534 results about "Iridium" patented technology

The invention discloses a component gradient iridium tantalum coating anode and a preparation method thereof, the component gradient iridium tantalum coating anode comprises a titanium-based bottom layer, a middle layer and a surface active layer structure with component gradient, and the middle layer and the active layer are both prepared through a thermal decomposition method. And the intermediate layer is prepared on the titanium substrate and is composed of TiO2 / Ta2O5 mixed oxide. The surface active layer is prepared on the outer side of the middle layer and comprises a plurality of layers of IrO2 / Ta2O5 oxide coatings with different iridium-tantalum proportions. Compared with a traditional uniform coating anode, the prepared component gradient iridium tantalum coating anode can relieve the stress concentration phenomenon and reduce coating cracking, the service life of the anode is remarkably prolonged, and the catalytic activity of the anode is remarkably improved; the modified carbon nano tube is added into the active layer precursor solution, so that the conductivity change caused by component gradient is improved, and the cell voltage of the component gradient iridium tantalum coating anode is effectively reduced; and moreover, the iridium content is lower, and the preparation cost of the electrode is reduced.

The invention discloses a Ti / IrO2-SnO2-SbO2 gradient active coating anode with low cost and high stability and a preparation process of the Ti / IrO2-SnO2-SbO2 gradient active coating anode. The gradient active coating is characterized in that the gradient active coating is composed of 3-5 layers, the total thickness is 5-15 microns, the thickness of each layer is 1-5 microns, the molar percentage content of iridium in a bottom layer is 0-5%, the sum of the molar percentage content of tin and antimony is 95-100%, the molar percentage content of iridium in a surface layer is 10-20%, the sum of the molar percentage content of tin and antimony is 80-90%, and the thickness of each layer is 1-5 microns. The molar percentage content of iridium from the bottom layer to the surface layer is sequentially increased from 2% to 10%, the molar percentage content of tin and antimony is sequentially reduced from 2% to 10%, and the total iridium loading amount in the gradient active coating is 0.05-0.2 mg / cm < 2 >. The preparation method comprises the three steps of titanium substrate pretreatment, precursor salt alcohol solution preparation and gradient active coating preparation. By adopting a gradient coating mode, the thermal stress between the coating and the titanium substrate in the preparation process is remarkably reduced, the consumption of noble metal is reduced, the oxygen evolution activity of the anode is improved, and the service life of the anode is prolonged. The method is simple to operate and low in cost, and has remarkable industrialization advantages.

The invention discloses a high-precision point iridium welding device and process, and relates to the technical field of pen point welding. The device comprises a conveying assembly capable of moving along an annular path, a welding assembly arranged below the conveying path and positioning tools arranged corresponding to conveying blocks. The conveying assembly comprises a plurality of conveying blocks, and the positioning tool is used for inserting a to-be-welded pen point base material; the welding assembly comprises a hopper, a feeding pipe coaxially connected with the hopper in a sliding mode, an electrode ring fixed to the top end of the feeding pipe and an inverted-cone-frustum-shaped iridium particle groove formed in the top end. The hopper can be filled with iridium particles to be welded, the feeding pipe can ascend and descend in the vertical direction, and the iridium particle groove can bear one iridium particle. Through cooperation of the conveying block and the positioning tool, quick assembly and feeding of the pen point base material are facilitated, the feeding difficulty is reduced, and manual feeding is more labor-saving.

The invention belongs to the technical field of organic electroluminescent materials, and provides an iridium-containing heterocyclic phosphorescent doping material and an organic electroluminescent device.The doping material has a compound general formula shown in the formula I. Quinoline and a naphthalene ring are connected through silane or germane, and a silicon or germanium six-membered heterocyclic structure is formed. And reacting with iridium metal and a diketone monomer to obtain the iridium metal heterocyclic phosphorescent organic light-emitting material. The heteroatom silicon or germanium in the material can adjust molecular orbital HOMO and LUMO energy levels, and the polarity effect of heteroatoms promotes electron migration, reduces interface potential barriers and electron injection barriers, reduces carrier injection loss and improves carrier mobility, so that driving voltage is reduced, and the external quantum efficiency of a device is improved. In addition, the silicon or germanium heterocyclic ring has better rigidity, so that the overall stability of the structure is enhanced, and the rigid structure can prolong the service life of the device.

The invention discloses a titanium-based-iridium tantalum oxidation coating anode and a preparation method and application thereof, and belongs to the technical field of anode preparation, and the preparation process of the titanium-based-iridium tantalum oxidation coating anode comprises the steps that a titanium substrate is brushed with a solution containing a tantalum source A, then sintering is conducted, brushing-sintering is repeated, and a tantalum-coated titanium substrate is obtained; the tantalum-coated titanium substrate is brushed with the iridium-tantalum oxidation coating liquid, then sintering is carried out, and brushing-sintering is repeated, so that the tantalum-coated titanium substrate is obtained; the iridium-tantalum oxidation coating liquid contains a tantalum source B, an iridium source and a zirconium source; in the iridium tantalum oxidation coating liquid, the mass ratio of tantalum to iridium is (6-7): (4-5), according to the preparation method provided by the invention, through two times of brushing, the tantalum content in the titanium-based-iridium tantalum oxidation coating anode is more than 5% greater than the iridium content, and when the titanium-based-iridium tantalum oxidation coating anode is used for an alkaline citric acid electroplating system, the decomposition of a complexing agent can be effectively inhibited, the components of the electroplating liquid are maintained to be stable, so that the quality of a plating layer is ensured, and the service life of the plating layer is prolonged. The maintenance cost of the plating solution is reduced and the service life is prolonged.

A method may include operating a dehydrogenation process whereby a hydrocarbon-containing feed is converted to light olefins, wherein the dehydrogenation process utilizes a fluidized process catalyst that circulates between a reactor and a combustor. The method may comprise withdrawing the process catalyst from the dehydrogenation process, modifying the process catalyst to form a modified catalyst, and adding the modified catalyst back to the dehydrogenation process. The process catalyst may include from 0.1 wt. % to 10 wt. % of one or more metals chosen from gallium, indium, thallium, or combinations thereof, from 1 ppmw to 1000 ppmw of one or more metals chosen from platinum, palladium, rhodium, iridium, ruthenium, osmium, or combinations thereof, and at least 85 wt. % support. Modifying the process catalyst may include adding one or more of manganese, iron, chromium, or vanadium.

The invention discloses an ultrahigh-temperature multi-element iridium alloy material and a preparation method thereof, and belongs to the technical field of alloy materials. The iridium alloy material comprises the following elements in percentage by mass: 53 to 58.5 percent of Ir, 40 percent of Ta, 0.5 to 2 percent of Y and 1 to 5 percent of Re. The preparation method of the iridium alloy material comprises the following steps: weighing Ir, Ta, Y and Re metal powder in proportion and uniformly mixing; blank pre-pressing treatment is conducted on the evenly-mixed metal powder, the metal powder is die-cast into a block, and a pressed blank is obtained; the pressed blank is smelted through an electric arc smelting method, and an iridium alloy crude product is obtained after smelting is finished; and the smelting is repeated for more than 7 times, so that the pressed blank is uniformly smelted, the content of each component reaches the standard, and the iridium alloy material is prepared. According to the iridium alloy material, through the synergistic effect of multiple elements and the preparation technology, the triple effects of structural distortion strengthening, high-temperature stability and oxidation film integrity are achieved. And due to the high mixed entropy, a similar high-entropy alloy structure is formed, the high-temperature oxidation resistance is remarkably improved, and the alloy is suitable for various ultra-high-temperature environments.

The invention provides an iridium-ruthenium oxide composite catalyst, a preparation method thereof and a proton exchange membrane water electrolysis device, and relates to the field of hydrogen production through water electrolysis. The preparation method of the iridium-ruthenium oxide composite catalyst comprises the following steps: mixing sodium nitrate, ruthenium chloride and water to prepare a mixed solution, and then drying and grinding to obtain a mixture; placing the mixture on the surface of nickel foil, carrying out first heating by using Joule heating equipment, and then cooling to obtain ruthenium oxide; mixing ruthenium oxide, hexadecyl trimethyl ammonium bromide and ethylene glycol, and performing ultrasonic dispersion to obtain a ruthenium oxide solution; and mixing the ruthenium oxide solution, H2IrCl6 and potassium hydroxide, adjusting the pH value of the system to be alkaline, then carrying out second heating until reflux and constant-temperature reaction, carrying out solid-liquid separation on the reaction product, and washing to obtain the iridium-ruthenium oxide composite catalyst. The iridium-ruthenium oxide composite catalyst provided by the invention has high activity, high stability and high water electrolysis efficiency.

The invention discloses a preparation method of a low-iridium-content catalyst for PEM electrolyzed water anode oxygen evolution, and belongs to the field of PEM electrolyzed water. The method comprises the following steps: (1) dissolving a manganese salt, potassium permanganate and a cerium salt in water, adding an acid, adjusting the pH value to 3-7, uniformly stirring, and aging to form a uniform suspension; then transferring into a reaction kettle, and carrying out hydrothermal reaction; roasting by using a muffle furnace to obtain a cerium-manganese-based metal oxide carrier; (2) adding iridium salt into deionized water, stirring, and carrying out ultrasonic dispersion to obtain an iridium-containing precursor solution; and adding the iridium-containing precursor solution into the cerium-manganese-based metal oxide carrier suspension, stirring and mixing, then carrying out ball milling treatment, washing and drying to obtain the supported low-iridium-content catalyst, namely the low-iridium-content catalyst for PEM electrolytic water anode oxygen evolution. The use amount of Ir is reduced, more active sites of Ir are exposed, and the performance of the catalyst is improved.

A method may include contacting a hydrocarbon-containing feed with a catalyst in a reactor to form an olefin-containing effluent, then at least partially separating the olefin-containing effluent from the catalyst. Passing the catalyst to a combustor and heating the catalyst by combusting a supplemental fuel. The supplemental fuel includes methane in an amount greater than or equal to 1 mol. %. Passing the catalyst from the combustor to the reactor, such that at least a portion of the catalyst continuously cycles between the reactor and the combustor. The catalyst includes from 0.1 wt. % to 10 wt. % of one or more metals chosen from gallium, indium, thallium or combinations thereof, from 5 ppmw to 1000 ppmw of one or more metals chosen from platinum, palladium, rhodium, iridium, ruthenium, osmium, or combinations thereof, from 100 ppmw to 30000 ppmw of chromium, and at least 85 wt. % support.

The invention belongs to the technical field of preparation of electrocatalytic oxygen evolution catalysts, and particularly discloses a doping regulation type ruthenium-iridium-based electrocatalytic oxygen evolution catalyst and a preparation method thereof.The preparation method comprises the following steps that S1, ruthenium salt, iridium salt and doped metal salt are dispersed in a solvent, the doped metal salt is selected from one or more of yttrium salt, strontium salt, potassium salt, calcium salt, magnesium salt, scandium salt, gallium salt and aluminum salt; s2, preparing a precursor mixture; s3, performing heat treatment to obtain a solid product; and S4, washing and drying to obtain the metal element doped ruthenium-iridium-based electro-catalytic oxygen evolution catalyst. According to the doping regulation type ruthenium-iridium-based electro-catalysis oxygen evolution catalyst and the preparation method thereof, the process is simple, the universality is high, doping of multiple elements can be achieved only by replacing the doped metal salt, and the obtained catalyst has excellent acidic water electrolysis oxygen evolution activity and long circulation stability; and excessive phase splitting of the Y element and excessive lattice distortion of other elements can be avoided.

A catalyst suitable for dehydrogenation of hydrocarbons may include from 0.0005 wt.% to 0.1 wt.% of platinum, palladium, rhodium, iridium, ruthenium, osmium, or combinations thereof; from 0.1 wt.% to 10 wt.% of gallium, indium, thallium, or combinations thereof; from 0.1 wt.% to 5 wt.% of lanthanum, yttrium, or zirconium; at least 85 wt.% support, and from 0 wt.% to 0.001 wt.% cerium.

A process for producing amines by reductive amination, the process includes introducing a feed stream, the feed stream comprising an amino alcohol and a reducing agent, and hydrogen in a reaction zone of a reactor, and contacting the feed stream with a catalyst in the reaction zone. A hydrogen flow rate into the reaction zone is adjusted, and a product stream comprising ethyleneamines is extracted. The catalyst includes a carrier component selected from alumina, silica, and combinations thereof; and an active component having a first metal, a second metal, and a third metal. The first metal is selected from cobalt, nickel, and copper, the second metal is selected from rhenium, ruthenium, chromium, zinc, sodium, calcium, magnesium, strontium, lithium, potassium, barium, cesium, lanthanum, tungsten, iron, silver, titanium, manganese, aluminum, rhodium, platinum, palladium, iridium, and combinations thereof, and the third metal is niobium.

The application relates to a high-conductivity and high-activity Ir@TiO2 anode catalyst, a preparation method and application thereof in a proton exchange membrane electrolytic cell, and belongs to the technical field of inorganic functional catalyst materials. The iridium source and the titanium source are mixed at room temperature, a reducing agent magnesium diboride is added, the mass ratio of the magnesium diboride and the iridium source is 2:1, the mass ratio of the titanium source and the iridium source is 1-100:1; then the mixture is placed in a high-temperature and high-pressure reaction kettle, and is reacted at 80-200 DEG C for 10 min-4 h, and the high-conductivity, high-activity and easily enlarged Ir@TiO2 anode catalyst is obtained after being reduced to room temperature. The obtained Ir@TiO2 anode catalyst is dispersed in a mixed solution of water and ethanol with a volume ratio of 1:1, is prepared into slurry, is prepared into a membrane electrode through a coating means, and is assembled in a PEM electrolytic cell, and when the iridium load is 0.5 mg / cm 2 , the high activity and stability are still maintained.

The invention relates to a carbon-supported noble metal ordered alloy electrocatalyst capable of realizing mass production. The electrocatalyst comprises a carbon carrier and small-size noble metal ordered alloy nanoparticles loaded on the carrier, the loading capacity of the alloy is 20 to 90 weight percent; the average particle size of the precious metal ordered alloy nanoparticles is 1-10 nm; the noble metal ordered alloy comprises an alloy consisting of a noble metal and at least one different transition metal M; wherein the noble metal is platinum, palladium, iridium, rhodium or ruthenium. The method is used for solving the problem that the size of catalyst particles becomes large in the high-temperature ordering process, high metal loading capacity is achieved, the feed ratio is increased to 60 times, successful synthesis of the catalyst can be achieved on the gram scale level, and the method can be popularized to actual production to achieve large-scale production.

The invention provides a catalyst for maleic acid water phase hydrogenation as well as a preparation method and application thereof. The catalyst comprises a carrier, an active metal component and a nitrogen-doped carbon layer, wherein the nitrogen-doped carbon layer is formed by shrinking and carbonizing melamine and formaldehyde in pores of the carrier loaded with the active metal component, and the active metal component is coated with the nitrogen-doped carbon layer; the active metal component is selected from at least one of palladium, ruthenium, gold, rhodium and iridium, and the carrier is a spherical or granular porous material. The catalyst disclosed by the invention comprises the nitrogen-doped carbon layer formed by shrinking melamine and formaldehyde in pores of the carrier loaded with the active metal components and carbonizing, so that the active metal components of specific types can be promoted to be uniformly dispersed in the catalyst structure, and the catalytic performance is improved; meanwhile, by combining the effect of the carrier, the mechanical strength of the catalyst is effectively improved, so that the catalyst can still maintain high activity after being used in an acid environment for a long time, and the maleic acid water-phase hydrogenation reaction can be efficiently catalyzed in a long-life manner.

The invention belongs to the field of analytical chemistry, and particularly discloses a method for determining trace precious metals in copper-nickel flotation tailings. According to the method, trace precious metal in the tailings is enriched through a nickel matte assaying method, and nickel matte alloy rich in precious metal is formed; the nickel matte alloy is inlaid or crushed and doped with carbon to prepare a sample meeting the measurement requirement of the glow discharge mass spectrometry, and the content of the noble metal in the sample is measured and converted by adopting the glow discharge mass spectrometry. The method effectively solves the problems of low precious metal content in tailings and large fluctuation of detection results, improves the detection accuracy and stability, and is suitable for determination of trace precious metals such as gold, silver, platinum, palladium, rhodium and iridium.

The electron source is provided with: an electron emission unit containing an alloy of iridium and a rare earth element; a support part made of metal; and a joining part that joins the electron emission part and the support part. The bonding portion has a coating layer containing iridium and the metal in the support portion, and the coating layer contains iridium and the metal in the support portion.

A method for producing 2,5-dimethylfuran according to one embodiment of the present invention includes a step for reacting a furan compound having a specific structure with hydrogen in a non-aqueous solvent in the presence of a hydrogenation catalyst. In this method for producing 2,5-dimethylfuran, the hydrogenation catalyst includes at least one type selected from among a first component group and at least one type selected from among a second component group. The first component group includes chromium, molybdenum, manganese, rhenium, ruthenium, rhodium, iridium, nickel, palladium, platinum, copper, zinc, and the like. The second component group includes aluminum oxide, silicon oxide, titanium oxide, zirconium oxide, carbon, and the like.

This invention discloses an upflow electrochemical treatment device and method for treating wastewater containing hexavalent chromium. The device includes a cylindrical inner reaction chamber and a double-layer reaction chamber. The inner reaction chamber contains a mesh-like ruthenium-iridium-titanium anode and a carbon fiber felt membrane cathode. The double-layer reaction chamber includes an external overflow chamber and an internal upflow chamber. The method includes the following steps: S1, preliminary preparation; S2, wastewater injection; S3, continuous wastewater treatment; S4, detection. This invention mainly uses an upflow electrochemical water purification membrane for wastewater treatment, which can efficiently reduce highly toxic hexavalent chromium to less toxic trivalent chromium, effectively reducing the toxicity of the wastewater. Simultaneously, it utilizes the oxygen released during the reduction of hexavalent chromium to achieve the simultaneous generation of hydrogen peroxide, improving resource utilization and reducing treatment costs.

The invention discloses an iridium-ruthenium diatom / sponge nickel composite material, a preparation method thereof and application of the iridium-ruthenium diatom / sponge nickel composite material in alkaline electro-catalytic hydrogen evolution. The preparation method comprises the following steps: weighing nickel acetate, dissolving hydrazine hydrate, chloroiridic acid and a ruthenium trichloride aqueous solution in deionized water to prepare a mixed solution, placing the mixed solution in a high-pressure reaction kettle, and carrying out a hydrothermal reaction to obtain the iridium-ruthenium diatom / sponge nickel composite material electrocatalyst. Compared with an original sponge nickel electrocatalyst, the iridium ruthenium diatom / sponge nickel composite material prepared by the invention has better alkaline electrocatalytic hydrogen evolution performance; the method has the advantages that the acidity of chloroiridic acid enables part of Ni atoms to be dissolved out to generate Ni vacancies, so that iridium-ruthenium diatomic nucleation sites are provided. The composite material can synergistically catalyze alkaline hydrogen evolution, the mechanism of the composite material provides alkaline H2O cracking sites for nickel sites, active hydrogen species are obtained, rapid desorption of hydrogen protons is further achieved through iridium-ruthenium diatoms, and therefore more excellent alkaline electrocatalytic hydrogen evolution performance is obtained.

A platinum alloy composition is composed of, in weight percent, 0.0 to 5.0 gold, 0.0 to 2.5 cobalt, 0.0 to 3.0 copper, 0.0 to 5.0 iron, 0.0 to 2.75 gallium, 0.0 to 3.0 indium, 0.0 to 5.0 iridium, 0.0 to 5.0 manganese, 0.0 to 5.0 palladium, 0.0 to 5.0 rhenium, 0.0 to 5.5 rhodium, 0.0 to 5.0 ruthenium, 0.0 to 3.0 tin, 0.0 to 5.0 silver, and incidental impurities, where the sum of platinum and iridium is 95.0 or more, and wherein the following formula is satisfied, in which the sum of platinum and iridium is 95.0 or more. WCo, WCu, WFe, WGa, WIn, WNi, WPd, WSn, WRh, WIr, WAu, WRu, WRe, WAg and WMn are respectively weight percentages of cobalt, copper, iron, gallium, indium, nickel, palladium, tin, rhodium, iridium, gold, ruthenium, rhenium, silver and manganese in the alloy, 60 + WPd * 2.5 + WRh * 3.4 + WIr * 6.455 + WIr * 16.6 + WNi * 16.9 + WMn * 18.48 + WCo * 18.69 + WFe * 21.879 + WIn * 29 + WSn * 28.207 + WGa * 42.379 + WAg * 9.0 > = 130, and wherein the following conditions are satisfied, in which the weight percentages of cobalt, copper, iron -0.10406 * WAg-0. 1028 * WCo-0. 1201 * WCu-0. 2113 * WFe-0. 3368 * WGa-0. 1125 * WIn-0. 1639 * WNi-0. 0959 * WSn + 17.276261-0.20 * WMn + 0.0678 * WRu + 0.035 * WIr + 0.045 * WRh-0. 059 * WAu + 0.066 * WRe < = 17.1, and wherein the following formula is satisfied in which WCo, WCu, WFe, WGa, WIn, WNi, WPd, WSn, WMn, WRu, WIr, WRh, WAu, WAg and WRe are respectively aluminum, cobalt, copper, iron, gallium, indium, nickel, palladium

There is provided a method for decreasing leakage of matter from an object to a surrounding, said object being coated with a coating at least partially applied on the object, said coating comprising an at least partially covering layer comprising silver, said object optionally comprising area(s) without said layer, said coating comprising metal particles applied on the layer and optionally on areas without said layer, said metal particles comprising palladium and at least one metal selected from the group consisting of gold, ruthenium, rhodium, osmium, iridium, niobium, neodymium and platinum and wherein the amount of the metal particles is in the interval 0.01-8 μg / cm . Advantages include that leakage of matter such as latex allergens of metal ions can be reduced while the coating is both biocompatible and antimicrobial. Further, the blood clotting can be reduced.

The application discloses a CT cathode tube cathode surface coating and a preparation method thereof. The coating is prepared by improving a magnetron sputtering process, using iridium (Ir) and osmium (Os) as metal targets, and depositing a metal coating with a thickness of 10-20 microns on a molybdenum base. The prepared metal coating has a bonding force to the base which can exceed 100 N, and the coating is dense and has good uniformity, and can be used as a cathode for exciting electrons on the surface of a cathode tube in a CT X-ray tube.

This invention discloses a proton exchange membrane hydrogen pump anode and its application. The anode includes an anode sheet and a catalyst composited on the anode sheet. The catalyst includes a support and a first metal and a second metal composited on the support. The first metal is selected from one or more of platinum, iridium, palladium, and ruthenium; the second metal is selected from one or more of iron, cobalt, nickel, molybdenum, and vanadium. The first metal serves as the main active center for the hydrogen oxidation reaction, and the second metal can regulate the electronic structure of the first metal, thereby reducing the adsorption of carbon monoxide at the active site or promoting its oxidative removal. The synergistic effect of the two metals allows the anode containing the catalyst to maintain high hydrogen oxidation activity and stability in hydrogen fuel containing carbon monoxide, thereby improving the carbon monoxide poisoning resistance of the proton exchange membrane hydrogen pump containing the anode.

The invention relates to a preparation method and application of an amorphous IrLa spherical oxide catalyst, and the preparation method comprises the following steps: S1, dissolving an iridium salt and a lanthanum salt in water to obtain a precursor salt solution; s2, adding a reducing agent into the precursor salt solution, carrying out a hydrothermal reaction at 100-220 DEG C, and separating a solid to obtain an intermediate material; the reducing agent is selected from one or more of citric acid and citrate; and S3, carrying out heating treatment on the intermediate material in an aerobic environment, and carrying out acid pickling and drying on a heating product to obtain the amorphous IrLa spherical oxide catalyst. The preparation method is simple to operate, controllable and good in repeatability, and the amorphous IrLa spherical oxide catalyst prepared by the preparation method is composed of nano-particles, is high in uniformity, small in particle size, good in surface continuity and free of agglomeration phenomenon, has excellent acidic OER catalytic performance and stability, and is suitable for industrial production. Good application prospects are realized in the aspect of hydrogen production by electrolyzing water.

The invention relates to the technical field of water electrolysis hydrogen production, and discloses a PdIr / PdO catalyst and a preparation method thereof.The catalyst comprises PdO and PdIr alloy, PdO serves as a carrier, PdIr alloy metal active components are loaded on the PdO carrier, the loading amount of the PdIr alloy on PdO ranges from 30 wt% to 60 wt%, and the atom molar ratio of Pd to Ir of the PdIr alloy is 1: 1-0.5. The preparation method of the catalyst comprises the following steps: S1, respectively weighing an iridium source, a palladium source and molten salt according to a required stoichiometric ratio, grinding and mixing; s2, calcining the ground mixture in a carbon dioxide atmosphere to obtain impurity-containing solid powder; and S3, dispersing the obtained impurity-containing solid powder in a sulfuric acid solution, stirring and pickling, carrying out centrifugal separation, carrying out vacuum drying, and collecting purified solid powder to obtain the PdIr / PdO catalyst. According to the technical scheme, the purposes of improving the stability of the catalyst, reducing the loading capacity of noble metal Ir and weakening the agglomeration driving force among particles in the preparation process of the catalyst are achieved.

The application discloses a precious metal embedded porous carbon coated honeycomb ceramic monolithic catalyst and application thereof. The liquid phenolic resin polymer containing chloroplatinic acid is uniformly coated on the surface of the cordierite honeycomb ceramic through impregnation treatment; in an oxygen-nitrogen mixed atmosphere, one-stage solidification makes the liquid phenolic resin polymer containing chloroplatinic acid coated on the surface of the cordierite honeycomb ceramic completely solidified; two-stage calcination makes oxygen react with chloroplatinic acid, so that the chloroplatinic acid is decomposed, and the negative influence of chloride ions on the catalyst is eliminated; in an inert gas argon atmosphere, carbonization makes the phenolic resin polymer carbonize under high-temperature conditions to form porous carbon, and meanwhile, platinum ions are reduced to platinum single elements and embedded by the porous carbon, so that the precious metal (platinum, iridium) embedded porous carbon coated honeycomb ceramic monolithic catalyst is finally prepared.

The present specification describes a process for preparing an oxygen evolution reaction catalyst, the process comprising the steps of: (i) mixing an iridium powder and a peroxide salt to produce a powder mixture; (ii) heat treating the powder mixture; (iii) dissolving the product from (ii) in water to produce a solution; (iv) reducing the pH of the solution from (iii) to affect precipitation and form solids and a supernatant; (v) separating the solid from the supernatant; and (vi) drying the solid. An oxygen evolution catalyst obtainable by the process is also described.

The invention relates to the technical field of electrode material preparation, in particular to a supported iridium-based catalyst with a carrier surface rich in hydroxyl and a preparation method and application thereof.The preparation method comprises the steps that cerous nitrate, sodium hydroxide and water are mixed and subjected to a hydrothermal reaction, and a cerium dioxide precursor is obtained; mixing the cerium dioxide precursor, a hydrogen peroxide solution, a sulfuric acid solution and water, and reacting to obtain an intermediate of which the surface is loaded with hydroxyl; and mixing the intermediate of which the surface is loaded with hydroxyl, iridium metal salt and an alcohol solvent, and carrying out reduction reaction to obtain the supported iridium-based catalyst of which the carrier surface is rich in hydroxyl. The preparation method provided by the invention is a universal preparation method of a nanoparticle electrode material, the process is simple, the operation is convenient, the cost is low, and the prepared catalyst has good electrochemical activity and high stability, can show relatively excellent electrochemical performance in an electrolyzed water OER reaction, and is suitable for industrial production. And a new research scheme is provided for industrial application of electrolyzed water.