The application discloses a supramolecular
nanotube based on cation-
pi interaction and application, and belongs to the technical field of supramolecular functional materials. The supramolecular
nanotube based on cation-
pi interaction is a hexagonal columnar structure formed by self-
assembly of cations of V-type
pyridine, and the V-type
pyridine is 4,4'-((1E,1'E)-(5'-(undecan-11-yloxy)-[1,1':3',1''-triphenyl]-4,4''-diyl)bis(ethene-2,1-diyl))bis(1-
methylpyridinium-1-
iodide) or 4,4'-((1E,1'E)-(5'-(undecan-11-yloxy)-[1,1':3',1''-triphenyl]-4,4''-diyl)bis(ethene-2,1-diyl))bis(1-
methylpyridinium-1-
chloride), and structural formulae are as follows: or.