The invention relates to the technical field of
OLED (Organic
Light Emitting Diode) luminescent materials, in particular to an
anthracene azepine material as well as a preparation method and application thereof, and the structure of the
anthracene azepine material is as shown in the following formula: # imgabs0 #, r is any one of a deuterated
terphenyl group, an isoquinolyl group, a piryl group, a 9, 9-diphenyl fluorenyl group, a dibenzothienyl group and a deuterated N-phenyl carbazolyl group. The
parent structure of the
anthracene-
azepine material has anthracene, deuterated
carbazole, azepine structures and the like, and intramolecular large steric hindrance space distorted structures, so that the spin-
orbit coupling effect between different excited states is remarkably improved, the molecules are greatly limited during relaxation, and finally, the device realizes dark
blue light emission, and has wide application prospects. The introduced
aryl heterocyclic structure can greatly improve the stability of the material, and meanwhile, the deuterated structure can obviously prolong the service life of the device and obviously improve the luminous efficiency of the device.