422results about How to "Avoid reunion" patented technology

The invention discloses a composite catalyst for a peracetic acid activation system and a preparation method and application thereof, and relates to the technical field of advanced oxidation water treatment. The preparation method of the catalyst comprises the following steps: preparing an aqueous solution of a cobalt source as a precursor solution; adding a manganese source into the precursor solution to obtain a Co-Mn mixed salt solution; adding a complexing agent into the Co-Mn mixed salt solution to form a stable sol system; heating the sol system at constant temperature to obtain wet gel; drying the wet gel to obtain a porous dry gel precursor; calcining the porous xerogel precursor, and then cooling and grinding to obtain the composite catalyst for the peracetic acid activation system. The composite structure in the catalyst greatly improves the rate of generating hydroxyl radicals and organic oxygen radicals by decomposing peracetic acid by promoting electron transfer circulation of a metal active center, shows good structural stability and recyclability, and is especially suitable for degradation of an organic pollutant sulfamethoxazole in a water body.

The invention discloses a polypropylene composite material with high dielectric constant, high strength and high modulus as well as a preparation method and application thereof, and belongs to the technical field of polymer composite materials. According to the composite material, homo-polypropylene is used as a matrix and matched with a high-dielectric-constant composite filler, a modified reinforcing filler and a functional additive, and through reasonable component design and process optimization, the dielectric property and the mechanical property are synergistically improved. Wherein the barium titanate-graphene with the core-shell structure is used as a high-dielectric-constant composite filler, and an efficient dielectric path can be constructed in a polypropylene matrix; the epoxy resin modified chopped glass fiber can significantly enhance the mechanical strength and modulus of the material; the maleic anhydride grafted polypropylene effectively improves the interfacial compatibility of the filler and the matrix. The dielectric constant (10GHz) of the prepared composite material is greater than or equal to 8, the tensile strength is greater than or equal to 60 MPa, and the bending modulus is greater than or equal to 4000 MPa. The composite material has excellent dielectric properties and mechanical properties, and can be widely applied to the fields of electronic appliances, high-frequency communication, new energy automobiles and the like.

The application belongs to the technical field of polymer materials, and particularly relates to a high-performance fiber composite material and a preparation method thereof. The preparation method of the high-performance fiber composite material comprises the following steps: adding pretreated aluminum oxide whiskers into a solvent, then adding pretreated carboxymethyl cellulose and gallic acid, and heating to reflux to obtain modified aluminum oxide whiskers; then mixing epoxy resin, the modified aluminum oxide whiskers, a curing agent and an accelerator uniformly to coat a film to obtain a resin adhesive film; and compounding the resin adhesive film and carbon fibers through hot pressing to obtain carbon fiber prepreg, and heating and curing the obtained prepreg to obtain the high-performance fiber composite material. The fiber composite material obtained by the application not only has high strength and rigidity, but also has excellent toughness, can effectively resist the impact of the external environment, has oxidation resistance and long-term stability, and has a wide application prospect in the fields of aerospace and new energy equipment.

The utility model provides power battery subassembly intelligence fine separation equipment, including main part assembly, the main part assembly includes support, first motor, chain transmission mechanism, guide wheel, conveying chain, liquid storage tank, bearing seat, separation drum and guide plate, the inner side wall of support is installed with first motor, the output shaft of first motor is connected with chain transmission mechanism transmission, the outside of chain transmission mechanism is equipped with conveying chain, the inner side wall of support is rotatably connected with guide wheel. The utility model discloses through chain conveying mechanism and convey material into liquid storage tank, through cleaning agent and wash recycling material, and through the material of different size particle of separation drum separation, prevent material agglomeration, realize the fine separation of material. Through conveying chain and convey large size material to guide plate, through spiral feeder and convey small size material, and the convenient staff unified processing size different material.

The invention discloses an optical film, a preparation method thereof and a display device, and relates to the technical field of optical functional films. The optical film comprises a base film layer and an antistatic coating arranged on the surface of at least one side of the base film layer. The antistatic coating comprises the following raw material components: water-dispersible polyester resin, water-soluble resin, a cross-linking agent and an antistatic agent; the antistatic agent is obtained by compounding a single-walled carbon nanotube modified with a hydrophilic group and polyaniline acid, the antistatic agent comprises an inner core and a coating layer at least partially coating the inner core, the inner core comprises the single-walled carbon nanotube modified with the hydrophilic group, and the coating layer comprises the polyaniline acid. According to the optical film, the single-walled carbon nanotubes and the polyaniline acid form a composite conductive structure, and then the composite conductive structure is crosslinked with the water-soluble resin and the crosslinking agent to form a three-dimensional conductive network structure, so that the optical film obtains lasting and efficient antistatic performance with extremely low environmental humidity dependence on the premise of keeping high light transmittance, low haze and good coating adhesiveness.

This invention discloses a high salt spray resistant stainless steel material and its preparation method, relating to the field of metal materials technology. In preparing the high salt spray resistant stainless steel material, the present invention involves weighing raw materials including Cr, Ni, Al, Si, Mn, Mo, Nb, C, Zr, Ti, and Fe according to specific mass percentages, and obtaining an alloy ingot through melting and casting; subjecting the alloy ingot to homogenization heat treatment and forging to obtain a stainless steel matrix; using the stainless steel matrix as the working electrode, surface modification is performed through cathodic polarization treatment in an electrolyte containing amidated carbon nanotube-boron nitride composite filler, thereby obtaining the high salt spray resistant stainless steel material. The high salt spray resistant stainless steel material prepared by this invention exhibits excellent salt spray corrosion resistance.

The invention belongs to the technical field of anhydrous magnesium chloride production, and particularly relates to a preparation process of anhydrous magnesium chloride, which comprises the following steps: firstly, dissolving magnesium chloride hexahydrate in absolute ethyl alcohol to form a magnesium chloride ethanol aqueous solution, and then dehydrating the magnesium chloride ethanol aqueous solution by using a molecular sieve to obtain the magnesium chloride ethanol solution; carrying out secondary cooling, stirring crystallization, secondary solid-liquid separation and vacuum drying on the magnesium chloride ethanol solution to obtain high-purity anhydrous magnesium chloride; and recycling ethanol liquid obtained by solid-liquid separation and ethanol gas obtained by vacuum drying. The technical scheme provided by the invention is simple in process flow, low in energy consumption, low in equipment requirement, high in product yield and high in purity, and can be directly applied to the fields of electrolytic preparation of magnesium, catalyst carriers and the like.

This invention discloses a magnetic solid-phase extraction method for detecting trace amounts of glucocorticoids in hydrophilic media, belonging to the field of sample pretreatment and chromatographic analysis technology. The method includes: adjusting the pH of a hydrophilic medium sample containing glucocorticoids and adding an ionic strength modifier to obtain a pretreated sample; mixing a magnetic covalent organic framework-based composite nanomaterial with the pretreated sample and performing oscillatory extraction under a dynamic gradient magnetic field to adsorb the glucocorticoids onto the material surface; separating the material adsorbed with glucocorticoids using an external magnetic field and discarding the supernatant; performing ultrasonic-assisted elution of the material using an elution solvent and collecting the eluent; and detecting the eluent using high-performance liquid chromatography-diode array detector (HPLC-DID) and calculating the glucocorticoid concentration based on a standard curve.

The application provides a porous carbon nanofiber electrocatalyst loaded with cobalt / lanthanum hydroxide heterojunction and a preparation method. The preparation method comprises the following steps: adding 4,4-diamino diphenyl ether and pyromellitic dianhydride into a solvent, uniformly mixing, and preparing a polyamide acid precursor spinning solution; electrospinning the prepared polyamide acid precursor spinning solution to prepare polyamide acid nanofibers; immersing the prepared polyamide acid nanofibers in a mixed metal salt solution containing cobalt salt, lanthanum salt and zinc salt to prepare polyamide acid nanofiber precursors loaded with metal ions; and performing programmed temperature heat treatment on the prepared polyamide acid nanofiber precursors loaded with metal ions in a protective atmosphere to prepare the porous carbon nanofiber electrocatalyst loaded with cobalt / lanthanum hydroxide heterojunction. The prepared porous carbon nanofiber electrocatalyst loaded with cobalt / lanthanum hydroxide heterojunction has excellent electrochemical oxygen reduction reaction and oxygen evolution reaction bifunctional catalytic activity.

This invention belongs to the technical field of lithium battery anode materials, specifically relating to a highly conductive graphite electrode material and its preparation method. The preparation method includes: pre-dissolving sodium carboxymethyl cellulose into a gel solution, then ball-milling and mixing graphite and conductive carbon black, dispersing them together with a cobalt hexacyanorubium(II)-dodecyltungstencobalt(III) salt hybrid material and hafnium diboride nanomaterials in the gel solution, adjusting the acidity, adding styrene-butadiene rubber emulsion to obtain a uniform slurry, and then coating, drying, and compacting to obtain the anode sheet. This invention significantly improves the conductivity and structural stability of the graphite anode through the synergistic effect of the interface modification of the cobalt hexacyanorubium(II)-dodecyltungstencobalt(III) salt hybrid material and the conductive framework of the hafnium diboride nanomaterials. The process is safe and controllable, and suitable for industrial production of lithium-ion batteries.

The utility model belongs to the technical field of material mixing, and particularly relates to a superfine talcum powder and polypropylene material mixing device. The device comprises a device body, the device body comprises a machine body support, a material mixing box, a feeding mechanism and a discharging mechanism, the material mixing box is installed above the machine body support, the feeding mechanism is located at the top of the material mixing box, and the discharging mechanism is located on one side of the material mixing box. The material mixing box comprises an outer static box body and an inner movable box body, the inner movable box body is located in the outer static box body, the outer static box body and the inner movable box body are of a cylindrical structure, a stirring motor is installed on one side of the inner movable box body, the output end of the stirring motor is connected with a stirring assembly, and the stirring assembly is connected with a motor. The stirring assembly is movably mounted in the inner movable box body, and a swinging mechanism is mounted at the bottom of the inner movable box body.

The application belongs to the field of new materials, and discloses a lead-free perovskite X-ray shielding composite material and a preparation method and application thereof, and comprises the following steps: mixing ANF / DMSO dispersion liquid with ethanol to obtain re-protonated ANF dispersion liquid; mixing the re-protonated ANF dispersion liquid, CsI powder and ethanol, and stirring to obtain two portions of the same CsI / ANF dispersion liquid; mixing re-protonated ANF, Cs3Bi2I9 powder and ethanol, and stirring to obtain Cs3Bi2I9 / ANF dispersion liquid; sequentially filtering the first portion of CsI / ANF dispersion liquid, the Cs3Bi2I9 / ANF dispersion liquid and the second portion of CsI / ANF dispersion liquid by using a gel-gel method, and vacuum hot-pressing to obtain a composite gradient film with a biomimetic symmetrical structure, which is used as a lead-free perovskite X-ray shielding composite material; and the application realizes continuous and efficient X-ray shielding effect, and can improve the mechanical flexibility and thermal stability of the material.

The application discloses a wet oxidation catalyst, which comprises the following raw materials in percentage by weight: 0.1-2% noble metal, 1-10% graphene-based material, and the rest is a carrier, wherein the carrier is modified titanium dioxide, specifically, a rare earth-transition metal-oxygen vacancy-mesoporous three-dimensional gradient titanium dioxide carrier. The application aims at solving the technical problem of poor stability of the catalyst.

The invention provides a wear-resistant anti-aging waterproof tarpaulin and a preparation method thereof, and belongs to the technical field of tarpaulin. The wear-resistant anti-aging waterproof tarpaulin comprises a base cloth layer and a PVC (polyvinyl chloride) coating coated on the base cloth layer, wherein the PVC coating is prepared from the following raw materials: 70 to 90 parts of PVC paste resin, 5 to 15 parts of a composite plasticizer, 10 to 30 parts of TiO2-HNTs powder, 3 to 5 parts of chlorinated paraffin, 8 to 12 parts of an additive and 80 to 100 parts of a solvent. The titanium dioxide and the halloysite nanotubes are compounded, the titanium dioxide is loaded on the halloysite nanotubes, agglomeration of the titanium dioxide is prevented, and the mechanical property and wear resistance of the tarpaulin can be effectively enhanced by adding the halloysite nanotubes.

The application discloses a mural reinforcing protective agent and a preparation method and application thereof, belongs to the technical field of cultural relic restoration, and can solve the technical problems that existing mural reinforcing materials cannot reinforce the lower layer structure of ancient murals and are prone to being attached to the surface of murals to cause the whitening of the surface pigments. The mural reinforcing protective agent comprises a bacterial cellulose carrier and Ba(OH)2 nanoparticles loaded on the bacterial cellulose carrier in situ. The application plays a reinforcing role on the lower layer structure of murals, realizes deep reinforcement of ancient murals, improves the protection effect, stability and durability, and the surface of the mural will not be whitened.

The application provides a mechanical seal for a latex pump, which comprises a shaft sleeve, an outer part of the shaft sleeve is sleeved with a static ring seat, one end of the shaft sleeve is formed with a mounting step, a main seal is arranged between the mounting step and one end of an inner cavity of the static ring seat, an outer part of the other end of the shaft sleeve is sleeved with a driving ring, a secondary seal is arranged between the driving ring and the other end of the inner cavity of the static ring seat; an annular mounting seat is detachably connected to one end of the static ring seat close to a driving ring, the mounting seat is located at a radial outer part of the mounting step, a plurality of first convex teeth which are distributed in a circumferential direction and extend in a radial direction of the mounting seat are arranged on a radial inner end surface of the mounting seat, inner ends of the first convex teeth are in sliding fit with a radial outer wall of the mounting step, and medium can be cut and dispersed by the first convex teeth when the shaft sleeve rotates, the application provides a mechanical seal for a latex pump, which can cut and disperse medium before the medium contacts a sealing surface, avoids that particulate matter or viscous matter directly contacts the sealing surface, and improves sealing performance and a service life of the sealing.

The present application relates to the technical field of sodium battery materials, in particular to a sodium supplement coating based on a spiral iron-carbon composite material and a preparation method thereof, a spiral polypyrrole template is synthesized by a chiral template method, Fe3C@CNS spiral carbon composite material rich in Fe3C nanocrystals and iron single-atom sites is prepared through iron loading, sulfidation and high-temperature pyrolysis, Na2C2O4@Fe3C@CNS composite material is prepared by highly dispersing sodium oxalate on the surface and in the pores of the spiral carbon composite material through a recrystallization method, finally, a slurry is prepared by mixing the Na2C2O4@Fe3C@CNS composite material with a conductive agent and a binder, and the slurry is coated on the surface of an electrode to form a functional sodium supplement coating. The sodium supplement coating based on the spiral iron-carbon composite material and the preparation method thereof solve the problems of poor interface stability and first-cycle irreversible sodium loss of existing sodium ion batteries, realize efficient sodium pre-activation and interface synergistic regulation, and improve the comprehensive performance of the battery.

The invention relates to the technical field of composite materials, in particular to a synergistic flame-retardant epoxy resin-based porous sound insulation composite material and application thereof. The raw materials comprise 100 parts of bisphenol A epoxy resin, 15 parts of an aliphatic amine curing agent, 12 parts of ammonium dihydrogen phosphate, 6 parts of melamine, 4 parts of nano silicon dioxide, 5 parts of sodium chloride, 2 parts of ammonium bicarbonate, 0.8 part of carbon nanotubes and 0.5 part of a silane coupling agent. The synergistic flame-retardant epoxy resin-based porous sound-insulation composite material provided by the invention effectively solves the technical bottleneck that the flame-retardant, sound-insulation and mechanical properties of an epoxy resin-based material in the prior art are difficult to synergistically improve, and has remarkable beneficial effects in multiple aspects.

The application relates to a method for removing iron from aluminum electrolysis high-iron waste residue, and belongs to the technical field of solid waste resource recovery. The method comprises the following steps: finely grinding aluminum electrolysis high-iron waste residue to obtain aluminum electrolysis high-iron waste residue powder; mixing the aluminum electrolysis high-iron waste residue powder with water to obtain slurry; mixing and stirring the slurry with polyethylene glycol to obtain mixed slurry; and performing multi-stage centrifugal separation on the mixed slurry to obtain high-iron residue and high-carbon residue. The separated high-carbon residue meets the quality requirements for returning to an electrolysis process, the obtained high-iron residue is recovered as a byproduct, and finally the iron and carbon in the aluminum electrolysis high-iron waste residue are recycled and utilized as resources.

This invention relates to the field of flue gas treatment technology, specifically to a sulfur dioxide gas absorbent, comprising the following raw materials by weight: 90-100 parts of an aqueous amine solution and 2-6 parts of additives. In this invention, the nitrogen-zinc ion-sulfur active center of the catalyst acts as a molecular key, efficiently and reversibly coordinating and activating sulfur dioxide molecules, significantly reducing the reaction energy barrier and fundamentally improving the intrinsic absorption rate. The enhancer, with its high specific surface area, provides a large interface for the reaction. Its surface sulfonic acid groups not only buffer the decrease in system pH, maintaining the optimal acid-base environment for the reaction, but also catalyze the conversion of absorption intermediates into more stable products, thereby shifting the reaction equilibrium to the right. Under the combined effect of these two factors, the catalyst accelerates the reaction towards equilibrium, while the enhancer continuously shifts the equilibrium point, resulting in a higher absorption capacity for the absorbent.

The invention provides a coating with optical permeability and a preparation method thereof. The coating with optical permeability is prepared from the following raw materials in parts by mass: 25 parts of water-based acrylate copolymer emulsion, 25 to 35 parts of water, 0.8 to 1.5 parts of transparent functional particles, 16 to 20 parts of functional modified inorganic filler, 5.5 to 7.5 parts of boric acid ester-silanol-hydroxyl three-function cross-linked gel precursor solution, 0.2 to 0.5 part of thickening agent, 0.2 to 0.4 part of defoaming agent, 0.5 to 1 part of dispersing agent and 0.1 to 0.3 part of preservative. 0.2 to 0.5 part of an organic amine alcohol compound; the transparent functional particles comprise at least one of glass sand and cross-linked polymethyl methacrylate microspheres; the functional modified inorganic filler comprises at least one of amino silane modified snowflake white quartz sand and amino silane modified calcined sand white marble. The coating with optical permeability is suitable for the field of indoor and outdoor decoration.

The application discloses a wear-resistant EVA material and a preparation method thereof, and relates to the technical field of polymer materials. In the preparation of the wear-resistant EVA material, modified nano cellulose is prepared by reacting nano cellulose and a triazole type ultraviolet absorber; modified silicon dioxide is prepared by sequentially reacting silicon dioxide with 4-anilinoethyl triethoxysilane and 4-vinyl aniline; modified ethylene-vinyl acetate copolymer is prepared by sequentially reacting ethylene-vinyl acetate copolymer with allyl phosphine dichloride and eugenol; the modified ethylene-vinyl acetate copolymer, the modified nano cellulose, the modified silicon dioxide, hydrogen-containing silicone oil and chloroplatinic acid are melt-mixed to prepare the wear-resistant EVA material by compression molding. The wear-resistant EVA material prepared by the application has excellent wear resistance, flame retardation and anti-aging performance.

The invention relates to high-solid-content AlN ceramic slurry for tape casting, a substrate and a preparation method of the substrate, and belongs to the field of ceramic substrates. The ceramic slurry is prepared from the following components in percentage by mass: 60 to 68 weight percent of high-purity AlN powder, 3 to 6 weight percent of dispersing agent, 3 to 5 weight percent of binding agent, 4 to 6 weight percent of plasticizer, 3 to 6 weight percent of sintering aid and 32 to 45 weight percent of solvent, the mass ratio of the plasticizer to the binder ranges from 3: 5 to 4: 5. By regulating and controlling the proportion of the dispersing agent in the AlN ceramic slurry and the solid content of the high-purity AlN powder, the slurry has excellent flowability, dispersity and stability while maintaining high solid content, and is suitable for a tape casting process. The AlN ceramic substrate prepared through sintering is high in density and excellent in heat conductivity, and engineering application can be achieved.

The application relates to the technical field of modified asphalt preparation, in particular to a device for preparing emulsified rubber modified asphalt through plastic waste at low temperature and a preparation method thereof. The device for preparing emulsified rubber modified asphalt through plastic waste at low temperature comprises a lifting plate and a feeding port arranged on a stirring cylinder, the lifting plate is provided with a rotating disc, the rotating disc is provided with a storage cylinder, and the storage cylinder is arranged in three groups along the circumferential direction of the rotating disc; the rotating disc is connected with a stirring rod rotatingly arranged in the stirring cylinder through an intermittent rotating assembly; when the stirring rod rotates, the intermittent rotating assembly can drive the rotating disc to intermittently rotate, so that the storage cylinder is intermittently arranged above the feeding port; the storage cylinder is provided with a discharging mechanism, the discharging mechanism comprises a plugging assembly and a driving assembly; when the storage cylinder rotates to above the feeding port, a trigger member cooperates with the driving assembly, the plugging assembly can be driven to open the storage cylinder, and when the storage cylinder is separated from the feeding port, the driving assembly is reset, so that the storage cylinder can be quickly closed.

The application discloses an organic amine modified HMS molecular sieve and application thereof in carbon dioxide capture, and specifically relates to the following steps: first, preparing mesoporous molecular sieve HMS, which contains two kinds of pore structures, 4.5-8.0 nm and 11.5-17.5 nm respectively, and a single wide diffraction peak is presented at 2theta=2.6 degrees in X-ray powder diffraction; then, grafting amino silane on the surface of the mesoporous molecular sieve HMS; and finally, immersing the mesoporous molecular sieve HMS in an organic amine solution to obtain a multilevel organic amine modified HMS molecular sieve. The synthesis method is simple, the carbon dioxide adsorption efficiency is high, and the thermal stability is good.

The application provides a kind of polyhedral oligomeric silsesquioxane and its preparation method and application, belong to polyhedral oligomeric silsesquioxane technical field, the structural formula of polyhedral oligomeric silsesquioxane of the application is as shown in formula (1): formula (1) in, R a , R b , R c , R d , R e , R f , R g , R h At least one of them is different, and each is independently-SCH2COOCH2CH (OH) CH2OOC (CH3) =CH2, -SCH2COOCH2CH (OH) CH2O (CH2) 4Si (OCH3) 3.The polyhedral oligomeric silsesquioxane of the application is applied to adhesive or coating material, which can improve the hardness, wear resistance of adhesive or coating material, and reduce the shrinkage rate when resin curing.

The invention provides a preparation method of isostatic pressing graphite with a superfine structure, belongs to the technical field of preparation of isostatic pressing graphite, and aims to solve the technical problem that the product reliability is influenced due to low dispersion efficiency and easy agglomeration of graphene in the existing one-step mixing. The method comprises the following steps: step S1, aggregate preparation; s2, gradient mixing: adding graphene accounting for 1-3% of the total weight of the basic aggregate into the basic aggregate, mixing by adopting a gradient mixing method, premixing the basic aggregate accounting for 40-60% of the total weight with all graphene to prepare a master batch, and finally mixing the master batch with the residual basic aggregate to obtain a composite reinforced aggregate; step S3, mixing and kneading; step S4, powder pressing; step S5, isostatic pressing molding; step S6, roasting; and step S7, graphitizing. According to the preparation method, a gradient mixing method is adopted, so that the enhancement effect of the graphene can be fully exerted, and the problems that the graphene is easy to agglomerate and is difficult to uniformly disperse in the micron powder are effectively solved through a step-by-step dilution mechanism.

The application discloses a method for treating antibiotic wastewater by using a graphdiyne / ferrous indium sulfide nanocomposite to activate persulfate, and the method is characterized by using the graphdiyne / ferrous indium sulfide nanocomposite as a catalyst to activate persulfate for degrading and treating antibiotic wastewater, wherein the graphdiyne / ferrous indium sulfide nanocomposite comprises ferrous indium sulfide nanoparticles, and the nanoparticles are loaded with graphdiyne nanosheets. The method for treating antibiotic wastewater by using the graphdiyne / ferrous indium sulfide nanocomposite to activate persulfate uses the graphdiyne / ferrous indium sulfide nanocomposite as a catalyst, wherein the nanocomposite has many reactive sites, high catalytic activity and good stability, can efficiently activate persulfate with a smaller amount of catalyst, can efficiently remove antibiotics in wastewater, and has the advantages of low cost, high treatment efficiency, good removal effect, green environmental protection and the like, and therefore, the method has important significance for effectively purifying antibiotic wastewater, has high use value and good application prospect.

This invention relates to the field of cable technology, specifically to a high-performance polyvinyl chloride (PVC) cable material and its preparation method. The cable material is based on PVC resin, combined with plasticizers and multifunctional flame-retardant composite fillers, with the filler content being 85-95 parts by weight per 100 parts by weight of resin. The multifunctional flame-retardant composite filler employs a multi-layered interface design: using magnesium hydroxide / calcium carbonate as the core, it first undergoes silane treatment to introduce epoxy sites, then constructs a phytic acid-tin-calcium-zinc chelate layer, and immobilizes double-grafted modified carboxymethyl-β-cyclodextrin, ultimately forming a tannic acid-metal ion polyphenol network layer. The preparation method includes pre-plasticization, segmented mixing with filler addition, and extrusion granulation. This invention effectively improves the filler-matrix interface compatibility, enhances flame retardancy, mechanical properties, and thermal stability, and solves the problem of insufficient durability in high-filler systems.

This invention relates to the field of polymer foaming materials technology, and discloses a plant fiber composite nucleating agent for microfoaming of biodegradable materials and its application. The plant fiber composite nucleating agent is made from raw materials comprising the following parts by weight: 80-95 parts of primary ultrafine plant fiber powder, 5-20 parts of surface modifier, and 0.1-5 parts of dispersing lubricating wax; the surface modifier and dispersing lubricating wax are coated on the surface of the primary ultrafine plant fiber powder. The application steps are as follows: adding the plant fiber composite nucleating agent to a biodegradable material matrix to obtain a pre-foaming blend, introducing foaming gas or adding a chemical foaming agent for foaming treatment. The nucleating agent of this invention improves the compatibility between plant fibers and hydrophobic biodegradable matrices, provides heterogeneous nucleation sites in the matrix while increasing the polymer melt strength, inhibits cell coalescence and rupture, and obtains microfoamed materials with uniform pore size. Furthermore, the nucleating agent itself is completely biodegradable.