-0.05, and M is a rare earth element of which the atomic radius is greater than that of Ti; the preparation method comprises the following steps: sequentially carrying out mixed smelting, crushing and grinding, vacuum treatment and activating treatment on the raw materials to obtain the hydrogen storage material. Rare earth elements are doped in the Zr0. 8Ti0. 2Co alloy, more hydrogen atom transmission channels are triggered through grain boundary and second phase regulation and control, and the diffusion speed of hydrogen atoms can be increased. The doped rare earth element can also reduce hydrogen atom adsorption energy and dehydrogenation performance energy barriers and improve hydrogen absorption and desorption kinetics, meanwhile, the rare earth element can also increase adsorption sites of hydrogen atoms, the hydrogen storage capacity is further improved, and the rare earth element can further optimize the microstructure of the hydrogen storage alloy and regulate and control the electronic structure so as to optimize the kinetics performance.

This reactive silicon group-containing organopolysiloxane, which contains, per molecule thereof, one group represented by structural formula (1) and bonded to a silicon atom at the end of a linear organopolysiloxane, forms a film having excellent water repellency, water sliding properties, and durability. (In the formula, R1 and R2 each independently represent a hydrogen atom, a C1-C10 aliphatic saturated hydrocarbon group, or a C6-C10 aryl group, R3s each independently represent a C1-C10 aliphatic saturated hydrocarbon group or a C6-C10 aryl group, Z represents an oxygen atom, a C2-C12 alkylene group, or a C8-C12 alkylene arylene group, and a line with a wavy line represents a bond.)

The invention discloses a method for predicting hydrogen diffusion of a multi-coating material on the surface of a material in a vacuum environment, and belongs to the technical field of hydrogen diffusion of materials. On the basis of a hydrogen atom diffusion mass transfer theory in a single-layer matrix material, a hydrogen atom diffusion mass transfer model of the double-coating material is constructed. The hydrogen atom diffusion differential equation, the capture / removal differential equation and the boundary desorption / adsorption differential equation of the single-layer matrix material are established in combination with respective material parameters corresponding to different materials of each layer, boundary condition parameters are introduced into an interlayer interface, the flux continuity and concentration transition relation between the matrix and the plating layer is processed, and the plating layer is obtained. And further obtaining the hydrogen concentration distribution and the dynamic hydrogen release rate in the multi-coating material. The prediction method disclosed by the invention is suitable for any coating combination, can quickly migrate only by replacing material data, and is suitable for multiple fields such as electronic packaging, vacuum devices, hydrogen fuel cells and the like.

Provided is a resist composition which generates an acid upon exposure to light, and the solubility of which with respect to a developer solution is changed by the action of the acid. The present invention employs the resist composition containing a compound (D0) that is represented by general formula (d0). In the formula, Rar represents an aromatic ring which may have a substituent. R01 represents a chain saturated hydrocarbon group having 1 to 10 carbon atoms. R02 represents a hydrogen atom or an optionally substituted chain saturated hydrocarbon group having 1 to 10 carbon atoms. R03 represents a halogen atom. j represents an integer of 1 or more, valence permitting. k represents an integer of 1 or more, valence permitting. Yd0 represents a divalent linking group or a single bond. m represents an integer of 1 or more, and Mm+ represents an organic cation having a valence of m.

This nonspecific reaction inhibitor is a copolymer containing a first repeating unit represented by formula (1) and a second repeating unit represented by formula (2). In formula (1), R1, R2, and R3 are each independently a hydrogen atom or a methyl group, X is NH or an oxygen atom, Y is SO3 - or COO-, and Yn and m are each independently an integer from 1 to 5. In formula (2), R4 is a hydrogen atom or a methyl group, Z is NH or an oxygen atom, and A is a linear or branched alkyl group with 12 to 40 carbon atoms.

The embodiment of the invention provides a metal organic material, the structural formula of which is as shown in the formula (I): # imgabs0 #, in the formula (I), X1, X2, X7, X8, X9 and X10 are respectively and independently CH or N, and X3, X4, X5 and X6 are respectively and independently CH, C or N; each R1, R2, R3, R4, R5, R6 independently represents a hydrogen atom, a deuterium atom, a halogen atom, a substituted or unsubstituted alkyl group, or the like; each R7 is independently a hydrogen atom, a deuterium atom, a halogen atom, a substituted or unsubstituted alkyl group, or the like; z1 and Z2 are respectively connected with X3 and X4, or X4 and X5, or X5 and X6, one of Z1 and Z2 is a single bond, and the other is oxygen, sulfur, selenium or a divalent atomic group. The metal organic material can be applied to the organic electroluminescent device as a luminescent material, and the luminescent color purity, the device efficiency and the device stability of the organic electroluminescent device are improved.

The present invention provides a resin composition, a cured product, a prepreg, a metal foil-clad laminate, a resin composite sheet, a printed wiring board, and a semiconductor device. The resin composition contains an elastomer (A), a compound (B) represented by formula (GU), and a radical polymerization initiator (C). The elastomer (A) includes a polymer block (a1) containing a conjugated diene compound unit and a styrene compound unit having a radical reactive group. The content of the elastomer (A) is 1-30 parts by mass with respect to 100 parts by mass of the resin solid content. In formula (GU), R1 and R2 are hydrogen atoms or substituents, two R2 are the same as each other, at least one of R1 and R2 is a group including a (meth)allyl group, and R3 and R4 each independently represent a hydrogen atom, an alkyl group, or an aryl group.

The present invention provides: a liquid crystal alignment film which has good liquid crystal alignment properties, while having excellent pretilt angle developability; a liquid crystal display element which is provided with this liquid crystal alignment film; and a liquid crystal aligning agent which enables the achievement of this liquid crystal alignment film. The present invention provides a liquid crystal aligning agent which contains: as a component (A), a compound that has a thermally crosslinkable group and a photo-alignment group represented by formula (pa-1), wherein the thermally crosslinkable group is capable of forming a covalent bond by being reacted with a carboxy group; and as a component (B), a polyamic acid and a solvent. (In formula (pa-1), A represents a phenylene group or the like; R1 represents —COO— or —OCO—; R2 represents a cyclohexane-1,4-diyl group; R3 represents a cyclohexane-1,4-diyl group; R4 represents a linear or branched alkyl group having 1 to 40 carbon atoms, and some or all of the hydrogen atoms in this alkyl group may be substituted by fluorine atoms; D represents an oxygen atom, a sulfur atom or —NRd-; a represents an integer of 0 to 3; and * denotes a bonding position.)

A photoresin composition for photopatterning in an oxygen-containing environment has a viscosity of about 300 cP or higher and contains: a reactive monomer with no hydrogen atoms having a bond-dissociation energy of less than about 410 kJ / mol, the hydrogen atoms; a non-amine reducing agent; and, a Norrish Type II photo-initiator. A volumetric additive manufacturing (VAM) process involves: immersing a solid base object in a liquid photoresin composition containing a photo-initiator and a multifunctional material; removing the solid base object with a film coating thereon from the liquid photoresin composition; and, selectively irradiating the composition at the surface of the object with patterned light to initiate covalent grafting or adhesion of the multifunctional material to the surface of the object to pattern only a portion of the surface of the object, where the portion of the surface of the object corresponds to the selectively irradiated surface of the object.

The invention belongs to the technical field of energy materials, and discloses a coating material as well as a preparation method and application thereof. The coating material comprises the following components in parts by weight: 50-55 parts of zirconium oxide, 15-18 parts of aluminum oxide, 5.5-9 parts of rare earth oxide, 10-12 parts of a fluorocarbon polymer and 3-4 parts of a silane coupling agent, the rare earth oxide comprises yttrium oxide and cerium oxide. A natural gas hydrogen-doped pipeline coating prepared from the coating material has low permeability, high adhesive force, high hardness and excellent stability, can effectively inhibit hydrogen atoms from gathering and diffusing in the material in high-temperature, high-pressure, hydrogen-doped and other complex environments, has excellent hydrogen embrittlement resistance and good chemical stability and mechanical property, and can be used for preparing the natural gas hydrogen-doped pipeline coating. The pipeline failure risk caused by hydrogen embrittlement can be remarkably reduced, the performance degradation phenomena such as aging and decomposition are not prone to occurring, and long-term stable operation of the pipeline can be guaranteed.

Provided is a charge-transporting composition that contains: a charge-transporting substance comprising a polythiophene derivative represented by formula (1); a fluorine-based surfactant; metal oxide nanoparticles; and a solvent.(R1 and R2 are each independently a hydrogen atom, an alkoxy group having 1-40 carbon atoms, —O—[Z—O]p—Re, a sulfonic acid group, or the like, or R1 and R2 bond to each other to form —O—Y—O—. Y is an alkylene group having 1-40 carbon atoms, which may contain an ether bond and which may be substituted with a sulfonic acid group. Z is an alkylene group having 1-40 carbon atoms, which may be substituted with a halogen atom. p is 1 or more, and Re is a hydrogen atom, an alkyl group having a 1-40 carbon atoms, or the like.)

The invention discloses a hydrogen brittleness performance evaluation method for a hydrogen transport pipeline, which comprises the following steps: obtaining the average hydrogen concentration in a sample through a high-pressure hydrogen permeation test of a wafer sample, and obtaining the hydrogen concentration and hydrogen diffusion coefficient of the surface of the sample under a specific electrochemical hydrogen charging condition through an electrochemical hydrogen charging test of the wafer sample; a finite element analysis model of a target sample is established to simulate the change relation of the total amount of hydrogen atoms in the target sample along with time under the electrochemical hydrogen charging condition, and the electrochemical hydrogen charging time equivalent to the high-pressure gaseous hydrogen charging is obtained by comparing the high-pressure gaseous hydrogen charging with the electrochemical hydrogen charging. The target sample is charged with hydrogen through an electrochemical hydrogen charging method, and finally the hydrogen embrittlement performance of the target sample is obtained through a hydrogen embrittlement performance test. According to the method, simple finite element simulation and electrochemical hydrogen charging are combined, high-pressure gaseous hydrogen charging which is complex, low in efficiency and high in danger is replaced, and the detection time of the hydrogen embrittlement performance test of the hydrogen charging pipe is shortened.

A resist composition including a resin component having a constitutional unit derived from a compound represented by General Formula (a0-1), in which R01 represents a hydrogen atom, L01 represents a divalent linking group, Ra01 and Ra02 each independently represent a hydrocarbon group which may have a substituent, Ar01 represents an aryl group in which some or all hydrogen atoms are substituted with iodine atoms, and the aryl group may have a substituent other than the iodine atoms

A deuterated composition, a preparation method therefor, a light-emitting layer, and an organic light-emitting device, relating to the field of organic light-emitting materials. The deuterated composition comprises different deuterated compounds of a compound represented by formula I, wherein in formula I, Ar1 is selected from phenyl or naphthyl. For the different deuterated compounds of the same compound, the average deuteration rate of deuterium-exchangeable hydrogen atoms on Ar1 and anthryl is greater than 98%, and the average deuteration rate of deuterium-exchangeable hydrogen atoms on phenanthryl is 96%-98%. When the deuterated composition is used as a light-emitting material of organic light-emitting devices, the service lifetime of the devices is significantly prolonged.

To provide a protective film composition for dicing which can suppress temporal lowering of absorbance, and can suppress temporal increase in the number of defects, and a wafer manufacturing method and a wafer processing method which use the same.SOLUTION: A protective film composition for dicing contains an ultraviolet absorber containing a compound (1) represented by the following general formula (1), a water-soluble resin, formic acid ions, and water, and the content of the formic acid ions is 300 to 6,000 mass ppm. In the formula, X represents a hydrogen atom, and -OR1; R1 represents a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms; n represents the number of 1 to 5; and m represents the number of 0 to 4.SELECTED DRAWING: None

A thermal conductive addition-curable silicone composition includes: an organopolysiloxane (A) having at least one aliphatic unsaturated hydrocarbon group in one molecule and having a kinematic viscosity at 25° C. of 60 to 100,000 mm2 / s; a phenol compound (B) at an amount of 0.01 to 10 mass % relative to an entirety of the composition; a silver powder (C) at an amount of 10 to 98 mass % relative to the entirety of the composition; an organohydrogenpolysiloxane (D) having two or more hydrogen atoms bonded to a silicon atom in one molecule at an effective amount sufficient for the composition to form a cured product; and a platinum-group metal catalyst (E) at an effective amount. This configuration provides a thermal conductive addition-curable silicone composition having excellent heat-dissipating ability.