146 results about "Triphenylene" patented technology

An organic electroluminescence device includes: a cathode; an anode; and a single-layered or multilayered organic thin-film layer provided between the cathode and the anode. The organic thin-film layer includes at least one emitting layer. The at least one emitting layer contains at least one phosphorescent material and a host material represented by the following formula (1).In the formula, Ar1, Ar2, Ar3, B1, B2, B3 and B4 each represent a substituted or unsubstituted benzene ring or a substituted or unsubstituted condensed aromatic hydrocarbon ring selected from a naphthalene ring, a chrysene ring, a fluoranthene ring, a phenanthrene ring, a benzophenanthrene ring, a dibenzophenanthrene ring, a triphenylene ring, a benzo[a]triphenylene ring, a benzochrysene ring, a benzo[b]fluoranthene ring and a picene ring. p is 0 or 1.

An organic electroluminescence device includes: a cathode; an anode; and a single-layered or multilayered organic thin-film layer provided between the cathode and the anode. The organic thin-film layer includes at least one emitting layer. The at least one emitting layer contains at least one phosphorescent material and a host material represented by the following formula (1).Ra-Ar1-Rb  (1)In the formula, Ar1, Ra and Rb each represent a substituted or unsubstituted benzene ring or a condensed aromatic hydrocarbon ring selected from a substituted or unsubstituted naphthalene ring, a substituted or unsubstituted chrysene ring, a substituted or unsubstituted fluoranthene ring, a substituted or unsubstituted phenanthrene ring, a substituted or unsubstituted benzophenanthrene ring, a substituted or unsubstituted dibenzophenanthrene ring, a substituted or unsubstituted triphenylene ring, a substituted or unsubstituted benzo[a]triphenylene ring, a substituted or unsubstituted benzochrysene ring, a substituted or unsubstituted benzo[b]fluoranthene ring and a substituted or unsubstituted picene ring. Substituents for Ra and Rb are not aryl groups.

In a rechargeable non-aqueous electrolyte secondary battery using positive electrodes, negative electrodes and a non-aqueous electrolytic solution, additives to the electrolytic solution are used in combination, preferably in combination of at least two compounds selected from o-terphenyl, triphenylene, cyclohexylbenzene and biphenyl, and thus there are provided batteries excellent in safety and storage characteristics.

An organic electroluminescence device includes: a cathode; an anode; and a single-layered or multilayered organic thin-film layer provided between the cathode and the anode. In the organic electroluminescence device, the organic thin-film layer includes at least one emitting layer, and the at least one emitting layer contains: at least one phosphorescent material; and a host material represented by the following formula (1).Ra—Ar1—Ar2—Rb   (1)In the formula, Ar1, Ar2, Ra and Rb each represent a substituted or unsubstituted benzene ring or a substituted or unsubstituted condensed aromatic hydrocarbon group selected from a group consisting of a naphthalene ring, a chrysene ring, a fluoranthene ring, a triphenylene ring, a phenanthrene ring, a benzophenanthrene ring, a dibenzophenanthrene ring, a benzotriphenylene ring, a benzochrysene ring, a picene ring and a benzo[b]fluoranthene ring.

The invention provides a novel compound, which has stable compound property, a simple preparation process, high luminous efficiency and high carrier mobility and can be applied to a phosphorescent main body material and an electron transfer layer of an electroluminescent element. According to an applied device, the driving voltage can be reduced remarkably, and the current efficiency is increased. The structural general formula of the compound is shown as a formula I, wherein a mother nucleus is selected from triphenylene; terminal groups Ar1, Ar2 and Ar3 are selected from a pyridine group, a phenyl group, a biphenylyl group or a naphthyl group; A, B and C are chemical bonds or aromatic rings with 6-30 carbon atoms; and m, n and p are integers of 0-2.

Disclosed is a triphenylene based aromatic compound, wherein a benzene center is substituted with a triphenylene group and another aromatic group such as triphenylenyl, pyrenyl, phenylvinyl, carbazolylphenyl, or arylanthryl in the meta position of the benzene center. The meta-substituted aromatic compound of the invention has better thermal stability (Tg) than the conventional para-substituted aromatic compound. The meta-substituted aromatic compound, served as a hole transporting layer or a host material applied in a light emitting layer in an OLED, is more preferable than the conventional para-substituted aromatic compound.

The present invention provides a compound of the general formulaAr1—R1—Ar2   (I)wherein Ar1 and Ar2 independently represent triphenylenyl or pyrenyl, and R1 represent a bond, aryl, or heteroaryl. The present invention also provides a process for the preparation of the compound formula (□), and an organic electroluminescence device utilizing luminescent material comprising the compound of formula (□) as an emitting layer.

The present invention discloses an indenotriphenylene-based iridium complexes is represented by the following formula (1), the organic EL device employing the derivative as light emitting dopant of emitting layer can display good performance like as lower driving voltage and power consumption, increasing efficiency and half-life time.wherein A ring represents an imidazole, a pyridine, a quinoline and an isoquinoline, X1-X2 represents a bidentate ligand, and m, n and R1 to R4 are the same definition as described in the present invention.

The invention provides a triarylated amine derivative and an organic light-emitting device, and relates to the technical field of organic light-emitting materials. A furan or thiophene derivative group, a fluorene derivative group, and a triphenylene group are connected on a triarylated amine main structure to obtain the triarylated amine derivative, the film forming property of the triarylated amine derivative is good, the thermal stability is good, the triarylated amine derivative has an excellent hole transfer capability, is simple to synthesize and easy to operate, can be applied into theorganic light-emitting device to serve as a hole transfer layer, effectively solves the problems of poor thermal stability of a hole transfer material in the organic light-emitting device, difficultyin film forming, low light emitting efficiency of the device and serious roll-off, and the organic light emitting device has the advantages of low drive voltage, high light emitting efficiency and long service life.

The present invention provides a triphenylene-perylene monoimide diformate binary compound, which has a structure represented by a general formula I. The present invention further provides a preparation method of the triphenylene-perylene monoimide diformate binary compound, and applications of the triphenylene-perylene monoimide diformate binary compound as an organic solar cell active layer. Compared to the compound in the prior art, the compound of the present invention has advantages of easy adjustment of liquid crystal phase change temperature and temperature range, such that the compound has optical, electronic and electro-optical uses, and especially has uses as the organic solar cell active layer. The general formula (I) is defined in the specification.

Organic electroluminescent compounds comprising a triphenylene conjugated to a five-ring fused heterocyclic system, as depicted in formula 1 are provided. Also provided is an organic electroluminescent device comprising these compounds. The organic electroluminescent compounds disclosed herein exhibit good luminous efficiency and excellent material life. They can be used to manufacture OLED devices very superior in terms of operating life and which consume less power due to improved power efficiency.

The present invention discloses an triphenylene-based fused carbazole compound is represented by the following formula (1) or formula (2), the organic EL device employing the derivative as light emitting host of emitting layer can display good performance like as lower driving voltage and power consumption, increasing efficiency and half-life time.wherein Ar, X1 to X4, m, and R1 to R3 are the same definition as described in the present invention.

The invention discloses a preparation method of a phenazine-connecting two-dimensional covalent organic framework material of a novel structure. The synthesized phenazine-connecting two-dimensional covalent organic framework material of the novel structure has a highly planar rigid structure in a graphene-like single layer, and is also highly conjugated between layers. A synthesis method is a solvothermal method and is easy and safe to operate, the reaction is a molecular level reaction, and the synthesized product is more ordered and more stable. According to the method, triphenylene-2,3,6,7,10,11-hexaaminotriphenylene and hexaketocyclohexane octahydrate serve as raw materials, 1,4-dioxane and 1,3,5-mesitylene serve as organic solvents, and the phenazine-connecting two-dimensional covalent organic framework material of the novel structure is successfully prepared through the solvothermal method under the condition that acetic acid is used for adjusting the acid environment.

Various embodiments disclosed relate to conjugated polyelectrolytes and methods of using the same. Various embodiments provide a conjugated polyelectrolyte including a subunit having the structure —R1—Y—R2—Z—. At each occurrence, R1 is independently chosen from 1,4-bonded phenylene substituted by —X—R3—R4 j times and 2,5-bonded thiophene substituted by —X—R3—R4 j times. At each occurrence, Y is independently chosen from a bond and —C≡C—. At each occurrence, R2 is independently chosen from a bond, a substituted or unsubstituted phenylene, thiophenylene, azulenylene, heptalenylene, biphenylene, indacenylene, fluorenylene, phenanthrenylene, triphenylenylene, pyrenylene, naphthacenylene, chrysenylene, biphenylenylene, anthracenylene, and naphthylene. At each occurrence, Z is independently chosen from a bond and —C≡C—. The variables j, R3, and R4 are as defined herein.

The invention discloses a method for synthesising 1,5,9-trinitro-2,3,6,7,10,11-hexa-alkoxy triphenylene. The method comprises the following step of synthesising 1,5,9-trinitro-2,3,6,7,10,11-hexa-alkoxy triphenylene by taking 2,3,6,7,10,11-hexa-alkoxy triphenylene as a raw material, and taking nitrate and alkyl sulfonyl chloride as nitration reagents. Compared with literature report methods, the method disclosed by the invention has the advantages of being moderate in reaction conditions, simple to operate, high in product yield, without the need of other strong acid reagents during a reaction process, and the like.

The invention belongs to the field of an organic microporous polymer, and particularly relates to a nanometer organic microporous polymer and a method for adsorbing heavy metal in drinking water. The nanometer organic microporous polymer provided by the invention has a structure shown as a formula (I) shown in description, and comprises a condensed polycyclic aromatic structure unit; the nanometer organic microporous polymer is prepared from triquinoyl octahydrate, 4,5-dichloro-1,2 phenylenediamine and 2,3,6,7,10,11 hexahydroxy triphenylene through reaction; the nanometer organic microporous polymer is fully organic aromatic framework solid capable of being highly recovered; no metal ions are contained; the synthesis does not need a transition metal catalyst; no halogen-containing by-products are generated; green and environment-friendly effects are achieved; a very important function is provided for the green and sustainable development technology. Experiments prove that the organic microporous polymer provided by the invention can fast adsorb heavy metal materials in the drinking water, so that the heavy metal content is lower than the drinkable limit; the nanometer organic microporous polymer scan be widely applied to drinking water purifications.

The present invention discloses a triphenylene-based fused biscarbazole derivative expressed by a formula (1) or formula (2) and the use thereof. The triphenylene-based fused biscarbazole derivative can be used in an organic EL component mainly as a light emitting host of a light emitting layer, so that the organic EL component having low drive voltage, low power consumption, high efficiency and long half-life time. The invention also relates to an organic EL component containing the derivative expressed by the formula (1) or formula (2).

The present invention relates to a 1, 5, 9-trisubstituted coronene compound and a synthesis method thereof. The structural formula of the compound is shown in img file = 'dest _ path _ image 001. TIF 'wi = '109 'he = '108', wherein R represents H, C1-C18 alkyl, phenyl, 4-methylphenyl, 4-methoxy phenyl, benzyl, cyclohexyl, 4-trifluoromethylphenyl, thiophene, furan and the like. According to the technical scheme of the invention, the easily prepared 1, 5, 9-triamido triphenylene is subjected to diazotization and halogenation reaction to obtain the tri-halogenated triphenylene. After that, the tri-halogenated triphenylene is subjected to Sonogashira reaction with various alkynes to generate atriyne-triphenylene compounds. Finally, through the metal-catalyzed reaction and the cyclization reaction under the effect of an organic base, various 1, 5, 9-trisubstituted coronene compounds, novel in structure, can be obtained. According to the technical scheme of the invention, raw materials are easy for mass preparation. Meanwhile, the synthesis step is relatively short and the operation is convenient. The obtained trisubstituted coronene compound is good in thermal stability and chemical stability, and the trisubstituted coronene emits the relatively strong fluorescence within the range of 420-550 nm according to the fluorescence emission spectrum of the trisubstituted coronene compound. Therefore, the trisubstituted coronene is an excellent fluorescent material for preparing UV ultraviolet charge-coupled devices (UV-CCD) and organic light-emitting diodes (OLEDs), and has a wide application prospect in the field of electronic materials.

The present invention provides a novel compound represented by general formula (I) below, a method of manufacturing the same and an organic electroluminescent device employing the same;where R1 to R6 are independent of one another and are each a hydrogen atom or a substituent represented by general formula (II) below, and at least one of R1 to R6 is a substituent represented by general formula (II):—C≡C—SiRaRbRc  (II)where Ra, Rb and Rc are independent of one another and are each an aliphatic hydrocarbon group having 1 to 10 carbon atoms or an aromatic hydrocarbon group.

The invention discloses an arylamine derivative and an organic light-emitting device, and relates to the technical field of organic photoelectric materials. The arylamine derivative is an electron-rich system, and has a large conjugation structure, and hole transport performance is good. In addition, the light refraction index of the arylamine derivative is high, and when the arylamine derivativeis used as a light taking-out layer of the organic light-emitting device, the light exiting efficiency of the device can be improved effectively. In addition, the arylamine derivative has a large rigid structure due to introduction of large-size triphenylene, the glass transition temperature and thermal stability of the material are improved effectively, and film forming of the material is facilitated. The organic light-emitting device comprises an anode, a cathode and an organic matter layer, and the organic matter layer is positioned between the anode and the cathode, and comprises the arylamine derivative. The organic light-emitting device has low driving voltage, high light-emitting efficiency and long service life.

The invention provides a triphenylene derivate and an organic electroluminescence device, and belongs to the technical field of organic electroluminescence materials. The compound has the structure asshown in formula (I). According to the triphenylene derivate, triphenylene and benzimidazole are condensed, so that the obtained material is high in glass transition temperature and is capable of avoiding crystalizing; the synthesizing method is simple, and easy to operate; the organic electroluminescence device prepared through the triphenylene derivate is high in luminescence efficiency and lowin driving voltage.

Provided are: an organic electroluminescent element which exhibits higher performance and has particularly good driving voltage and external quantum efficiency, while having a longer service life; and an electronic device which is provided with this organic electroluminescent element. Also provided is a compound which enables the achievement of the organic electroluminescent element and the electronic device. Specifically provided are: a compound of a specific structure having a triphenylene skeleton; an organic electroluminescent element which uses this compound; and an electronic device which is provided with this organic electroluminescent element.

Disclosed are a copper-hexahydroxy triphenylene-based miRNA-21 electrochemical sensor and a detecting method thereof. The copper-hexahydroxy triphenylene-based miRNA-21 electrochemical sensor is in athree-electrode system, wherein an auxiliary electrode is a platinum electrode, a reference electrode is an Ag / AgCl electrode, and a working electrode is a copper-hexahydroxy triphenylene-based miRNA-21 eletrode. The copper-hexahydroxy triphenylene-based miRNA-21 electrochemical sensor is characterized in that the copper-hexahydroxy triphenylene-based miRNA-21 electrode is modified with a Cu-CAT (catalase) membrane, and the Cu-CAT membrane absorbs nucleotide products produced by shearing DNA / miRNA-21 (deoxyribonucleic acid / miRNA-21) with ExoIII (exonuclease III). Through the specific hydrophobic pi-pi stack effects between Cu-CAT and oligonucleotide products sheared by ExoIII, the copper-hexahydroxy triphenylene-based miRNA-21 electrochemical sensor can achieve high-sensitivity, rapid andprobe fixing-free sensing analysis on HCC (hepatocellular carcinoma) biomarkers.

The present invention discloses a indenotriphenylene-based amine derivative is represented by the following formula(I), the organic EL device employing the derivative as hole transport material, electron blocking material, can increasing efficiency and half-life time.wherein R1 to R4, p, X, A ring, L and Ar are the same definition as described in the present invention.

The present invention discloses an triphenylene-based fused biscarbazole derivative is represented by the following formula(1) or formula(2), the organic EL device employing the derivative as light emitting host of emitting layer can display good performance like as lower driving voltage and power consumption, increasing efficiency and half-life time.wherein G1, G2, L1, L2, X1 to X8, m, and R1 to R3 are the same definition as described in the present invention.

The present invention discloses a indenotriphenylene-based amine derivative is represented by the following formula (A), the organic EL device employing the compound as hole transport material, electron blocking material, can lower driving voltage and power consumption, increasing efficiency and half-life time.Wherein R1 to R5, m, n, p, L and Ar are the same definition as described in the present invention.