1414 results about "Bismuth" patented technology

The invention discloses a preparation method of a proton exchange membrane water electrolysis hydrogen production membrane electrode, and belongs to the technical field of proton exchange membranes, a catalyst carrier is prepared, S101, a polyimide membrane is inversely fixed in a magnetron sputtering vacuum coating chamber, a cavity cover of the magnetron sputtering vacuum coating chamber is closed, vacuumizing is performed, and a substrate is heated; and S102, argon is introduced into a cavity of the magnetron sputtering vacuum coating chamber, coating is started, the power of the bismuth metal target is set to be 0.2-0.5 kW, and the deposition time is 60-1800 s. In the invention, the physical vapor deposition method is utilized to load the catalyst on the surface of the metal oxide carrier with high specific surface area and ordered nanostructure, so that the exposure of active sites of the catalyst is increased, the dosage of the noble metal catalyst is reduced, and the bonding strength between the catalyst and the carrier is enhanced; the catalyst is not easy to separate from the surface of the carrier, and large-scale slurry agglomeration is avoided.

The invention relates to the technical field of liquid metal driving equipment, in particular to an annular channel induction type lead-bismuth electromagnetic pump. The lead-bismuth electromagnetic pump comprises an internal stator, an annular flow channel, an external stator, an electromagnetic coil and an electromagnetic pump shell; the outer wall of the annular runner is coated with a protective layer; the protective layer is made of nanometer flexible heat preservation cotton, the thickness of the protective layer ranges from 5 mm to 10 mm, and the protective layer is configured to enable the surface temperature of the protective layer to be controlled to be 100 DEG C or below. Compared with an existing annular channel induction type lead-bismuth electromagnetic pump, the annular channel induction type lead-bismuth electromagnetic pump has the advantages that the nanometer flexible heat preservation cotton with the better heat insulation performance is mainly adopted as the main material of the protection layer, the heat insulation performance of the protection layer is improved by designing the thickness of the protection layer, and the operation temperature range of the annular channel induction type lead-bismuth electromagnetic pump is widened; the problems that an existing annular channel induction type electromagnetic pump is low in running temperature, consequently, running conditions are limited, and efficiency is low are solved.

The invention discloses a high-bismuth slag and precious lead co-processing and efficient recycling method, and belongs to the technical field of non-ferrous metallurgy. High-bismuth slag and precious lead are mixed to obtain impurity-removed precious lead through impurity removal processes such as plug-blow antimony removal, liquation copper removal and tellurium removal by adding agents, and the impurity-removed precious lead is subjected to an oxidation refining process to obtain gold-silver alloy to recover precious metal. Bismuth and lead are similar, silver can be infinitely dissolved in a molten state, and the silver trapping agent has good silver trapping capacity. The high-bismuth slag and the precious lead are mixed to greatly reduce the temperature of a system, volatilization and unknown loss of metal such as Ag are reduced, energy consumption is remarkably reduced, the production cost is reduced, the recovery rate of metal such as bismuth, antimony and silver is increased, and the production efficiency is improved. The obtained molten slag is used for smelting high-bismuth slag, the obtained soot is used for smelting crude antimony, and efficient cyclic utilization of rare and precious metal resources is achieved.

The invention discloses a method for recovering nearly all elements in low-precious-metal zinc replacement powder, which belongs to the technical field of non-ferrous metal wet smelting, and comprises the following steps: preparing zinc replacement powder, oxidizing and leaching, extracting copper, preparing cuprous chloride, electrodepositing zinc in raffinate, extracting precious metal by using a gold extracting agent, extracting, reducing and smelting to prepare a gold ingot and a silver ingot, and dissolving by using sodium hydroxide. Preparing lead carbonate; carrying out oxidation acid leaching; replacing; and smelting bismuth. According to the technology for achieving recovery and high-value utilization of nearly all elements in the zinc replacement powder under the mild condition, the technology can be carried out at the normal temperature, the high-pressure condition does not need to be provided, the zinc replacement powder is leached through the acid solution, then various valuable metals are selectively extracted from the leaching solution, corresponding downstream products are prepared, and the method is suitable for industrial production. The method realizes value maximization, does not generate secondary pollution, does not introduce fluorine, has low requirements on equipment, is simple in process and easy to operate, and makes up for the defects of the zinc replacement powder treatment process in the prior art.

The invention discloses an antibacterial material rich in a bismuth metal organic framework and a preparation method thereof, the method comprises the following steps: adding an indole monomer and an alcohol monomer into a solvent, and then adding nitrosalicylaldehyde into the solvent to obtain a spiropyran compound; the preparation method comprises the following steps: adding humic acid into a binary solvent consisting of dioxane and butanol to obtain a mixed solution; the ratio of the mass of the humic acid to the volume of the binary solvent is (2-3): (20-40) g / ml; sequentially adding a bismuth source, 2-bromo-5-(trifluoromethyl) pyridine and 4-(trifluoromethyl) phenylboronic acid into the mixed solution to obtain a bismuth metal organic framework; and adding the spiropyran compound into the bismuth metal organic framework to obtain the antibacterial material rich in the bismuth metal organic framework. The antibacterial capability of the antibacterial material is improved.

The invention provides application of a silver-bismuth tungstate catalyst in preparation of methanol from light-driven CO2, and belongs to the technical field of CO2 conversion and reduction. Bismuth tungstate nanosheets, silver salt and water are mixed, the size of silver particles is controlled by adjusting the pH value, the silver-bismuth tungstate catalyst is obtained, and the size of the silver particles is 20-50 nm; silver is evenly distributed on the surface of bismuth tungstate, the obtained silver-bismuth tungstate catalyst is large in specific surface area and high in light response capacity, the silver-bismuth tungstate catalyst can generate a large number of high-energy hot electrons during illumination, in-situ photo-thermal conversion is achieved, no external heat source is needed for heat supply, the photo-thermal effect is enhanced, CO2 conversion is promoted, and the methanol yield is increased.

The method comprises the following steps: weighing an oxide precursor of metal indium, an oxide precursor of metal M, an ammonium salt and a lithium salt according to a chemical formula of indium-based halide, fully mixing, and calcining in an inert atmosphere to obtain the indium-based halide solid electrolyte. Forming an indium-based halide solid electrolyte through a solid-phase reaction; wherein M is selected from at least one of magnesium, calcium, strontium, barium, aluminum, gallium, indium, bismuth, scandium, yttrium, zinc, germanium, tin, lanthanum, cerium, samarium, gadolinium, holmium, erbium and ytterbium. The method can greatly simplify the synthesis process, reduce the raw material cost and realize industrial batch preparation.

The invention provides a lead-bismuth reactor nuclear sampler coating and a preparation method thereof.The preparation method comprises the steps that S3, according to the thickness of a CrAl coating, the bias voltage and target current of multi-arc ion plating equipment are adjusted, the bonding strength of the coating and a base body is optimized, and the target adhesive force reaches the scratch test critical load or above; s4, according to the bonding strength, the nitrogen flow and the air pressure are adjusted, a compact CrAl coating microstructure with the porosity lower than a porosity threshold value is generated, and the quality of the microstructure is detected and verified through a scanning electron microscope; s7, according to the thickness consistency, a screw rod or a pin shaft is selected as a base body part, a CrAl coating is deposited on the surface of the screw rod or the pin shaft to be matched with the sleeve cap, and the gap between the sleeve cap and the shaft part is controlled to be within a gap threshold value; and S10, according to hardness and wear resistance test results, the deposition time and bias voltage are adjusted, the performance of the CrAl coating and the performance of the TiN coating are optimized, and the requirements for long-term corrosion resistance and wear resistance in the lead-bismuth alloy environment are met. According to the invention, excellent performances of long-term corrosion resistance and wear resistance in a high-temperature lead-bismuth environment are realized, and the service life of parts is remarkably prolonged.

The invention discloses a preparation method of an aperture-adjustable and metal-loaded graphite felt flow battery electrode, which comprises the following steps: (1) pretreatment and pore separation: mixing a graphite felt with an alkali solution, magnetically stirring, heating, cooling to room temperature, and treating again to obtain a pore separation material; (2) loading neodymium oxide: dipping the porous material in a solution containing neodymium salt and polyamino acid, heating, cleaning, and drying to obtain a neodymium oxide modified electrode material; (3) loading oxygen-deficient CoMnOx: coating the mixed slurry containing manganese and cobalt on an electrode plate, heating, cleaning and drying to obtain an oxygen-deficient CoMnOx loaded electrode; and (4) carrying out electro-deposition on the electrode loaded with the oxygen defect CoMnOx to obtain the novel bismuth-deposited graphite felt electrode. According to the electrode product obtained through the method, the energy efficiency is improved to 85% or above, and the stable cycle index for maintaining the energy efficiency can exceed 1440 times.

The invention belongs to the technical field of bismuth oxygen selenium nanosheets, and particularly relates to a preparation method of a Bi3O2.5 Se2 nanosheet. According to the preparation method, a chemical vapor deposition method is adopted, Bi2Se3 and KI containing crystal water are respectively used as a precursor and an oxygen supply source to form a mixture, a substrate is placed above the mixture, the mixture is heated under the condition that a carrier gas is introduced for reaction, and the Bi3O2.5 Se2 nanosheet grows on the surface of the substrate to obtain the Bi3O2.5 Se2 nanosheet. According to the preparation method provided by the invention, the uniformity and the crystallization quality of the Bi3O2.5 Se2 nanosheet are remarkably improved, the roughness of a crystal domain combination interface is effectively reduced, and the quality of the crystal domain combination interface is improved; meanwhile, the growth temperature is low, energy consumption and equipment loss are reduced, and the method is more suitable for industrial application.

The invention provides a preparation method of a plate-shaped glassy carbon electrode, which comprises the following steps: curing a resin raw material into a plate-shaped resin block, carbonizing in an inert atmosphere, and respectively introducing a nitrogen source and a boron source for doping operation to obtain a co-doped plate-shaped resin block precursor; placing the co-doped plate-shaped resin block between two porous graphite plates, and carrying out high-temperature treatment to obtain a glassy carbon matrix; and immersing the glassy carbon substrate into the adhesion layer solution to form an adhesion layer, transferring the adhesion layer into a deposition solution which comprises a bismuth-containing solution and a gold-containing solution, forming bismuth-gold nano-dots on the adhesion layer, and washing and drying the bismuth-gold nano-dots to obtain the plate-shaped glassy carbon electrode. Through directional arrangement of crystal orientations, the tantalum carbide coating achieves higher electrical conductivity and thermal conductivity. And the sensitivity and the service life of the plate-shaped glassy carbon electrode are obviously improved and prolonged.

The invention relates to the field of solder materials, and provides a non-ferrous metal solder for low-temperature brazing and application, the solder is composed of carbon-coated copper nanorods, tin-bismuth alloy-coated silver nanoparticles, 2-mercaptobenzimidazole, rosin resin, an organic active agent, a dispersing agent, ionic liquid, hydroxyethyl cellulose, indium nitrate and citric acid. The silver particles are of a core-shell structure and are coated with tin-bismuth alloy layers, and continuous carbon layers are formed on the surfaces of the copper nanorods, so that the conductivity and the interface stability of the solder are effectively improved. The non-ferrous metal solder with excellent conductivity, low melting point and good wettability is prepared through step-by-step mixing, hot press molding and low-temperature heat treatment processes, and is suitable for electronic device packaging, power device connection and flexible circuit interconnection, and the defects of existing solder in the aspects of low-temperature welding and high conductivity are overcome.

A solder composition includes a solder paste including a tin (Sn)-bismuth (Bi) alloy and / or a tin (Sn)-silver (Ag)-copper (Cu) alloy and a plurality of nanoparticles dispersed in the solder paste, wherein each of the nanoparticles includes a core that is spherical, the core includes a metal oxide, and the metal oxide has a density of 7 g / cm3 or more and a melting point of 2000° C. or higher.

The invention belongs to the field of chemical engineering, and relates to a preparation method of a high-chroma bismuth vanadate pigment for a coating, which comprises the following steps: mixing a titanium-based ion sieve with an acidic vanadium leachate, filtering after the reaction is completed to obtain a first filtrate, adding mercaptoacetic acid into the first filtrate, and filtering after the reaction is completed to obtain a second filtrate; preparing a bismuth salt solution containing yttrium ions and zirconium ions, mixing the bismuth salt solution with the second filtrate, adjusting the pH value to be in linear gradient change from acidity to neutrality, heating to a first temperature at a set heating rate, aging, centrifuging and drying to obtain a precursor; and calcining the precursor at a second temperature to obtain the bismuth vanadate pigment. According to the method, the acid vanadium leaching solution is used as a raw material, and the bismuth vanadate pigment with high chromaticity and chemical stability is obtained while the production cost is reduced through an innovative ion sieve purification technology and lattice stabilization doping, so that the method has obvious economic benefits.

The invention relates to the technical field of welding materials, and particularly discloses a high-temperature-resistant flux-cored wire containing rare earth elements and a preparation method of the high-temperature-resistant flux-cored wire. The high-temperature-resistant flux-cored wire containing the rare earth elements comprises a welding wire skin and a flux core. The flux core comprises the following raw materials of dehydrated rutile, dehydrated potassium feldspar, zircon sand, metal chromium powder, metal nickel powder, electrolytic manganese, ferrotitanium, ferro-aluminum, potassium cryolite, potassium titanate, sodium titanate, fine iron powder, yttrium-based iron alloy powder, atomized ferrosilicon, nitrided ferrochrome, bismuth oxide, auxiliaries and the balance reduced iron powder. The auxiliary agent is a mixture of a zirconium-iron alloy, a titanium-iron alloy and an aluminum-magnesium alloy. A specific alloy auxiliary is introduced into the flux core to protect stable transition of rare earth yttrium, yttrium and multiple components synergistically optimize the weld joint performance, 253MA heat-resistant steel is matched, slag and electric arc regulation and control components and a reasonable process are matched, and the welding quality of the welding wire is improved.

The invention relates to the technical field of catalytic materials, and particularly discloses a visible light photocatalyst and a preparation method thereof.The visible light photocatalyst comprises a core layer-shell layer-dynamic regulation and control layer three-stage structure; the core layer is heterojunction nano-particles formed by bismuth vanadate and bismuth oxyiodide, and the bismuth vanadate particles are uniformly dispersed on the surface of the bismuth oxyiodide to form a p-n heterojunction; the molar ratio of bismuth vanadate to bismuth oxyiodide in the core layer is 1: (0.5-2), and the particle size range is 30-80 nm; through an elaborately designed three-level structure and a dynamic regulation and control mechanism, the response efficiency and environmental adaptability of the photocatalyst to visible light are remarkably improved. A built-in electric field is formed by utilizing the energy band matching characteristic of bismuth vanadate and bismuth oxyiodide, so that the separation of photo-induced electron-hole pairs is effectively promoted, and the absorption boundary of visible light is expanded to 650nm.

The invention discloses an experimental research device and an experimental method for deposition of particles in high-temperature liquid lead bismuth, and belongs to the technical field of lead-based reactor thermotechnical waterpower. The device comprises a lead-bismuth liquid storage tank, a main loop, a test section, a sampling branch, a filtering branch, a heat exchange branch and a pipeline, the test section comprises a rod bundle structure with a winding wire, a rectangular channel with a visual window and a rectangular channel with a temperature measuring point; through the design of the test section of the device, the device can well test the influence of factors such as thermophoresis, gravity and buoyancy on particle deposition in a lead-bismuth medium, and can simulate the deposition of particles in liquid lead-bismuth on a pipeline wall surface and a reactor core rod bundle structure so as to analyze the deposition behavior of the particles in lead-bismuth; and meanwhile, basic experimental data is provided for numerical calculation in the field.

A self-closing residential fire hinge apparatus for closing a door during a fire includes a door hinge with a spring-actuated release mechanism. The spring-actuated release mechanism includes a spring that is pre-tensioned in an open position and a coating covering the spring. The coating is a solid material that retains the spring in the open position. The coating has a melting point less than a melting point of the spring. For example, the coating may be formed of bismuth. When the coating is heated and becomes malleable, the spring is released to a closed position. When the coating is solid and not malleable, the door hinge allows regular opening and closing of the door. The apparatus may also include a spring assembly cap, improving the aesthetics of the assembly. The spring assembly cap may be composed of copper, improving conduction of the ambient heat to melt the coating even faster.

The invention relates to the technical field of material protection, in particular to a lead-bismuth-resistant coating and a preparation method thereof.The coating is composed of a metal bonding layer, a functional transition layer and a corrosion-resistant layer, the metal bonding layer is formed by compounding a high-entropy alloy and a medium-entropy alloy, a component gradient transition structure is formed, the high-entropy alloy is a near-equal-atomic-ratio alloy of Fe, Co, Ni, Cr and Al, and the medium-entropy alloy is a near-equal-atomic-ratio alloy of Fe, Co, Ni, Cr and Al. %, and the medium-entropy alloy is a FeCoNiCr system quaternary alloy, and the content of the Al element is 5-10 at. The functional transition layer is a transition metal nitride layer; and the corrosion-resistant layer is an eutectic composite layer of rare earth oxide and stabilized oxide. Therefore, the problems of insufficient bonding strength, limited corrosion resistance, poor process stability and the like in the prior art are solved.

A bismuth vanadate pigment comprising a bismuth- and vanadium-containing core doped with one or more of magnesium, calcium, aluminium and phosphorus, the doped core being coated with an oxidic coating comprising one or more of magnesium, calcium, aluminium and phosphorous.

The invention relates to a lead-bismuth reactor damaged core melt migration experiment system and method, and the system comprises an experiment section, a simulation fuel rod, a shielding gas module, a direct current power supply heating module, a shooting recording module and an instrument module, a direct-current power supply is used for heating an electric heating wire simulation core block to serve as an internal heat source to generate heat to melt a fuel rod, air in a system is exhausted by filling argon, and inert environment protection is provided; the melting of lead and bismuth is realized by the heating of the heating wire; and the specific behaviors of gathering and migration of the melt above the lead-bismuth liquid level can be observed through the visible window on the top cover. The simulated fuel pellet is made of metal molybdenum, the simulated fuel rod cladding is made of stainless steel, and liquid lead bismuth serves as a cooling agent. Meanwhile, a multi-layer structure is designed for the experimental section, and stainless steel serving as a shell is prevented from being melted along with melting of the stainless steel cladding of the fuel rod. According to the invention, simulation experiments of melting of a single fuel rod and a fuel rod bundle, pellet fragmentation and melt migration can be carried out, and a reference is provided for safety design of a lead-bismuth reactor.

The invention discloses a process for comprehensively utilizing sintering machine head ash, which comprises the following steps of: preparing the sintering machine head ash, oxidizing and leaching, carrying out filter pressing, and washing chlorine and dehydrating a filter cake to obtain fine iron powder; the method comprises the following steps: preparing metal cesium by replacing and recovering valuable metal from filtrate, performing primary heavy metal removal, performing secondary impurity removal, performing evaporative crystallization, crystallizing potassium chloride and sodium chloride, extracting cesium, concentrating and crystallizing a cesium chloride solution, preparing metal cesium, extracting rubidium from cesium extraction raffinate, and concentrating and crystallizing a rubidium chloride solution, thereby preparing metal rubidium; after the metal replacement powder is dissolved by a certain concentration of acid, copper, zinc, gold, silver and bismuth in the metal replacement powder are recovered step by step, and toxic and harmful elements such as thallium, chromium and cadmium are concentrated from a system. The method can comprehensively and efficiently recover sylvite, sodium salt and valuable metal in the sintering machine head dedusting ash, solves the problem that the normal production of a blast furnace is influenced by overhigh alkali metal content accumulation, and solves the environmental pollution caused by machine head ash stacking and burning.

The invention relates to the technical field of wastewater treatment, and discloses a ceramic membrane catalyst and a preparation method thereof as well as a ceramic membrane catalytic reactor and application thereof, the ceramic membrane catalyst comprises a ceramic membrane and bismuth oxide loaded on the ceramic membrane, and the loading capacity of the bismuth oxide is 1-100g / m < 2 >. By adopting the loaded ceramic membrane catalyst, the dissolution of ozone can be enhanced, the utilization rate of ozone is improved, the operation cost of an ozone process is reduced, and the treatment effect of the ozone process is improved.

The present invention relates to a bismuth alloy composition and a design method thereof. The alloy composition according to the present invention is an alloy composition comprising bismuth and a second element. The second element selected on the basis of an atomic radius difference between constituent atoms and mixing enthalpy is alloyed in an appropriate content according to a principle of improving liquid stability to provide an alloy composition satisfying a low melting point and a high degree of supercooling and exhibiting excellent flowability, which can be used as a liquid metal ion source.

The invention belongs to the technical field of casting, and provides a method for improving shrinkage porosity of a reversing frame casting and the reversing frame casting, and the method comprises the following steps: obtaining a reversing frame by adopting the process steps of molten iron smelting, spheroidizing treatment, inoculation treatment and casting molding; wherein the carbon content in the casting is 3.8%, and the silicon content in the casting is 2.6%; the casting temperature is 1400 DEG C; a chilling block is arranged in the mold; the casting contains 0.0041%-0.0062% of bismuth, and the bismuth is added after spheroidizing and before inoculation. According to the method, by optimizing the technological conditions in the casting technology, the optimal technological conditions for casting are determined, the carbon content is 3.8%, the silicon content is 2.6%, the casting temperature is 1400 DEG C, and the chilling block is arranged, so that the shrinkage porosity and cavity defects of the casting are remarkably improved; and meanwhile, by further optimizing the components and the content relation of the casting, the strength performance of the casting is further improved on the premise that the shrinkage porosity and cavity defect improvement state is guaranteed, and the casting is made to be more suitable for the high-strength application scene requirement.

The invention relates to a preparation method of an oxygen vacancy-rich bismuth molybdate / bismuth vanadate composite photo-anode and a product and application thereof, and belongs to the technical field of photoelectrocatalysis. The invention discloses a preparation method of an oxygen vacancy-rich bismuth molybdate / bismuth vanadate (Bi2Mo2O9 / BiVO4) composite photo-anode, which mainly comprises the following steps: immersing a fluorine ion-doped tin dioxide (FTO) conductive glass substrate into a Bi < 3 + > ion solution and an I <-> ion solution to form a bismuth oxyiodide (BiOI) film, dropwise adding a dimethyl sulfoxide solution of vanadyl acetylacetonate (VO (acac) 2), and putting into a muffle furnace to prepare the BiVO4 photo-anode. And then vertically immersing into a Bi < 3 + > ion solution and a Mo < 6 + > ion solution, and carrying out annealing treatment in an argon atmosphere to prepare the Bi2Mo2O9 / BiVO4 composite photoanode rich in oxygen vacancies. The Bi2Mo2O9 / BiVO4 material rich in oxygen vacancies is a metal oxide composite photo-anode, the photoelectrocatalysis efficiency can be improved, and hydrogen peroxide (H2O2) can be continuously generated in natural seawater through photoelectrocatalytic oxidation of water for a long time.

The invention relates to the technical field of thermite, in particular to a thermite system of an ultralow condensed phase combustion product and a preparation method of the thermite system. The preparation method of the aluminothermic system comprises the following steps: S1, synthesizing nanoscale BiF3 particles; s2, immersing a mixed oxidizing agent into a copper nitrate solution, dropwise adding ammonia water into a system, reacting for a period of time, standing and aging the reaction system, performing centrifugal separation, washing, and performing vacuum freeze drying to obtain BiF3-coated TACN core-shell structure particles; and S3, adding the acid-activated nano aluminum powder and the BiF3-coated TACN core-shell structure particles into an n-hexane medium, carrying out ultrasonic treatment, and drying to obtain thermite powder. Through the high reaction interface of the nano-scale bismuth-based fluoride and the activation strategy of the high-energy gas production compound on the interface, the output of ultralow condensed phase combustion products and the efficient release of system energy are realized.

Electrochemical systems and methods for removing and recovering phosphorus in the form of phosphate from aqueous solutions are provided. Phosphate radical removal is performed in an electrochemical cell having an electrode containing bismuth (Bi), zinc (Zn), copper (Cu), iron (Fe), or an oxide thereof. During the removal of phosphate radicals from an aqueous solution, the metal (Bi, Zn, Cu or Fe) and / or metal oxide of the electrode is converted into its corresponding metal phosphate within the electrode by a reversible conversion reaction. The phosphate stored in the electrode during the removal step is subsequently released into the recovery solution by electrochemical reduction of the metal phosphate to a metal.

The present invention relates to a process for synthesizing copper-supported cobalt-doped bismuth oxide nanomaterial electrode for supercapacitor applications. For the synthesis of said nanomaterial electrode, Successive Ionic Layer Adsorption and Reaction (SILAR) technique is used. The present invention carried out the maticulous fabrication of copper-supported cobalt doped Bi2O3 nanomaterial electrode, wherein the synthesized nanomaterial electrode, harnesses the unique properties of each constituent material to achieve superior electrochemical performance. Through precise control of SILAR parameters, including deposition cycles and solution concentrations, a finely tuned composite material is produced, characterized by enhanced conductivity, stability, and specific capacitance. The strategic incorporation of copper and cobalt doping within the Bi2O3 matrix synergistically enhances the overall electrochemical behavior, facilitating efficient charge transfer and storage.

The invention discloses a cast iron material suitable for a large-size thin-wall high-strength wind power hub and a preparation method and application of the cast iron material, and belongs to the technical field of materials and casting technologys.By optimizing alloy component design and combining the synergistic effect of trace rare metal elements of barium (Ba), antimony (Sb) and bismuth (Bi) and rare earth elements (RE), the high-strength wind power hub is obtained; and by adding a three-phase SiC / SiO2 / TiC nano-particle reinforced phase, pearlite formation is inhibited, graphite nodules are refined, the spheroidization rate is larger than or equal to 95%, and the ferrite content is larger than or equal to 90%. And by adding a nano-particle reinforced phase and controlling the proportion of alloy elements such as Ni < = 0.8%, the corrosion resistance of the material is further improved. The ductile cast iron material with high spheroidization rate, excellent mechanical property, low-temperature impact resistance and corrosion resistance is prepared by using the low-temperature-resistant and high-strength casting process and the intelligent temperature-controlled and cold-controlled casting process, and the requirements of light weight, high strength, corrosion resistance and high reliability of 18MW-grade offshore wind power hubs are met.