4404 results about "Pyrolysis" patented technology

An integrated carbon honeycomb structure material and its preparation method are disclosed, belonging to the field of carbon materials technology. Based on a co-sacrificial template low-temperature pyrolysis strategy, the target material can be obtained through three main steps: preparation of a metal salt-colloidal microsphere template precursor, precursor pressing and molding, and subsequent calcination and carbonization. This technology has the characteristics and advantages of simple preparation process, regular and controllable macroscopic structure of the sample (such as shape, area, and thickness), rich and tunable chemical composition, and three-dimensional interconnection of graphene carbon matrix. It has great application potential in many fields such as electrochemical energy storage, catalysis, gas separation, adsorption, and electromagnetic shielding.

The invention provides a method for selecting a high-concentration VOCs adsorbent at different temperatures and application, and belongs to the technical field of waste gas governing. According to the method, through testing pore structure parameters of a model adsorption material with concentrated pore size distribution, a static adsorption isotherm and a dynamic penetration curve for VOCs at different temperatures, a high-concentration VOCs adsorbent is obtained; a linear relation equation of the critical aperture and the critical pressure is established through linear fitting, then a correlation equation of the critical aperture, the temperature and the partial pressure is established, and the appropriate aperture distribution range and the model selection standard of the high-concentration VOCs adsorbent at different temperatures are determined by combining dynamic adsorption results. According to the method, the ternary matching relation equation of the VOCs partial pressure, the temperature and the critical aperture is constructed, accurate type selection of the high-concentration VOCs adsorbent at different temperatures is achieved, the pore volume utilization rate and the adsorption capacity can be improved, meanwhile, desorption energy consumption and the VOCs pyrolysis risk are reduced, and a theoretical basis is provided for adsorbent type selection and technical optimization.

The invention discloses a geothermal development oil shale and CO2 geological storage integrated method, which relates to the field of complex oil and gas reservoir development, and comprises the following steps: designing U-shaped well process parameters, enabling CO2 fluid to flow to a high-temperature geothermal reservoir through a descending section of a U-shaped well, injecting the CO2 fluid into the oil shale reservoir along an ascending section of a shaft after sufficient heat exchange, preheating the oil shale, and storing the CO2 fluid into a high-temperature geothermal reservoir through the descending section of the U-shaped well. Terrestrial heat extraction and utilization are realized; after the temperature of the oil shale layer rises to the target temperature, the oil shale layer is further heated through manual heating, and in-situ conversion development of the oil shale is achieved; after completion, produced CO2 is injected into the oil shale layer again through the U-shaped well, and collaborative development of CO2 geological storage, geothermal extraction and oil shale in-situ conversion is achieved. Geothermal energy is efficiently extracted through CO2 and used for oil shale in-situ pyrolysis, the extra manual heating cost needed by oil shale in-situ conversion is remarkably reduced, and the economic feasibility of a pure storage project and oil shale in-situ conversion development is improved.

The invention discloses a method for preparing a carbon monoxide oxidation catalyst by using red mud and tungsten-molybdenum smelting slag, which comprises the following steps of: uniformly stirring and mixing the red mud and the tungsten-molybdenum smelting slag at a high speed, mixing with inorganic strong acid, and performing ultrasonic-assisted stirring to obtain acid leaching slag; the acid leaching residues are subjected to low-temperature plasma activating treatment and then microwave activating treatment, and microwave activated plasma residues are obtained; weighing tricalcium phosphate and microwave activated plasma slag, and uniformly stirring to obtain phosphorus-calcium doped activated slag; weighing an ammonium sulfide solution and the phosphorus-calcium doped activated slag, uniformly stirring, transferring the obtained sulfur-phosphorus-calcium doped activated slag into a hydrothermal reaction kettle, carrying out hydrothermal reaction, carrying out compression molding on the obtained hydrothermal composite material, and carrying out pyrolysis carbonization treatment in an inert gas atmosphere to obtain the phosphorus-calcium doped activated slag. The obtained pyrolysis composite material is soaked with a silane coupling agent solution and then roasted again, and the carbon monoxide oxidation catalyst is obtained. The catalyst prepared by the invention can realize efficient oxidation photocatalysis of carbon monoxide under the conditions of normal temperature and normal pressure.

Provided are equipment and methods for intelligent mobile medical waste disposal and flue gas purification, and the equipment includes a vehicle-mounted mobile platform and a skid-mounted standard container; where, the vehicle-mounted mobile platform is composed of a standard semi-trailer truck and a truck carriage base; the vehicle-mounted mobile platform is used for realizing functions of mobile transportation, cargo loading, fuel loading and unloading, power charging and discharging and network information transmission; the skid-mounted standard container is loaded above the truck carriage base of the vehicle-mounted mobile platform; and the skid-mounted standard container consists of a standard container and contents in the standard container; and the contents include: an intelligent collection and transportation feeding system, a medical waste pyrolysis incineration system, an incineration flue gas purification system, and an intelligent management and control system for medical waste disposal.

The invention belongs to the technical field of chemical catalysis, and particularly relates to a preparation method of an alkali metal cation modified cobalt-nitrogen-carbon monatomic catalyst and application of the catalyst in electrosynthesis of hydrogen peroxide. The Co-N-C / X catalyst is obtained by taking a cobalt-containing compound as a metal source, mixing the metal source with a nitrogen-containing organic matter and a carbon material, performing rotary evaporation, grinding and high-temperature pyrolysis in an inert atmosphere, performing acid washing with strong acid to construct surface defects, and finally performing stirring adsorption with an alkali metal salt solution, suction filtration and drying. Alkali metal cations are physically adsorbed and anchored on the surface and interface of the Co-N-C catalyst instead of being dissolved in a solution, so that the electronic structure of Co active sites and the adsorption energy of the * OOH intermediate are optimized, and the problem of separation of alkali metal and a product is solved. When the catalyst is used for electro-catalytic oxygen reduction reaction, the H2O2 selectivity reaches up to 98%, the preparation process is simple, the cost is low, large-scale production can be realized, and the problems that the traditional method is high in energy consumption and large in pollution and the existing catalyst is insufficient in selectivity are solved.

The invention discloses a recovery device and a recovery method for a photovoltaic multi-layer stacked assembly. The recovery device comprises a dismounting unit, a pyrolysis unit and a waste gas treatment unit which are arranged in sequence, the pyrolysis unit comprises a tunnel kiln, a bearing assembly and a conveying assembly. The recycling method comprises the steps that S1, the disassembling unit is used for disassembling, and the frame is stripped; s2, the photovoltaic multi-layer laminated assembly is sent to a pyrolysis unit for pyrolysis, and a glue film layer in the photovoltaic multi-layer laminated assembly is removed; and S3, the waste gas is discharged after being treated. By means of the innovative disassembling system, the multi-plate stacking tunnel kiln pyrolysis scheme and the multi-stage waste gas treatment system, the industrial production capacity of treating 1-3 tons of photovoltaic panels per hour can be achieved, the pyrolysis effect is good, the silicon material recovery rate can reach 98.5% or above, energy consumption is low, and the tail gas emission index is superior to the national standard by 50% or above.

The invention discloses preparation of a high-performance carbon matrix embedded iron-based catalyst based on a metal organic framework precursor and application of the high-performance carbon matrix embedded iron-based catalyst in reverse water-gas shift reaction. In the preparation process, commercially available 1, 3, 5-trimesic acid iron (the chemical formula is C9H3FeO6, abbreviated as Fe-BTC) is selected as a raw material, pyrolysis treatment is carried out in an argon atmosphere, then air passivation is carried out, and finally the high-performance carbon matrix embedded iron-based catalyst based on the metal organic framework precursor is successfully prepared. The MOF-600 has excellent performance in many catalysts, the carbon dioxide production rate reaches 24.0 mmol CO.gcat <-1 >. S <-1 > at the temperature of 400 DEG C in a reverse water gas shift reaction, the performance is remarkably superior to that of an existing non-noble metal catalyst, and extremely high catalytic efficiency and application potential are shown.

The invention discloses a catalyst for hydrogen production through tar steam reforming and a preparation method and application thereof. The catalyst comprises a cobalt-magnesium-aluminum composite spinel carrier and an active component loaded on the cobalt-magnesium-aluminum composite spinel carrier, the active component comprises nickel and at least one metal additive selected from iron, zirconium and ruthenium. The preparation method mainly comprises the following steps: preparing the carrier by adopting a coprecipitation method, loading the active component by adopting an impregnation method, and drying and reducing to obtain the final catalyst. The catalyst is used for tar component steam reforming hydrogen production reaction, especially for treating raw materials containing phenol and water vapor at 600-700 DEG C, tar conversion can be efficiently catalyzed, product gas rich in hydrogen can be generated, hydrogen selectivity is high, and almost no methane is generated. The catalyst has the advantages of high activity, good stability, strong carbon deposition resistance and the like, and is suitable for purification and high-value utilization of biomass pyrolysis tar.

The invention discloses preparation and application of an environment-friendly P, N and Si synergistic flame retardant. According to the flame retardant (KDOPO-LDH (at) GO), a plurality of flame-retardant elements such as P, N and Si are integrated, so that an efficient synergistic flame-retardant system is constructed. Wherein the existence of the N element and the Si element effectively promotes the uniform dispersion of the flame retardant in an epoxy resin matrix; meanwhile, the unique molecular structure of the P-containing component endows the carbon-forming agent with excellent carbon-forming performance under a high-temperature condition. Through the synergistic effect of multiple elements, the flame retardant property of the epoxy resin is remarkably improved, and meanwhile, the good mechanical property of the material is effectively maintained. In addition, halogen-free and low-toxicity substances are mainly generated in the pyrolysis process of the flame retardant, and the green chemical concept is met.

The invention discloses a cobalt-copper bimetallic nitrogen-doped carbon catalyst, which is characterized in that CoCu-coated LNC, Co and Cu nanoparticles are anchored on a nitrogen-doped carbon carrier derived from lignin. Accordingly, the inventor also establishes a corresponding preparation method, and the catalyst is prepared by taking lignin as a carrier, cobalt-copper bimetal as an active component and dicyandiamide as a nitrogen source through one-pot pyrolysis. The method has the characteristics of simple and efficient process, high catalyst stability and activity, economy, high efficiency, environmental friendliness and the like. The method is used for preparing 2, 5-furandicarboxylic acid through thermal catalytic oxidation of 5-hydroxymethylfurfural, the yield of the target product FDCA almost reaches 100%, and the application prospect is wide.

The invention discloses a mucosal epithelial cell targeted oral ROS response type nano-enzyme as well as a preparation method and application thereof, and relates to the technical field of biological medicines. The oral ROS response type nano-enzyme comprises Ce-CDs carbon dots and a betaine polymer, and the betaine polymer is coated on the surfaces of the Ce-CDs carbon dots to form nano-particles; the Ce-CCDs carbon dots are prepared by taking a metal cerium source and chlorogenic acid as raw materials through a pyrolysis method. Through structural innovation and function integration, the prepared nano-enzyme shows outstanding advantages in the aspects of catalytic activity, targeted delivery, collaborative treatment, industrial application and the like, a new technical scheme is provided for efficient and safe treatment of inflammatory bowel diseases, and the nano-enzyme has remarkable technical innovation and clinical application value.

The invention belongs to the technical field of membrane separation, and particularly relates to a recrystallized silicon carbide ceramic nanofiltration membrane as well as a preparation method and application thereof. The preparation method comprises the following steps: applying a polycarbosilane solution to a silicon carbide ceramic ultrafiltration body, and carrying out first pyrolysis to obtain a pyrolysis material; a polycarbosilane solution is applied to the pyrolysis material, and then second pyrolysis is carried out; the first pyrolysis process comprises the following steps: heating to 290-310 DEG C from room temperature, and preserving heat; raising the temperature from 290-310 DEG C to 790-810 DEG C, and keeping the temperature; raising the temperature from 790 to 810 DEG C to 1190 to 1210 DEG C, and keeping the temperature; the second pyrolysis comprises first pyrolysis and recrystallization which are carried out in sequence; the recrystallization process comprises the following steps: heating from 1190-1210 DEG C to 1590-1610 DEG C, and preserving heat; the temperature is increased to 2190-2210 DEG C from 1590-1610 DEG C, and heat preservation is conducted. The aperture of the recrystallized silicon carbide ceramic nanofiltration membrane is smaller than 10 nm, and nanofiltration can be achieved.

The invention provides a method for detecting micron and nano plastics in soil or sediments and related application. The detection method comprises the following steps: providing a soil or sediment sample to be detected; the method comprises the following steps: pretreating a to-be-detected soil or sediment sample to obtain a to-be-detected solution; performing multi-stage filtration treatment on the solution to be detected to obtain micro-plastic particles in a plurality of particle size intervals; wherein the plurality of particle size intervals comprise a first particle size interval, a second particle size interval and a third particle size interval; the particle size of the first particle size interval is 1-5000 [mu] m; the particle size of the second particle size interval is 220-1000 nm; the particle size of the third particle size interval is 10-220nm; and performing quantitative analysis on the micro-plastic particles in the plurality of particle size intervals through pyrolysis-gas chromatography / mass spectrometry to obtain the mass concentration of the micro-plastic particles in the plurality of particle size intervals. The problem that the risk assessment of micron and nano plastics is not accurate enough at present can be solved to a certain extent.

The invention provides a CoCe-SNC catalyst and a preparation method and application thereof, and belongs to the technical field of hydrogen fuel cell / metal air cell cathode catalysts. The preparation method comprises the following steps: mixing and grinding a metal organic framework ZIF-8 and KSCN, carrying out first pyrolysis, compounding the obtained nitrogen and sulfur-containing co-doped carbon with two metal complexes Co-PM and Ce-PM, and carrying out second pyrolysis to obtain the CoCe-SNC diatomic catalyst. According to the invention, the two-dimensional lamellar structure carbon material and the asymmetric coordination diatomic metal are compounded, so that the catalytic performance of the whole catalyst is improved, and meanwhile, the yield of hydrogen peroxide generated by side reaction is reduced. The catalyst is applied to a hydrogen fuel cell / metal air cell, and the defects that in the prior art, a noble metal catalyst is high in cost, and a non-noble metal catalyst is low in catalytic activity, high in hydrogen peroxide yield, poor in catalyst stability and the like are overcome.

The invention provides an efficient chloramphenicol degradation method based on Co-Cu-carbon composite nano-catalyst activated peroxymonosulfate, which comprises the following steps: regulating the Co / Cu molar ratio in a bimetal organic framework precursor, and performing pyrolysis to prepare the Co-Cu-carbon composite catalyst with an optimized pore structure, graphitization degree and metal dispersity; peroxymonosulfate is activated by utilizing the synergistic effect of Co / Co and Cu / Cu redox pairs to generate sulfate free radicals, hydroxyl free radicals, singlet oxygen and superoxide free radicals, and direct oxidative degradation of chloramphenicol is promoted by taking a catalyst as an electron transfer bridge; the method realizes rapid and efficient removal of chloramphenicol, high mineralization rate, excellent cycle stability and strong anti-interference capability, and solves the technical problems of low removal efficiency, high cost and easy secondary pollution in the prior art.

The invention belongs to the technical field of nanofiltration, and provides a preparation method of a recrystallized silicon carbide-silicon carbonitride ceramic membrane. The preparation method comprises the following steps: applying a polysilazane solution to a porous substrate for the first time, and then performing first pyrolysis to obtain a pyrolysis material; and applying a polysilazane solution on the pyrolysis material for the second time, and then carrying out second pyrolysis to obtain the recrystallized silicon carbide-silicon carbonitride ceramic membrane. According to the invention, a solution containing propargyl polysilazane or organic polysilazane Durazane 1500 quick-drying resin is used as a precursor to prepare the ceramic membrane, and the ceramic membrane has the advantages of high ceramic yield, excellent high-temperature stability, high retention rate and controllable microstructure, and is suitable for separation and protection application in extreme environments.

The invention belongs to the technical field of thermal protection materials, and provides a temperature sensing array based on fabric type flexibility, a preparation method and a spinning solvent. The preparation method comprises the following steps: S1, forming a polymer precursor through a spinning forming process to obtain an initial fiber; s2, performing twisting forming on the initial fibers to form twisted fibers; s3, the twisted fibers are subjected to curing treatment and pyrolysis treatment, and sensing yarn is obtained; s4, the sensing yarn is integrated on the flexible ceramic fiber cloth, and the flexible ceramic fiber cloth with the sensing array ceramic temperature-sensitive yarn is obtained; s5, performing laser local heating on the wire connection position of the sensing array to prepare a conductive electrode; and S6, selecting a wiring mode according to the conductivity and the target test temperature, and identifying a real-time temperature field according to the temperature resistance characteristic. Array integration of the woven thermal protection material can be realized through a weaving process.

The invention discloses a preparation method of a high-temperature-resistant wave-absorbing honeycomb sandwich structure in the technical field of wave-absorbing materials, which comprises the following steps: synthesizing a transition metal modified polycarbosilane precursor under the protection of inert gas, and performing high-temperature cracking to obtain a magnetic silicon carbide wave-absorbing agent; blending and grinding the wave-absorbing agent and high-temperature-resistant resin to prepare a wave-absorbing glue solution; after a honeycomb core material is formed by adopting inorganic fiber cloth, a wave-absorbing glue solution is loaded through a repeated dipping-drying process, and the high-temperature-resistant wave-absorbing honeycomb is obtained through gradient heat treatment. And finally, compounding and curing with the wave-transparent skin and the carbon fiber composite material through a high-temperature-resistant adhesive film. The sandwich structure is prepared on the basis of the composite material, and the magnetic silicon carbide wave-absorbing agent has the characteristics of high temperature resistance, low density, oxidation resistance and adjustable dielectric property; the phthalocyanine resin matrix is adopted, so that excellent formability and high-temperature stability are guaranteed; honeycomb nodes are sewn and reinforced by silicon carbide fibers, so that the problem of node cracking in a high-temperature environment is solved.

The invention discloses a preparation method and application of a high-valence nickel monatomic catalyst, through the synergistic effect of nickel-phenanthroline complexing and inert template anchoring, dense and stable anchoring sites are provided for nickel atoms, atom migration and agglomeration in the high-temperature pyrolysis process are effectively inhibited, and the high-valence nickel monatomic catalyst is prepared. Meanwhile, by combining with an air-inert atmosphere two-step calcination procedure, air pre-oxidation is carried out, and a nickel precursor is stabilized in a carrier framework to prevent the nickel precursor from being reduced into a metal state in subsequent high-temperature inert calcination, so that the nickel precursor is locked in an electron-deficient high valence state, and a nickel-loaded material with the nickel loading capacity of 2.9-9.2 wt% and the nickel loading capacity of 9.2-9.2 wt% is prepared. And the nickel element stably exists mainly in the form of Ni < 3 + > or a higher-valence monatomic form, so that the three-in-one breakthrough of high load, high valence and high stability is realized. When the obtained catalyst activates persulfate, high-valence metal oxygen species are preferentially generated, various new pollutants are degraded, and the catalyst has high activity, selectivity and high stability.

The invention discloses a method for preparing biomass-based hard carbon through in-situ continuous catalytic carbonization and application, and belongs to the technical field of biomass-based carbon material preparation and energy storage. The method comprises the following steps: mixing a biomass raw material with a zinc salt aqueous solution; performing low-temperature pyrolysis and carbonization on the mixed material in an inert atmosphere; performing high-temperature carbonization on the low-temperature pyrolysis carbonization intermediate in an inert atmosphere; and after high-temperature carbonization is finished, naturally cooling to room temperature, washing and drying to obtain the hard carbon material. By utilizing the differentiated existence forms of the zinc salt at different temperatures and the characteristics of in-situ continuous catalysis and high-temperature volatilization, special rapid heating equipment is not needed, and the catalyst does not need to be washed off after low-temperature pyrolysis carbonization, so that the cooperative regulation and control of the interlayer spacing and the closed-pore structure of the biomass-based hard carbon microcrystalline are realized; the biomass-based hard carbon with wide microcrystalline interlayer spacing and rich closed pore structures is obtained. The obtained hard carbon has large reversible specific capacitance, high platform capacity and high rate performance when being applied to a sodium / lithium ion battery negative electrode material.

The invention relates to the technical field of battery negative electrode materials, in particular to irregular spherical porous carbon and a preparation method and application thereof, and a silicon-carbon composite material and a preparation method and application thereof. The liquid phenolic resin is emulsified, compounded, cross-linked and cured under the condition of an oil-soluble and water-soluble compound emulsifier, meanwhile, the shape of the obtained resin is changed in an ultrasonic-assisted mode under the combined action of ultrasonic disturbance and different interfacial tensions, spherical resin is adjusted into irregular spherical resin, and the spherical resin is prepared into the irregular spherical resin. And performing pyrolysis and gas activation to obtain the irregular porous spherical carbon. Compared with spherical carbon, the irregular spherical carbon prepared by the invention has the advantages that on the premise of keeping the strength of the spherical carbon, the irregular spherical carbon can increase the contact area between carbon particles and a binder, and the carbon particles and the binder are not easy to separate, so that the cycling stability of a battery (especially a lithium ion battery) is improved.

The invention relates to a heavy metal stabilizer and a preparation method and application thereof, and relates to the technical field of heavy metal stabilizers. The preparation method comprises the following steps: weighing sepiolite, adding hydrochloric acid, carrying out constant-temperature water bath, carrying out centrifugal separation to obtain a precipitate, drying the precipitate, and grinding to obtain the heavy metal stabilizer for sludge pyrolysis. Natural sepiolite is used as a base material, acid activation treatment is carried out through hydrochloric acid to obtain the heavy metal stabilizer, the heavy metal stabilizer is used in sludge pyrolysis, in the pyrolysis process, the heavy metal stabilizer fixes heavy metal in a pyrolysis product carbon in a stable form through the effects of surface adsorption, ion complexation, high-temperature packaging and the like, and the heavy metal stabilizer is used for sludge pyrolysis. Therefore, the emission of heavy metals in the pyrolysis process is reduced, and the ecological risk and the use risk of the pyrolysis product carbon are reduced.

The invention relates to a method for decoupling organic matter primary-secondary cracking hydrocarbon generation conversion rate based on gold tube hydrocarbon generation thermal simulation-solid product pyrolysis experiment. The method comprises the following steps: step 1, kerogen gold tube hydrocarbon generation simulation and solid product rock pyrolysis experiment data acquisition; step 2, parametric modeling of the kerogen hydrocarbon generation process; step 3, constructing a least square model of multi-source experimental information collaborative constraint; 4, carrying out optimization solution under a multi-source experiment information collaborative constraint condition; and 5, calculating the hydrocarbon generation conversion rate. According to the method, conversion rate evolution characteristics of each hydrocarbon generation process are quantitatively represented, conversion rate calculation is performed on cumulant of each hydrocarbon generation process obtained through decoupling, and conversion rate evolution rules of kerogen oil generation, kerogen gas generation, crude oil cracking gas generation, non-reactive carbon formation and other processes along with maturity changes in the crude oil cracking process can be obtained; and a quantitative basis is provided for refined hydrocarbon generation evaluation.

The invention discloses a metal in-situ anchoring carbon nanocluster catalyst as well as a preparation method and application thereof, and belongs to the technical field of unconventional oil and gas resource development. The metal in-situ anchored carbon nano-cluster catalyst provided by the invention is amorphous nano-particles without pore channel confinement, all active sites are exposed on the surface, and macromolecular organic matters in an in-situ pyrolysis process can be directly adsorbed and activated; the metal center is anchored to a flexible carbon skeleton in an atomic scale through M-N-C and M-O-C coordination bonds, and high dispersity and structural stability are still kept at the formation temperature of 500 DEG C; meanwhile, the catalyst is easily and uniformly injected into an oil shale reservoir through fracturing fluid and is well dispersed in a complex pore network, and the solid-solid catalytic interface efficiency is remarkably improved; the catalyst does not have a strong acid center, promotes selective fracture of C-C / C-H bonds mainly through metal electron transfer, and reduces the risk of formation blockage; therefore, the method has a good application prospect in oil shale in-situ pyrolysis.

The invention provides a method for constructing an axial halogen coordination iron-based catalyst and application of the axial halogen coordination iron-based catalyst, and belongs to the technical field of catalytic materials and environmental pollution control. The preparation method comprises the following steps: introducing amino to the surface of a multi-walled carbon nanotube to obtain a modified multi-walled carbon nanotube; iron tetracarboxyl phthalocyanine and the modified multi-walled carbon nanotubes are subjected to covalent grafting through an amidation reaction, and a precursor is obtained; mixing the precursor with a halogen-containing solid source and a nitrogen source, and carrying out temperature programming and segmented pyrolysis in an inert gas atmosphere to obtain a pyrolysis product; and carrying out acid pickling on the pyrolysis product. The core of the preparation method disclosed by the invention lies in a multi-step collaborative strategy of molecular isolation, interface bridging, gas phase migration, fixed-point capture and coordination regulation, so that ultrahigh monatomic dispersity is realized, and unification of high density and high dispersity is ensured; meanwhile, the electronic structure of the iron center is effectively optimized, and excellent intrinsic activity is shown.

The present invention provides a biomass gasification control system and a biomass gasification control method, and belongs to the field of biosynthesis, the biomass gasification control system comprises: a first-stage fluidized bed pyrolysis reactor for performing a preliminary pyrolysis reaction on a biomass raw material to obtain a pyrolysis reactant; the second-stage fluidized bed gasification reactor is used for carrying out gasification reaction on the pyrolysis reactant by utilizing various gasification agents to obtain target synthesis gas, including H2 and CO; wherein the multiple gasifying agents comprise oxygen, water vapor and carbon dioxide; the sensor monitoring module is used for monitoring real-time state data in the first-stage fluidized bed pyrolysis reactor and the second-stage fluidized bed gasification reactor; the central control module is used for sending out an adjusting instruction according to the real-time state data, and the adjusting instruction is used for adjusting and controlling the flow of the multiple gasifying agents, the rotating speed of the fan and the reaction temperature, so that the molar ratio of H2 to CO in the generated target synthesis gas is within a first threshold value range.

The invention relates to the technical field of composite material performance prediction, and discloses a composite material flame retardant property and thermal stability prediction method based on thermogravimetric analysis and infrared spectrum data fusion. The invention aims to solve the problem that it is difficult to effectively fuse multi-modal data to realize quantitative prediction in the prior art. The method comprises the following steps: firstly, collecting thermogravimetric and infrared spectrum combined data, calculating gas transmission lag time, and carrying out forward correction on infrared spectrum data to realize time sequence alignment; then solid-phase thermogravimetric feature vectors and gas-phase infrared feature vectors are extracted, and a fusion feature matrix is generated; extracting solid-phase and gas-phase characteristics respectively by using a dual-channel LSTM network, and performing weighted fusion based on a self-attention mechanism; and finally, synchronously outputting a flame retardant index predicted value and a flame retardant grade classification result through numerical mapping and classification judgment. According to the method, multi-dimensional feature mining of the whole pyrolysis process of the material is realized, and a rapid and accurate digital evaluation means is provided for screening of the flame-retardant material.

The invention provides a garbage pyrolysis gasification multi-stage directional regulation-gas-solid phase reforming synergistic hydrogen production treatment process which comprises the following steps: first-stage regulation: pretreatment and graded feeding: crushing, sorting, drying and catalytic coating treatment are performed on garbage through a physical-chemical directional means; second-stage regulation and control: performing low-temperature pyrolysis directional dechlorination, and performing thermochemical directional conversion on plastic and biomass garbage at 350-450 DEG C; third-stage regulation and control: gasifying and melting are coordinated and oriented, and a gas-solid phase coupling reaction is realized in double fluidized beds at 800-900 DEG C; four-stage regulation and control: multi-stage gas-solid phase reforming is carried out, and the hydrogen yield is increased through catalysis-adsorption synergistic effect in a 700 DEG C moving bed; and five-stage regulation and control: deep purification and hydrogen purification, wherein the synthesis gas is selectively oxidized by utilizing chemical looping combustion to release hydrogen with the purity being greater than or equal to 99.99%. According to the invention, the molten ash is used as a catalytic carrier, and the Fe-Ce active sites of the molten ash are utilized to synchronously realize tar cracking and synthesis gas reforming, so that the conversion rate of tar is effectively improved.

Methods and systems are provided for the conversion of waste plastics into various useful downstream recycle-content products. More particularly, the present system and method involves pyrolyzing one or more waste plastics into various pyrolysis products, including a carbon solids-containing pyrolysis residue, and then subjecting the pyrolysis residue to partial oxidation gasification to thereby form a syngas composition.