The invention discloses fluororesin radiating paint and a preparation method thereof. The paint mainly comprises an electron transfer type organic compound, graphene, a carbon nanotube, titanium white, other additives and fluororesin, wherein the fluororesin is a paint brand having the highest comprehensive property at present; the electron transfer type organic compound can greatly enhance the thermal radiation rate of the paint; the graphene and the carbon nanotube can further accelerate thermal conduction; and the electron transfer type organic compound, the carbon nanotube and the graphene finally form a full three-dimensional network distribution of granules (electron transfer type organic compound), wires (carbon nanotube) and planes (graphene) in a fluid. The fluororesin radiating paint disclosed by the invention has high thermal radiation rate, high thermal conductivity and low thermal resistance, can realize radiation cooling, and simultaneously has the effects of self cleaning, acid/alkali resistance and super high insulativity, thereby having high practical value.