1526 results about "Electron transfer" patented technology

NADP-dependent oxidoreductase compositions, and electrodes, sensors and systems that include the same. Analyte sensors include an electrode having a sensing layer disposed thereon, the sensing layer comprising a polymer and an enzyme composition distributed therein. The enzyme composition includes nicotinamide adenine dinucleotide phosphate (NAD(P)+) or derivative thereof, an NAD(P)+-dependent dehydrogenase; an NAD(P)H oxidoreductase; and an electron transfer agent comprising a transition metal complex.

NADP-dependent oxidoreductase compositions, and electrodes, sensors and systems that include the same. Analyte sensors include an electrode having a sensing layer disposed thereon, the sensing layer comprising a polymer and an enzyme composition distributed therein. The enzyme composition includes nicotinamide adenine dinucleotide phosphate (NAD(P)+) or derivative thereof, an NAD(P)+-dependent dehydrogenase; an NAD(P)H oxidoreductase; and an electron transfer agent comprising a transition metal complex.

NADP-dependent oxidoreductase compositions, and electrodes, sensors and systems that include the same. Analyte sensors include an electrode having a sensing layer disposed thereon, the sensing layer comprising a polymer and an enzyme composition distributed therein. The enzyme composition includes nicotinamide adenine dinucleotide phosphate (NAD(P)+) or derivative thereof; an NAD(P)+-dependent dehydrogenase; an NAD(P)H oxidoreductase; and an electron transfer agent comprising a transition metal complex.

NADP-dependent oxidoreductase compositions, and electrodes, sensors and systems that include the same. Analyte sensors include an electrode having a sensing layer disposed thereon, the sensing layer comprising a polymer and an enzyme composition distributed therein. The enzyme composition includes nicotinamide adenine dinucleotide phosphate (NAD(P)+) or derivative thereof; an NAD(P)+-dependent dehydrogenase; an NAD(P)H oxidoreductase; and an electron transfer agent comprising a transition metal complex.

NADP-dependent oxidoreductase compositions, and electrodes, sensors and systems that include the same. Analyte sensors include an electrode having a sensing layer disposed thereon, the sensing layer comprising a polymer and an enzyme composition distributed therein. The enzyme composition includes nicotinamide adenine dinucleotide phosphate (NAD(P)+) or derivative thereof, an NAD(P)+-dependent dehydrogenase; an NAD(P)H oxidoreductase; and an electron transfer agent comprising a transition metal complex.

NADP-dependent oxidoreductase compositions, and electrodes, sensors and systems that include the same. Analyte sensors include an electrode having a sensing layer disposed thereon, the sensing layer comprising a polymer and an enzyme composition distributed therein. The enzyme composition includes nicotinamide adenine dinucleotide phosphate (NAD(P)+) or derivative thereof; an NAD(P)+-dependent dehydrogenase; an NAD(P)H oxidoreductase; and an electron transfer agent comprising a transition metal complex.

The invention relates to the technical field of catalysts, and discloses a preparation method and application of a copper-based metal-organic framework catalytic material.The preparation method comprises the following steps that S1, cuprous salt, N, N '-bis (5-aminonicotinyl) naphthalimide and a solvent are mixed, and a mixture is obtained; s2, heating the mixture to a reaction temperature, carrying out a constant-temperature reaction, and cooling to obtain a crystal; and S3, washing and drying the crystal to obtain the copper-based metal-organic framework catalytic material. According to the preparation method of the copper-based metal-organic framework catalytic material provided by the invention, N, N '-bis (5-aminonicotinyl) naphthalimide is used as an organic ligand to prepare the copper-based metal framework Cu-PTD with N / O co-coordination, and the copper-based metal framework Cu-PTD has relatively strong electrocatalytic carbon dioxide reduction and electron transfer capabilities; and the catalyst has relatively high selectivity on electrocatalytic carbon dioxide reduction products.

The invention discloses a synthesis method and application of an iron-aluminum co-doped catalyst, and the synthesis method is characterized by comprising the following steps: S1, dissolving an aluminum metal salt and an iron metal salt in a beaker containing deionized water to obtain a solution A; s2, adding a phosphorus source into the solution A, and adjusting the pH to form a turbid liquid B; s3, biomass is added into the turbid liquid B to be stirred for 30 min, and a solution C is obtained; s4, adding a nitrogen source into the solution C, and drying the beaker in a water bath kettle; mixing the obtained dried product with an activating agent, and calcining under inert gas to obtain a catalyst crude product; and S5, grinding the catalyst crude product, washing with ethanol and deionized water, and carrying out vacuum drying to obtain the iron-aluminum co-doped catalyst. The preparation method is simple and low in equipment requirement. The invention discloses a novel nitrogen-doped carbon-coated zero-valent iron nanoparticle catalyst which can degrade pollutants by utilizing electron transfer of the pollutants and the catalyst under the condition of adding any oxidizing agent. Under the neutral room temperature condition, the catalyst has a very good removal effect on degradation of organic pollutants which are difficult to biodegrade, has very good stability, and is low in iron ion dissolution rate.

The invention discloses a compound containing a urea structure as well as a preparation method and application of the compound in a color developing agent, and relates to the technical field of color developing agents. The compound containing the urea structure is a # imgabs0 # structure as shown in a formula 1. The compound containing the urea structure is synthesized through multiple steps of Suzuki reaction, bromination reaction and substitution reaction. The compound is used as an electron donor to be applied to a thermosensitive color development system and forms a color development composition with a phenolic compound and an acidic material, and the activation temperature is as low as 60-120 DEG C. The ureido structure stabilizes a reaction intermediate through a hydrogen bond network, enhances the electron transfer efficiency, and significantly improves the color developing sensitivity; the aryl / heteroaryl substituent optimizes the color contrast through the conjugation effect, and meanwhile, the synergistic effect of the hot-melt filler ensures the stability of the system. Compared with a traditional color developing agent, the color developing agent has the advantages of low-temperature activation, high color developing intensity and excellent weather resistance, is suitable for the fields of thermal printing, anti-counterfeiting materials and the like, and overcomes the defects of high reaction temperature and insufficient stability in the prior art.

A method for enhancing hydrogen uptake by cells of an acetogenic bacterium in a culture is provided. The method comprises incubating the cells in a liquid medium supplemented with an external gas mixture, wherein the external gas mixture comprises H2 and CO2; overexpressing an uptake hydrogenase and an associated electron transfer protein in the cells; increasing uptake of the H2 by the cells; and enhancing uptake of the CO2 by the cells. The culture may be a coculture with additional cells of a non-acetogenic bacterium, which produces natively H2 from catabolism of an organic molecule.

The invention relates to the technical field of environmental functional materials and water treatment, and discloses a preparation method and application of a persulfate activator for efficiently removing drug-resistant bacteria and drug-resistant genes in water. Waste biomass and waste plastics are used as raw materials, solid waste resource utilization is achieved through synergistic pyrolysis, compared with a traditional catalyst, the preparation cost can be reduced by more than 40%, and remarkable economic and environmental benefits are achieved. The catalyst has the following advantages: 1) the limitation of a traditional single-active-site catalyst is broken through through the triple synergistic effect of transition metal oxide variable valence activation, nonmetal doped carbon electron conduction and an oxygen vacancy non-free radical path; 2) physical interception of ARB and enrichment of ARGs can be realized at the same time by utilizing a multi-stage pore channel structure; and (3) activating persulfate to generate free radicals (SO4 <->. / . OH) and non-free radicals (1O2 / electron transfer) to generate a double-path synergistic effect, thereby realizing efficient removal of ARB / ARGs in water.

The invention relates to the technical field of remediation for synergistic treatment of rice field soil arsenic and greenhouse gas emission reduction, in particular to a zero-valent manganese nitrate synergistic soil remediation agent and application thereof to remediation of rice field arsenic pollution and inhibition of greenhouse effect. The invention provides a technical scheme for synergistically repairing arsenic pollution in the rice field and inhibiting the greenhouse effect based on zero-valent manganese / nitrate, an electron transfer shunt network driven by manganese circulation is constructed, a slow release reaction-dynamic regeneration-electron shunt three-in-one system is constructed, and synergistic interaction of arsenic fixation and greenhouse gas emission reduction is realized. According to the technical scheme, the potential regulation and control contradiction between arsenic fixation aerobic and carbon reduction anaerobic is successfully broken, and an innovative solution is provided for multi-target remediation of rice field soil. According to the self-sustaining circulating system, the specific surface area of the manganese oxide is stabilized at 50m < 2 > / g to 120m < 2 > / g, and the regeneration rate is gt; 95%. Experiments show that compared with a single technology, the synergistic treatment group improves the arsenic fixing efficiency to 100%, and the comprehensive emission reduction intensity of greenhouse gas reaches 76%.

The invention provides a catalyst, a preparation method and application thereof, and a method for preparing primary amine by catalyzing nitrile compound hydrogenation, and particularly relates to the technical field of catalyst synthesis. The catalyst comprises a nickel / cobalt-based catalyst and a metal salt; wherein the nickel / cobalt-based catalyst is selected from any one of a supported nickel / cobalt-based catalyst, a Raney nickel / cobalt catalyst or a nickel / cobalt nanocrystal; the metal salt comprises any one or a combination of at least two of tungsten salt, molybdenum salt, vanadium salt, aluminum salt and cerium salt. The metal salt and the nickel / cobalt main catalyst have a synergistic effect: the surface electron density is adjusted through electron transfer, the hydrogen dissociation and cyano adsorption activation capacities are enhanced, the hydrogenation activity is improved, and the mild condition reaction is assisted; the surface chemical environment is changed or steric hindrance is borrowed, the primary amine selectivity is improved, and byproducts are inhibited; aluminum salt, cerium salt and the like inhibit nickel / cobalt agglomeration, increase active sites, enhance stability, prolong the service life and reduce the dosage.

The invention relates to the technical field of environmental pollution control, in particular to application of grass acidified zero-valent iron in in-situ remediation of organic polluted underground water. According to the preparation method, oxalic acid and micron zero-valent iron are evenly mixed and then subjected to ball milling treatment, oxalic acid zero-valent iron of a core-shell structure is obtained through post-treatment, the oxalic acid zero-valent iron has high electron transfer efficiency, Fe < 2 + > / Fe < 3 + > circulation is further regulated and controlled through oxalic acid coordination in the oxalic acid zero-valent iron, interface electron transfer is enhanced, and the preparation method is suitable for industrial production. Peroxyacetic acid is promoted to be activated to generate various active oxygen species, and efficient degradation of organic pollutants is achieved. The invention solves the problems of low zero-valent iron electron transfer efficiency, single active oxygen species, secondary pollution of iron sludge and the like in the process of degrading organic pollutants by using the existing zero-valent iron advanced oxidation technology.

The invention relates to the field of waste polymer material recovery and resource utilization, and particularly discloses a method for realizing ultra-fast recovery of fluorine-containing organic waste through a self-propagating reaction. According to the method, liquid sodium-potassium alloy (NaK) is used as a reaction medium, under the protection of inert atmosphere, fluorine-containing organic solid waste is in contact with NaK, electron transfer is induced through mechanical friction, C-F bond breakage is catalyzed and induced, a defluorination reaction is triggered, reaction heat is released, a self-propagating combustion reaction is initiated, and finally, carbon materials and metal fluoride products are recycled. The method is rapid in reaction, does not need external heating, can efficiently recover fluorine-containing waste and prepare high-added-value materials, and is suitable for green large-scale treatment of waste fluoropolymers and preparation of functional materials.

The invention provides a carbon emission management monitoring method and device for rice planting in a cold region, and relates to the technical field of carbon emission management monitoring. Vertical three-layer parameters of a soil profile, namely the surface methane concentration, the middle oxidation-reduction potential and the deep organic acid concentration, are collected; the method comprises the following steps: mapping a middle-layer potential into an inhibition coefficient according to a microbial electrochemical principle, further calculating potential uplink electron flux and actual downlink electron sedimentation intensity, identifying an electron transport chain breakage risk through a residual error of the potential uplink electron flux and the actual downlink electron sedimentation intensity, and carrying out nonlinear fusion on the electron transport residual error and environment weights of all layers by adopting a p-norm model. Through the risk amplification coefficient, the superlinear conduction of the local risk to the whole system is realized, the dominant risk layer is accurately positioned based on the comprehensive weight, the differential field management strategy is automatically generated, and finally the closed-loop intelligent management normal form is constructed, and the accurate control of the carbon emission based on the mechanism model is realized.

The invention belongs to the technical field of catalyst preparation and wastewater treatment, and particularly relates to an iron-nitrogen co-modified biochar catalyst as well as a preparation method and application thereof. Comprising the following steps: (1) pyrolyzing a biomass precursor at 200-400 DEG C in an inert gas atmosphere to obtain low-temperature biochar; (2) sufficiently mixing an iron salt solution, an organic nitrogen source and the low-temperature biochar through an impregnation method to obtain a mixed solution, and drying the mixed solution to obtain an iron-nitrogen co-modified biochar precursor; and (3) pyrolyzing the iron-nitrogen co-modified charcoal precursor at 600-1000 DEG C in an inert gas atmosphere to obtain the iron-nitrogen co-modified charcoal catalyst. The iron-nitrogen co-modified biochar catalyst is used for treating organic matters in high-salt organic wastewater, can realize catalytic polymerization removal of the organic matters, and effectively solves the problems that the number of active sites of biochar is limited, the electron transfer efficiency is relatively low, and the utilization efficiency of an oxidant in a persulfate activation technology is low and the mineralization ability is poor.

The invention belongs to the technical field of immunoassay and biosensing, and provides a novel construction mode of a heterojunction dual-photoelectrode photoelectric sensing strategy and a preparation method of an in-situ heterojunction MIO photocathode. The invention relates to a preparation method of a heterojunction dual-photoelectrode type photoelectrochemical sensor based on multi-ball cascade DNA reaction amplification. Specifically, the design is composed of an In2O3 / CdS photoanode and an in-situ formed MIL-68 / In2O3 (MIO) photocathode. The heterojunction dual-photoelectrode sensing strategy effectively prolongs an electron-hole transmission path, enhances photo-generated charge separation, and realizes' super-open 'PEC signal output, thereby providing a steady baseline for signal conversion. Meanwhile, a multi-sphere cascade DNA reaction is combined to output a three-dimensional DNA net structure to provide a large number of sites for embedding of a PEC quenching probe doxorubicin-ferrocene carboxylic acid (DOX-FcCOOH), obvious PEC signal quenching is realized by utilizing the efficient competitive electron transfer capability of the three-dimensional DNA net structure, and finally, a signal conversion system with'opening-super opening-closing 'multistage response characteristics is constructed. The detection of the nucleic acid marker Pax-5a gene of the B cell acute lymphatic leukemia is realized by detecting target objects with different concentrations.

The invention relates to the technical field of sewage treatment, and discloses a novel sulfur autotrophic denitrification filter material and a preparation method and application thereof.The particle size of the filter material is 3.0-4.0 mm, and the filter material is prepared from 40%-45% of a composite sulfur source, 70 + / -2% of sulfur and 30 + / -2% of sodium thiosulfate, 30%-35% of modified ceramsite, 50-100 [mu] m / 200-300 [mu] m of bimodal pore size and 8%-10% of a conducting medium. The ratio of graphene to biochar is 3: 1), a buffer medium (5%-7%, Fe2O3 (52% + / -2%), CaCO3 (31% + / -2%) and MgO (17% + / -2%), a binder and an inert filler. The preparation method comprises the steps of raw material pretreatment, mixing granulation, stepped calcination, gradient impregnation, buffer medium directional loading, post-treatment and the like. The filter material solves the problems of by-product accumulation, insufficient microbial adhesion, large pH fluctuation and blockage of a traditional filter material through gradient sulfur release, a three-dimensional electron transfer network, a multistage pore anti-blockage design and a composite pH buffer system, is suitable for sewage denitrification treatment, and is high in denitrification efficiency and good in stability.

The invention discloses preparation and application of a manganese hydroxylate modified zirconium-based metal organic framework, and belongs to the technical field of wastewater treatment. According to the preparation method, firstly, Mn oxide serves as a dopant, naphthalic acid serves as a frame connector, a zirconium-manganese bimetal organic frame is prepared through a hydrothermal method, and hydroxylation treatment is conducted through an alkali solution; mn replaces Zr atoms on a zirconium cluster to form high charge density with Zr, Mn and Zr can jointly participate in an electron transfer process and an active oxygen generation process to form double active centers, and the catalytic activity of a Fenton-like system is enhanced, so that the oxidative adsorption removal rate of As is remarkably improved. Experimental results show that the As removal rate can still reach 95.1% after five cycles, the targets of oxidative adsorption of As and reutilization are achieved, and the application of the zirconium-based metal organic framework in the field of catalytic adsorption of As is expanded.

The invention discloses a gas-sensitive material based on double noble metal doped holmium iron oxide and application of the gas-sensitive material to detection of hydrogen sulfide in a sulfur-containing ore body exploration environment, and relates to the technical field of gas-sensitive materials. HoFeO3 is used as a substrate material, and two elements of Au and Pt are used for doping modification of the HoFeO3 to prepare the gas sensitive material based on double noble metal doped holmium iron oxide. Au and Pt are combined to perform doping modification on HoFeO3, a synergistic effect is achieved on improving the temperature stability of the gas-sensitive material, the sensitivity of the gas-sensitive material in a high-humidity environment can be improved, in addition, due to the synergistic catalysis effect of Au and Pt, an energy barrier of H2S adsorption reaction can be remarkably reduced, surface electron transfer and reaction activity are promoted, and the sensitivity of the gas-sensitive material in a high-humidity environment is improved. Therefore, the working temperature is reduced, the response value is improved, and the method is suitable for detecting hydrogen sulfide gas in a sulfur ore body exploration environment.

The invention discloses a micro-structure electrode flexible electrochemical sensor which comprises a flexible electrode substrate with a hemispherical array and three surface electrodes (a working electrode, a counter electrode and a reference electrode). The working electrode comprises a protruding metal array and a through hole array, protruding metal corresponds to the hemisphere array of the substrate, and the through hole array penetrates through the substrate. According to the sensor, the reaction area is increased through the three-dimensional structure, electron transfer is promoted, oxygen supply is guaranteed through the through hole array, the mechanical stability is enhanced through the flexible substrate and the structural design, and the sensor is suitable for wearable equipment.

The invention provides an efficient chloramphenicol degradation method based on Co-Cu-carbon composite nano-catalyst activated peroxymonosulfate, which comprises the following steps: regulating the Co / Cu molar ratio in a bimetal organic framework precursor, and performing pyrolysis to prepare the Co-Cu-carbon composite catalyst with an optimized pore structure, graphitization degree and metal dispersity; peroxymonosulfate is activated by utilizing the synergistic effect of Co / Co and Cu / Cu redox pairs to generate sulfate free radicals, hydroxyl free radicals, singlet oxygen and superoxide free radicals, and direct oxidative degradation of chloramphenicol is promoted by taking a catalyst as an electron transfer bridge; the method realizes rapid and efficient removal of chloramphenicol, high mineralization rate, excellent cycle stability and strong anti-interference capability, and solves the technical problems of low removal efficiency, high cost and easy secondary pollution in the prior art.

The invention discloses a nitrogen-doped oxygen-vacancy-rich three-dimensional flower-shaped bismuth oxide electrocatalyst as well as a preparation method and application thereof, relates to the technical field of electrocatalysts, and solves the problems that a traditional bismuth oxide catalyst is insufficient in electron transfer capability and low in active site utilization rate. The preparation method comprises the following steps: dissolving bismuth nitrate, polyvinylpyrrolidone and sodium oleate in a mixed solvent of methanol and N, N-dimethylformamide, and stirring and dissolving to obtain a solution A; the preparation method comprises the following steps: dissolving 1, 3, 5-tri (4-carboxyl phenyl) benzene in a mixed solvent of methanol and N, N-dimethylformamide, and stirring and dissolving to obtain a solution B; and adding the B into the A, uniformly stirring, heating in an oil bath, reacting under magnetic stirring, cooling to room temperature, filtering, washing and drying the product to obtain white powder, calcining in a tubular furnace to obtain three-dimensional flower-shaped Bi2O3, putting in the tubular furnace, introducing argon, introducing ammonia gas, heating, and carrying out heat preservation reaction to obtain the electrocatalyst. The catalyst can be used for catalyzing nitrogen reduction synthesis ammonia reaction.

The invention discloses a method for promoting acid production and alcohol production through fermentation of clostridium perdali C1 gas by using a biological source carbon-based redox regulation and control medium. The preparation method comprises the following steps: obtaining biochar by adopting a high-temperature pyrolysis method, grinding and sieving to obtain a biogenic carbon-based redox regulation medium, adding the biogenic carbon-based redox regulation medium into a fermentation culture medium, inoculating clostridium perdali into a fermentation device filled with the fermentation culture medium, controlling the volume ratio of H2 to CO2 in the fermentation device to be (1.5: 1)-(2.5: 1), and carrying out anaerobic fermentation for 20-30 days to obtain the biogenic carbon-based redox regulation medium. According to the invention, a biological source carbon-based redox regulation medium is introduced into a clostridium perdali gas fermentation system, and the medium not only can enrich CO2 gas, but also can improve the mass transfer efficiency of a gaseous substrate; the method has the advantages that the method is simple and convenient to operate, extra reducing power is provided for a fermentation system, electron transfer is mediated, the CO2 utilization rate of the strain and the fermentation product generation rate are remarkably increased, secondary resource utilization of solid waste biomass is achieved, C1 gas is effectively converted into high-value chemicals, and a green, economical and sustainable development road is provided for conversion of CO2.

The invention relates to the technical field of wastewater treatment, and discloses a high-salinity wastewater treatment method and device for achieving bacterium-alga granulation and synergistic denitrification, the high-salinity wastewater treatment method for achieving bacterium-alga granulation and synergistic denitrification comprises the following steps: placing microalgae and aerobic granular sludge in a photobioreactor for initial culture; after initial culture, adding magnetic iron oxide nanoparticles into the photobioreactor, and carrying out enhanced culture, so as to obtain the algal-bacterial symbiotic aerobic granular sludge, and carrying out denitrification treatment on wastewater by utilizing the bacteria-algae symbiotic aerobic granular sludge. The magnetic iron oxide nanoparticles are added in the growth process of bacteria and algae, so that the problems of slow aggregation and nucleation of bacteria and algae, low activity of photosynthetic electron carriers of algae cells under high salt stress, reduction of denitrification efficiency and the like in the ABGS formation process can be effectively solved; rapid aggregation and nucleation of bacteria-algae cells can be synchronously enhanced, the electron transfer efficiency of an algae cell photosynthetic system under high salt stress is improved, and the denitrification efficiency of microorganisms is improved.

The invention discloses a method for synergistically enhancing biological oxidation of arsenopyrite by utilizing symbiotic minerals, which particularly comprises the following steps: adding a certain amount of pyrite into an arsenopyrite biological oxidation system, and improving the quantity and activity of acidophilic thiobacillus ferrooxidans by utilizing chemical change of a solution generated by oxidation of the pyrite. The mineral leaching capability of the functional microorganisms is optimized; meanwhile, under the dual action of pyrite and microorganisms, the content of Fe < 3 + > in the solution is remarkably increased, and the Fe < 3 + > serves as a main oxidizing agent for oxidizing arsenopyrite; due to the difference between the surface potentials of the pyrite and the arsenopyrite, a galvanic couple effect is formed between minerals, the electron transfer efficiency between the arsenopyrite and the oxidizing agent is accelerated, and finally the purpose of improving the leaching rate of the arsenopyrite in a biological system is achieved; according to the method, the leaching rate of arsenic in an arsenopyrite biological oxidation system is increased by nearly 8 times at most, the reinforcing effect on arsenopyrite oxidation is remarkable, and meanwhile the method is simple in process, mild in condition, easy and convenient to operate and low in cost.

The invention discloses a metal in-situ anchoring carbon nanocluster catalyst as well as a preparation method and application thereof, and belongs to the technical field of unconventional oil and gas resource development. The metal in-situ anchored carbon nano-cluster catalyst provided by the invention is amorphous nano-particles without pore channel confinement, all active sites are exposed on the surface, and macromolecular organic matters in an in-situ pyrolysis process can be directly adsorbed and activated; the metal center is anchored to a flexible carbon skeleton in an atomic scale through M-N-C and M-O-C coordination bonds, and high dispersity and structural stability are still kept at the formation temperature of 500 DEG C; meanwhile, the catalyst is easily and uniformly injected into an oil shale reservoir through fracturing fluid and is well dispersed in a complex pore network, and the solid-solid catalytic interface efficiency is remarkably improved; the catalyst does not have a strong acid center, promotes selective fracture of C-C / C-H bonds mainly through metal electron transfer, and reduces the risk of formation blockage; therefore, the method has a good application prospect in oil shale in-situ pyrolysis.

The invention relates to the technical field of photocatalysis, in particular to a Ni / Ga bimetal doped g-C3N4 nanotube composite material as well as a preparation method and application thereof. The Ni / Ga bimetal doped g-C3N4 nanotube composite material with the nitrogen vacancy is formed by doping Ni and Ga bimetals into the g-C3N4 nanotube and calcining the g-C3N4 nanotube in the air atmosphere to introduce the nitrogen vacancy. Nitrogen vacancies and double metal doping synergistically improve the efficiency of photocatalytic hydrogen production, because the Ni / Ga double metal doped g-C3N4 nanotube composite material with the nitrogen vacancies has a wider visible light absorption range, a lower carrier recombination rate, a higher electron transfer rate and higher stability, the composite material further has higher hydrogen production efficiency.

The invention relates to the technical field of preparation of catalysts, in particular to a CuNiSn-based molten catalyst for preparing graphene and a preparation method of the CuNiSn-based molten catalyst for preparing the graphene. The preparation method comprises the steps that S1, NiO-SnO2 precursor powder is prepared; s2, NiO-SnO2 powder and copper particles are mixed, high-purity nitrogen is injected into a reactor, then the temperature is increased to 800 DEG C, heat preservation is conducted for 3-4 h, and CuNi-Sn alloy blocks are obtained after the temperature is decreased to the room temperature; and S3, a smelting furnace is preheated in advance and pumped to a high-vacuum state, the CuNi-Sn alloy block and the alloy modifier are put into a crucible and put into the smelting furnace, it is ensured that the CuNi-Sn alloy block and the alloy modifier are fully mixed with the CuNi-Sn alloy block, then heat preservation is conducted for 10-15 h, and the CuNiSn-based fusion catalyst for preparing the graphene is obtained after the CuNi-Sn alloy block is cooled to the room temperature. The low solubility and high diffusivity characteristics of Ga and the ability of In to reduce the viscosity of the Ga-Sn liquid alloy, improve the carbon diffusion kinetics and enhance the electron transfer efficiency in cooperation with a conductive network of boron-doped graphdiyne jointly act on the waste plastic cracking process, the number of carbon layers of graphene can be effectively controlled, and the specific surface area and quality of graphene can be improved.