The invention relates to the technical field of
lithium ion batteries, in particular to a doped
lithium-rich
manganese-based positive
electrode material and a preparation method thereof, the molecular formula of the doped
lithium-rich
manganese-based positive
electrode material is LiaNibCocMndAWBxCyDzO2, 1.13 < = a < = 1.20, 0.10 < = b, c and d < = 0.80, 0.001 < = w, and x, y and z < = 0.03; wherein A is one or more of high-valence
transition metal elements such as W < 6 + >, Mo < 6 + >, Ta < 5 + >, Nb < 5 + > and Ti < 4 + >, B is one or more of
rare earth elements such as La < 3 + >, Y < 3 + > and Ce < 4 + >, C is one or more of alkaline earth elements such as Sr < 2 + >, Mg < 2 + > and Ba < 2 + >, and D is one or more of alkaline
metal elements such as Li < + >, Na < + > and K < + >. According to the technical scheme, the synergistic effect of multiple elements is achieved, the comprehensive performance such as the first coulombic efficiency and the
cycling stability of the lithium-rich
manganese-based positive
electrode material can be remarkably improved, the preparation method is simple, the lithium-rich manganese-based positive
electrode material can be prepared through simple mixing and multi-element synergistic
doping solid-phase
sintering, the requirement for equipment is low, and the application range is wide. And large-scale popularization of the process is facilitated, and the market competitiveness of the product is improved.