3443results about "Group 4/14 element organic compounds" patented technology

The invention discloses a self-assembled monomolecular layer hole transport material, a hole transport layer and a battery thereof. According to the present invention, the compound having different anchoring groups and represented by the formula (I) can be subjected to firm self-assembly with the substrate surface through the chemical bonding manner, such that the good coverage rate is provided, the film forming quality is increased, and the transmission performance is improved; and meanwhile, the material has a rigid conjugate large-plane condensed ring core structure, so that the hole transmission performance of the material is ensured, and the photovoltaic performance is favorably improved. When the material is applied to a perovskite solar cell to prepare a hole transport layer, the hole extraction capability can be enhanced, and the open-circuit voltage, the filling factor and the photoelectric conversion efficiency of a device can be improved.

Compound (I), deuterated derivatives, and pharmaceutically acceptable salts of any of the foregoing are disclosed. Methods of treating cystic fibrosis using these compounds are also disclosed.

A method for efficiently and safely cleaning an apparatus for tin compound and a highly purified tin compound apparatus are provided. A cleaning method for an apparatus that has been in contact with a tin compound having formula (1) below includes at least steps (A) to (C), in which step (B) is performed after step (A), and step (C) is performed after step (B):(A) a step of cleaning the apparatus with a non-protic solvent,(B) a step of cleaning the apparatus with alcohol, and(C) a step of cleaning the apparatus with ultrapure water having a resistivity value of 17 MΩ·cm at 25° C.RpSnXm  (1)In formula (1), R is a hydrocarbon group, p is an integer from 1 to 3, X is a hydrolyzable substituent, and m=4−p.

The present invention uses commercially available 3-aminopropylsilane coupling agent, diallylamino polyether acrylate, and an alkylating agent, or γ-propanesultone, or γ-butyrolactone as raw materials, and through an aza-Michael addition reaction and a quaternization reaction, a multifunctional silane coupling agent containing one or more quaternary ammonium cations, or sulfobetaine, or carboxybetaine in its molecular structure is prepared, which is used for the surface modification of bioactive glass, and the bioactivity, antibacterial and antifungal properties, and hydrophilicity enhancement effects after the surface modification of bioactive glass are obtained.

A method for efficiently and safely cleaning an apparatus for a tin compound and a highly purified apparatus for a tin compound are provided. A method of cleaning an apparatus that has been in contact with a tin compound having formula (1) includes at least steps (A) to (C) in this order:(A) a step of cleaning the apparatus with a non-protonic solvent,(B) a step of cleaning the apparatus with an acidic aqueous solution and / or alkaline aqueous solution, and(C) a step of cleaning the apparatus with ultrapure water having a resistivity of 17 MΩ·cm at 25° C.RpSnXm  (1)R is a hydrocarbon group, p is an integer of 0 to 3, X is a hydrolyzable substituent, and m=4-p.

The invention discloses a lubricant composition and application thereof in processing of a high-weather-resistance PC hollow plate, and relates to the technical field of lubricant compositions. The lubricant composition comprises the following components in parts by mass: 40-60 parts of base oil, 5-15 parts of a weather-resistant stable additive, 3-8 parts of an anti-wear reagent at extreme pressure, 2-6 parts of a dispersing agent, 1-4 parts of an antioxidant, 0.5-2 parts of a coupling agent and 20-30 parts of a solvent. Through the molecular collaborative design of the polar base oil and the solvent, the thermal decomposition tendency in the processing process is remarkably reduced, and a lubricating system is promoted to be upgraded to a low-volatilization and low-pollution green process direction. A weather-resistant additive molecular skeleton with anti-oxidation and anti-ultraviolet characteristics is innovatively constructed, integration of multiple protection mechanisms in material processing and service stages is realized, and dependence on secondary addition of auxiliaries in a traditional process is reduced.

The invention relates to the technical field of fabrics, and discloses an anti-ultraviolet modified polyester fabric preparation method, which comprises: using bis (3-chloropropyl) amine and allyltriethoxysilane as raw materials, carrying out Michael addition to obtain an intermediate 1, carrying out a ring-opening reaction on the intermediate 1 and 1, 3-propane sultone to obtain an intermediate 2, and sequentially carrying out a ring-opening reaction on the intermediate 2 and 2, 3-propane sultone to obtain the anti-ultraviolet modified polyester fabric. The preparation method comprises the following steps: carrying out substitution reaction and quaternization reaction on 2, 4-dihydroxybenzophenone and modified ferulic acid to obtain bis-benzophenone quaternary ammonium salt and ferulate terylene quaternary ammonium salt, and carrying out condensation on the ferulate terylene quaternary ammonium salt and siloxy groups contained in the bis-benzophenone quaternary ammonium salt and hydroxyl contained in the alkali-treated polyester fabric to obtain the polyester fabric. The anti-ultraviolet modified polyester fabric is obtained.

The present invention provides a multifunctional silane coupling agent, which is prepared from commercially available 3-aminopropylsilane coupling agent, acryloxy polyetheramine, and one of an alkylating agent, polyether sulfonate, γ-propane sultone or γ-butyrolactone through Michael addition reaction and quaternization reaction. The multifunctional silane coupling agent is a new variety carrying zwitterions, quaternary ammonium cations and polyether chains, enriching the functions and application scope of silane coupling agents. It can endow some modified materials with surface hydrophilicity, conductivity, antibacterial, antifogging, antifouling, biocompatibility, anticoagulant and wet lubrication properties, etc. at the same time.

The present invention relates to a nitrogen-containing tricyclic PRMT5 inhibitor, a method for producing the same, and a pharmaceutical use thereof. In particular, the present invention relates to a PRMT5 inhibitor having a structure represented by formula (I), a method for producing the same, a drug composition containing the same, and its use as a PRMT5 inhibitor and its use in the treatment and / or prevention of diseases mediated by PRMT5. Here, each substituent of formula (I) is the same as defined in the specification. 【Chemical 1】 TIFF2025516926000204.tif44144

A semiconductor photoresist composition and a method of forming patterns using the semiconductor photoresist composition are disclosed. The semiconductor photoresist composition may include a tin (Sn)-containing organometallic compound, deuterium oxide (D2O), and a solvent.

A method of preparing an acrylate-functional branched organosilicon compound (“compound”) is provided, and comprises reacting (A) a branched organosilicon compound and (B) an acrylate compound in the presence of (C) a catalyst, wherein component (A) has the general formula X—Si(R1)3, where X comprises a halogen-functional moiety and each R1 is selected from R and —OSi(R4)3, with the proviso that at least one R1 is —OSi(R4)3; each R4 is selected from R, —OSi(R5)3, and —[OSiR2]mOSiR3; each R5 is selected from R, —OSi(R6)3, and —[OSiR2]mOSiR3; each R6 is selected from R and —[OSiR2]mOSiR3; each R is an independently selected hydrocarbyl group; and 0≤m≤100; with the proviso that at least one of R4, R5 and R6 is —[OSiR2]mOSiR3. The compound prepared by the method, a copolymer comprising the reaction product of the compound and a second compound, a method of forming the copolymer, and a composition comprising the copolymer are each also provided.

The present disclosure relates to precursor compositions for forming irradiation sensitive films. In particular, the disclosure is directed to use of metal-containing precursors having haloaliphatic or unsaturated substituents, or other reactive moieties which advantageously react in the presence of extreme ultraviolet exposure to form resist films having increased etch resistance and / or reduced shrinkage upon processing. Alternatively, the use of metal-containing precursors having haloaliphatic or unsaturated substituents, or other reactive moieties for patterning structures having carbon-containing underlayers may advantageously react with the underlayer to increase adhesion of the resist film to the underlayer.

A photosensitive surface treating agent containing a compound represented by the following Formula (M1). In Formula (M1), R1 is a linear, branched or cyclic alkyl group having 1 to 6 carbon atoms, Y1 is a linear or branched alkylene group having 1 to 4 carbon atoms or a single bond, and the terminal carbon atom of the alkyl group for R1 may be bonded to a carbon atom constituting the alkylene group for Y1, and R1 and Y1 may form a ring. R2 is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, R3 and R4 are each independently an alkyl group having 1 to 3 carbon atoms, n0 is an integer of 0 or more, and X is a halogen atom or an alkoxy group.

The invention relates to a compound, a preparation method, a hole transport layer material, a photovoltaic device and a photovoltaic module. R1 and R4 are respectively and independently selected from amino and derivatives thereof, hydroxyl and derivatives thereof, methoxyl and derivatives thereof, sulfydryl and derivatives thereof, methylthio and derivatives thereof, thiophene groups and derivatives thereof, phosphate groups and derivatives thereof, carboxylic acid groups and derivatives thereof, and sulfonic acid groups and derivatives thereof; r2 and R3 are independently selected from alkyl, a phosphate group and derivatives thereof, a carboxylic acid group and derivatives thereof, a sulfonic acid group and derivatives thereof, and trimethoxysilyl propyl and derivatives thereof. The material is beneficial to improving the photoelectric conversion efficiency of photovoltaic devices and photovoltaic modules.

Certain embodiments of the invention provide a cationic lipid of formula (I):wherein R1, R2, R3 and R4 are defined as described herein, as well as methods of making these lipids. Certain embodiments of the invention also provide nucleic acid-lipid particles comprising a cationic lipid of formula (I), methods of making the lipid particles, and methods of delivering and / or administering the lipid particles.

The invention discloses a nitrogen-containing heterocyclic ring compound as well as a preparation method and application thereof, and particularly relates to a nitrogen-containing heterocyclic ring compound as shown in a general formula (I), or pharmaceutically acceptable salts thereof, or enantiomers, diastereoisomers, tautomers, torsion isomers, solvates, polymorphic substances or prodrugs thereof, and a preparation method and pharmaceutical application thereof. Wherein the definition of each group is described in the specification. # imgabs0 #

The invention relates to the technical field of silicon dioxide surface modification, in particular to a silicon dioxide hollow sphere with an MOF composite layer, a manufacturing method and a dielectric loss prediction method. The silicon dioxide hollow sphere comprises a hollow spherical structure formed by silicon dioxide, an amino silane layer grafted on the surface of an inner core layer through a covalent bond, a ZIF-8 crystal layer growing in situ by taking amino as a nucleation site, and thiol groups distributed on the outer surface of an MOF crystal. According to the silicon dioxide hollow sphere with the MOF composite layer, the manufacturing method and the dielectric loss prediction method, the silicon dioxide hollow sphere with the MOF composite layer has good compatibility and stability in an LCP matrix, the dielectric loss is small, and the performance of a high-frequency FPC is effectively improved.

The invention relates to the technical field of organic electroluminescent materials, in particular to a carbazole compound and an organic electroluminescent device thereof. The carbazole compound provided by the invention has a relatively high hole transport rate, and when the carbazole compound is applied to a hole transport region of the organic electroluminescent device, the luminous efficiency of the organic electroluminescent device is improved, and the service life of the organic electroluminescent device is prolonged; moreover, the carbazole compound provided by the invention has a relatively large conjugate plane, can adjust carrier transport balance in a luminescent layer, broaden a carrier recombination region and improve the exciton recombination rate, and can improve the luminescent efficiency of the organic electroluminescent device and improve the efficiency roll-off when being applied to the luminescent layer of the organic electroluminescent device. And the preparation method has good application effect and industrialization prospect, and can be applied to various fields such as display, illumination, business, medicine and the like.

The invention discloses a surface-modified bioactive glass oral cavity desensitization paste and a preparation method thereof, and relates to the technical field of oral cavity desensitization pastes. The surface-modified bioactive glass oral desensitization paste is prepared from the following raw materials in parts by weight: 5 to 15 parts of bioactive glass, 3 to 6 parts of modifier, 3 to 5 parts of silicon dioxide, 20 to 30 parts of humectant, 0.5 to 1 part of sweetening agent, 0.5 to 1.5 parts of foaming agent, 0.5 to 2 parts of thickening agent and 60 to 120 parts of deionized water. The surface modified bioactive glass oral cavity desensitization paste prepared by the invention has excellent antibacterial performance and dentinal tubule sealing effect.

The present invention provides a method for preparing dimethyldichlorosilane. The method comprises: performing a cracking and disproportionation reaction on high-boiling substances produced as a by-product in the production of an organosilicon monomer dimethyldichlorosilane under the action of a Ni@ZSM-5 catalyst encapsulating nickel nanoparticles to prepare dimethyldichlorosilane. The method not only solves the problem of a large amount of excess high-boiling substances in the production process of the organosilicon monomer and realizes high-value utilization of the high-boiling substances, but also has easy-to-control reactions, simple processes, and mild conditions. Moreover, the method has a single-pass conversion rate of the high-boiling substances of ≥90%, and a selectivity for dimethyldichlorosilane of ≥70%, thus having broad prospects for industrial application.

The present invention relates to the technical field of supported metallocene catalysts, and particularly relates to a supported metallocene catalyst additive, a preparation method thereof and an application. The supported metallocene catalyst additive has the following structure: #imgabs0#, wherein R is selected from C1-C10 alkyl groups, R1 and R3 are selected from alkyl groups and adamantyl groups and are in the ortho and para positions of -OH, R2 is selected from C1-C10 alkyl groups and cycloalkyl groups, and R' is selected from alkyl groups. This additive can greatly retain the catalytic activity and copolymerization performance of the metallocene catalyst, increase the metal loading and catalytic activity, and reduce the dosage of the traditional cocatalyst MAO.

The invention relates to a composite catalyst for improving synthesis of methylchlorosilane and a preparation method of the composite catalyst, and belongs to the technical field of composite catalysts. The catalyst comprises a main catalyst (a compound of cuprous chloride and metal zinc, the molar ratio of Cu to Zn being 1: (0.1-0.5)), a co-catalyst (alumina or stannic chloride, the mass of which is 5%-20%) and a carrier (porous silica gel or nitrogen-doped activated carbon, the loading capacity of which is 3-8 times). Through optimization of catalyst composition, carrier functionalization (such as sulfydryl modification) and a preparation process, the selectivity (greater than or equal to 85%) of dimethyldichlorosilane is remarkably improved, and the stability and activity of the catalyst are enhanced. The preparation method comprises the steps of ball milling and heat treatment of the main catalyst, addition of the cocatalyst, acid pickling and modification of the carrier, loading and drying of the catalyst and the like. The method has the advantages of high selectivity, good stability, simple process and the like, and is suitable for efficient synthesis of methyl chlorosilane.

The present disclosure provides for an organic electroluminescent device (OLED) including an anode; a cathode; and an emissive layer, disposed between the anode and the cathode. The emissive layer includes a phosphorescent dopant, a first host, and a second host, wherein the first host transports holes, the second host transports electrons, and the first host is fully or partially deuterated. Consumer products that include the OLED are also provided.

The compound shown in formula I, its stereoisomers or pharmaceutically acceptable salts, or a pharmaceutical composition containing them, and their use in the manufacture of a therapeutic agent for treating related diseases as a PDE4B inhibitor, wherein each group shown in formula (I) is as defined in the specification. [Chemical formula 1] TIFF2025518257000169.tif37156

An article containing an organic tin compound in an industrially usable container is provided, in which the container is sealable, and the part of the container in contact with the organic tin compound is made of stainless steel with a specific surface structure that has been electrolytically polished. This article makes it possible to store organic tin compounds with high reactivity while maintaining their purity for a long period of time.

The present invention relates to the technical field of reflective film and discloses a reflective film for photovoltaic use and a preparation method thereof. The present invention prepares a four-layer composite structure, namely a protective layer, a reflective layer, a base layer, and an adhesive layer. Each layer is bonded together by a hot pressing composite process. Each layer has insulating properties. In addition, a modified EVA adhesive layer is used as a bottom functional layer, which has both strong adhesiveness and insulating properties. The prepared reflective film has excellent insulating properties, weather resistance, and high reflectivity, and has great application value in the field of photovoltaic reflective film.

To provide, e.g., a transition metal compound capable of producing an olefin polymer having a high molecular weight and a high melting point with high productivity, even under high-temperature conditions that are advantageous in industrial production methods.SOLUTION: A transition metal compound (A) is represented by the general formula [I] in the figure.SELECTED DRAWING: None

Fluorinated coupling agents and polymerizable compositions including such fluorinated coupling agents and at least one free-radically polymerizable monomer, oligomer, or mixture thereof. Multilayer films including a substrate and at least a first layer overlaying a surface of the substrate also are described, in which the at least first layer includes a (co)polymer obtained by polymerizing the foregoing polymerizable compositions. Processes for making a multilayer film using the polymerizable composition also are taught. Articles including the multilayer film also are disclosed, in which the article preferably is selected from a photovoltaic device, a display device, a solid-state lighting device, a sensor, a medical or biological diagnostic device, an electrochromic device, light control device, or a combination thereof.

Intermolecular interactions and molecular chain mobility are improved when a hydrocarbon-terminal-group-containing compound represented by formula (1) is used as a surface protective agent for a non-fluorine-based material, and a surface treatment agent containing the compound can form a cured coating film having excellent water repellency, slipperiness, ease of soil removal, and abrasion resistance, in particular, steel wool abrasion resistance. (R is a C1-60 monovalent hydrocarbon group, Z is a divalent connecting functional group containing at least one selected from O, N, S, and Si, Y is a C1-30 divalent hydrocarbon group, A is a monovalent reactive group, and k is 1-3.)