515 results about "Electrostatic interaction" patented technology

The invention discloses a novel long-acting bird repellent and a preparation method thereof, and belongs to the technical field of chemical bird repelling. The bird repellent is composed of a core material and a wall material, the core material is a mixture of geraniol, cinnamyl aldehyde and allicin according to the mass ratio of 1: (1.2-1.5): (0.5-0.8), the wall material is modified beta-cyclodextrin and pumpkin seed protein nanoparticles, and the mass ratio of the geraniol, the cinnamyl aldehyde and the allicin is (5-7): (3-5): (1-3). The preparation method comprises the following steps: preparing the quaternary ammonium salt modified beta-cyclodextrin, including the core material, performing high-speed shearing emulsification on the quaternary ammonium salt modified beta-cyclodextrin and the pumpkin seed protein nano dispersion liquid, and performing freeze drying to obtain a final product. According to the invention, a stable and compact'molecular inclusion + physical barrier 'dual slow-release structure is constructed by utilizing the electrostatic interaction between the positively charged modified beta-cyclodextrin and the negatively charged protein nanoparticles, the release time of effective components is remarkably prolonged to 9 months or more, and the composite material has excellent rain wash resistance and ultraviolet resistance, and can be used for preparing a composite material with a good application prospect. And efficient, environment-friendly and long-acting bird repelling is realized.

The invention provides a perovskite solar cell. The perovskite solar cell comprises a conductive substrate; a hole transport layer; a polymer hydrophobic layer; the polymer hydrophobic layer is formed by polymer ionic liquid; a perovskite thin film layer; an electron transport layer; an electrode layer; the polymer ionic liquid comprises a structure as shown in a formula (I). Compared with the prior art, the polymer ionic liquid provided by the invention has hydrophobicity and can effectively block invasion of water vapor to a perovskite layer when being applied; secondly, a monomer in the polymer ionic liquid contains imidazole, C-H in the monomer can form hydrogen bonds with halogen atoms in the perovskite, the interaction between a polymer chain and the perovskite is enhanced, and the phase change of the perovskite is inhibited; in addition,-SO3-at one end of the polymer ionic liquid can be combined with Pb < 2 + > in perovskite through electrostatic interaction, phase change of the polymer ionic liquid is further inhibited, and Pb leakage is reduced.

The invention discloses a covalent organic framework with oxidation-reduction activity and a bionic nano-channel structure as well as a preparation method and application of the covalent organic framework, and belongs to the technical field of environmental protection. According to the preparation method, 2, 4-dihydroxybenzene-1, 3, 5-tricarboxaldehyde and 2, 5-bis (allyloxy) terephthaloyl hydrazine are taken as raw materials, a two-dimensional covalent organic framework with oxidation-reduction activity is synthesized, and then a sulfonic acid group with negative charges is covalently grafted, so that a functional material with a bionic nano-channel structure is formed. The material has regular porous channels and rich functional sites, the porous channels provide efficient mass transfer paths and adsorption spaces for uranyl ions, and the functional sites realize specific recognition of the uranyl ions through oxidation-reduction reaction and electrostatic interaction, so that the material shows synergistic advantages of strong selectivity, high adsorption capacity and rapid adsorption kinetics on uranium. The method is simple and low in cost, and the prepared material is clear in structure, good in hydrophilicity, capable of efficiently adsorbing uranyl ions and good in application prospect.

The invention belongs to the technical field of stamping machining feeding, and particularly relates to automatic feeding equipment of a continuous stamping die, which comprises an automatic feeding machine, the automatic feeding machine is arranged on one side of stamping die equipment and is used for automatically feeding the stamping die equipment, a feeding cavity is formed in the automatic feeding machine, paired feeding rollers are arranged in the feeding cavity, and the feeding rollers are connected with the automatic feeding machine. The feeding roller is connected with power equipment on the inner wall of the feeding cavity; the compacting plates on the upper side and the lower side are controlled to be close to the surface of the metal coiled material, meanwhile, airflow containing positive and negative ions is released, the electrostatic adsorption effect between metal chippings and the metal coiled material is reduced, and the metal chippings are promoted to be separated from the surface of the metal coiled material along with the flowing airflow and enter the recycling cavity along with the airflow; the defect that metal scraps on the surface of the metal coiled material are difficult to clean normally due to the electrostatic interaction is effectively overcome, purification treatment on the metal scraps attached to the surface of the metal coiled material is achieved, and the surface quality of the metal coiled material is improved.

The invention discloses a manganese-enriched albumin boron-containing nano preparation as well as a preparation method and application thereof, and belongs to the field of medicines and nano biological materials. According to the manganese-enriched albumin boron-containing nano preparation, albumin serves as a core carrier, phenylboronic acid derivatives are loaded through covalent or electrostatic interaction, then a manganese oxide layer is deposited on the surface in situ, and the prepared manganese-enriched albumin boron-containing nano preparation can remarkably increase the boron accumulation amount in tumor tissue; local and systemic immune response of tumors is promoted through the immune activation effect of manganese ions, so that the treatment effect of boron neutron capture therapy (BNCT) is remarkably improved. According to the invention, a phenylboronic acid derivative with tumor targeting is compounded with albumin, and manganese oxide is deposited in situ on the surface of the phenylboronic acid derivative, so that a multifunctional nano preparation with high boron delivery efficiency, immunological enhancement and magnetic resonance imaging functions is formed.

The invention discloses a three-dimensional porous carbon encapsulated V2O5 carbon fiber electrode constructed by in-situ growth and a preparation method and application thereof, belongs to the technical field of aluminum ion battery positive electrode materials, and aims to solve the problems that the intercalation and deintercalation dynamics of AlCl4 in a polyacrylonitrile (Pan)-based carbon fiber is blocked due to disordered graphite structure, and the performance of the Pan-based carbon fiber is influenced. And the material cannot be used as an effective electrode material to be applied to an aluminum ion battery system. According to the preparation method, an in-situ growth technology is adopted, a three-dimensional porous carbon substrate is grown on the surface of carbon fiber, then an orthorhombic system vanadium pentoxide (V2O5) nano material which has high theoretical specific capacity and can realize large-current charging and discharging is packaged in the three-dimensional porous carbon substrate, and the V2O5-based carbon fiber electrode is prepared. According to the electrode, the electrostatic interaction between Al < 3 + > ions and crystal lattices is effectively relieved, the structural advantages of the carbon fibers and the energy storage performance of V2O5 are fully combined, the energy storage effect of the aluminum ion battery is remarkably improved, and a new effective scheme is provided for development of aluminum ion battery electrode materials.

The invention discloses a bio-based recoverable high-thermal-conductivity dynamic ordered network composite material and a preparation method thereof, and is characterized in that the material takes a bio-based multifunctional epoxy system and a carboxylic acid compound containing disulfide bonds as reaction monomers, and the reaction monomers are reacted under the conditions of high temperature and metal salt catalyzed epoxy-carboxylic acid esterification reaction to obtain the bio-based recoverable high-thermal-conductivity dynamic ordered network composite material. A dynamic ordered network structure simultaneously containing disulfide bonds and beta-hydroxyl ester bonds is constructed, and the dynamic ordered network can be used as a springboard for phonon transmission, serves as an efficient'thermal bridge ', and plays a role similar to an ordered'crystal domain', so that higher heat-conducting property is shown when heat-conducting filler is not introduced, high flexibility and intrinsic heat conduction are realized, and the service life of the material is prolonged. And the material is endowed with reprocessing and recycling characteristics. Due to the synergistic existence of carboxyl, hydroxyl generated by epoxy ring opening and metal coordination in the system, and in combination with electrostatic interaction, Van der Waals force and hydrophobic interaction, the material has the adhesion characteristic suitable for a thermal interface at the same time.

The invention discloses a biological patch material with dry-state adhesion and wet-state easy stripping characteristics and application thereof, and belongs to the field of biological medicine. The biological patch material is prepared according to the following steps: by taking water-soluble protein as a template and copper ions in water-soluble copper salt as a metal coordination center, carrying out self-assembly on the template and drug molecules with phenolic hydroxyl structures to form nanoflowers; mixing the acrylamide, the sodium alginate, the water-soluble calcium salt and the nano-flowers to obtain the water-soluble calcium-based water-soluble nano-flower fertilizer. The biological patch material is adhered to the skin through electrostatic interaction, covalent bonds, physical interpenetration and topological tissues. The patch has skin adhesion in a dry state, so that the patch is convenient to fix; after the patch is in contact with burnt skin, the patch absorbs water and swells, the adhesive force is obviously reduced, and painless, easy and non-invasive stripping is realized. In addition, the patch has immunoregulation performance, can prevent stimulation and anaphylaxis caused by long-term contact with the skin, and promotes burn repair.

The invention belongs to the technical field of food additives and new materials, and discloses a thermostable embedding method and application of an alpha-amylase inhibitor, and the method comprises the following steps: respectively adjusting the pH values of an alpha-AL stock solution and an iota-CG stock solution to 6, then mixing the stock solutions according to the mass ratio of alpha-AL to iota-CG of 2: 1, and carrying out heat preservation for 2-3 hours, so as to obtain the thermostable embedding method of the alpha-amylase inhibitor. According to the method disclosed by the invention, the stable ion compound is formed under the condition that the pH is equal to 6 by utilizing the electrostatic interaction and the hydrogen-bond interaction between the negatively charged sulfuric acid group in the iota-carrageenan molecule and the positively charged amino acid residue on the surface of the white kidney bean alpha-amylase inhibitor. According to the compound, stable combination among molecules is achieved by constructing a structured water molecular layer barrier, so that the tolerance of the white kidney bean alpha-amylase inhibitor to heat treatment is remarkably improved, and the defect that the heat stability of the white kidney bean alpha-amylase inhibitor is poor is overcome.

The invention relates to the technical field of hydrogel, in particular to a preparation process of antibacterial hydrophilic hydrogel and application of the antibacterial hydrophilic hydrogel in organoid tissue engineering. The preparation process comprises the following steps: S1, preparing a base material; the base material is prepared from the following raw materials in parts by weight: 300 to 400 parts of deionized water, 60 to 80 parts of acryloyloxyethyl trimethyl ammonium chloride, 40 to 60 parts of polyoxyethylene, 20 to 30 parts of antibacterial agent, 6 to 10 parts of methyl methacrylate and 1 to 3 parts of photoinitiator 1173. According to the preparation method, the contact area between the silver nanoparticles and bacteria is increased, cell membranes are damaged, silver ions are released, chitosan and beta-sodium glycerophosphate form a temperature-sensitive gel precursor after being dissolved, and due to the fact that chitosan carries positive charges, the bacteria can be adsorbed and cell walls can be damaged through the electrostatic interaction; the chitosan and the silver nanoparticles form a slow-release carrier, so that the release time of silver ions is prolonged, and the antibacterial property of the antibacterial hydrophilic hydrogel is further improved.

The invention discloses an aggregation-induced emission photosensitizer as well as a preparation method and application thereof. A D-A-pi-A-D symmetrical structure is adopted, the spatial effect and the conjugation degree are adjusted through a pi bridge, the molar absorption coefficient is increased, and singlet excitons are increased; and furthermore, a pyridine ring with positive charges is used for accelerating electron transfer, the yield of triplet excitons and ROS is improved, compared with a traditional photosensitizer, the ROS efficiency is improved by 2-3 times, the efficient killing capability of the photosensitizer on pathogens can be ensured, and a guarantee is provided for rapid healing of infectious wounds. A pyridine ring with positive charges is introduced into an MTCNPy molecule, and the targeting property of the photosensitizer to pathogens is enhanced by utilizing the electrostatic interaction between the pyridine ring and a bacterial negative charge cell membrane, so that the damage to surrounding healthy tissues is reduced. The preparation process is simple, the cost is low, and the hydrogel has excellent hydrophilicity and biocompatibility so as to be more suitable for the biological environment.

The invention provides a cobalt tungstate and bismuth vanadate photocatalytic material as well as a preparation method and application thereof, and belongs to the technical field of material synthesis and photocatalytic application. In the presence of monoclinic-phase decahedron BiVO4, CoWO4 nanoparticles grow in situ on an electron-rich (010) crystal face of the CoWO4 nanoparticles through a hydrothermal reaction, and the cobalt tungstate and bismuth vanadate photocatalytic material is obtained. According to the cobalt tungstate and bismuth vanadate photocatalytic material, a simple hydrothermal method is adopted, in the synthesis process, a CoWO4 precursor is guided by electrostatic interaction, preferentially adsorbed and subjected to nucleation growth on the (010) crystal face of BiVO4, a compact chemical bonding interface is constructed through selective growth, the charge migration distance is effectively shortened, and the photocatalytic performance of the material is improved. The interface charge transfer resistance is reduced to the greatest extent, and the formed binary photocatalyst has excellent effects on photocatalytic hydrogen evolution and tetracycline degradation.

The invention relates to preparation and application of a desoxyribonucleic acid and desoxyribonucleic acid derivative transdermal delivery system, and belongs to the technical field of biological medicine and skin care products. Desoxyribonucleic acid and derivatives thereof have the effects of resisting aging, repairing and the like, but are difficult to penetrate through a skin barrier due to large molecular weight and strong polarity. According to the invention, hydroxyethyl chitosan, desoxyribonucleic acid and derivatives thereof are combined through electrostatic interaction to form the nano-composite. The compound is small in particle size and can promote transdermal absorption through hair follicle or cuticle gaps. The preparation method is simple, does not need an auxiliary reagent, and comprises the step of mixing a hydroxyethyl chitosan solution and a deoxyribonucleic acid derivative solution. Experiments show that the compound significantly enhances the transdermal efficiency, and has the effects of promoting cell repair and proliferation and resisting inflammation. The composition can be used for skin care products, and is high in safety and wide in application prospect.

The invention discloses a medical pressure-sensitive adhesive patch based on citric acid, a preparation method and application, the medical pressure-sensitive adhesive patch is composed of an adhesion layer and an anti-adhesion layer, and the thickness ratio of the adhesion layer to the anti-adhesion layer is 1: 1-100: 1; the adhesion layer is obtained by polymerizing a citric acid unit and a polyhydroxy compound unit; the hydrophobic high-molecular polymer is selected from at least one of a polylactic acid-glycolic acid copolymer, polylactic acid, polyurethane and polyether urethane. According to the preparation method, three carboxyl groups in the citric acid not only can be used for esterification reaction with polyhydric alcohols to form a network, but also can provide excellent adhesive force for contact between the adhesive patch and the tissue surface through electrostatic interaction or hydrogen-bond interaction. The anti-sticking layer prepared from the hydrophobic high-molecular polymer can effectively resist invasion of external moisture and bacteria, so that the service time of the adhesive patch is prolonged; meanwhile, the anti-sticking layer can also play a supporting role, so that the mechanical strength of the adhesive tape is improved.

The invention provides a water-based composite electrolyte and a preparation method and application thereof. The water-based composite electrolyte comprises soluble zinc salt, amino acid hydrochloride additives and deionized water. The aqueous composite electrolyte can be used for a symmetrical button cell, a half cell or an aqueous zinc ion total cell. By adjusting zinc ion deposition on the surface of the zinc electrode, the growth of zinc dendrites is reduced, and the shuttle effect of the iodine positive electrode is inhibited, so that the coulombic efficiency and the cycle performance of the water-based zinc-iodine battery are improved. The additive disclosed by the invention can be adsorbed on the surface of a zinc negative electrode, delays the nucleation process and inhibits the growth of zinc dendrites; the form of hydrochloride can play a role of a buffer solution, stabilize the pH value of the electrolyte, inhibit the corrosion of the zinc negative electrode and reduce the hydrogen evolution reaction; the hydrochloride form can weaken the protonation effect of amino acid groups and enhance the electrostatic interaction between the amino acid groups and the polyiodide, so that the shuttle effect is inhibited, and the coulombic efficiency and the cycle performance of the aqueous zinc-iodine battery are improved.

The invention belongs to the field of antibiotic analysis and detection, and discloses a quinolone drug SERS (Surface Enhanced Raman Scattering) detection method based on an improved silver nano-substrate and a spectral angle matching model. An improved Lee-Meisel method is adopted to synthesize silver nano sol with precisely controlled particle size, molecular adsorption is realized by utilizing electrostatic interaction of a positively charged quinolone drug and negatively charged silver nano particles, and a high-density Raman enhanced hot spot is formed after an agglomeration agent is added; the SERS spectrum is collected at the excitation wavelength of 785 nm and the integral time of 10 s, qualitative distinguishing of drugs is achieved by combining a spectrum angle matching model, and quantitative detection is achieved by constructing a standard curve through the linear relation between the characteristic peak intensity and the drug concentration logarithm. The detection limit of the four drugs is as low as 1.03-1.16 ppb, the classification accuracy rate reaches 100%, the method is obviously superior to existing similar methods, the detection matrix range is wide, such as animal food and dairy products, and universality and high sensitivity are both considered.

The invention relates to a composite diaphragm, a preparation method thereof and a secondary battery. The composite diaphragm comprises a base membrane and a first coating arranged on one side surface of the base membrane in the thickness direction, the first coating comprises a modified MOF material, the modified MOF material comprises a first MOF material and a coating layer coating the first MOF material, and the coating layer comprises a functional group capable of generating electrostatic interaction and / or coordination interaction with active ions. Therefore, the cycle performance of the battery can be effectively improved.

The invention belongs to the technical field of lithium ion battery materials, and particularly relates to a carbon-coated aluminum foil coating and a preparation method thereof. The invention aims to solve the problem of contradiction between high conductivity and strong adhesive force of the current carbon-coated aluminum foil coating. According to the invention, a multi-stage dimensional composite conductive network is taken as a design core, and the conductive performance of the coating is improved through a ternary composite system formed by conductive carbon black, one-dimensional carboxylated multi-walled carbon nanotubes and two-dimensional sulfonated graphene oxide; the binder adopts a bio-based water-based system and is formed by compounding carboxylated cellulose nanocrystals and quaternized chitosan, and a compact and tough bonding network layer is formed through electrostatic interaction and hydrogen bond combination; the conductive adhesive is excellent in conductivity and strong in adhesive force, the preparation process is environment-friendly and efficient, and the contradictory problem that the conductivity and the adhesive force are difficult to consider at the same time in the prior art is solved.

The invention discloses an electrolyte used in a high cut-off voltage environment and a preparation method thereof, and relates to the technical field of battery electrolyte materials. According to the electrolyte, molecular components with electrochemical activity in anthocyanin can be specifically extracted by utilizing the extraction effect of a reference electrolyte solution, and the molecular components can be preferentially adsorbed on the surface of a high-cut-off-voltage positive electrode with negative electricity through electrostatic interaction, so that a chain decomposition reaction can be cut off, lattice oxygen can be directly anchored, and the electrochemical activity of anthocyanin is improved. Lattice oxygen release is inhibited from the source; the synergistic effect of a dual protection mechanism of'dynamic clearing-static anchoring 'is realized; moreover, the impedance of ion transmission is prevented from being increased by utilizing high-speed centrifugal treatment; the electrolyte can significantly inhibit a chain decomposition reaction in a high cut-off voltage environment, effectively avoids the formation of an over-thick or over-high impedance interface layer, ensures the capacity and cycle capacity retention ratio of the battery in the high cut-off voltage environment, and is suitable for large-scale application in lithium batteries in the high cut-off voltage environment.

The invention discloses a preparation method of an MF (at) NH2 (at) Ag SERS (Surface Enhanced Raman Scattering) sensor for detecting paraquat and diquat, belongs to the field of nano material synthesis and spectral analysis, and solves the problems that a traditional detection method is complicated in process and cannot detect pesticides and free radicals thereof at the same time, and a traditional SERS substrate is poor in enhancement effect and low in stability. The preparation method comprises the following steps: firstly segmenting melamine foam, cleaning and drying, soaking in hydrochloric acid, soaking in a polyethyleneimine aqueous solution to modify amino, drying, soaking in a silver nitrate solution for ultrasonic treatment, adding a sodium borohydride solution under an ice bath, stirring and reducing, and finally cleaning and drying to obtain the sensor. The sensor takes three-dimensional melamine foam as a support, silver nanoparticles are uniformly loaded on the surface of the three-dimensional melamine foam, paraquat, aquacide and free radicals thereof are enriched through electrostatic interaction based on a localized surface plasma resonance principle, and Raman signal enhancement is realized. The detection limit is 10 <-9 > mol / L, the signal stability and repeatability are excellent, the applicability to actual water sample detection is good, the detection of other pesticides can be expanded, and the method is suitable for on-site rapid trace detection.

The invention discloses a method for improving organic load to restore and disintegrate aerobic granular sludge, and belongs to the field of biological sewage treatment. The principle of the invention is as follows: (1) the EPS secretion of microorganisms is stimulated by rapidly increasing the organic load of inlet water, and the aggregation and attachment of the microorganisms are enhanced by the viscous action of EPS; (2) the XDLVO theory shows that the electronegativity between microorganisms is reduced by the change of EPS properties on the surfaces of the microorganisms, so that the electrostatic repulsion is weakened; the reduction of the electrostatic interaction energy among the microorganisms reduces the energy barrier for hindering the aggregation of the microorganisms, so that the microorganisms are more easily aggregated, and the recovery of the compact and stable structure of the decomposed aerobic granular sludge is realized; according to the invention, the compact structure of the decomposed aerobic granular sludge can be recovered within a short time, so that the stable operation of the system and the rapid treatment of wastewater are ensured; the method can be used for decomposing SVI5 from gt of the aerobic granular sludge; 100 mL / g is reduced to 1t; the method recovers the excellent settling performance of the granular sludge, and is simple to operate and remarkable in effect.

The invention discloses an ion locking fixed cyclodextrin cross-linked polymer functionalized cellulose-based textile material and a preparation method thereof, and the method comprises the following steps: cross-linking hydroxypropyl-beta-cyclodextrin (HP-beta-CD) by using 1, 2, 3, 4-butanetetracarboxylic acid (BTCA) to prepare a cross-linked polymer containing carboxyl / carboxylate groups, and carrying out cross-linking on the cross-linked polymer containing carboxyl / carboxylate groups to prepare the ion locking fixed cyclodextrin cross-linked polymer functionalized cellulose-based textile material. Polyphenols active molecules (such as luteolin) are clathrated and / or loaded; depositing the cross-linked polymer loaded with the active molecules on the surface of a cellulose-based textile base material which is subjected to cationization modification and has quaternary ammonium salt cationic groups on the surface through electrostatic interaction; divalent metal ions (preferably Ca < 2 + >) are further introduced to coordinate with carboxyl / carboxylate groups in the cross-linked polymer to form physical cross-linking points, so that locking and fixation of a functional layer are realized, and the release behavior of active molecules is regulated and controlled. The material has the comprehensive performance of stable fixation, washability, durability, breathability, comfort and maintenance and controllable release mode, and can be applied to application scenes such as skin contact textiles and dressing materials.

The present application relates to a kind of nanodroplet system based on interface crosslinking curcumin and its preparation method, by the crosslinking complexation between gallic acid ester, metal ion, curcumin to construct nanodroplet system.Gallic acid ester is polyphenol compound, contains a large number of phenolic hydroxyl in structure, has strong chelating metal ability, can be complexed with most of trivalent metal ions and divalent excessive metal ions, called metal phenolic network;Metal ions such as copper, iron and other metal ions form complex by electrostatic interaction with the beta diketone group in the structure of curcumin.Therefore, the nanodroplet system constructed by the present application can maintain the chemical stability and light stability of curcumin, and has wide prospect for improving the current food field curcumin low solubility, poor stability and other problems.

The utility model discloses an electrostatic induction pendulum for earthquake monitoring and early warning based on electrostatic induction. The device comprises a pendulum and an electrostatic induction sensor, and tiny potential changes can be detected in the swinging process. As a core component, the electrostatic induction sensor consists of the following key parts: a weight module, a connecting layer I, an electrode layer, a connecting layer II and an electrostatic interaction layer. Wherein the weight module provides necessary mass so as to ensure the dynamic characteristics of the pendulum; the first connecting layer is used for fixing the connection between the weight module and the electrode layer; the electrode layer is responsible for detecting electrostatic induction signals generated by pendulum motion and converting the signals into measurable potential change; the second connecting layer is used for fixing the electrode layer and the electrostatic interaction layer; the material of the electrostatic interaction layer carries charges, and the electrostatic induction signal of the electrode layer is enhanced in the earthquake monitoring and early warning process. Through the design, the device can realize high-sensitivity monitoring of earthquake precursor, and can capture fine ground movement caused by earthquake waves. In combination with a data acquisition system and a machine learning algorithm, the device can analyze the signals in real time and automatically send early warning information to related departments and individuals when an abnormal vibration mode is detected, so that precious time is won for taking preventive measures.

The invention provides a CD (at) HZ composite material with electrostatic gating, a preparation method of the CD (at) HZ composite material and application of the CD (at) HZ composite material in carbon capture, and belongs to the technical field of composite material preparation, mixed matrix membrane material preparation and carbon capture. The preparation method comprises the following steps: compounding CD and HZ to obtain a CD-coated HZ composite material with electrostatic gating, and physically blending the CD-coated HZ composite material serving as a filling agent with a Pebax matrix to form a mixed matrix membrane; in the mixed matrix membrane, CD selectively recognizes CO2 and CH4 through electrostatic interaction force, HZ provides a rapid CO2 transfer channel, and the mixed matrix membrane has excellent selectivity on CO2 / CH4, can efficiently separate CO2 / CH4 and has good application in carbon capture.

The application relates to the field of electrochemiluminescence detection, in particular to a preparation method and a detection method of an electrochemiluminescence sensor for detecting di(2-ethylhexyl) phthalate. Technical points are as follows: the electrochemiluminescence aptamer sensor is formed by loading carboxylated ligands on the surface of a Zr-MOF / GDY composite material modified glassy carbon electrode; the Zr-MOF / GDY composite material is formed by electrostatic interaction between Zr-MOF and GDY; and the carboxylated aptamer is an aptamer containing a base sequence of 5'-GGGTAGGGCGGGAAGTTACTGTCTTACTGTC GTA-3'. The recovery effect of DEHP on the ECL signal intensity of the electrochemiluminescence aptamer sensor of the GDY and Zr-MOF composite material is used to realize the detection of DEHP, and the detection method is simple in operation, good in selectivity and high in sensitivity.

The invention relates to the technical field of organic photoelectric materials and photovoltaic devices, in particular to a fluorine-substituted benzimidazolyl aniline compound and a synthesis method and application thereof. The structural general formula of the compounds is as shown in a formula I in the specification. The compound is introduced into a perovskite precursor solution as an additive and is used for preparing a perovskite thin film and a trans-perovskite solar cell. According to the compound provided by the invention, synergistic passivation of multi-site defects such as uncoordinated Pb < 2 + > and iodine vacancies is realized through aniline amino and benzimidazole ring N atoms in molecules, and non-radiative recombination is remarkably reduced; the strong electronegativity of fluorine atoms can enhance the electrostatic interaction between molecules and a perovskite Pb-I skeleton, meanwhile, a large conjugated system promotes pi-pi accumulation, and experimental results show that the photoelectric conversion efficiency of a champion device based on the additive can reach 23.3%; .

The invention discloses antibacterial coating liquid, a preparation method thereof and an implantable medical device. In preparation of the antibacterial coating liquid, firstly, polyvinyl alcohol and phytic acid are mixed and stirred to realize crosslinking, and then the mixture is mixed with tannic acid and an SBMA zwitterionic solution to prepare the coating liquid. The coating liquid can be loaded on the surface of a substrate through a simple method to prepare an antibacterial coating, and the coating has excellent adhesion performance and can be prevented from falling off in the use process. Due to the excellent hydrophilicity, the adhesion of bacteria, platelets and the like can be effectively reduced. Meanwhile, the phytic acid and cationic groups in the SBMA zwitterions are combined with bacterial cell membranes through electrostatic interaction, so that the bacterial structure is destroyed, and the antibacterial performance of the coating is further enhanced. In an in-vivo implantation experiment, the coating shows good biocompatibility.

The application discloses a preparation method of all-weather bimetallic porphyrin CMP material, and specifically comprises the following steps: performing polycondensation reaction on M1-TCPP-COCl and 5,5'-diamino-2,2'-bipyridine in an organic solvent, performing suction filtration, washing and drying on a product to obtain M1Por-CMP; and performing coordination reaction on M1Por-CMP and metal M2 in acetonitrile, and performing suction filtration, washing and drying on a product, and the preparation method is completed. The M1Por-M2Bpy-CMP prepared by the application has rich pore structure and conjugate structure, can realize massive adsorption of pollutants through π-π interaction and physical adsorption. Meanwhile, the coordination bimetal in the CMP material can also increase the adsorption of pollutants through electrostatic interaction. The synergistic effect of the above various adsorptions can realize mass transfer strengthening before degradation.

This invention relates to a reflective film surface coating and an anti-fouling reflective film. The reflective film surface coating comprises carbon nanotubes, silica sol, tetraethyl orthosilicate, fluorosilane, an antistatic agent, isopropanol, ammonia, and water. The reflective film surface coating prepared by this invention has a large contact angle with water droplets, thus exhibiting excellent superhydrophobic properties. Fine water droplets condensed on the reflective film quickly roll off, solving the problem of the influence of fine water droplets on the retroreflective performance of the reflective film. By adding an appropriate amount of antistatic agent to the coating material, combined with the good conductivity of carbon nanotubes, charged particles attached to the reflective film surface can be rapidly discharged, eliminating the electrostatic interaction between charged particles and the reflective film, thereby preventing particulate pollutants such as dust in the air from depositing on its smooth surface.