The invention belongs to the technical field of
sewage treatment, and particularly relates to a
sulfur conversion driven
chlorohydrocarbon polluted underground
water treatment method. According to the method, the multifunctional
biochar is prepared through high-temperature
ammonia gas modification, PS can be activated to oxidize and remove chlorinated
hydrocarbon, then
sulfide reduction is catalyzed to remove residual chlorinated
hydrocarbon, a porous structure of BC provides
pollutant adsorption and fixation functions, and after MFBC, PS and
sulfate reducing
bacteria are sequentially added into a chlorinated
hydrocarbon pollution medium, the
pollution medium is subjected to high-temperature
ammonia gas modification to remove the residual chlorinated hydrocarbon. The
sulfur-containing species undergo a cyclic conversion process from PS-
sulfate ion-
sulfide-elemental
sulfur-
sulfate ion. In the conversion process, various oxidation and reduction active substances can be used for effective detoxification of chlorinated hydrocarbon, and MFBC and
sulfate reducing bacteria play a key role in mediating
sulfide conversion. According to the method, the
chlorohydrocarbon in the high-permeability medium can be rapidly removed firstly, and then the
chlorohydrocarbon slowly released by the low-permeability medium can be slowly removed at low cost. And the method is low-carbon and environment-friendly, has no secondary
pollution such as
heavy metals and has obvious application advantages.