705 results about "Electrostatic interaction" patented technology

The invention relates to the technical field of heavy metal recovery, in particular to a method for recovering heavy metal from metal waste. Comprising the following steps: preparing silicon-tungsten composite acid salt; preparing heteropolyacid powder; preparing a resin heteropolyacid composite material; heavy metals are recovered from metal wastes by a resin adsorption method. The silicon-tungsten composite acid salt is prepared under mild conditions through reaction of sodium metasilicate, sodium tungstate and potassium chloride, the operation is simple, the conditions are easy to control, the silicon-tungsten composite acid salt has rich active sites and a large specific surface area, the surface of the silicon-tungsten composite acid salt carries negative charges, and the surface of the silicon-tungsten composite acid salt is not prone to damage. Compared with a traditional chemical precipitation method, the method for extracting the heavy metal by using the silicon-tungsten composite acid salt does not need to add a large number of chemical reagents, and secondary pollution is reduced.

The invention discloses a novel long-acting bird repellent and a preparation method thereof, and belongs to the technical field of chemical bird repelling. The bird repellent is composed of a core material and a wall material, the core material is a mixture of geraniol, cinnamyl aldehyde and allicin according to the mass ratio of 1: (1.2-1.5): (0.5-0.8), the wall material is modified beta-cyclodextrin and pumpkin seed protein nanoparticles, and the mass ratio of the geraniol, the cinnamyl aldehyde and the allicin is (5-7): (3-5): (1-3). The preparation method comprises the following steps: preparing the quaternary ammonium salt modified beta-cyclodextrin, including the core material, performing high-speed shearing emulsification on the quaternary ammonium salt modified beta-cyclodextrin and the pumpkin seed protein nano dispersion liquid, and performing freeze drying to obtain a final product. According to the invention, a stable and compact'molecular inclusion + physical barrier 'dual slow-release structure is constructed by utilizing the electrostatic interaction between the positively charged modified beta-cyclodextrin and the negatively charged protein nanoparticles, the release time of effective components is remarkably prolonged to 9 months or more, and the composite material has excellent rain wash resistance and ultraviolet resistance, and can be used for preparing a composite material with a good application prospect. And efficient, environment-friendly and long-acting bird repelling is realized.

The invention discloses an oral monoclonal antibody micro-coated nanopolysaccharide microsphere preparation for targeted therapy of inflammatory bowel diseases and a preparation method thereof. According to the method, oxidized mannan and an anti-TNF-alpha monoclonal antibody are mixed and cross-linked by a cross-linking agent containing a diselenide bond to form the drug-loaded nanoparticles. Mixing the drug-loaded nanoparticles with pectin, dropwise adding the mixture into a calcium chloride solution through an electrostatic spinning device, and carrying out ionic crosslinking to obtain the oral monoclonal antibody micro-coated nano polysaccharide microsphere preparation with the particle size range of 180-200 microns. The drug-loaded polysaccharide microsphere delivers the wrapped drug-loaded nanoparticles to a colitis disease part through electrostatic interaction. The drug-loaded nanoparticles are targeted to macrophages, release of the monoclonal antibody is accelerated under the triggering of high-concentration active oxygen at an inflammation part, and the oral stability and the treatment effect of the monoclonal antibody drug are improved. The polysaccharide is used as a monoclonal antibody targeted delivery carrier, raw materials are cheap and easy to obtain, the preparation process is simple and convenient, reaction conditions are mild, and application and development are easy.

The invention provides a perovskite solar cell. The perovskite solar cell comprises a conductive substrate; a hole transport layer; a polymer hydrophobic layer; the polymer hydrophobic layer is formed by polymer ionic liquid; a perovskite thin film layer; an electron transport layer; an electrode layer; the polymer ionic liquid comprises a structure as shown in a formula (I). Compared with the prior art, the polymer ionic liquid provided by the invention has hydrophobicity and can effectively block invasion of water vapor to a perovskite layer when being applied; secondly, a monomer in the polymer ionic liquid contains imidazole, C-H in the monomer can form hydrogen bonds with halogen atoms in the perovskite, the interaction between a polymer chain and the perovskite is enhanced, and the phase change of the perovskite is inhibited; in addition,-SO3-at one end of the polymer ionic liquid can be combined with Pb < 2 + > in perovskite through electrostatic interaction, phase change of the polymer ionic liquid is further inhibited, and Pb leakage is reduced.

The invention discloses a covalent organic framework with oxidation-reduction activity and a bionic nano-channel structure as well as a preparation method and application of the covalent organic framework, and belongs to the technical field of environmental protection. According to the preparation method, 2, 4-dihydroxybenzene-1, 3, 5-tricarboxaldehyde and 2, 5-bis (allyloxy) terephthaloyl hydrazine are taken as raw materials, a two-dimensional covalent organic framework with oxidation-reduction activity is synthesized, and then a sulfonic acid group with negative charges is covalently grafted, so that a functional material with a bionic nano-channel structure is formed. The material has regular porous channels and rich functional sites, the porous channels provide efficient mass transfer paths and adsorption spaces for uranyl ions, and the functional sites realize specific recognition of the uranyl ions through oxidation-reduction reaction and electrostatic interaction, so that the material shows synergistic advantages of strong selectivity, high adsorption capacity and rapid adsorption kinetics on uranium. The method is simple and low in cost, and the prepared material is clear in structure, good in hydrophilicity, capable of efficiently adsorbing uranyl ions and good in application prospect.

The invention belongs to the technical field of stamping machining feeding, and particularly relates to automatic feeding equipment of a continuous stamping die, which comprises an automatic feeding machine, the automatic feeding machine is arranged on one side of stamping die equipment and is used for automatically feeding the stamping die equipment, a feeding cavity is formed in the automatic feeding machine, paired feeding rollers are arranged in the feeding cavity, and the feeding rollers are connected with the automatic feeding machine. The feeding roller is connected with power equipment on the inner wall of the feeding cavity; the compacting plates on the upper side and the lower side are controlled to be close to the surface of the metal coiled material, meanwhile, airflow containing positive and negative ions is released, the electrostatic adsorption effect between metal chippings and the metal coiled material is reduced, and the metal chippings are promoted to be separated from the surface of the metal coiled material along with the flowing airflow and enter the recycling cavity along with the airflow; the defect that metal scraps on the surface of the metal coiled material are difficult to clean normally due to the electrostatic interaction is effectively overcome, purification treatment on the metal scraps attached to the surface of the metal coiled material is achieved, and the surface quality of the metal coiled material is improved.

The invention discloses a manganese-enriched albumin boron-containing nano preparation as well as a preparation method and application thereof, and belongs to the field of medicines and nano biological materials. According to the manganese-enriched albumin boron-containing nano preparation, albumin serves as a core carrier, phenylboronic acid derivatives are loaded through covalent or electrostatic interaction, then a manganese oxide layer is deposited on the surface in situ, and the prepared manganese-enriched albumin boron-containing nano preparation can remarkably increase the boron accumulation amount in tumor tissue; local and systemic immune response of tumors is promoted through the immune activation effect of manganese ions, so that the treatment effect of boron neutron capture therapy (BNCT) is remarkably improved. According to the invention, a phenylboronic acid derivative with tumor targeting is compounded with albumin, and manganese oxide is deposited in situ on the surface of the phenylboronic acid derivative, so that a multifunctional nano preparation with high boron delivery efficiency, immunological enhancement and magnetic resonance imaging functions is formed.

The invention discloses a three-dimensional porous carbon encapsulated V2O5 carbon fiber electrode constructed by in-situ growth and a preparation method and application thereof, belongs to the technical field of aluminum ion battery positive electrode materials, and aims to solve the problems that the intercalation and deintercalation dynamics of AlCl4 in a polyacrylonitrile (Pan)-based carbon fiber is blocked due to disordered graphite structure, and the performance of the Pan-based carbon fiber is influenced. And the material cannot be used as an effective electrode material to be applied to an aluminum ion battery system. According to the preparation method, an in-situ growth technology is adopted, a three-dimensional porous carbon substrate is grown on the surface of carbon fiber, then an orthorhombic system vanadium pentoxide (V2O5) nano material which has high theoretical specific capacity and can realize large-current charging and discharging is packaged in the three-dimensional porous carbon substrate, and the V2O5-based carbon fiber electrode is prepared. According to the electrode, the electrostatic interaction between Al < 3 + > ions and crystal lattices is effectively relieved, the structural advantages of the carbon fibers and the energy storage performance of V2O5 are fully combined, the energy storage effect of the aluminum ion battery is remarkably improved, and a new effective scheme is provided for development of aluminum ion battery electrode materials.

The invention discloses a nitrogen / boron-doped non-noble metal-based material, a synthesis method thereof and application of the nitrogen / boron-doped non-noble metal-based material in a microbial fuel cell. According to the method, a carbon fiber brush is used as a substrate, urea and sodium borohydride are used as a nitrogen source and a carbon source respectively, and the nitrogen / boron doped non-noble metal-based material is synthesized through a hydrothermal method. The electrostatic interaction between graphene oxide and FeCoNi-LDH is utilized to realize tight combination, so that FeCoNi-LDH nanosheets are uniformly dispersed on the surface of the carbon fiber brush, and the problems that LDHs are easy to agglomerate and poor in conductivity are solved; in the boron / nitrogen co-doping process, an efficient electron transmission channel is constructed by adjusting the electronic structure of the composite material, and the material is endowed with excellent electron transmission capability and oxygen reduction performance. In an MFC (Microbial Fuel Cell) test constructed by taking a nitrogen / boron-doped non-noble metal-based material as a cathode, the output voltage and the maximum power density are several times of those of commercial Pt / C and a blank carbon fiber brush, and the carbon fiber brush has a wide application prospect in the field of microbial fuel cells.

The invention relates to a chitosan-collagen synergistic self-assembly fiber material and a preparation method thereof, and belongs to the technical field of biological fiber materials. According to the method, the mass ratio of chitosan to collagen is controlled, co-assembly is induced through hydrogen bonds and electrostatic interaction in a low-temperature PBS solution, and then glutaraldehyde crosslinking, gradient dehydration and supercritical drying are performed to prepare the freeze-dried fiber. The obtained material completely retains the triple helix conformation of collagen, and has excellent conformation stability and enzymolysis resistance. The mechanical strength of the composite fiber is remarkably improved, and the composite fiber has excellent antibacterial property and cell affinity. The process does not need a toxic cross-linking agent, the operation is simple and convenient, and the prepared fiber is suitable for the high-end biomedical fields of tissue engineering scaffolds, intelligent antibacterial dressings, degradable nerve conduits and the like.

The invention discloses a bio-based recoverable high-thermal-conductivity dynamic ordered network composite material and a preparation method thereof, and is characterized in that the material takes a bio-based multifunctional epoxy system and a carboxylic acid compound containing disulfide bonds as reaction monomers, and the reaction monomers are reacted under the conditions of high temperature and metal salt catalyzed epoxy-carboxylic acid esterification reaction to obtain the bio-based recoverable high-thermal-conductivity dynamic ordered network composite material. A dynamic ordered network structure simultaneously containing disulfide bonds and beta-hydroxyl ester bonds is constructed, and the dynamic ordered network can be used as a springboard for phonon transmission, serves as an efficient'thermal bridge ', and plays a role similar to an ordered'crystal domain', so that higher heat-conducting property is shown when heat-conducting filler is not introduced, high flexibility and intrinsic heat conduction are realized, and the service life of the material is prolonged. And the material is endowed with reprocessing and recycling characteristics. Due to the synergistic existence of carboxyl, hydroxyl generated by epoxy ring opening and metal coordination in the system, and in combination with electrostatic interaction, Van der Waals force and hydrophobic interaction, the material has the adhesion characteristic suitable for a thermal interface at the same time.

Specifically, firstly, montmorillonite (MMT) powder is stripped into a nanosheet layer by using an ultrasonic dispersion technology, a two-dimensional layered structure of the nanosheet layer forms rich nanoscale ion channels, and an efficient path is provided for ion directional migration in salinity gradient power generation; meanwhile, after the cellulose is stripped and dispersed by a DMSO solution, a uniform polymer network is formed, the uniform polymer network is used as a substrate material to improve the mechanical strength of the film, and the interfacial ion adsorption and conduction capability is optimized through hydrophilic groups. When the MMT nanosheet and the cellulose suspension are mixed, the MMT nanosheet and the cellulose suspension form an interpenetrating network structure through physical winding and electrostatic interaction, ordered stacking is achieved through vacuum filtration, and finally the composite film with both ion selectivity and structural stability is formed on the substrate. The preparation process is high in material adaptability, green and controllable in preparation process, high in competitiveness in large-scale production and practical application and beneficial to popularization.

The invention discloses a polymer solid electrolyte containing a zwitterionic monomer and a preparation method and application thereof, and belongs to the technical field of solid-state lithium batteries. The polymer solid electrolyte is prepared by taking a polymer matrix as a substrate and taking a zwitterionic monomer as a functional modified monomer through copolymerization modification. According to the in-situ polymerized zwitterionic monomer polymer solid electrolyte disclosed by the invention, dissociation of lithium salt or other salts can be promoted through electrostatic interaction, so that the lithium ion conductivity of the solid electrolyte is optimized; the ion atmosphere of original anions and lithium ions in the electrolyte can be interfered, so that the migration of the lithium ions is released and promoted. Meanwhile, the movement of anions is inhibited by immobilized cations, the dissociation and migration of lithium ions are further promoted, the transference number of the lithium ions is favorably increased, and the long-term stable circulation of the battery is facilitated. In addition, the preparation method of the electrolyte is simple, the cost is low, and the actual requirement of mass production can be met.

The invention discloses a biological patch material with dry-state adhesion and wet-state easy stripping characteristics and application thereof, and belongs to the field of biological medicine. The biological patch material is prepared according to the following steps: by taking water-soluble protein as a template and copper ions in water-soluble copper salt as a metal coordination center, carrying out self-assembly on the template and drug molecules with phenolic hydroxyl structures to form nanoflowers; mixing the acrylamide, the sodium alginate, the water-soluble calcium salt and the nano-flowers to obtain the water-soluble calcium-based water-soluble nano-flower fertilizer. The biological patch material is adhered to the skin through electrostatic interaction, covalent bonds, physical interpenetration and topological tissues. The patch has skin adhesion in a dry state, so that the patch is convenient to fix; after the patch is in contact with burnt skin, the patch absorbs water and swells, the adhesive force is obviously reduced, and painless, easy and non-invasive stripping is realized. In addition, the patch has immunoregulation performance, can prevent stimulation and anaphylaxis caused by long-term contact with the skin, and promotes burn repair.

The invention belongs to the technical field of food additives and new materials, and discloses a thermostable embedding method and application of an alpha-amylase inhibitor, and the method comprises the following steps: respectively adjusting the pH values of an alpha-AL stock solution and an iota-CG stock solution to 6, then mixing the stock solutions according to the mass ratio of alpha-AL to iota-CG of 2: 1, and carrying out heat preservation for 2-3 hours, so as to obtain the thermostable embedding method of the alpha-amylase inhibitor. According to the method disclosed by the invention, the stable ion compound is formed under the condition that the pH is equal to 6 by utilizing the electrostatic interaction and the hydrogen-bond interaction between the negatively charged sulfuric acid group in the iota-carrageenan molecule and the positively charged amino acid residue on the surface of the white kidney bean alpha-amylase inhibitor. According to the compound, stable combination among molecules is achieved by constructing a structured water molecular layer barrier, so that the tolerance of the white kidney bean alpha-amylase inhibitor to heat treatment is remarkably improved, and the defect that the heat stability of the white kidney bean alpha-amylase inhibitor is poor is overcome.

Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component. Printed parts having piezoelectric properties may be formed using compositions comprising a plurality of piezoelectric particles non-covalently interacting with at least a portion of a polymer material via π-π bonding, hydrogen bonding, electrostatic interactions stronger than van der Waals interactions, or any combination thereof. The piezoelectric particles may be dispersed in the polymer material and remain substantially non-agglomerated when combined with the polymer material. The polymer material may comprise at least one thermoplastic polymer, optionally further including a polymer precursor. The compositions may define an extrudable material that is a composite having a form factor such as a composite filament, a composite pellet, a composite powder, or a composite paste. Additive manufacturing processes using the compositions may comprise forming a printed part by depositing the compositions layer-by-layer.

The invention relates to the technical field of hydrogel, in particular to a preparation process of antibacterial hydrophilic hydrogel and application of the antibacterial hydrophilic hydrogel in organoid tissue engineering. The preparation process comprises the following steps: S1, preparing a base material; the base material is prepared from the following raw materials in parts by weight: 300 to 400 parts of deionized water, 60 to 80 parts of acryloyloxyethyl trimethyl ammonium chloride, 40 to 60 parts of polyoxyethylene, 20 to 30 parts of antibacterial agent, 6 to 10 parts of methyl methacrylate and 1 to 3 parts of photoinitiator 1173. According to the preparation method, the contact area between the silver nanoparticles and bacteria is increased, cell membranes are damaged, silver ions are released, chitosan and beta-sodium glycerophosphate form a temperature-sensitive gel precursor after being dissolved, and due to the fact that chitosan carries positive charges, the bacteria can be adsorbed and cell walls can be damaged through the electrostatic interaction; the chitosan and the silver nanoparticles form a slow-release carrier, so that the release time of silver ions is prolonged, and the antibacterial property of the antibacterial hydrophilic hydrogel is further improved.

The invention discloses an aggregation-induced emission photosensitizer as well as a preparation method and application thereof. A D-A-pi-A-D symmetrical structure is adopted, the spatial effect and the conjugation degree are adjusted through a pi bridge, the molar absorption coefficient is increased, and singlet excitons are increased; and furthermore, a pyridine ring with positive charges is used for accelerating electron transfer, the yield of triplet excitons and ROS is improved, compared with a traditional photosensitizer, the ROS efficiency is improved by 2-3 times, the efficient killing capability of the photosensitizer on pathogens can be ensured, and a guarantee is provided for rapid healing of infectious wounds. A pyridine ring with positive charges is introduced into an MTCNPy molecule, and the targeting property of the photosensitizer to pathogens is enhanced by utilizing the electrostatic interaction between the pyridine ring and a bacterial negative charge cell membrane, so that the damage to surrounding healthy tissues is reduced. The preparation process is simple, the cost is low, and the hydrogel has excellent hydrophilicity and biocompatibility so as to be more suitable for the biological environment.

The invention provides a cobalt tungstate and bismuth vanadate photocatalytic material as well as a preparation method and application thereof, and belongs to the technical field of material synthesis and photocatalytic application. In the presence of monoclinic-phase decahedron BiVO4, CoWO4 nanoparticles grow in situ on an electron-rich (010) crystal face of the CoWO4 nanoparticles through a hydrothermal reaction, and the cobalt tungstate and bismuth vanadate photocatalytic material is obtained. According to the cobalt tungstate and bismuth vanadate photocatalytic material, a simple hydrothermal method is adopted, in the synthesis process, a CoWO4 precursor is guided by electrostatic interaction, preferentially adsorbed and subjected to nucleation growth on the (010) crystal face of BiVO4, a compact chemical bonding interface is constructed through selective growth, the charge migration distance is effectively shortened, and the photocatalytic performance of the material is improved. The interface charge transfer resistance is reduced to the greatest extent, and the formed binary photocatalyst has excellent effects on photocatalytic hydrogen evolution and tetracycline degradation.

The invention belongs to the technical field of preparation of functional environment-friendly materials, and discloses a preparation method of phosphoric acid modified cotton hull biochar for treating antibiotic wastewater. And carrying out high-temperature calcination in a nitrogen atmosphere to prepare the modified biochar material with rich pore structures and phosphorus-containing functional groups. The material has extremely high adsorption capacity to ciprofloxacin, the maximum adsorption capacity can reach 572.8 mg / g, and the material has a good removal effect and coexistence interference resistance to ciprofloxacin in actual wastewater. The adsorption mechanism mainly comprises electrostatic interaction, pi-pi interaction, hydrogen-bond interaction, surface complexation and the like. The material is simple in preparation process, low in cost, good in reproducibility and suitable for treatment of water bodies containing antibiotic pollutants such as pharmaceutical wastewater and aquaculture wastewater. The method fills the technical blank of high-value recycling of the cotton hull waste and cooperative treatment of antibiotic pollution, and has important environmental application prospects and industrial popularization values.

The invention discloses a synthesis method and application of a redox cation covalent organic framework, and belongs to the technical field of functional adsorption materials. 2, 5-dihydroxy benzaldehyde and triamino guanidine chloride are used as reaction monomers, a covalent organic framework is constructed through a Schiff alkali condensation reaction, guanidyl cation sites are synchronously introduced, hydroxyl redox active groups are reserved, and a redox cation covalent organic framework (AGS-TPA-OH) uniformly-distributed high-density guanidyl salt cation and hydroquinone active unit is prepared. Cr2O7 < 2-> is efficiently captured through electrostatic interaction. The synthesis method is green and efficient, the adsorption capacity of the obtained AGS-TPA-OH on Cr2O7 < 2-> reaches 4377.25 mg / g, the removal rate in 50 minutes exceeds 98%, an innovative solution is provided for efficient treatment and resource recycling of hexavalent chromium in industrial wastewater, and the method has remarkable environmental and economic benefits.

The invention belongs to the technical field of adsorbents, and discloses a core-shell structure composite material as well as a preparation method and application thereof. Ferroferric oxide is loaded on biochar by coprecipitation of ferric salt, ferrous salt and biochar, amination modification is performed by using polyethyleneimine, and a COF shell layer is prepared in situ by using a magnetic core. The shell layer is chemically connected with the magnetic core, and is coated by the COF shell, so that the structural stability is improved, the porous structure of the biochar is not easy to collapse, and the magnetic particles are not easy to fall off; the shell contains sulfonic acid groups, has electronegativity, and is combined with metal ions through electrostatic interaction, so that the adsorption sites of the adsorbent are increased. Meanwhile, the COF shell is of a porous structure, the specific surface area is large, the COF shell has the adsorption effect on metal ions, more adsorption sites are provided for the metal ions through the multiple adsorption effects of the COF shell and the magnetic core, and the removal rate is effectively increased.

The invention relates to a paper pulp-based hydroxyethyl cellulose antibacterial composite film as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) preparing paper pulp-based hydroxyethyl cellulose; (2) preparing a peppermint essential oil nano-emulsion; and (3) preparing the paper pulp-based hydroxyethyl cellulose antibacterial composite film. The average thickness of the paper pulp based hydroxyethyl cellulose antibacterial composite film provided by the invention is 0.205 + / -0.017 mm, and the density is 0.59 + / -0.05 g / cm < 3 >. Hydroxyl in paper pulp base HEC and carboxyl and hydroxyl of SA form a multiple hydrogen bond network; pO is used as a hydrophobic plasticizer and generates interfacial tension with a hydrophilic SA / HEC matrix, and tiny liquid drops or agglomerates are easily formed in the film forming process; ca < 2 + > and carboxylate radicals in SA form ionic bonds through electrostatic interaction to generate a calcium alginate gel network, so that the tensile strength of the paper pulp-based hydroxyethyl cellulose antibacterial composite film reaches 6.1 MPa, the water vapor permeability is 5.32 * 10 <-10 > g.m <-1 >. S <-1 >. Pa <-1 >, and the paper pulp-based hydroxyethyl cellulose antibacterial composite film has a remarkable inhibition effect on growth of penicillium oxalicum.

The invention relates to preparation and application of a desoxyribonucleic acid and desoxyribonucleic acid derivative transdermal delivery system, and belongs to the technical field of biological medicine and skin care products. Desoxyribonucleic acid and derivatives thereof have the effects of resisting aging, repairing and the like, but are difficult to penetrate through a skin barrier due to large molecular weight and strong polarity. According to the invention, hydroxyethyl chitosan, desoxyribonucleic acid and derivatives thereof are combined through electrostatic interaction to form the nano-composite. The compound is small in particle size and can promote transdermal absorption through hair follicle or cuticle gaps. The preparation method is simple, does not need an auxiliary reagent, and comprises the step of mixing a hydroxyethyl chitosan solution and a deoxyribonucleic acid derivative solution. Experiments show that the compound significantly enhances the transdermal efficiency, and has the effects of promoting cell repair and proliferation and resisting inflammation. The composition can be used for skin care products, and is high in safety and wide in application prospect.

The invention discloses a medical pressure-sensitive adhesive patch based on citric acid, a preparation method and application, the medical pressure-sensitive adhesive patch is composed of an adhesion layer and an anti-adhesion layer, and the thickness ratio of the adhesion layer to the anti-adhesion layer is 1: 1-100: 1; the adhesion layer is obtained by polymerizing a citric acid unit and a polyhydroxy compound unit; the hydrophobic high-molecular polymer is selected from at least one of a polylactic acid-glycolic acid copolymer, polylactic acid, polyurethane and polyether urethane. According to the preparation method, three carboxyl groups in the citric acid not only can be used for esterification reaction with polyhydric alcohols to form a network, but also can provide excellent adhesive force for contact between the adhesive patch and the tissue surface through electrostatic interaction or hydrogen-bond interaction. The anti-sticking layer prepared from the hydrophobic high-molecular polymer can effectively resist invasion of external moisture and bacteria, so that the service time of the adhesive patch is prolonged; meanwhile, the anti-sticking layer can also play a supporting role, so that the mechanical strength of the adhesive tape is improved.

The invention provides a water-based composite electrolyte and a preparation method and application thereof. The water-based composite electrolyte comprises soluble zinc salt, amino acid hydrochloride additives and deionized water. The aqueous composite electrolyte can be used for a symmetrical button cell, a half cell or an aqueous zinc ion total cell. By adjusting zinc ion deposition on the surface of the zinc electrode, the growth of zinc dendrites is reduced, and the shuttle effect of the iodine positive electrode is inhibited, so that the coulombic efficiency and the cycle performance of the water-based zinc-iodine battery are improved. The additive disclosed by the invention can be adsorbed on the surface of a zinc negative electrode, delays the nucleation process and inhibits the growth of zinc dendrites; the form of hydrochloride can play a role of a buffer solution, stabilize the pH value of the electrolyte, inhibit the corrosion of the zinc negative electrode and reduce the hydrogen evolution reaction; the hydrochloride form can weaken the protonation effect of amino acid groups and enhance the electrostatic interaction between the amino acid groups and the polyiodide, so that the shuttle effect is inhibited, and the coulombic efficiency and the cycle performance of the aqueous zinc-iodine battery are improved.

The invention belongs to the field of antibiotic analysis and detection, and discloses a quinolone drug SERS (Surface Enhanced Raman Scattering) detection method based on an improved silver nano-substrate and a spectral angle matching model. An improved Lee-Meisel method is adopted to synthesize silver nano sol with precisely controlled particle size, molecular adsorption is realized by utilizing electrostatic interaction of a positively charged quinolone drug and negatively charged silver nano particles, and a high-density Raman enhanced hot spot is formed after an agglomeration agent is added; the SERS spectrum is collected at the excitation wavelength of 785 nm and the integral time of 10 s, qualitative distinguishing of drugs is achieved by combining a spectrum angle matching model, and quantitative detection is achieved by constructing a standard curve through the linear relation between the characteristic peak intensity and the drug concentration logarithm. The detection limit of the four drugs is as low as 1.03-1.16 ppb, the classification accuracy rate reaches 100%, the method is obviously superior to existing similar methods, the detection matrix range is wide, such as animal food and dairy products, and universality and high sensitivity are both considered.

The invention relates to the technical field of biomedical materials, and particularly discloses a tracheal catheter with antibacterial and lubricating functions and a preparation method thereof.According to the tracheal catheter, 2, 3-epoxypropyltrimethylammonium chloride is adopted for modifying polyethyleneimine, and the antibacterial performance of the polyethyleneimine is enhanced; then modified polyethyleneimine and tannic acid are adopted as a composite antibacterial coating, so that the tracheal catheter has good antibacterial activity on various bacteria; then N-vinyl pyrrolidone and modified fucoidin are adopted as functional monomers, ultraviolet-initiated polymerization is conducted, the hydrophilic lubricating coating is obtained, sulfuric acid groups in the hydrophilic lubricating coating are negatively charged and can attract quaternary ammonium salt cations in the antibacterial coating through electrostatic interaction, and therefore the hydrophilic lubricating coating is formed. Compared with a single polyvinylpyrrolidone (PVP) hydrophilic coating which is easy to fall off, the hydrophilic lubricating coating disclosed by the invention effectively solves the problem that the traditional hydrophilic coating is easy to fall off.

The invention relates to a composite diaphragm, a preparation method thereof and a secondary battery. The composite diaphragm comprises a base membrane and a first coating arranged on one side surface of the base membrane in the thickness direction, the first coating comprises a modified MOF material, the modified MOF material comprises a first MOF material and a coating layer coating the first MOF material, and the coating layer comprises a functional group capable of generating electrostatic interaction and / or coordination interaction with active ions. Therefore, the cycle performance of the battery can be effectively improved.

The application discloses a vaccine and a preparation method thereof, and the preparation method comprises the following steps: mixing an acidic protein antigen solution containing a phosphate buffer solution with an aluminum adjuvant to make the molar ratio of phosphorus and aluminum below 0.9, so as to obtain an acidic protein vaccine; or mixing the aluminum adjuvant with a solution containing phosphate ions to make the molar ratio of phosphorus and aluminum above 0.2, and then mixing the aluminum adjuvant with an alkaline protein antigen solution containing a phosphate buffer solution, so as to obtain an alkaline protein vaccine; wherein the acidic protein antigen is any kind of protein antigen with a net negative charge; and the alkaline protein antigen is any kind of protein antigen with a net positive charge. According to the preparation method, the molar ratio of phosphorus and aluminum is adjusted to a specific range according to the net charge of the protein antigen, so that the isoelectric point of the aluminum adjuvant can be effectively changed, the charge carried by the aluminum adjuvant is opposite to the charge carried by the protein antigen, and then the aluminum adjuvant and the protein antigen are attracted to each other through electrostatic interaction. The vaccine antigen prepared by the method has high antigen adsorption rate and good stability, the preparation method is simple, and the method is suitable for industrial application.