959 results about "Hemicellulose" patented technology

The invention relates to a weight-losing enzyme and a preparation method thereof, and belongs to the technical field of biology, and the weight-losing enzyme comprises a fruit enzyme, a vegetable enzyme, a seed enzyme and a lotus leaf extract; the fruit enzyme is obtained by performing enzymolysis on mixed fruit pulp of apples, lemons, grapefruits and haws through pectinase, performing enzymolysis through pepsase and performing co-fermentation through bifidobacterium longum and lactobacillus acidophilus; the vegetable enzyme is obtained by performing enzymolysis on mixed vegetable pulp of wax gourd pulp, celery and spinach through pectinase, performing enzymolysis through pepsin and performing fermentation through lactobacillus plantarum and bifidobacterium adolescentis; the seed enzyme is obtained by carrying out trypsin enzymolysis on mixed powder of semen raphani and phaseolus calcaratus, then carrying out nattokinase enzymolysis and then fermenting with bifidobacterium breve; the lotus leaf extract is obtained by sequentially carrying out enzymolysis on lotus leaves through hemicellulase, snail protease and nattokinase. All the components are matched for use, so that the weight-losing food has the effects of promoting digestion, inhibiting fat absorption, regulating intestinal flora, promoting metabolism and the like, and has a good weight-losing effect.

The invention discloses a deep eutectic solvent / bimetal organic framework co-catalyzed straw polyol as well as a preparation method and application thereof, the straw polyol is prepared by the following method: uniformly mixing straw powder, small molecular alcohol, an acid catalyst and a deep eutectic solvent in a nitrogen atmosphere, and reacting to obtain a reaction product; and adding a bimetal organic framework catalyst into the reaction product, and reacting to obtain the straw polyol. A green, natural and pollution-free eutectic solvent catalytic liquefaction technology is adopted, lignin and hemicellulose can be dissolved, the cross-linking effect between lignin and hemicellulose and cellulose is reduced, the crystalline structure of cellulose can be destroyed, the available surface area is increased, the contact with a liquefying agent is enhanced, the conversion efficiency is improved, and the residue rate is reduced; the bimetallic organic framework catalyst is added in the middle and later periods of the reaction, aldehydes, ketones and acid and ester substances can be reduced and upgraded into alcohols, the hydroxyl value of the liquefied polyol is greatly increased, and the film-forming crosslinking degree is improved.

The invention discloses a rice straw decomposition process full life cycle monitoring system based on a cloud platform, and relates to the field of agricultural informatization, and the system comprises a field data collection terminal which is used for collecting near infrared spectrum data, image data and operation and environment data of a straw decomposition process; the layered identification and modeling unit is used for identifying initial mass proportions and decomposition progress of soluble components, cellulose components, hemicellulose components and lignin components of the straws, and establishing a layered progress bar; the fusion progress calculation unit is used for weighting each layered progress bar based on the initial mass ratio to generate an overall decomposition progress bar; the progress output unit is used for simultaneously outputting a layered progress bar and an overall decomposition progress bar; and the mode mining unit is used for clustering the historical layered progress bars, forming a progress category prototype library and outputting potential blocking reasons. The problems that the field straw decomposition process is difficult to monitor in real time and the blocking reason is difficult to identify are solved.

Methods and systems for preparing agricultural residue or other agricultural feedstock for use as a pulp. The method includes providing non-wood agricultural residue (e.g., corn stover) or other agricultural feedstock that includes agricultural fibers, chemically pulping the agricultural fibers in a preliminary alkaline chemical pulping process at a low consistency and at a low temperature to produce partially pulped agricultural fibers, such step including separating lignin and hemicellulose from the partially pulped agricultural fibers, introducing the partially pulped agricultural fibers into a first reactor, wherein the first reactor operates at a low temperature of less than 100° C. (e.g., 65° C.), introducing the agricultural fibers from the first reactor into a second reactor, where the second reactor operates at a low temperature, of less than 100° C. (e.g., 94-96° C.), the second reactor operating at a higher temperature than the first reactor, to produce pulped agricultural fibers.

The invention provides an irpex lacteus GJ243 strain and application thereof, the preservation number of the strain is CGMCC (China General Microbiological Culture Collection Center) NO: 41281, and the preservation date is April 7, 2024. The strain has a degradation effect on cellulose, lignin and hemicellulose. Compared with the prior art, the Irpex lacteus GJ243 disclosed by the invention has the advantages that ligninase and cellulase generated by the Irpex lacteus GJ243 are relatively high in activity, and the Irpex lacteus GJ243 is high in degradation capacity on lignin, cellulose and hemicellulose. Meanwhile, 15% of Irpex lacteus GJ243 is added, so that degradation of lignocellulose of the rape straw is facilitated, the content of humus in soil is increased, and the method has a wide application prospect.

The invention discloses a preparation method for treating bagasse to obtain hard carbon, application of the hard carbon and a sodium-ion battery negative electrode, and relates to the field of sodium-ion batteries. The preparation method of the bagasse-based hard carbon comprises the following steps: crosslinking lignin and cellulose in the bagasse-based hard carbon by using an acid solution, and partially stripping ash of biomass. And stripping hemicellulose of the bagasse by using a weak base solution to expose cellulose. By regulating and controlling the concentration, the treatment time and the treatment temperature of the alkali solution, reasonable lignin is reserved in the cellulose, so that regulation and control of a plain pore structure in the carbonization process are promoted. After the alkali solution treatment, a hydrochloric acid solution is used for cleaning the solid, and freeze drying is carried out, so that a proper pore structure is reserved. And then carrying out high-temperature heat treatment in a protective atmosphere, wherein the heat treatment is carried out in three stages. The reaction process is a cellulose deoxidation process, the treatment temperature is 300-400 DEG C, and primary carbonization of cellulose is realized; secondly, carbonizing, namely further deoxidizing after primary carbonization, wherein a large number of C = C / C-C bonds are formed at the treatment temperature of 800-1000 DEG C; and finally, forming a hard carbon graphite layer, wherein the treatment temperature is 1300-1500 DEG C. The bagasse-based hard carbon prepared by the preparation method can be efficiently and stably circulated in a sodium ion battery, and shows excellent rate capability.

The invention relates to bacillus amyloliquefaciens which is classified and named as bacillus amyloliquefaciens LDB1, the preservation number of the bacillus amyloliquefaciens is CCTCC No: M 20231897, and the preservation date is October 16, 2023. The invention relates to application of bacillus amyloliquefaciens in citrus waste compost. The invention relates to a microbial agent, which comprises bacillus amyloliquefaciens LDB1, bacillus amyloliquefaciens, bacillus subtilis and bacillus velezensis. The invention relates to application of a microbial agent in citrus waste compost. The method has the beneficial effects that lignin peroxidase, laccase and manganese peroxidase can be produced, good lignin degradation capability is achieved, degradation of lignocellulose in citrus waste compost can be effectively promoted by matching with other strains, the degradation rates of hemicellulose, cellulose and lignin are 33.8%, 36.5% and 38.5% respectively, and the method is suitable for industrial production. The strain and the microbial inoculum thereof have important application value in the aspect of recycling of high-lignin fiber organic wastes.

The invention discloses hard carbon with a molecular sieve type closed-pore structure and a preparation method thereof.The preparation method comprises the steps that a biomass mixture such as cotton and crop waste serves as a raw material, or a mixture containing 70-90% of cellulose, 9-20% of hemicellulose, 1-10% of lignin and the like serves as a raw material, calcination is conducted at the temperature of 300-600 DEG C, and a pre-carbonized precursor is obtained; and then cleaning the precursor with an alkali solution, and finally carrying out secondary calcination at 900-1400 DEG C to obtain a hard carbon product with a molecular sieve type closed pore structure.

The invention relates to the field of microorganisms, and discloses a microbial composite inoculant and a method for degrading lignocellulose. The compound microbial agent comprises phanerochaete chrysosporium, aspergillus niger, trichoderma reesei, neurospora crassa and gloeophyllum trabeum. The phanerochaete chrysosporium is a white-rot fungus with strong performance, and can secrete a plurality of lignocelluloses at the same time. Aspergillus niger, trichoderma reesei, neurospora crassa and gloeophyllum trabeum are mainly used for secreting high-activity cellulase and hemicellulase. Destroying the lignocellulose structure needs the combined action of various lignocellulose enzyme systems, and after the five strains are mixed, the synergistic effect among the enzyme systems in the system can be remarkably enhanced, the lignocellulose structure is efficiently destroyed, and the degradation rate of the wood fiber raw material is increased.

The invention discloses a method for preparing fermentable sugar from recyclable low-concentration p-toluenesulfonic acid pretreated lignocellulose, which comprises the following steps: firstly, pretreating lignocellulose by using a low-concentration p-toluenesulfonic acid aqueous solution, and carrying out solid-liquid separation to obtain hemicellulose hydrolysate and a pretreated solid component; then saccharifying and pretreating the solid component by using cellulase to obtain hydrolysate rich in glucose, adsorbing the hemicellulose hydrolysate by using hypercrosslinked adsorption resin, carrying out solid-liquid separation to obtain hydrolysate rich in xylose, and carrying out desorption treatment on the resin by using industrial ethanol to obtain xylose; and performing rotary evaporation on the desorbed liquid to remove the industrial ethanol to obtain p-toluenesulfonic acid. According to the method, hemicellulose is efficiently degraded to obtain derived sugar of hemicellulose, meanwhile, the saccharification efficiency of cellulase is improved, p-toluenesulfonic acid is recycled through the hypercrosslinked adsorption resin, and the method has the advantages of being high in fermentable sugar yield, recyclable in acid catalyst, low in cost, environmentally friendly and the like.

The invention discloses a biomass-based hard carbon negative electrode material with high specific capacity and high magnification as well as a preparation method and application of the biomass-based hard carbon negative electrode material. The method comprises the following steps: pretreating lignocellulose biomass by a hot pressing method, and carbonizing in a protective gas atmosphere to obtain the hard carbon material. A hot-pressing pretreatment process adopted by the invention can decompose part of hemicellulose to obtain a precursor rich in lignin and cellulose, so that the thermal stability of the material is improved. In the process, the lignin can effectively inhibit the rapid centralized pyrolysis of the cellulose and weaken the rearrangement of the pyrolysis product of the cellulose. The method not only helps to prevent overgrowth of hard carbon graphite microcrystals during high-temperature carbonization, but also promotes generation of a small-size closed-pore structure, so that the microstructure of the hard carbon material is optimized. The hard carbon material shows high specific capacity and excellent rate capability when being applied to a sodium-ion battery negative electrode. The method has the advantages of simplicity in operation, low requirements on equipment, no need of adding chemical reagents, greenness, environmental protection and the like.

The invention discloses a method for preparing high-quality dissolving pulp from low-grade plant fiber raw materials, and belongs to the technical field of biomass pulping. The preparation method comprises the following steps: screening a low-grade plant fiber raw material to obtain a fiber raw material of which the length is 20-30 mm, the width is 10-15 mm and the thickness is 3-5 mm; carrying out deep prehydrolysis-sulfate cooking treatment on the screened fiber raw materials to obtain unbleached sulfate pulp fibers; performing deep eutectic solvent and elemental chlorine-free bleaching treatment on the unbleached sulfate pulp fiber to obtain paper pulp fiber with low kappa number; and carrying out biological enzyme treatment on the paper pulp fibers with low kappa number to obtain the high-quality dissolving pulp. According to the method, the morphology and the structure of chemical pulp fibers are effectively regulated and controlled by designing deep eutectic solvent treatment, and deep dissolution of residual hemicelluloses and lignin is achieved; through biological enzyme treatment, the alpha-cellulose content and the Fock reaction performance are further improved, and finally the high-quality dissolving pulp is prepared.

The invention belongs to the technical field of biology, and particularly relates to a method for producing xylitol through two-step enzyme catalysis of hemicellulose hydrolysate, and the method comprises the following steps: taking hemicellulose hydrolysate as a raw material, adding arabinose dehydrogenase, NADH oxidase and coenzyme NADH, and carrying out first-step fermentation until no L-arabinose residue exists in fermentation liquor to obtain fermentation reaction liquor I; and adding xylose reductase and glucose dehydrogenase into the fermentation reaction liquid I, and carrying out second-step fermentation to obtain a fermentation product containing xylitol. According to the two-step enzyme catalysis method provided by the invention, xylitol is prepared, and high-purity xylose does not need to be used as a raw material; according to the present invention, the cheap hemicellulose hydrolysate can be directly adopted as the raw material, the xylose conversion rate and the xylitol yield can exceed 99%, the impurity arabitol content in the product is low, the other impurity saccharic acid is easy to separate, and the problems of complex process, large separation difficulty and high cost in the xylitol refining process are successfully solved.

The invention discloses bacillus subtilis WJL-2 and application thereof, and relates to the technical field of microorganisms. The bacillus subtilis WJL-2 disclosed by the invention is preserved in Guangdong Province Microbial Culture Collection Center, the preservation number is GDMCC No: 65111, the preservation date is September 9, 2024, and the preservation address is the 5th floor, No. 59 building, No. 100 Courtyard, Xianlie Middle Road, Guangzhou. Results of the embodiment of the invention show that the strain WJL-2 has the capability of degrading cellulose, and when the strain WJL-2 is used for a liquid fermentation test, the degradation rate of the strain WJL-2 on sugarcane straws on the 12th day is 26.45%, and the degradation rate of the strain WJL-2 on straws on the 3rd day of culture reaches 26.37%. The highest hemicellulose degradation rate of the strain WJL-2 is 58.72%, and the highest cellulose degradation rate of the strain WJL-2 is 39.88%.

The invention belongs to the technical field of microbial protein preparation, and particularly relates to a method for preparing microbial protein from crop straw and application of the microbial protein. According to the method, the crop straw is subjected to biomass conversion pretreatment, so that the accessibility and hydrolysis efficiency of cellulose are improved; on the basis, the pretreated biomass is subjected to enzymolysis through cellulase, cellulose and hemicellulose components in the biomass are converted into glucose and xylose, and the glucose and the xylose are utilized by saccharomycetes in the subsequent saccharomycetes fermentation process to synthesize the microbial protein. The microbial protein obtained through the method has the advantages of being rich in nutrition and high in essential amino acid content, and has wide application prospects in the fields of food and feed. Therefore, after the crop straw is subjected to chemical or physical-biological treatment, a new way is provided for high-value utilization of the crop straw on the basis of obtaining the nutrient-rich microbial protein.

The invention discloses a method for value-added utilization of straw biomass and extraction and purification of fulvic acid and fulvic acid derivatives of the straw biomass, and belongs to the field of resource utilization of agricultural and forestry wastes. Through regulation and control of raw materials in feed liquid, fulvic acid, vegetable protein and other organic matters can be efficiently separated from three elements in straw, cellulose and hemicelluloses are further efficiently separated from lignin, and then fulvic acid and derivatives thereof are efficiently separated from other organic matters and purified through an extraction separation method. The functionalization degree and the functional group type of the fulvic acid or the fulvic acid derivative thereof are regulated and controlled according to different components of the added cooking liquor, the high-purity fulvic acid or the new derivative thereof is obtained, and other organic matters containing protein and the like can be used as natural organic fertilizers; meanwhile, the obtained three elements are subjected to secondary cooking treatment, and lignin can be effectively separated and purified from cellulose and hemicellulose by regulating and controlling components of cooking liquor. And finally, the straw proliferation waste-free efficient utilization is realized.

The invention discloses an element liquid fertilizer for promoting nutrient absorption and a preparation method thereof, and belongs to the technical field of fertilizers. Comprising monoammonium phosphate; urea; potassium nitrate; cake fertilizer leach liquor; trace elements; a wetting agent; a stabilizer; a biological agent; an adsorbent; deionized water; the preparation method of the adsorbent comprises the following steps: A1, taking loofah sponge powder, and removing lignin and hemicellulose to obtain loofah sponge cellulose powder; a2, mixing the loofah sponge cellulose powder, deionized water, a chitosan solution and plant ash, mechanically pulping uniformly, performing vacuum freeze-drying treatment to form holes, crushing and grinding to obtain the adsorbent, root development can be promoted, elongation and thickening of stems are promoted, the photosynthetic rate of plants is increased, and the crop yield is increased.

A polymer-nanocellulose-lignin composite as disclosed comprises a polymer, nanocellulose, and lignin, wherein lignin forms a hydrophobic interface between the polymer and the nanocellulose. In some variations, a process is disclosed for producing a polymer-nanocellulose-lignin composite material, comprising: fractionating lignocellulosic biomass in the presence of an acid, a solvent for lignin, and water, to generate cellulose-rich solids and a liquid containing hemicellulose and lignin, wherein lignin deposits onto fiber surfaces or into fiber pores; mechanically treating the cellulose-rich solids to form a hydrophobic nanocellulose material comprising cellulose fibrils and / or cellulose crystals; hydrolyzing the hemicellulose to generate fermentable hemicellulosic sugars; fermenting the fermentable hemicellulosic sugars to generate a monomer or monomer precursor; polymerizing the monomer to produce a polymer; and combining the polymer with the lignin-coated nanocellulose to generate a polymer-nanocellulose-lignin composite material for use in a wide variety of products.

The invention discloses bacillus subtilis capable of producing cellulase at high yield and application of the bacillus subtilis, and belongs to the technical field of biology, the bacillus subtilis is classified and named as bacillus subtilis KC7-2, the bacillus subtilis KC7-2 is preserved in China Center for Type Culture Collection on July 15, 2024, and the preservation number is CCTCC NO: M20241570. The bacillus subtilis provided by the invention shows excellent performance in the aspect of secretion of cellulase and hemicellulase, especially reaches an enzymatic activity peak in the early growth stage (24h) of a strain, and can maintain a certain level of enzymatic activity for a long time later. Due to the characteristics, the strain has important application value in the fields of forage feed improvement, biomass degradation, environmental protection and the like.

The invention discloses a preparation method and application of high-purity natural cellulose. According to the method, a pre-cooled phosphoric acid / hydrogen peroxide mixed aqueous solution system is adopted, phosphoric acid is a cellulose intercrystalline swelling reagent, and hydrogen peroxide is an oxidation reagent precursor. The invention provides a cellulose intercrystalline swelling strategy to promote full exposure of hemicellulose embedded in a cellulose crystalline region and further realize deep removal of hemicellulose through acidic hydrolysis dissolution; meanwhile, peroxyphosphoric acid is used for promoting oxidative degradation and dissolution of residual lignin under mild conditions, and the purity of natural cellulose is further improved. The natural cellulose prepared by the method has high purity, and can be applied to the field of manufacturing of high-end cellulose of lyocell grade, acetification grade, nitration grade and the like. The method is mild in condition, simple in process and controllable in process, the cellulose industry is promoted to extend to the high end of a value chain, and the method has a wide application prospect.

The present invention relates to a prebiotic feed additive for promoting intestinal health of pigs, belonging to the technical field of feed, the prebiotic feed additive of the present invention comprises prebiotic components and biological adjuvants, the prebiotic components comprise oligofructose, oligoisomaltose, inulin and resistant dextrin, the biological adjuvant is a product obtained by co-enzymatic hydrolysis of dandelion and houttuynia cordata by hemicellulase and pectinase, then fermented by Lactobacillus acidophilus and Propionibacterium freudenreichii in sequence, and finally enzymatic hydrolyzed by bromelain and trypsin step by step. The components in the additive are used in combination to have a good effect of promoting intestinal health of pigs, can balance and improve the intestinal microenvironment, improve feed nutrient utilization, enhance immunity, reduce diarrheal diseases, and promote growth and weight gain.

The invention discloses a preparation method of a lignin-coated cellulose nanofiber sodium-ion battery diaphragm, and relates to the technical field of electrochemistry and battery diaphragms.The preparation method comprises the steps that bamboo particles are pretreated through a hydrothermal method; then carrying out bamboo particle nanocrystallization by adopting a mechanical dissociation method to obtain a lignin-coated cellulose nanofiber suspension, and preparing the lignin-coated cellulose nanofiber into a thin film by adopting a vacuum filtration method. The preparation process of the cellulose coated with the lignin nanoparticles is direct, simple, efficient and environment-friendly, chemical reagents such as acid and alkali do not need to be adopted for removing hemicellulose and lignin, meanwhile, the diffusion rate of sodium ions in the charging and discharging process is effectively increased due to coating of the lignin nanoparticles, and the sodium ion conductivity is improved. The specific discharge capacity and the cycling stability are realized.

The invention discloses a three-sludge treatment agent and a preparation method thereof, and belongs to the technical field of oily sludge treatment, the three-sludge treatment agent comprises a treatment agent A and a treatment agent B. The treatment agent B comprises the following raw materials by mass: 30-40 parts of polyacrylamide, 8-10 parts of modified attapulgite clay, 5-6 parts of a compound, and 40-55 parts of deionized water. The modified attapulgite clay is strongly combined with protective films at oil-water and oil-sludge interfaces in the oil sludge through electrostatic force, hydrogen bonds and hydrophobic interaction, the protective films at the oil-water and oil-sludge interfaces are destroyed, oil drops are released and coalesced to form an oil phase, and separation of oil, water and sludge is achieved; positive charges carried in the modified attapulgite clay can be adsorbed to the surfaces of sludge particles with negative charges to be settled and separated out; carboxyl groups contained in the modified hemicellulose can be combined with hydrophilic groups of sophorolipid to form stable mixed micelles, so that the situation that the sophorolipid is easily influenced by the environment to lose efficacy, and oil drops are regathered and precipitated is avoided.

The invention discloses a Coaerella coagulum-plant lactobacillus synergistic fermentation inoculant and a process for staged solid-state fermentation of American ginseng by using the same, and belongs to the technical field of biological fermentation. According to the invention, two strains, i.e., the plant lactobacillus and the hainerella coagulatum, are obtained by screening food-grade probiotic strains, and the ginsenoside conversion capability of the two strains is verified by utilizing culture. The invention also provides a probiotic fermentation process for improving the content of rare ginsenoside in American ginseng, namely, the staged synergistic fermentation of the Halidernia coagulum and the phytobacterium plantarum is utilized, so that the content of the rare ginsenoside in the American ginseng is improved; cellulase and hemicellulase secreted by the Haihdrikia coagulatum can decompose cellulose, lignin and the like in cell walls of the surface layer of the American ginseng raw material in the early stage of fermentation, so that ginsenoside in cells is fully released, and beta-glucosidase from different sources is utilized to synergistically convert prototype ginsenoside in the later stage of fermentation. The content of various rare ginsenosides in American ginseng can be remarkably increased through the solid-state fermentation process. Meanwhile, the solid-state fermentation process has the advantages of mild conditions, less wastewater treatment, environmental protection, low cost, process safety and the like, has important significance in improving the resource utilization of American ginseng and promoting the industrial development of American ginseng, and has relatively good practicability.

The invention relates to a method for extracting and purifying lycium barbarum polyphenol by combining bacteria and enzymes. The method comprises the following steps: pretreating lycium barbarum fruits to obtain lycium barbarum powder; extracting the wolfberry powder by using a first solvent to obtain a first crude extract; fermenting the first crude extract with lactobacillus plantarum to obtain a second crude extract; performing enzymolysis on the second crude extract by using pectinase, hemicellulase and beta-glucosidase in sequence to obtain an enzymolysis extracting solution; adsorbing and purifying the enzymolysis extracting solution by using first ion exchange resin, washing and eluting to obtain a first eluent; adsorbing and purifying the first eluent by using second ion exchange resin, washing and eluting to obtain a second eluent; and concentrating and drying the second eluent to obtain wolfberry polyphenol powder. According to the method disclosed by the invention, the fermentation of lactobacillus plantarum is combined with the synergistic effect of pectinase, hemicellulase and beta-glucosidase, polysaccharide in a crude extract is decomposed, polyphenol is released and combined, the extraction rate and the purity of the polyphenol are improved, and meanwhile, a continuous purification process of macroporous resins AB-8 and D-101 is combined, so that the product quality is further improved.

The present invention provides a deep eutectic solvent and its preparation and application. The deep eutectic solvent comprises choline chloride, p-toluenesulfonic acid, 1,4-butanediol, and water; wherein the molar ratio of choline chloride, p-toluenesulfonic acid, and 1,4-butanediol is 1-2:3-6:2-8, and the ratio of the total mass of choline chloride and p-toluenesulfonic acid to the mass of water is 20:9-11. When used for the pretreatment of Miscanthus sinensis, the deep eutectic solvent of the present invention can effectively remove hemicellulose and lignin from the cell walls of Miscanthus sinensis, thereby significantly improving the efficiency of its enzymatic hydrolysis of cellulose.

The invention belongs to the technical field of biological fermentation hydrogen production. The invention provides a method for producing hydrogen by dark fermentation of pericarp biomass, which comprises the following steps: drying pericarp, crushing, and sieving to obtain powdery pericarp particles; performing acid heat pretreatment on the powdery fruit peel particles to obtain fruit peel pretreatment liquid; and inoculating the clostridium butyricum solution into the pericarp pretreatment liquid, and carrying out dark fermentation under an anaerobic condition to obtain a fermentation gas containing hydrogen. According to the method, the pericarp byproducts are used for dark fermentation for hydrogen production, so that high-value recycling utilization of agricultural wastes is realized; lignin in the pericarp is effectively removed through acid heat pretreatment, the availability of cellulose and hemicellulose is remarkably improved, conditions such as acid concentration, temperature and time are optimized, the inhibition effect of by-products is avoided, and the hydrogen production efficiency is remarkably improved; moreover, the method has the advantages of good stability and high repeatability, and provides a new technical approach for efficient production of clean energy.

The invention discloses a method for preparing viscose fiber from alkali-soaked hemicellulose, and relates to the technical field of viscose fiber production and preparation, and the method comprises the following steps: sequentially carrying out multi-stage filtration and twice nanofiltration membrane filtration on alkali liquor squeezed from slurry porridge, and separating out high-concentration hemicellulose alkali liquor; after cellulose xanthate is generated through a xanthating machine reaction, high-concentration hemicellulose alkali liquor is added into the xanthating machine to be subjected to a xanthating reaction, and hemicellulose xanthate is generated; and adding dilute alkali liquor into the xanthating machine for dissolving, and sequentially filtering, defoaming and spinning to prepare the viscose fiber. After alkali cellulose and carbon disulfide are subjected to a yellowing reaction, high-concentration hemicellulose alkali liquor is added into a yellowing machine for secondary yellowing, then two xanthate esters are dissolved with dilute alkali liquor, and subsequent filtering, defoaming and spinning procedures are performed, so that full utilization of hemicellulose is realized, and the quality and spinnability of viscose fibers are guaranteed; meanwhile, pulp unit consumption and new alkali consumption are reduced, and the production cost is saved.

The invention discloses a method for cyclically preparing high-activity xylooligosaccharide from recoverable acid, and belongs to the technical field of xylooligosaccharide preparation. The method comprises the following steps: carrying out hydrolysis reaction on moso bamboo processing residues and a gallic acid solution, and carrying out solid-liquid separation to obtain a high-polymerization-degree xylooligosaccharide solution; then carrying out enzymolysis reaction on the xylooligosaccharide solution with high polymerization degree and xylanase to obtain a high-activity xylooligosaccharide solution, and carrying out concentration, refrigeration treatment and recrystallization on the obtained high-activity xylooligosaccharide solution to recover residual acid so as to obtain the high-concentration high-activity xylooligosaccharide solution. According to the method, the high-activity xylooligosaccharide is prepared through hydrolysis of the easily-recycled organic acid, and the method has the advantages of being high in xylooligosaccharide concentration, high in high-activity component content, simple in reagent recycling, easy to operate and the like and is suitable for preparing xylooligosaccharide through high-selectivity conversion of hemicellulose in bamboo processing residues.

The invention discloses a method for preparing phenol by utilizing a biomass raw material, which comprises the following steps: 1) crushing biomass, adding the crushed biomass into a caustic alkali solution to carry out hemicellulose removal treatment, and carrying out solid-liquid separation to take a solid substance, so as to obtain hemicellulose-removed biomass; 2) adding the hemicellulose-removed biomass into an ethylene glycol-ferric chloride eutectic solvent for lignin extraction, then adding an acetone-water mixed solution, then carrying out solid-liquid separation, taking a liquid substance, adding water to precipitate the lignin, then carrying out solid-liquid separation, and taking a solid substance to obtain the lignin; and 3) pyrolyzing the lignin in a protective atmosphere to obtain lignin oil containing phenol. The method for preparing phenol from biomass raw materials has the advantages of simple operation, high phenol yield, high product purity, low energy consumption, safety, environmental protection and the like, and is suitable for large-scale industrial application.