3444 results about "Chemical formula" patented technology

The invention relates to the technical field of fluorescence sensing development, in particular to a Cd (II)-based metal organic framework crystalline material as well as a preparation method and application thereof. The chemical formula of the Cd (II)-based metal organic framework crystalline material is {[Cd3 (H2O) 2 (DMA) 2 (5-CMOIA) 2]. 6 / 5H2O} n, the organic framework material is characterized by an X-ray single crystal diffractometer, and the result shows that the organic framework material is crystallized in a triclinic system P-1 space group, the asymmetric unit of the organic framework material is composed of three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions, three Cd (II) ions and three The complex is composed of two deprotonated (5-CMOIA) 3-ligands, two coordinated DMA solvent molecules, two coordinated water molecules and six fifths of crystal water molecules. The solid fluorescence spectrum of the Cd (II)-based metal organic framework crystalline material is measured, the fluorescence response of the Cd (II)-based metal organic framework crystalline material to metal ions in a solution is explored, and the result shows that the Cd (II)-based metal organic framework crystalline material can effectively recognize Hg < 2 + > from different ions and can be applied to the field of fluorescence sensing.

A positive electrode plate includes a positive electrode current collector and a positive electrode active material layer disposed on at least one surface of the positive electrode current collector, where the positive electrode active material layer includes two respective positive electrode active materials represented by chemical formula (1) and chemical formula (2): Li1+xNaaCo1+yAlzMgpTiuMvO2+w (1), where in chemical formula (1), M includes at least one of Zr, La, or Y, −0.1<x<0.1, 0<a<0.005, −0.05<y<0.05, 0.01<z<0.05, 0.001<p<0.01, 0<u<0.005, 0<v<0.005, and −0.05<w<0.05; and Li2+rNasN1+qO2+t (2), where in chemical formula (2), −0.2<r<0.2, 0≤s≤0.05, −0.1<q<0.1, −0.05<t<0.05, and N includes at least one of Ni, Cu, Mn, Fe, or Co. Such a positive electrode plate can achieve a high specific discharge capacity of the electrochemical apparatus, thereby increasing high-temperature cycling performance and energy density of the electrochemical apparatus.

Monoorgano tin trialkoxide compounds having chemical formula R'SnX3 and containing less than about 5 mol% R'2SnX2are described. R' is an optionally substituted organic substituent having about 1 to about 20 carbon atoms and each X is independently ORf, wherein Rf is a fluorinated organic substituent having about 1 to about 20 carbon atoms. Methods for synthesizing and purifying these compounds are also provided. The monoorgano tin compounds may be used for the formation of high-resolution EUV lithography patterning precursors and are attractive due to their high purity and minimal concentration of diorgano tin impurities.

The invention discloses a negative temperature coefficient medium-entropy thermistor material as well as a preparation method and application thereof. According to the invention, manganese dioxide, nickel oxide, cobalt sesquioxide, zinc oxide and copper oxide are used as raw materials, and a solid-phase reaction method is adopted to prepare the negative temperature coefficient medium-entropy thermistor material with a chemical formula of (NiX1CoX2ZnX3CuX4) Mn2O4. Wherein the values of X1, X2, X3 and X4 are 0.075-0.425, and X1 + X2 + X3 + X4 = 1. The negative temperature coefficient medium-entropy thermistor material is of a single spinel structure. The material has the hysteresis diffusion effect of medium-entropy ceramic, and by combining the coordinated optimization effect of multiple components, the material constant and the resistivity of the thermal sensitive ceramic can be remarkably reduced, and the anti-aging performance can be improved.

Monoorgano tin compounds having chemical formula R′SnX3 and high purity are described. R′ is an optionally substituted hydrocarbyl group, X is selected from NR2 and OR, and each R is independently a linear or branched alkyl group having about 1 to about 10 carbon atoms. Methods for synthesizing and purifying these compounds are also provided. The monoorgano tin compounds may be used for the formation of high-resolution EUV lithography patterning precursors and are attractive due to their high purity and minimal concentration of diorgano tin impurities.

The invention discloses a gas sensing material based on Ag / Pd-LaFeO3 and application of the gas sensing material in detection of hydrogen sulfide gas in municipal sewage, and relates to the technical field of gas sensing materials. The chemical formula of the gas sensing material based on Ag / Pd-LaFeO3 is X wt% of Ag-Y wt% of Pd-LaFeO3, wherein 0 lt; x < = 5, 0lt; y < = 5. According to the invention, on the basis of LaFeO3, the humidity interference resistance of the gas sensing material based on Ag / Pd-LaFeO3 can be improved through double noble metal surface modification of Ag and Pd. In addition, through double noble metal doping of Ag and Pd, the response sensitivity and selectivity of the prepared gas-sensitive material to H2S gas can be improved, and the working temperature of the gas-sensitive material is reduced. Specifically, at the working temperature of 110 DEG C, the response value of the prepared double noble metal modified LaFeO3 to 1ppm H2S gas is 46.16.

The invention discloses a series of alkali metal borate compounds and alkali metal borate crystals as well as a preparation method and application thereof, and belongs to the technical field of photoelectric functional crystal materials. The chemical general formula of the series of compounds and crystals thereof is A3RE (B3O6) 2, wherein A is K, Rb, Cs or NH4; rE = Sc and Y, the molecular weight is 355.93-744.48, the series of crystals belong to a trigonal system, the space group is P321, the cell parameters a = b = 10.5237 (13)-135237 (13), and # imgabs0 # Z = 3. The series of alkali metal borate compounds are synthesized by adopting a solid-phase reaction method or a hydrothermal method, and the series of crystals grow by adopting a high-temperature melt method or a hydrothermal method or a solution method. The series of materials can be used for manufacturing second harmonic generators, upper and lower frequency converters, optical parametric oscillators, polarizing prisms and the like.

The invention discloses a multiphase ferric sodium pyrophosphate positive electrode material as well as a preparation method and application thereof, and belongs to the technical field of positive electrode materials. The complex-phase phosphoric acid and sodium ferric pyrophosphate positive electrode material has the following chemical formula: xNa4Fe3 (PO4) 2 (P2O7). (1-x) Na3. 12Fe2. 44 (P2O7) 2 / C, C is a carbon coating layer, and the content of the C is 8-10 wt% of the total mass of the composite-phase phosphoric acid and sodium ferric pyrophosphate positive electrode material; xNa4Fe3 (PO4) 2 (P2O7). (1-x) Na3.12Fe2.44 (P2O7) 2 is a core layer, and x is greater than or equal to 0.76 and less than or equal to 0.88. Under the condition that transition metal elements are not added for doping, the electrochemical performance of the complex-phase ferric sodium phosphate pyrophosphate positive electrode material can be obviously improved by regulating and controlling the ratio of positive ions to negative ions of original components of ferric sodium phosphate pyrophosphate, and the complex-phase ferric sodium phosphate pyrophosphate positive electrode material is low in cost, simple to prepare and suitable for large-scale production and application.

A compound of Chemical Formula 1 and an organic light emitting device including the same are provided. The compound is used as a material of an organic material layer of the organic light emitting device, and provides high color purity, high efficiency and enhanced lifetime properties.

The invention relates to the technical field of electrocatalysis development, in particular to a Co-based two-dimensional coordination polymer electrocatalyst and a preparation method and application thereof. The chemical formula of the Co-based two-dimensional coordination polymer electrocatalyst is {[Co3 (H2O) 4 (5-CMOIA) 2]. 10H2O} n, an X-ray single crystal diffraction test shows that the coordination polymer belongs to a triclinic system and a P-1 space group, and the minimum asymmetric unit of the coordination polymer contains three Co (II) ions, two deprotonated (5-CMOIA) 3-ligands, four coordination water molecules and ten crystal water molecules. The Co-based two-dimensional coordination polymer has relatively high specific surface area and rich active sites, is good in dispersity in a solution, and can be applied to the field of electrocatalysis.

A composition for an organic optoelectronic device, an organic optoelectronic device, and a display device, the composition including a first compound represented by Chemical Formula I, a second compound represented by Chemical Formula II, and a third compound represented by a combination of Chemical Formula III and Chemical Formula IV,

The invention relates to the technical field of luminescent materials, and discloses a preparation method and application of a transition metal and chalcogen ion doped metal halide high-efficiency wide-spectrum luminescent material, the chemical formula of the transition metal and chalcogen ion doped metal halide is Cs2Sn1-x-yCl6: x% Te < 4 + >, yMo < 4 + >, the ultra-wideband fluorescent powder converted light emitting diode (LED) covers the range from visible light (VIS) to near infrared light (NIR), and shows remarkable potential in practical application. According to the invention, ultra-wide spectrum emission from 400 nm to 1400 nm is realized in Mo < 4 + >-Te < 4 + > co-doped Cs2SnCl6, and the photoluminescence quantum yield of 95.3% is achieved, the excellent performance is realized through efficient energy transfer from Te < 4 + > to Mo < 4 + > and passivation synergistic effect of vacancy defects, and the performance can be verified through theoretical calculation and spectral research; finally, the ultra-wideband fluorescent powder conversion LED based on the Mo < 4 + > and Te < 4 + > co-doped Cs2SnCl6 is successfully prepared and is applied to the fields of blood gas analysis and night vision imaging.

This application relates to the field of biosynthesis technology, and specifically discloses a pyridone compound, its biosynthesis method and application. Based on synthetic biology-related technologies, this application modifies non-ribosomal peptide synthetase, heterologously expresses non-ribosomal peptide synthetase mutants in a variety of hosts, and for the first time discovers and obtains a pyridone compound, and determines its chemical formula as C5H4N2O3, named 5-amino-pyridine-2,3,6-trione or 5-hydroxy-3-imino-pyridine-2,6-dione. This novel pyridone compound can be used as a raw material or intermediate in the development and preparation of novel antibiotics, drugs and dyes.

The invention belongs to the technical field of novel energy storage battery materials, and particularly relates to a high-entropy Prussian blue positive electrode material as well as a preparation method and application thereof. The chemical formula of the positive electrode material is NaxM [Fe (CN) 6] y.mH2O (at) C, M comprises five different elements of Fe, Ni, Co, Mn, Zn, Ti, V or Cu, the molar ratio of the five different elements is 1: 1: 1: 1: 1-1: 3: 3: 3: 3, x is larger than 0 and smaller than or equal to 2, y is larger than 0 and smaller than or equal to 3, m is larger than 0 and smaller than or equal to 5, and the molar ratio of a carbon component to a high-entropy Prussian blue component is 1: 5-1: 10. Different physical and chemical properties of a plurality of metal elements are utilized, different transition metal elements are coordinated with cyano groups, respective advantages are exerted, the defects of a single metal element are overcome, a stable continuous transmission channel for sodium ions and electrons is constructed in a Prussian blue structure, and the performance of the Prussian blue is improved. Jahn-Teller distortion can be effectively inhibited through the synergistic effect of various metals, and the long cycle stability of the Prussian blue material is remarkably improved.

The invention discloses a neodymium-zirconium co-substituted M-type strontium ferrite wave-absorbing material and a preparation method thereof, the chemical formula of the neodymium-zirconium co-substituted M-type strontium ferrite wave-absorbing material is Sr1-xNdxZr0. 2Fe11.8 O19, and x is more than or equal to 0.1 and less than or equal to 0.4. The method comprises the following steps: (1) mixing strontium nitrate, ferric nitrate nonahydrate, neodymium nitrate hexahydrate, zirconium nitrate pentahydrate, citric acid monohydrate and deionized water, stirring and dissolving to obtain sol; (2) adjusting the pH value of the sol to 6.5-7.5, and then heating to carry out sol-gel reaction to obtain wet gel; (3) drying and grinding the wet gel to obtain precursor powder; and (4) performing heat treatment on the precursor powder in a box-type furnace, cooling and grinding to obtain the neodymium-zirconium co-substituted M-type strontium ferrite wave-absorbing material. According to the material, effective wave-absorbing frequency band broadening is achieved, the matching thickness corresponding to the effective wave-absorbing bandwidth is as thin as 0.55-0.7 mm, and meanwhile, the performance requirements of thinness, width and strength in the field of electromagnetic compatibility are met.

The present invention belongs to the technical field of ceramic material preparation methods, and specifically relates to a lead-free piezoelectric ceramic, its preparation method, and application. The lead-free piezoelectric ceramic is a KNN-based lead-free piezoelectric ceramic or a BT-based lead-free piezoelectric ceramic having a perovskite structure; the KNN-based lead-free piezoelectric ceramic is prepared by doping gallium nitride with potassium sodium niobate (KNN) ceramic as the matrix, and the chemical formula is 0.955 (K 0.48 Na 0.52 )Nb 0.98 Sb 0.02 O3‒0.045Bi 0.5 Na 0.5 ZrO3‒0.75mol% GaN; The BT-based lead-free piezoelectric ceramic is prepared by doping gallium nitride with barium nitride (BT) as the matrix, and the chemical formula is (Ba 0.85 Ca 0.15 )(Ti 0.9 Zr 0.1 ) O‒1.75mol% GaN; the lead-free piezoelectric ceramic has a dense structure, is lead-free, and exhibits excellent electrochemical properties. The preparation method for the lead-free piezoelectric ceramic is simple, low-cost, pollution-free, and utilizes readily available raw materials. The lead-free piezoelectric ceramic can be used to prepare energy harvesters and has significant application value.

The invention discloses a reverse design method applied to a solid electrolyte material. The method comprises the following steps: firstly, constructing an inorganic solid electrolyte material field knowledge base; generating a chemical formula conforming to physical and chemical rationality through a chemical formula generator based on guidance of a domain knowledge base; based on the generated chemical formula, further utilizing a large language model to generate a candidate crystal structure information file, and performing optimization in combination with a Monte Carlo tree search method; in the optimization process, in order to evaluate the performance of the generated candidate crystal structure, a graph neural network model driven by domain knowledge is cooperated to carry out multi-target performance prediction, a prediction result is used as reward feedback, and then the generation quality of the candidate crystal structure is optimized; and finally, by taking activation energy and convex hull energy as indexes, screening out a potential novel inorganic solid electrolyte material meeting performance requirements. The development efficiency of the inorganic solid electrolyte material is improved.

To provide a method for manufacturing a thin film, capable of greatly improving step coverability and thin film thickness uniformity even when forming a thin film on a substrate having a complicated structure by controlling a side reaction to reduce a thin film growth rate and removing a process by-product in the thin film.SOLUTION: A method for manufacturing a thin film comprises the steps of: i) adsorbing a growth inhibitor for thin film formation represented by chemical formula (1) on a substrate surface; and ii) adsorbing a Ti-based thin film precursor on the substrate surface having the adsorbed growth inhibitor. AnBmXo (1) (where, A is carbon or silicon; B is hydrogen or 1-3C alkyl; X is halogen; n is any integer of 1-15; o is an integer of one or more; and m is 0 to 2n+1.).SELECTED DRAWING: Figure 2

The invention discloses an inorganic-organic hybrid compound crystal and a preparation method thereof, and belongs to the technical field of organic-inorganic hybrid materials. The preparation method comprises the following steps: mixing raw materials containing hydroiodic acid, organic cage molecules RCC3 and a lead source with a solvent, and carrying out solvothermal reaction to obtain the inorganic-organic hybrid compound crystal. The chemical formula of the prepared inorganic-organic hybrid compound crystal is ({H18 [C72H108N12] 2 [(Pb10I36)]}. 2I), wherein [C72H108N12] is RCC3 acidified by hydroiodic acid, the crystal has a supramolecular three-dimensional structure assembled by a [Pb5I8] 3-anion cluster unit and a protonated RCC3 molecular cage through electrostatic and hydrogen-bond interaction, and belongs to a monoclinic system, and the space group is P21. The crystal structure is a metal halide-based organic-inorganic hybrid crystal constructed by taking an organic molecular cage as nitrogen-containing cations and lead iodide for the first time.

A novel compound of Chemical Formula 1:wherein in the Chemical Formula 1: n is an integer of 1 to 6; X is O or S; L1 and L2 are each independently a single bond, substituted or unsubstituted C6-60 arylene, or substituted or unsubstituted C2-60 heteroarylene containing at least one heteroatom selected from the group consisting of O, S, Si, P and B; Ar1 is cyano, substituted or unsubstituted C6-60 aryl, or substituted or unsubstituted C2-60 heteroaryl containing at least one heteroatom selected from the group consisting of O, S, Si, P and B; and Ar2 and Ar3 are each independently substituted or unsubstituted C6-60 aryl or substituted or unsubstituted C2-60 heteroaryl containing at least one heteroatom selected from the group consisting of O, S, Si, P and B; and an organic light emitting device including the same.

The invention discloses a sodium ferric pyrophosphate material with a sodium storage dominant crystal face regulated and controlled by cation doping as well as a preparation method and application of the sodium ferric pyrophosphate material. The chemical formula of the prepared sodium ferric pyrophosphate material with the regulated and controlled crystal structure is Na < 4 > Fe < 2.97 > M < 0.03 > (PO4) < 2 > P < 2 > O < 7 >. Wherein M = Sr, or Sr and a second doping element, and the second doping element is selected from one of Cd, Bi, Mo, Ni and Al. The material is prepared by adopting a sol-gel method, an iron source, a chelating agent, a sodium source, a phosphorus source and doping elements are dissolved in deionized water, and stirring is performed until a gel state is formed; and drying and calcining twice to obtain a final product. The sodium ferric pyrophosphate electrode material prepared by the invention has more sodium storage dominant crystal faces, shows good electrochemical performance, has the advantages of simple preparation process, easily available raw materials and low cost, has remarkable industrial application value, and is easy for large-scale production.

The present invention relates to a compound represented by chemical formula 1 for an organic optoelectronic diode, a composition comprising same for an organic optoelectronic diode, an organic optoelectronic diode, and a display device. The details of chemical formula 1 is as defined in the specification.

The invention discloses an NZP-high-entropy (Ln1 / n) PO4 monazite type multiphase ceramic solidified body and a preparation method thereof, the chemical general formula of the NZP-high-entropy (Ln1 / n) PO4 monazite type multiphase ceramic solidified body is (1-x) Sr0. 5Zr2 (PO4) 3-x (Ln1 / n) PO4, x represents molar percentage, the value range is 0.1-0.9, x represents molar percentage, and the value range is 0.1-0.9. The NZP-high-entropy (Ln1 / n) PO4 monazite type multiphase ceramic solidified body is NZP-high-entropy (Ln1 / n) PO4 monazite type multiphase ceramic solidified body. N represents the number of element types of Ln lattice sites in the high-entropy (Ln1 / n) PO4 monazite type, and n is an integer and is larger than or equal to 5 and smaller than or equal to 7; the Ln element types comprise La, Nd, Sm, Eu, Gd, Ho, Er, Sr0. 5Zr2 (PO4) 3 and (Ln1 / n) PO4, and the molar ratio of the Ln element types to the Sr0. 5Zr2 (PO4) 3 to the (Ln1 / n) PO4 can be freely regulated and controlled. The NZP-high-entropy (Ln1 / n) PO4 monazite type multiphase ceramic solidified body adopts an in-situ preparation process, and integration of crystal phase synthesis and sintering densification can be realized. The preparation method comprises the following steps: uniformly mixing the raw materials, pretreating, adding a sintering aid, mixing again, granulating and aging the obtained powder, molding, removing plastic, and sintering to obtain the NZP-high-entropy (Ln1 / n) PO4 monazite type composite ceramic solidified body. The preparation process disclosed by the invention has the advantages of flexible composition design, capability of simultaneously curing various fission products and (sub) actinide series nuclides, short preparation period, low production energy consumption, high product compactness and the like.

The invention belongs to the photovoltaic field, and particularly relates to a passivation layer, a preparation method thereof and a perovskite solar cell. The passivation layer comprises an interface modification material, and the chemical formula of the interface modification material is shown as a formula A and / or a formula B. The passivation layer composed of the interface modification material can improve the photovoltaic performance and stability of the perovskite solar cell. # imgabs0 #

The invention relates to the technical field of organic and inorganic hybrid functional materials, in particular to a doped chiral metal halide material with light-induced circular polarization luminescence and a preparation method and application of the doped chiral metal halide material, the chemical formula of the doped chiral metal halide material is L2BnC1-nX4, and the value of n is 0 lt; n is less than 1. The fluorescence quantum yield of a film sample is remarkably improved by using a transition metal ion or rare earth ion doping method. According to the invention, the plug splitting energy in the chiral metal halide is adjusted, so that the chiral optical property of the film material is remarkably improved. The preparation process of the chiral metal halide thin film is simple, the thin film does not need to be prepared after a single crystal material is obtained through a harsh single crystal preparation method, and the material composition and the doping proportion can be easily adjusted according to the requirements of material properties. The invention provides a feasible way for regulating and controlling the chiral optical property of the chiral metal halide by doping transition metal ions or rare earth ions.

The present invention provides a cathode material, a preparation method thereof and an application. The chemical formula of the cathode material is xLi2MnO3·(1−x−y)LiNi a T M(1‑a) O2·yLiMn b A (1‑b) PO4, wherein 0 < x < 1, 0 < y < 1, 0 ≤ a ≤ 1, 0.5 ≤ b ≤ 1, T M and A each independently include a metal element; the cathode material can form a continuous phase transition, has a supercrystalline domain structure and a stable layered structure, can stabilize lattice oxygen, reduce voltage drop, and thus can significantly improve the cycling performance of the battery at high voltages.

The invention discloses a polyanion halide solid electrolyte material as well as a preparation method and application thereof. The chemical formula of the halide solid electrolyte material is Li < 3 > YCl < 6-2x > Br < x > I < x >, wherein 0 < x < 3. The chemical formula of the halide solid electrolyte material is Li < 3 > YCl < 5.8 > Br < 0.1 > I < 0.1 >, Li < 3 > YCl < 5.6 > Br < 0.2 > I < 0.2 >, Li < 3 > YCl < 5.4 > Br < 0.3 > I < 0.3 >, Li < 3 > YCl < 5.2 > Br < 0.4 > I < 0.4 >, Li < 3 > YCl < 5.0 > Br < 0.5 > I < 0.5 >, Li < 3 > YCl < 4.8 > Br < 0.6 > I < 0.6 >, Li < 3 > YCl < 4.6 > Br < 0.7 > I < 0.7 >, Li < 3 > YCl < 4.4 > Br < 0.8 > I < 0.8 >, Li < 3 > YCl < 4.2 > Br < 0.9 > I < 0.9 >, Li < 3 > YCl < 4.0 > The invention provides a series of Li3YCl6-2xBrxIx by taking economical and efficient Li3YCl6 as a main body and combining with an anion mixing strategy, the Li3YCl6-2xBrxIx has high ionic conductivity of 1.98 mS cm <-1 > and low activation energy of 0.257 eV, and has good compatibility with a Li4Ti5O12 (LTO) positive electrode and a Li-In alloy negative electrode. The construction of the anion mixed state not only can reduce the binding effect of an anion frame on Li < + > migration and improve the ionic conductivity, but also can soften anion crystal lattices and reduce the activation energy. More importantly, due to the introduction of I <->, a LiI self-limiting passivation interface layer is generated in situ, so that the stability of a Li interface is enhanced.

The invention relates to the technical field of electrochemistry, and provides a sulfide solid electrolyte, a preparation method thereof, a battery and application. The chemical formula of the sulfide solid electrolyte is Li7-aPS6-aXa, X is halogen, and a is greater than or equal to 1 and less than or equal to 2; wherein the peak area of a diffraction peak corresponding to a (111) crystal plane of the sulfide solid electrolyte is I1, the peak area of a diffraction peak corresponding to a (311) crystal plane of the sulfide solid electrolyte is I2, and I1 / I2 is larger than or equal to 0.2 and smaller than or equal to 0.3. The I1 / I2 of the sulfide solid electrolyte disclosed by the invention is within the range, a good crystal structure and a relatively large interface area can be provided, and ion movement is promoted, so that relatively high ionic conductivity is obtained. Furthermore, according to the method disclosed by the invention, the high ionic conductivity of the product is ensured by reducing the solvent dosage and optimizing the sintering step, and meanwhile, the environmental pollution, the energy consumption and the production cost are remarkably reduced.

The invention belongs to the technical field of liquid chromatography-mass spectrometry detection pretreatment, and particularly relates to a pretreatment method for liquid chromatography-tandem mass spectrometry analysis of pesticide and veterinary drug residues in serum, which comprises the following steps: (S1) carrying out heating reaction on Sc (III) salt, Cu (II) salt and 1H-pyrazole-4-formic acid (H2PyC) in a polar aprotic solvent, and cooling to obtain a green crystal, namely MOF-919; the chemical formula of the MOF-919 is [Sc < 3 > (mu3-O) (OH) < 3 >] [Cu3 (mu3-O) (mu-PyC) < 3 > (H2O) < 6 >] < 2 >; (S2) mixing the serum sample with an acetonitrile solution containing formic acid, carrying out ultrasonic treatment, vortex oscillation and centrifugation, taking supernate, and diluting the supernate with an aqueous solution containing formic acid to obtain a to-be-purified solution; and (S3) adding MOF-919 into the to-be-purified liquid, mixing, performing ultrasonic treatment, performing vortex oscillation, centrifuging, and taking supernate, thereby completing the pretreatment of the to-be-purified liquid. According to the method, the MOF-919 is used for adsorbing chemical pollutant residues in serum, especially phospholipids, so that the purpose of removing the chemical pollutant residues in blood is achieved. The method is simple and convenient to operate, small in organic solvent consumption and good in purification effect, and can be widely applied to residue analysis of chemical pollutants in serum.

The invention provides a composition for an organic optoelectronic device, an organic optoelectronic device, and a display device. The composition includes a first host represented by Chemical Formula 1, a second host represented by a combination of Chemical Formula 2 and Chemical Formula 3, and a dopant represented by Chemical Formula 4. The contents of Chemical Formulae 1 to 4 are as defined in the specification.